RU2018120730A - Эмульсии типа масло в воде - Google Patents
Эмульсии типа масло в воде Download PDFInfo
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- 239000000839 emulsion Substances 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- 239000007764 o/w emulsion Substances 0.000 claims 15
- 239000003921 oil Substances 0.000 claims 15
- 239000012071 phase Substances 0.000 claims 6
- 239000004215 Carbon black (E152) Substances 0.000 claims 5
- 229930195733 hydrocarbon Natural products 0.000 claims 5
- 150000002430 hydrocarbons Chemical class 0.000 claims 5
- 239000004094 surface-active agent Substances 0.000 claims 5
- 150000003973 alkyl amines Chemical class 0.000 claims 4
- 239000008346 aqueous phase Substances 0.000 claims 4
- 238000000034 method Methods 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 3
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims 2
- 229920002472 Starch Polymers 0.000 claims 2
- 238000000149 argon plasma sintering Methods 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims 2
- 150000007524 organic acids Chemical class 0.000 claims 2
- 230000006641 stabilisation Effects 0.000 claims 2
- 238000011105 stabilization Methods 0.000 claims 2
- 239000008107 starch Substances 0.000 claims 2
- 235000019698 starch Nutrition 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims 1
- 229920000896 Ethulose Polymers 0.000 claims 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 claims 1
- 229920002907 Guar gum Polymers 0.000 claims 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 239000010426 asphalt Substances 0.000 claims 1
- 238000004523 catalytic cracking Methods 0.000 claims 1
- 238000004517 catalytic hydrocracking Methods 0.000 claims 1
- 239000010779 crude oil Substances 0.000 claims 1
- 238000004821 distillation Methods 0.000 claims 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 claims 1
- 235000019253 formic acid Nutrition 0.000 claims 1
- 239000000446 fuel Substances 0.000 claims 1
- 239000000295 fuel oil Substances 0.000 claims 1
- 239000000665 guar gum Substances 0.000 claims 1
- 235000010417 guar gum Nutrition 0.000 claims 1
- 229960002154 guar gum Drugs 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 claims 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims 1
- 229940098779 methanesulfonic acid Drugs 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 238000007670 refining Methods 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 238000004230 steam cracking Methods 0.000 claims 1
- 238000004227 thermal cracking Methods 0.000 claims 1
- 238000005292 vacuum distillation Methods 0.000 claims 1
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Claims (16)
1. Эмульсия типа масло в воде для применения в качестве топлива, содержащая масляную фазу и водную фазу, по меньшей мере одно первичное поверхностно-активное вещество, выбранное из одного или нескольких веществ группы, состоящей из жирных алкиламинов, этоксилированных жирных алкиламинов, этоксилированных жирных алкилмоноаминов, метилированных жирных алкилмоноаминов, метилированных жирных алкиламинов и четвертичных жирных алкиламинов; содержащая в пределах от больше 0,3 до 2,0% масс вторичного поверхностно-активного вещества, выбранного из одного или нескольких лигнинаминов; и кислоту; где масляная фаза диспергирована в водной фазе, и где эмульсия типа масло в воде имеет следующие характеристики:
средний размер капель (D[4,3]) в пределах от 3 до 15 мкм, где средний размер капель выражен в виде среднего значения с моментами по объему, определенного с использованием методик рассеяния света;
меньше 3% масс капель имеет размер частиц больше 125 мкм, где размер капель определен с использованием методик рассеяния света; и
вязкость больше 100 и до 700 мПа⋅сек при 50°C±10% и 20 сек-1±10%, где вязкость определена в соответствие с раскрытием в описании.
2. Эмульсия типа масло в воде по п.1, содержащая от 0,05 до 0,6% масс первичного поверхностно-активного вещества.
3. Эмульсия типа масло в воде по любому из предшествующих пунктов, содержащая в пределах от больше 0,3 и до 0,7% масс вторичного поверхностно-активного вещества.
4. Эмульсия типа масло в воде по любому из предшествующих пунктов, в которой масло масляной фазы представляет собой углеводородсодержащее масло, имеющее вязкость до 300000 сантистокс при 100°C.
5. Эмульсия типа масло в воде по любому из предшествующих пунктов, в которой масло масляной фазы представляет собой углеводородсодержащее масло, имеющее вязкость, по меньшей мере, 200 сантистокс при 100°C.
6. Эмульсия типа масло в воде по любому из предшествующих пунктов, в которой масло масляной фазы представляет собой углеводородный остаток, полученный из одного или нескольких источников: из переработанной природной тяжелой сырой нефти или природного битума; от разгонки при атмосферном давлении на нефтеперерабатывающем предприятии; вакуумной разгонки на нефтеперерабатывающем предприятии; висбрейкинга на нефтеперерабатывающем предприятии, термического крекинга или парового крекинга; каталитического крекинга в псевдоожиженном слое на нефтеперерабатывающем предприятии; гидропереработки и гидрокрекинга на нефтеперерабатывающем предприятии и от процессов деасфальтирования.
7. Эмульсия типа масло в воде по любому из предшествующих пунктов, в которой углеводород представляет собой углеводородный остаток, выбранный из остатков, имеющих регистрационные номера в Chemical Abstracts Service (CAS) 8052-42-4, 64741-45-3, 64741-56-6, 64741-67-9, 64741-75-9, 64741-80-6, 64742-07-0, 64742-78-5, 64742-85-4, 68748-13-7, 68783-13-1, 70913-85-8, 91995-23-2 или 92062-05-0.
8. Эмульсия типа масло в воде по любому из пп.1-7, дополнительно содержащая один или несколько полимерных стабилизаторов, по меньшей мере один из которых выбран из группы, состоящей из простых алкиловых эфиров гидроксиалкилцеллюлозы, гуаровой смолы, крахмала и производных крахмала, гидроксиэтилцеллюлозы и этилгидроксилэтилцеллюлозы.
9. Эмульсия типа масло в воде по п.8, содержащая до 0,25% масс полимерных агентов для стабилизации; или содержащая от 0,03 до 0,08% масс полимерных агентов для стабилизации.
10. Эмульсия типа масло в воде по любому из предшествующих пунктов, содержащая одну или несколько органических кислот.
11. Эмульсия типа масло в воде по п.10, в которой, по меньшей мере, одна органическая кислота выбрана из метансульфоновой кислоты и муравьиной кислоты.
12. Композиция судового топлива, содержащая эмульсию типа масло в воде по любому из предшествующих пунктов.
13. Способ получения эмульсии типа масло в воде, определенной в любом из по любому из пп.1-11, включающий приготовление водной фазы, содержащей первичное поверхностно-активное вещество, нагревание углеводородсодержащей масляной фазы, смешивание углеводородсодержащего масла и водной фазы в условиях, достаточных для образования эмульсии типа масло в воде.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1519615.7A GB201519615D0 (en) | 2015-11-06 | 2015-11-06 | Oil-in-water emulsions |
| GB1519615.7 | 2015-11-06 | ||
| GB1609042.5 | 2016-05-23 | ||
| GBGB1609042.5A GB201609042D0 (en) | 2016-05-23 | 2016-05-23 | Oil-in-water emulsions |
| PCT/GB2016/053413 WO2017077302A2 (en) | 2015-11-06 | 2016-11-03 | Oil-in-water emulsions |
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| Publication Number | Publication Date |
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| RU2018120730A true RU2018120730A (ru) | 2019-12-10 |
| RU2018120730A3 RU2018120730A3 (ru) | 2020-03-18 |
| RU2731091C2 RU2731091C2 (ru) | 2020-08-28 |
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| RU2018120730A RU2731091C2 (ru) | 2015-11-06 | 2016-11-03 | Эмульсии типа масло в воде |
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| US (1) | US10704003B2 (ru) |
| EP (1) | EP3365415B1 (ru) |
| JP (1) | JP6807939B2 (ru) |
| CN (1) | CN108699463B (ru) |
| CA (1) | CA3004195C (ru) |
| ES (1) | ES2775298T3 (ru) |
| LT (1) | LT3365415T (ru) |
| PT (1) | PT3365415T (ru) |
| RU (1) | RU2731091C2 (ru) |
| SG (1) | SG11201803721UA (ru) |
| WO (1) | WO2017077302A2 (ru) |
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| GB201707556D0 (en) * | 2017-05-11 | 2017-06-28 | Quadrise Int Ltd | Oil-in water emulsions |
| CN113785036B (zh) * | 2019-05-03 | 2024-04-26 | 巴斯夫欧洲公司 | 用于燃料乳液的含有季铵表面活性剂的乳化剂包 |
| EP3868810A1 (en) | 2020-02-21 | 2021-08-25 | Nouryon Chemicals International B.V. | Biodegradable polyesters for water-resistant oil-in-water suncare formulations |
| GB202019106D0 (en) | 2020-12-03 | 2021-01-20 | Quadrise Int Ltd | Oil-in-water emulsions |
| GB2618100B (en) * | 2022-04-26 | 2024-05-29 | Quadrise International Ltd | System for producing an oil-in-water emulsion |
| GB2622054A (en) * | 2022-08-31 | 2024-03-06 | Quadrise International Ltd | Emulsions |
| CN117147395B (zh) * | 2023-11-01 | 2023-12-26 | 东北石油大学三亚海洋油气研究院 | 用于测量多孔介质内乳状液液滴大小的实验装置与方法 |
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| GB8404347D0 (en) | 1984-02-18 | 1984-03-21 | British Petroleum Co Plc | Preparation of emulsions |
| GB8431012D0 (en) | 1984-12-07 | 1985-01-16 | British Petroleum Co Plc | Preparation of emulsions |
| GB8521968D0 (en) | 1985-09-04 | 1985-10-09 | British Petroleum Co Plc | Preparation of emulsions |
| GB9110079D0 (en) | 1991-05-09 | 1991-07-03 | British Petroleum Co Plc | Fuel composition |
| US5354504A (en) | 1991-08-19 | 1994-10-11 | Intevep, S.A. | Method of preparation of emulsions of viscous hydrocarbon in water which inhibits aging |
| WO1993007238A1 (en) | 1991-10-01 | 1993-04-15 | Nalco Fuel Tech | Emulsification system for light fuel oil emulsions |
| US5603864A (en) | 1991-12-02 | 1997-02-18 | Intevep, S.A. | Method for the preparation of viscous hydrocarbon in aqueous buffer solution emulsions |
| JP3069673B2 (ja) | 1992-09-08 | 2000-07-24 | 花王株式会社 | 重質油エマルジョン燃料 |
| US5399293A (en) | 1992-11-19 | 1995-03-21 | Intevep, S.A. | Emulsion formation system and mixing device |
| US5863301A (en) | 1994-06-02 | 1999-01-26 | Empresa Colombiana De Petroleos ("Ecopetrol") | Method of produce low viscosity stable crude oil emulsion |
| JPH08277396A (ja) | 1995-04-05 | 1996-10-22 | Kao Corp | 重質油の燃焼方法 |
| JPH08325582A (ja) | 1995-06-01 | 1996-12-10 | Kao Corp | 超重質油エマルション燃料の製造方法 |
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| CA2205294A1 (en) | 1996-05-23 | 1997-11-23 | Kao Corporation | Method for producing superheavy oil emulsion fuel and fuel produced thereby |
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| US20130118598A1 (en) | 2011-11-11 | 2013-05-16 | Intevep, S.A. | Formation and breaking of emulsion using low molecular weight amine |
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-
2016
- 2016-11-03 SG SG11201803721UA patent/SG11201803721UA/en unknown
- 2016-11-03 PT PT168010064T patent/PT3365415T/pt unknown
- 2016-11-03 EP EP16801006.4A patent/EP3365415B1/en active Active
- 2016-11-03 ES ES16801006T patent/ES2775298T3/es active Active
- 2016-11-03 WO PCT/GB2016/053413 patent/WO2017077302A2/en active Application Filing
- 2016-11-03 CA CA3004195A patent/CA3004195C/en active Active
- 2016-11-03 JP JP2018543461A patent/JP6807939B2/ja active Active
- 2016-11-03 US US15/773,351 patent/US10704003B2/en active Active
- 2016-11-03 CN CN201680076268.0A patent/CN108699463B/zh active Active
- 2016-11-03 RU RU2018120730A patent/RU2731091C2/ru active
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Also Published As
| Publication number | Publication date |
|---|---|
| CN108699463A (zh) | 2018-10-23 |
| RU2731091C2 (ru) | 2020-08-28 |
| CA3004195A1 (en) | 2017-05-11 |
| PT3365415T (pt) | 2019-12-18 |
| JP2018536755A (ja) | 2018-12-13 |
| RU2018120730A3 (ru) | 2020-03-18 |
| US20180320096A1 (en) | 2018-11-08 |
| CN108699463B (zh) | 2021-06-08 |
| ES2775298T3 (es) | 2020-07-24 |
| WO2017077302A3 (en) | 2017-06-15 |
| US10704003B2 (en) | 2020-07-07 |
| EP3365415B1 (en) | 2019-09-04 |
| WO2017077302A2 (en) | 2017-05-11 |
| CA3004195C (en) | 2023-05-09 |
| SG11201803721UA (en) | 2018-06-28 |
| EP3365415A2 (en) | 2018-08-29 |
| LT3365415T (lt) | 2020-01-27 |
| JP6807939B2 (ja) | 2021-01-06 |
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