RU2017126006A - METHOD FOR COLLECTING 2,7-DIALKYL-4,9 (10) -DIMETHYL-2,3a, 5a, 7,8a, 10a-HEXAAZAPERHYDROPYRENES - Google Patents

METHOD FOR COLLECTING 2,7-DIALKYL-4,9 (10) -DIMETHYL-2,3a, 5a, 7,8a, 10a-HEXAAZAPERHYDROPYRENES Download PDF

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RU2017126006A
RU2017126006A RU2017126006A RU2017126006A RU2017126006A RU 2017126006 A RU2017126006 A RU 2017126006A RU 2017126006 A RU2017126006 A RU 2017126006A RU 2017126006 A RU2017126006 A RU 2017126006A RU 2017126006 A RU2017126006 A RU 2017126006A
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dimethyl
hexaazaperhydropyrenes
dialkyl
collecting
tetraazadecalines
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RU2017126006A
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RU2688220C2 (en
RU2017126006A3 (en
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Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Елена Борисовна Рахимова
Виктор Юрьевич Кирсанов
Борис Иванович Кутепов
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/22—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains four or more hetero rings

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  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

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Способ совместного получения 2,7-диалкил-4,9(10)-2,3а,5а,7,8а,10а-гексаазапергидропиренов общей формулы (1):The method of co-production of 2,7-dialkyl-4,9 (10) -2,3a, 5a, 7.8a, 10a-hexaazaperhydropyrenes of the general formula (1):
Figure 00000001
Figure 00000001
 R=н-пропил, н-бутилR = n-propyl, n-butyl отличающийся тем, что N,N-бис(метоксиметил)-N-алкил амин, где R - указанные выше, подвергают взаимодействию с изомерной смесью 2,6(7)-диметил-1,4,5,8-тетраазадекалинов в среде СН3ОН-Н2О в присутствии катализатора SmCl3⋅6H2O при мольном соотношении N,N-бис(метоксиметил)-N-алкиламин : изомерная смесь 2,6(7)-диметил-1,4,5,8-тетраазадекалинов : SmCl3⋅6H2O = 2:1:(0.03-0.07) при комнатной (~20°С) температуре и атмосферном давлении в течение 2.5-3.5 ч.characterized in that N, N-bis (methoxymethyl) -N-alkyl amine, where R is the above, is reacted with an isomeric mixture of 2,6 (7) -dimethyl-1,4,5,8-tetraazadecalines in a CH medium 3 OH-H 2 O in the presence of a SmCl 3 ⋅ 6H 2 O catalyst at a molar ratio of N, N-bis (methoxymethyl) -N-alkylamine: isomeric mixture of 2.6 (7) -dimethyl-1,4,5,8- tetraazadecalines: SmCl 3 ⋅6H 2 O = 2: 1: (0.03-0.07) at room temperature (~ 20 ° C) and atmospheric pressure for 2.5-3.5 hours.
RU2017126006A 2017-07-19 2017-07-19 Method for combined production of 2,7-dialkyl-4,9(10)-dimethyl-2,3a,5a,7,8a,10a-hexaazaperhydropyrenes RU2688220C2 (en)

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RU2556009C1 (en) * 2014-04-08 2015-07-10 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук METHOD OF OBTAINING 2,6-DIALKYL-HEXAHYDRO-1H,5H-2,3A,4A,6,7A,8A-HEXAAZACYCLOPENTA [def]FLUORENE-4,8-DIONS

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