RU2017101971A - Декоративные облицовочные покрытия, не содержащие поливинилхлорид - Google Patents

Декоративные облицовочные покрытия, не содержащие поливинилхлорид Download PDF

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RU2017101971A
RU2017101971A RU2017101971A RU2017101971A RU2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A
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mass
pvc
free
decorative
ethylene
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RU2017101971A
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RU2681900C2 (ru
RU2017101971A3 (ru
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Пьер БАСТЕН
КРОЧЕ Паскаль ДИ
Александр Сиш
Жан-Ив СИМОН
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Таркетт Гдл
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Claims (36)

1. Декоративное облицовочное покрытие, не содержащее ПВХ (поливинилхлорид), включающее упрочненный слой, который содержит носитель, пропитанный не содержащей ПВХ пастой, имеющей динамическую вязкость при 200°C и при скорости сдвига 100/с от 500 до 10000 Па⋅с, причем указанная паста содержит:
- от 5 до 50 масс. %, предпочтительно от 10 до 40 масс. % полиолефиновой смеси, причем указанные полиолефины характеризуются скоростью течения расплава равной или меньшей чем 15 г/10 минут при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238,
- от 45 до 90 масс. % одного или более чем одного наполнителя и
- от 0,5 до 12 масс. % одного или более чем одного смазывающего вещества.
2. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1, где не содержащая ПВХ паста имеет динамическую вязкость при 200°C и при скорости сдвига 100/с от 800 до 7000 Па⋅с, предпочтительно от 1000 до 2500 Па⋅с, причем указанная паста содержит:
- от 10 до 40 масс. %, более предпочтительно от 15 до 30 масс. % полиолефиновой смеси, причем указанные полиолефины характеризуются скоростью течения расплава от 1 до 10 г/10 минут, предпочтительно от 1 до 5 г/10 минут при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238,
- от 60 до 80 масс. % одного или более чем одного наполнителя и
- от 1 до 10 масс. %, предпочтительно от 3 до 7 масс. % одного или более чем одного смазывающего вещества.
3. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где полиолефиновая смесь содержит:
- от 5 до 55 масс. %, предпочтительно от 10 до 50 масс. %, более предпочтительно от 15 до 45 масс. % и наиболее предпочтительно от 20 до 40 масс. % гомо- или сополимера этилена (А), содержащего альфа-олефины,
- от 5 до около 55 масс. %, предпочтительно от 10 до 50 масс. %, более предпочтительно от 15 до 45 масс. % и наиболее предпочтительно от 20 до 40 масс. % сополимера этилена (В), содержащего винилкарбоксилат и/или алкил(мет)акрилат,
- от 5 до 55 масс. %, предпочтительно от 10 до 50 масс. %, более предпочтительно от 15 до 45 масс. % и наиболее предпочтительно от 20 до 40 масс. % полиолефинового эластомера (С),
- от 1 до 25 масс. %, предпочтительно от 3 до 20 масс. % и наиболее предпочтительно от 5 до 15 масс. % полиолефина (D), содержащего полярную группу.
4. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где гомо- или сополимер этилена (А) представляет собой гомо- или сополимер этилена очень низкой плотности, содержащий от 5 до 95 масс. % этилена и от 5 до 95 масс. % одного или более чем одного С3-С20 альфа-олефина, характеризуется плотностью менее 0,916 г/см3 и скоростью течения расплава от 0,5 до 15 г/10 мин, предпочтительно от 0,7 до 10 г/10 мин, более предпочтительно от 1,0 до 7 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
5. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где сополимер этилена (В), содержащий винилкарбоксилат, включает от 40 до 95 масс. % этилена и от 60 до 85 масс. % по меньшей мере одного сомономера, выбранного из группы, состоящей из виниловых сложных эфиров насыщенных карбоновых кислот, где кислотная группировка имеет вплоть до 4 атомов углерода, и С1-С20 алкил(мет)акрилатов, характеризуется скоростью течения расплава от 0,1 до 10 г/10 мин, предпочтительно от 0,5 до 8 г/10 мин и наиболее предпочтительно от 1,0 до 5 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
6. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где полиолефиновый эластомер (С) представляет собой гомополимер С2-С20 олефинов или сополимер этилена с по меньшей мере одним С3-С20 альфа-олефином и/или С2-С20 ацетилен-ненасыщенным мономером, и/или С4-С18 диолефинами, характеризуется скоростью течения расплава от 0,1 до 13 г/10 мин, предпочтительно от 0,5 до 8 г/10 мин и более предпочтительно от 1,0 до 5 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
7. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где полиолефин (D), содержащий полярную группу, представляет собой эластомерный сополимер этилена и одного или более чем одного С4-С10 альфа-олефина, содержит от 0,1 до 20 масс. % одной или более чем одной полярной группы относительно массы полиолефина, выбранной из группы, состоящей из ангидридов органических кислот и карбоновых кислот, и характеризуется скоростью течения
расплава от 0,5 до 15 г/10 мин, предпочтительно от 0,7 до 10 г/10 мин, более предпочтительно от 1,0 до 8 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
8. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где одно или более чем одно смазывающее вещество выбрано из группы, состоящей из представителей стеариновых кислот, сложных эфиров жирных кислот, амидов жирных кислот, парафиновых углеводородов, мыл металлов, силиконов, используемых отдельно или в виде смеси.
9. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где один или более чем один наполнитель выбран из группы, состоящей из талька, слюды, карбоната кальция, карбоната магния или карбоната кальция-магния, барита, каолина, кремнезема, стекла или любой их комбинации.
10. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где носитель включает стекловолоконный мат, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
11. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где носитель включает нетканый материал, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
12. Способ получения декоративного облицовочного покрытия, не содержащего ПВХ, по любому из пп. 1-11, включающий стадии:
a) подачи носителя;
b) контактирования носителя со стадии а) с не содержащей ПВХ пастой и пропитывания указанного носителя с использованием процесса каландрирования с образованием упрочненного слоя;
c) охлаждения упрочненного слоя со стадии b).
13. Способ по п. 12, включающий дополнительную стадию контактирования упрочненного слоя со стадии b) с одной или более чем одной не содержащей ПВХ пастой с использованием процесса каландрирования с образованием слоистого декоративного облицовочного покрытия.
14. Способ по п. 13, где каландрирование на стадии b) выполняют при внутренней температуре смеси от 180 до 240°C, предпочтительно от 190 до 230°C, более предпочтительно от 200 до 220°C.
15. Способ по любому из пп. 12-14, где носитель представляет собой стекловолоконный мат, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
16. Способ по любому из пп. 12-14, где носитель представляет собой нетканый материал, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
17. Способ по любому из пп. 12-14, где не содержащую ПВХ пасту получают в результате смешивания в расплаве:
- от 5 до 50 масс. %, предпочтительно от 10 до 40 масс. %, более предпочтительно от 15 до 30 масс. % не содержащей ПВХ полимерной смеси, характеризующейся скоростью течения расплава равной или менее 15 г/10 мин, предпочтительно от 1 до 10 г/10 мин, более предпочтительно от 1 до 5 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238,
- от 45 до 90 масс. %, предпочтительно от 60 до 80 масс. % одного или более чем одного наполнителя и
- от 0,5 до 12 масс. %, предпочтительно от 1 до 10 масс. %, более предпочтительно от 3 до 7 масс. % одного или более чем одного смазывающего вещества;
при внутренней температуре от 180 до 240°C, предпочтительно от 190 до 230°C, более предпочтительно от 200 до 220°C.
18. Способ по любому из пп. 12-14, где установленная температура цилиндров для каландрирования находится в диапазоне от 150 до 195°C, предпочтительно от 160 до 190°C, более предпочтительно от 165 до 185°C.
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