RU2017101971A - Декоративные облицовочные покрытия, не содержащие поливинилхлорид - Google Patents
Декоративные облицовочные покрытия, не содержащие поливинилхлорид Download PDFInfo
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- RU2017101971A RU2017101971A RU2017101971A RU2017101971A RU2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A RU 2017101971 A RU2017101971 A RU 2017101971A
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- RU
- Russia
- Prior art keywords
- mass
- pvc
- free
- decorative
- ethylene
- Prior art date
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- 229920000915 polyvinyl chloride Polymers 0.000 title claims 5
- 239000004800 polyvinyl chloride Substances 0.000 title claims 5
- 238000005253 cladding Methods 0.000 claims 9
- 238000000034 method Methods 0.000 claims 9
- 229920000098 polyolefin Polymers 0.000 claims 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 7
- 239000005977 Ethylene Substances 0.000 claims 7
- 239000000155 melt Substances 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 5
- 238000003490 calendering Methods 0.000 claims 4
- 229920001577 copolymer Polymers 0.000 claims 4
- 239000000945 filler Substances 0.000 claims 4
- 239000000314 lubricant Substances 0.000 claims 4
- 239000004711 α-olefin Substances 0.000 claims 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 3
- 239000011248 coating agent Substances 0.000 claims 3
- 238000000576 coating method Methods 0.000 claims 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 2
- 229920001038 ethylene copolymer Polymers 0.000 claims 2
- 239000000194 fatty acid Substances 0.000 claims 2
- 229930195729 fatty acid Natural products 0.000 claims 2
- 239000011152 fibreglass Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 229920006124 polyolefin elastomer Polymers 0.000 claims 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims 1
- 239000010428 baryte Substances 0.000 claims 1
- 229910052601 baryte Inorganic materials 0.000 claims 1
- 229910000019 calcium carbonate Inorganic materials 0.000 claims 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 229920001198 elastomeric copolymer Polymers 0.000 claims 1
- -1 fatty acid esters Chemical class 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims 1
- 239000001095 magnesium carbonate Substances 0.000 claims 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 229920002959 polymer blend Polymers 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000000344 soap Substances 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
Classifications
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- C08J2331/00—Characterised by the use of copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, or carbonic acid, or of a haloformic acid
- C08J2331/02—Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
- C08J2331/04—Homopolymers or copolymers of vinyl acetate
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- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
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Claims (36)
1. Декоративное облицовочное покрытие, не содержащее ПВХ (поливинилхлорид), включающее упрочненный слой, который содержит носитель, пропитанный не содержащей ПВХ пастой, имеющей динамическую вязкость при 200°C и при скорости сдвига 100/с от 500 до 10000 Па⋅с, причем указанная паста содержит:
- от 5 до 50 масс. %, предпочтительно от 10 до 40 масс. % полиолефиновой смеси, причем указанные полиолефины характеризуются скоростью течения расплава равной или меньшей чем 15 г/10 минут при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238,
- от 45 до 90 масс. % одного или более чем одного наполнителя и
- от 0,5 до 12 масс. % одного или более чем одного смазывающего вещества.
2. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1, где не содержащая ПВХ паста имеет динамическую вязкость при 200°C и при скорости сдвига 100/с от 800 до 7000 Па⋅с, предпочтительно от 1000 до 2500 Па⋅с, причем указанная паста содержит:
- от 10 до 40 масс. %, более предпочтительно от 15 до 30 масс. % полиолефиновой смеси, причем указанные полиолефины характеризуются скоростью течения расплава от 1 до 10 г/10 минут, предпочтительно от 1 до 5 г/10 минут при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238,
- от 60 до 80 масс. % одного или более чем одного наполнителя и
- от 1 до 10 масс. %, предпочтительно от 3 до 7 масс. % одного или более чем одного смазывающего вещества.
3. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где полиолефиновая смесь содержит:
- от 5 до 55 масс. %, предпочтительно от 10 до 50 масс. %, более предпочтительно от 15 до 45 масс. % и наиболее предпочтительно от 20 до 40 масс. % гомо- или сополимера этилена (А), содержащего альфа-олефины,
- от 5 до около 55 масс. %, предпочтительно от 10 до 50 масс. %, более предпочтительно от 15 до 45 масс. % и наиболее предпочтительно от 20 до 40 масс. % сополимера этилена (В), содержащего винилкарбоксилат и/или алкил(мет)акрилат,
- от 5 до 55 масс. %, предпочтительно от 10 до 50 масс. %, более предпочтительно от 15 до 45 масс. % и наиболее предпочтительно от 20 до 40 масс. % полиолефинового эластомера (С),
- от 1 до 25 масс. %, предпочтительно от 3 до 20 масс. % и наиболее предпочтительно от 5 до 15 масс. % полиолефина (D), содержащего полярную группу.
4. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где гомо- или сополимер этилена (А) представляет собой гомо- или сополимер этилена очень низкой плотности, содержащий от 5 до 95 масс. % этилена и от 5 до 95 масс. % одного или более чем одного С3-С20 альфа-олефина, характеризуется плотностью менее 0,916 г/см3 и скоростью течения расплава от 0,5 до 15 г/10 мин, предпочтительно от 0,7 до 10 г/10 мин, более предпочтительно от 1,0 до 7 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
5. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где сополимер этилена (В), содержащий винилкарбоксилат, включает от 40 до 95 масс. % этилена и от 60 до 85 масс. % по меньшей мере одного сомономера, выбранного из группы, состоящей из виниловых сложных эфиров насыщенных карбоновых кислот, где кислотная группировка имеет вплоть до 4 атомов углерода, и С1-С20 алкил(мет)акрилатов, характеризуется скоростью течения расплава от 0,1 до 10 г/10 мин, предпочтительно от 0,5 до 8 г/10 мин и наиболее предпочтительно от 1,0 до 5 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
6. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где полиолефиновый эластомер (С) представляет собой гомополимер С2-С20 олефинов или сополимер этилена с по меньшей мере одним С3-С20 альфа-олефином и/или С2-С20 ацетилен-ненасыщенным мономером, и/или С4-С18 диолефинами, характеризуется скоростью течения расплава от 0,1 до 13 г/10 мин, предпочтительно от 0,5 до 8 г/10 мин и более предпочтительно от 1,0 до 5 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
7. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 3, где полиолефин (D), содержащий полярную группу, представляет собой эластомерный сополимер этилена и одного или более чем одного С4-С10 альфа-олефина, содержит от 0,1 до 20 масс. % одной или более чем одной полярной группы относительно массы полиолефина, выбранной из группы, состоящей из ангидридов органических кислот и карбоновых кислот, и характеризуется скоростью течения
расплава от 0,5 до 15 г/10 мин, предпочтительно от 0,7 до 10 г/10 мин, более предпочтительно от 1,0 до 8 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238.
8. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где одно или более чем одно смазывающее вещество выбрано из группы, состоящей из представителей стеариновых кислот, сложных эфиров жирных кислот, амидов жирных кислот, парафиновых углеводородов, мыл металлов, силиконов, используемых отдельно или в виде смеси.
9. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где один или более чем один наполнитель выбран из группы, состоящей из талька, слюды, карбоната кальция, карбоната магния или карбоната кальция-магния, барита, каолина, кремнезема, стекла или любой их комбинации.
10. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где носитель включает стекловолоконный мат, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
11. Декоративное облицовочное покрытие, не содержащее ПВХ, по п. 1 или 2, где носитель включает нетканый материал, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
12. Способ получения декоративного облицовочного покрытия, не содержащего ПВХ, по любому из пп. 1-11, включающий стадии:
a) подачи носителя;
b) контактирования носителя со стадии а) с не содержащей ПВХ пастой и пропитывания указанного носителя с использованием процесса каландрирования с образованием упрочненного слоя;
c) охлаждения упрочненного слоя со стадии b).
13. Способ по п. 12, включающий дополнительную стадию контактирования упрочненного слоя со стадии b) с одной или более чем одной не содержащей ПВХ пастой с использованием процесса каландрирования с образованием слоистого декоративного облицовочного покрытия.
14. Способ по п. 13, где каландрирование на стадии b) выполняют при внутренней температуре смеси от 180 до 240°C, предпочтительно от 190 до 230°C, более предпочтительно от 200 до 220°C.
15. Способ по любому из пп. 12-14, где носитель представляет собой стекловолоконный мат, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
16. Способ по любому из пп. 12-14, где носитель представляет собой нетканый материал, характеризующийся воздухопроницаемостью более 3000 л/м2⋅с, предпочтительно от 3000 и 15000 л/м2⋅с и более предпочтительно от 3500 до 10000 л/м2⋅с.
17. Способ по любому из пп. 12-14, где не содержащую ПВХ пасту получают в результате смешивания в расплаве:
- от 5 до 50 масс. %, предпочтительно от 10 до 40 масс. %, более предпочтительно от 15 до 30 масс. % не содержащей ПВХ полимерной смеси, характеризующейся скоростью течения расплава равной или менее 15 г/10 мин, предпочтительно от 1 до 10 г/10 мин, более предпочтительно от 1 до 5 г/10 мин при 190°C и 2,16 кг в соответствии со стандартом ASTM D1238,
- от 45 до 90 масс. %, предпочтительно от 60 до 80 масс. % одного или более чем одного наполнителя и
- от 0,5 до 12 масс. %, предпочтительно от 1 до 10 масс. %, более предпочтительно от 3 до 7 масс. % одного или более чем одного смазывающего вещества;
при внутренней температуре от 180 до 240°C, предпочтительно от 190 до 230°C, более предпочтительно от 200 до 220°C.
18. Способ по любому из пп. 12-14, где установленная температура цилиндров для каландрирования находится в диапазоне от 150 до 195°C, предпочтительно от 160 до 190°C, более предпочтительно от 165 до 185°C.
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EP14174978 | 2014-06-30 | ||
EP14174978.8 | 2014-06-30 | ||
PCT/EP2015/061281 WO2016000869A1 (en) | 2014-06-30 | 2015-05-21 | Polyvinyl chloride-free decorative surface coverings |
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RU2017101971A3 RU2017101971A3 (ru) | 2018-07-30 |
RU2017101971A true RU2017101971A (ru) | 2018-07-30 |
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US7833611B2 (en) * | 2007-02-23 | 2010-11-16 | Mannington Mills, Inc. | Olefin based compositions and floor coverings containing the same |
US8410217B2 (en) * | 2008-12-15 | 2013-04-02 | Exxonmobil Chemical Patents Inc. | Thermoplastic polyolefin blends |
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EP3160239A1 (en) | 2017-05-03 |
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