RU2017140093A - Способ получения кислорода из композиций, содержащих ионные жидкости - Google Patents
Способ получения кислорода из композиций, содержащих ионные жидкости Download PDFInfo
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- RU2017140093A RU2017140093A RU2017140093A RU2017140093A RU2017140093A RU 2017140093 A RU2017140093 A RU 2017140093A RU 2017140093 A RU2017140093 A RU 2017140093A RU 2017140093 A RU2017140093 A RU 2017140093A RU 2017140093 A RU2017140093 A RU 2017140093A
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- oxides
- metal oxide
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- ionic liquid
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- 238000000034 method Methods 0.000 title claims 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims 11
- 239000002608 ionic liquid Substances 0.000 title claims 11
- 239000001301 oxygen Substances 0.000 title claims 11
- 229910052760 oxygen Inorganic materials 0.000 title claims 11
- 239000000203 mixture Substances 0.000 title claims 6
- 229910044991 metal oxide Inorganic materials 0.000 claims 16
- -1 peroxide compound Chemical class 0.000 claims 11
- 150000004706 metal oxides Chemical class 0.000 claims 8
- 229910052751 metal Inorganic materials 0.000 claims 6
- 239000002184 metal Substances 0.000 claims 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 5
- 150000001768 cations Chemical class 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 5
- 150000001450 anions Chemical class 0.000 claims 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims 3
- 150000002739 metals Chemical class 0.000 claims 3
- 239000000843 powder Substances 0.000 claims 3
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 claims 2
- FRZPYEHDSAQGAS-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;trifluoromethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)F.CCCC[N+]=1C=CN(C)C=1 FRZPYEHDSAQGAS-UHFFFAOYSA-M 0.000 claims 2
- 239000004484 Briquette Substances 0.000 claims 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 2
- 150000001340 alkali metals Chemical group 0.000 claims 2
- 239000004202 carbamide Substances 0.000 claims 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- GSGLHYXFTXGIAQ-UHFFFAOYSA-M 1,3-dimethylimidazol-1-ium;dimethyl phosphate Chemical compound COP([O-])(=O)OC.CN1C=C[N+](C)=C1 GSGLHYXFTXGIAQ-UHFFFAOYSA-M 0.000 claims 1
- WOKQGMYCUGJNIJ-UHFFFAOYSA-M 1,3-dimethylimidazol-1-ium;methyl sulfate Chemical compound COS([O-])(=O)=O.CN1C=C[N+](C)=C1 WOKQGMYCUGJNIJ-UHFFFAOYSA-M 0.000 claims 1
- FSUAYRLKFSKOJG-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;dimethyl phosphate Chemical compound COP([O-])(=O)OC.CCCC[N+]=1C=CN(C)C=1 FSUAYRLKFSKOJG-UHFFFAOYSA-M 0.000 claims 1
- MEMNKNZDROKJHP-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCN1C=C[N+](C)=C1 MEMNKNZDROKJHP-UHFFFAOYSA-M 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- KKUKTXOBAWVSHC-UHFFFAOYSA-N Dimethylphosphate Chemical compound COP(O)(=O)OC KKUKTXOBAWVSHC-UHFFFAOYSA-N 0.000 claims 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-O Piperidinium(1+) Chemical compound C1CC[NH2+]CC1 NQRYJNQNLNOLGT-UHFFFAOYSA-O 0.000 claims 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 claims 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-O Pyrrolidinium ion Chemical compound C1CC[NH2+]C1 RWRDLPDLKQPQOW-UHFFFAOYSA-O 0.000 claims 1
- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 claims 1
- WSZBCXXFBOTXDC-UHFFFAOYSA-N [Fe].[Ni].[La] Chemical compound [Fe].[Ni].[La] WSZBCXXFBOTXDC-UHFFFAOYSA-N 0.000 claims 1
- XGPJPLXOIJRLJN-UHFFFAOYSA-N [Mn].[Sr].[La] Chemical compound [Mn].[Sr].[La] XGPJPLXOIJRLJN-UHFFFAOYSA-N 0.000 claims 1
- WQHONKDTTOGZPR-UHFFFAOYSA-N [O-2].[O-2].[Mn+2].[Fe+2] Chemical class [O-2].[O-2].[Mn+2].[Fe+2] WQHONKDTTOGZPR-UHFFFAOYSA-N 0.000 claims 1
- PNEBHVWHKXQXDR-UHFFFAOYSA-N [O].[Mn].[Cu] Chemical class [O].[Mn].[Cu] PNEBHVWHKXQXDR-UHFFFAOYSA-N 0.000 claims 1
- XSGKJXQWZSFJEJ-UHFFFAOYSA-N bis(trifluoromethylsulfonyl)azanide;butyl(trimethyl)azanium Chemical compound CCCC[N+](C)(C)C.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F XSGKJXQWZSFJEJ-UHFFFAOYSA-N 0.000 claims 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 claims 1
- 229960001231 choline Drugs 0.000 claims 1
- QRXDDLFGCDQOTA-UHFFFAOYSA-N cobalt(2+) iron(2+) oxygen(2-) Chemical class [O-2].[Fe+2].[Co+2].[O-2] QRXDDLFGCDQOTA-UHFFFAOYSA-N 0.000 claims 1
- UBEWDCMIDFGDOO-UHFFFAOYSA-N cobalt(II,III) oxide Inorganic materials [O-2].[O-2].[O-2].[O-2].[Co+2].[Co+3].[Co+3] UBEWDCMIDFGDOO-UHFFFAOYSA-N 0.000 claims 1
- 238000005056 compaction Methods 0.000 claims 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 1
- IQKLAEINENLGAG-UHFFFAOYSA-N iron oxocopper Chemical class [Fe].[Cu]=O IQKLAEINENLGAG-UHFFFAOYSA-N 0.000 claims 1
- VKFOYDLMKRBPND-UHFFFAOYSA-N iron;oxonickel Chemical class [Fe].[Ni]=O VKFOYDLMKRBPND-UHFFFAOYSA-N 0.000 claims 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 claims 1
- YADSGOSSYOOKMP-UHFFFAOYSA-N lead dioxide Inorganic materials O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- WSHADMOVDWUXEY-UHFFFAOYSA-N manganese oxocobalt Chemical class [Co]=O.[Mn] WSHADMOVDWUXEY-UHFFFAOYSA-N 0.000 claims 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims 1
- JEMDLNFQNCQAKN-UHFFFAOYSA-N nickel;oxomanganese Chemical class [Ni].[Mn]=O JEMDLNFQNCQAKN-UHFFFAOYSA-N 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 claims 1
- 229910000029 sodium carbonate Inorganic materials 0.000 claims 1
- 235000017550 sodium carbonate Nutrition 0.000 claims 1
- 229910052596 spinel Inorganic materials 0.000 claims 1
- 239000011029 spinel Substances 0.000 claims 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 claims 1
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- C01B13/0222—Preparation of oxygen from organic compounds
- C01B13/0225—Peroxy compounds
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
- B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
- B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
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- B01J31/0288—Phosphorus
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- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
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- B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
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Claims (31)
1. Способ получения кислорода, включающий
обеспечение, по меньшей мере, одного источника кислорода,
обеспечение, по меньшей мере, одной ионной жидкости,
обеспечение, по меньшей мере, одного соединения оксида металла, причем:
источник кислорода представляет собой пероксидное соединение,
ионная жидкость находится в жидком состоянии, по меньшей мере, в диапазоне температур от -10°C до +50°C, и
соединение оксида металла представляет собой оксид единственного металла или двух, или более различных металлов, причем указанный(е) металл(ы) выбран(ы) из металлов групп 2-14 периодической таблицы элементов, и
приведение в контакт источника кислорода, ионной жидкости и соединения оксида металла.
2. Способ по п. 1, отличающийся тем, что источник кислорода и ионную жидкость обеспечивают в качестве первого компонента, соединение оксида металла обеспечивают в качестве второго компонента, а стадия приведения в контакт включает смешивание первого и второго компонентов.
3. Способ по п. 1, отличающийся тем, что соединение оксида металла и ионную жидкость обеспечивают в качестве первого компонента, источник кислорода обеспечивают в качестве второго компонента, а стадия приведения в контакт включает смешивание первого и второго компонентов.
4. Способ по п. 1, отличающийся тем, что источник кислорода и соединение оксида металла обеспечивают в качестве первого компонента, ионную жидкость обеспечивают в качестве второго компонента, а стадия приведения в контакт включает смешивание первого и второго компонентов.
5. Способ по любому из пп. 1-4, отличающийся тем, что источник кислорода выбран из перкарбонатов щелочных металлов, перборатов щелочных металлов, мочевины с пероксидом водорода и их смесей, и предпочтительно представляет собой один или более из Na2CO3×1,5 H2O2, NaBO3×4H2O, NaBO3×H2O и мочевины с пероксидом водорода.
6. Способ по любому из пп. 1-5, отличающийся тем, что ионная жидкость представляет собой по меньшей мере одну соль, содержащую катион и анион,
причем катион выбран из группы, состоящей из катионов имидазолия, пирролидиния, аммония, холина, пиридиния, пиразолия, пиперидиния, фосфония и сульфония, и, при этом, катион может содержать, по меньшей мере, один заместитель, или
ионная жидкость представляет собой по меньшей мере одну соль, содержащую катион и анион, притом, что анион выбран из группы, состоящей из диметилфосфата, метилсульфата, трифторметилсульфоната, бис(трифторметилсульфонил)имида, хлорида, бромида, йодида, тетрафторбората и гексафторфосфата.
7. Способ по любому из пп. 1-6, отличающийся тем, что ионная жидкость выбрана из группы, состоящей из
бутилтриметиламмония бис(трифторметилсульфонил)имида ([Me3BuN]TFSI),
1-бутил-3-метилимидазолия трифторметансульфоната (BMImOTf),
1-бутил-3-метилимидазолия диметилфосфата (BMImPO4Me2),
1-бутил-3-метилимидазолия метилсульфата (BMImSO4Me),
1,1-бутилметилпирролидиния бис(трифторметилсульфонил)имида (BmpyrTFSI),
1,3-диметилимидазолия диметилфосфата (MMImPO4Me2),
1,3-диметилимидазолия метилсульфата (MMImSO4Me).
8. Способ по любому из пп. 1-7, отличающийся тем, что соединение оксида металла представляет собой по меньшей мере один оксид, содержащий единственный металл, необязательно в разных состояниях окисления.
9. Способ по любому из пп. 1-8, отличающийся тем, что соединение оксида металла представляет собой один или более из MnO2, Co3O4, CrO3, Ag2O, CuO и PbO2.
10. Способ по любому из пп. 1-9, отличающийся тем, что соединение оксида металла представляет собой по меньшей мере один оксид, содержащий по меньшей мере, два разных металла.
11. Способ по любому из пп. 1-10, отличающийся тем, что соединение оксида металла выбрано из оксидов металлов шпинельного типа, оксидов металлов ильменитового типа и оксидов металлов перовскитного типа.
12. Способ по любому из пп. 1-11, отличающийся тем, что соединение оксида металла выбрано из смешанных оксидов кобальта железа, смешанных оксидов меди железа, смешанных оксидов никеля железа, смешанных оксидов марганца железа, смешанных оксидов меди марганца, смешанных оксидов кобальта марганца, смешанных оксидов никеля марганца, смешанных оксидов никеля кобальта, смешанных оксидов лантана железа никеля, смешанных оксидов лантана стронция марганца и их смесей.
13. Способ по любому из пп. 1-12, отличающийся тем, что по меньшей мере один из источника кислорода и соединения оксида металла находится в форме по меньшей мере одного брикета порошка или в форме брикетов порошка с разной степенью уплотнения.
14. Способ по п. 13, отличающийся тем, что, по меньшей мере, один брикет порошка спрессован при давлении в диапазоне от 1 до 220 МПа.
15. Способ по любому из пп. 1-14, отличающийся тем, что источник кислорода присутствует в количестве от 10 до 80% мас. композиции, ионная жидкость присутствует в количестве от 20 до 80% мас. композиции, и соединение оксида металла присутствует в количестве от более чем 0 до 20% мас. композиции.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16199633.5A EP3323781B1 (en) | 2016-11-18 | 2016-11-18 | Method for generating oxygen from compositions comprising ionic liquids |
| EP16199633.5 | 2016-11-18 |
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| Publication Number | Publication Date |
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| RU2017140093A true RU2017140093A (ru) | 2019-05-17 |
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| RU2017140093A RU2017140093A (ru) | 2016-11-18 | 2017-11-17 | Способ получения кислорода из композиций, содержащих ионные жидкости |
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| Country | Link |
|---|---|
| US (1) | US10549993B2 (ru) |
| EP (1) | EP3323781B1 (ru) |
| CN (1) | CN108069394B (ru) |
| BR (1) | BR102017024612A2 (ru) |
| RU (1) | RU2017140093A (ru) |
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| EP3604211A1 (en) * | 2018-07-30 | 2020-02-05 | Diehl Aviation Gilching GmbH | Oxygen generator and method for controlling the oxygen production rate of an oxygen generator |
| FR3111883B1 (fr) * | 2020-06-26 | 2022-08-26 | Commissariat Energie Atomique | Dispositif passif de generation de dioxygene |
| CN112723421B (zh) * | 2021-02-03 | 2023-01-24 | 江西理工大学 | 一种FeMnSx纳米片簇及其制备方法 |
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|---|---|---|---|---|
| US2035896A (en) | 1931-12-10 | 1936-03-31 | Frank C Kerwin | Liberation of oxygen from sodium perborate |
| US4548730A (en) | 1983-07-05 | 1985-10-22 | Koslow Technologies Corporation | Portable self-contained oxygen generator apparatus and method |
| JPS6177604A (ja) * | 1984-09-20 | 1986-04-21 | Nikka Micron Kk | 酸素発生器 |
| IT1214865B (it) | 1984-09-28 | 1990-01-18 | Caprara Mario | Procedimento per la produzione di ossigeno mediante apparecchiatura portatile, particolarmente per respirazione umana, ed apparecchiatura per attuare il procedimento. |
| JPS61227903A (ja) | 1985-04-03 | 1986-10-11 | Michimasa Oguri | デイスポ型酸素発生器 |
| JPS61236602A (ja) | 1985-04-11 | 1986-10-21 | Michimasa Oguri | 小型酸素発生器 |
| US4800070A (en) | 1987-09-08 | 1989-01-24 | Air Products And Chemicals, Inc. | Catalysts for absorptive air separation |
| US4963327A (en) | 1988-03-23 | 1990-10-16 | Z-Gard, Inc. | Oxygen generating module |
| DE3837432A1 (de) | 1988-11-04 | 1990-05-10 | Draegerwerk Ag | Sauerstoffentwickelnde chemikalmasse fuer atemschutzgeraete |
| DE19602149A1 (de) | 1996-01-22 | 1997-07-24 | Riera Gertraud Canavate | Mittel zur Freisetzung von Sauerstoff in Sauerstoffgeneratoren |
| US6007736A (en) | 1996-05-15 | 1999-12-28 | Be Intellectual Property | Oxygen generating compositions catalyzed by copper and nickel oxides |
| US6866794B1 (en) | 2000-11-15 | 2005-03-15 | Be Intellectual Property Inc. | Strontium peroxide catalyzed oxygen generating compositions |
| DE10246140A1 (de) * | 2002-10-01 | 2004-04-15 | Basf Ag | Umsetzungsprodukte von 2-Propylheptanol mit1-Halogen-2,3-epoxypropanen und 1-Hydroxy-2,3-epoxypropan |
| AT412842B (de) * | 2003-07-24 | 2005-08-25 | Gheczy Rudolf Von | Verfahren zum betrieb einer verbrennungsanlage |
| CA2596247A1 (en) | 2005-01-28 | 2006-08-10 | Oxysure Systems, Inc. | Method and apparatus for controlled production of a gas |
| DE102006042320A1 (de) * | 2006-09-08 | 2008-03-27 | Robert Bosch Gmbh | Verfahren und Vorrichtung zur Sauerstoffgewinnung |
| JP2009138254A (ja) | 2007-02-13 | 2009-06-25 | Teijin Pharma Ltd | 電気化学的酸素発生素子 |
| US8944048B2 (en) | 2008-03-26 | 2015-02-03 | Battelle Memorial Institute | Apparatus and methods of providing diatomic oxygen (O2) using ferrate(VI)-containing compositions |
| CN102203232A (zh) * | 2008-09-01 | 2011-09-28 | 恩维洛维斯科技有限公司 | 用于从基材上除去口香糖残余物的组合物和方法 |
| US10717929B2 (en) | 2009-08-11 | 2020-07-21 | Ionic Flame Retardant Inc. | Ionic liquid flame retardants |
| DE102009041065A1 (de) | 2009-09-10 | 2011-03-24 | Beller, Klaus-Dieter, Dipl.-Ing. Dr. med. | Verschlussdeckel mit vorbefülltem Dosierzylinder als Verpackung von in Flüssigkeit zu lösenden Stoffen im Pharma- und Nahrungsmittelbereich |
| US8147760B1 (en) * | 2011-08-04 | 2012-04-03 | Gary Huvard | Portable chemical oxygen generator |
| EA028747B8 (ru) | 2012-04-13 | 2018-02-28 | ДжейТи ИНТЕРНЕШНЛ СА | Выделяющие кислород вкладыши |
| EP2856867A4 (en) | 2012-05-31 | 2016-02-17 | Mitsubishi Gas Chemical Co | OXYGEN GENERATION / CO2 GAS ABSORBENT COMPOSITION, PACKAGING FOR OXYGEN GENERATION / CO2 GAS ABSORBENT AND TRANSPORT PROCESS FOR LIVE FISH AND SHELL FISH |
| CN105776144B (zh) * | 2014-12-17 | 2018-03-20 | 中国科学院大连化学物理研究所 | 一种基于两相转移体系的单重态氧产生方法 |
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- 2017-11-16 BR BR102017024612A patent/BR102017024612A2/pt not_active Application Discontinuation
- 2017-11-17 US US15/815,741 patent/US10549993B2/en active Active
- 2017-11-17 RU RU2017140093A patent/RU2017140093A/ru not_active Application Discontinuation
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Also Published As
| Publication number | Publication date |
|---|---|
| BR102017024612A2 (pt) | 2018-07-17 |
| EP3323781B1 (en) | 2019-08-14 |
| CN108069394A (zh) | 2018-05-25 |
| US20180141812A1 (en) | 2018-05-24 |
| CN108069394B (zh) | 2022-10-18 |
| EP3323781A1 (en) | 2018-05-23 |
| US10549993B2 (en) | 2020-02-04 |
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