RU2016147953A - Катализатор для уменьшения проскока аммиака, содержащий платину, пропитывающую высокопористые подложки - Google Patents

Катализатор для уменьшения проскока аммиака, содержащий платину, пропитывающую высокопористые подложки Download PDF

Info

Publication number
RU2016147953A
RU2016147953A RU2016147953A RU2016147953A RU2016147953A RU 2016147953 A RU2016147953 A RU 2016147953A RU 2016147953 A RU2016147953 A RU 2016147953A RU 2016147953 A RU2016147953 A RU 2016147953A RU 2016147953 A RU2016147953 A RU 2016147953A
Authority
RU
Russia
Prior art keywords
product according
catalytic product
paragraphs
molecular sieve
scr catalyst
Prior art date
Application number
RU2016147953A
Other languages
English (en)
Other versions
RU2016147953A3 (ru
Inventor
Хай-Ин ЧЭНЬ
Джозеф ФЕДЕЙКО
Original Assignee
Джонсон Мэтти Паблик Лимитед Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джонсон Мэтти Паблик Лимитед Компани filed Critical Джонсон Мэтти Паблик Лимитед Компани
Publication of RU2016147953A publication Critical patent/RU2016147953A/ru
Publication of RU2016147953A3 publication Critical patent/RU2016147953A3/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/763—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/072—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/723—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J35/19—
    • B01J35/394—
    • B01J35/56—
    • B01J35/60—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0246—Coatings comprising a zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1021—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2042—Barium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2045—Calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/204—Alkaline earth metals
    • B01D2255/2047—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2063—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B01D2255/2065—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20723—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/2073—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20753—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20769—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20776—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20784—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/209—Other metals
    • B01D2255/2094—Tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/30—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions

Claims (20)

1. Каталитическое изделие, содержащее: (a) высокопористую подложку, содержащую платину, палладий или их смесь, которые находятся в стенке высокопористой подложки, и (b) покрытие из катализатора SCR на стенке высокопористой подложки, где платина, палладий или их смесь присутствует в стенке высокопористого носителя в виде металла или в виде нанесенной(-ого) платины, палладия или их смеси.
2. Каталитическое изделие по п. 1, где платина, палладий или их смесь, либо нанесенная(-ый) платина, палладий или их смесь, присутствует также в виде покрытия на стенке высокопористого носителя.
3. Каталитическое изделие по любому из предшествующих пунктов, где высокопористая подложка имеет пористость от примерно 40% до примерно 80%.
4. Каталитическое изделие по любому из предшествующих пунктов, где катализатор SCR содержит базовый металл, выбранный из группы, состоящей из ванадия (V), молибдена (Mo) и вольфрама (W), хрома (Cr), церия (Ce), марганца (Mn), железа (Fe), кобальта (Co), никеля (Ni) и меди (Cu), и их смесей.
5. Каталитическое изделие по пп. 1-3, где катализатор SCR содержит молекулярное сито или молекулярное сито с обмененным металлом.
6. Каталитическое изделие по любому из предшествующих пунктов, где изделие содержит от примерно 0,1 масс. % до примерно 1 масс. % платины или от примерно 0,1 масс. % до примерно 2 масс. % палладия.
7. Каталитическое изделие по пп. 1-4 и 6, дополнительно содержащее по меньшей мере один промотор базового металла.
8. Каталитическое изделие по п. 7, где по меньшей мере один промотор базового металла выбран из группы, состоящей из неодима (Nd), бария (Ba), церия (Ce), лантана (La), празеодима (Pr), магния (Mg), кальция (Ca), марганца (Mn), цинка (Zn), ниобия (Nb), циркония (Zr), молибдена (Mo), олова (Sn), тантала (Ta), стронция (Sr) и их оксидов.
9. Каталитическое изделие по п. 5, где молекулярное сито с обмененным металлом представляет собой мелкопористое молекулярное сито с нанесенной медью (Cu), содержащее от примерно 0,1 до примерно 20,0 масс. % меди от общей массы катализатора.
10. Каталитическое изделие по пп. 1-3, 5-6 и 9, где катализатор SCR содержит мелкопористое молекулярное сито, выбранное из группы, состоящей из алюмосиликатных молекулярных сит, металлзамещенных алюмосиликатных молекулярных сит, алюмофосфатных (AlPO) молекулярных сит, металлзамещенных алюмофосфатных (MeAlPO) молекулярных сит, силикоалюмофосфатных (SAPO) молекулярных сит и металлзамещенных силикоалюмофосфатных (MeAPSO) молекулярных сит и их смесей.
11. Каталитическое изделие по пп. 1-3, 5-6, 9 и 10, где катализатор SCR содержит мелкопористое молекулярное сито, выбранное из группы типов каркасных структур, состоящей из ACO, AEI, AEN, AFN, AFT, AFX, ANA, APC, APD, ATT, CDO, CHA, DDR, DFT, EAB, EDI, EPI, ERI, GIS, GOO, IHW, ITE, ITW, LEV, KFI, MER, MON, NSI, OWE, PAU, PHI, RHO, RTH, SAT, SAV, SIV, THO, TSC, UEI, UFI, VNI, YUG и ZON, и их смесей и/или сростков.
12. Каталитическое изделие по пп. 1-3, 5-6 и 9-11, где катализатор SCR содержит мелкопористое молекулярное сито, выбранное из группы типов каркасных структур, состоящей из CHA, LEV, AEI, AFX, ERI, SFW, KFI, DDR и ITE.
13. Каталитическое изделие по пп. 1-3 и 5-6, где катализатор SCR содержит среднепористое молекулярное сито, выбранное из группы типов каркасных структур, состоящей из AEL, AFO, AHT, BOF, BOZ, CGF, CGS, CHI, DAC, EUO, FER, HEU, IMF, ITH, ITR, JRY, JSR, JST, LAU, LOV, MEL, MFI, MFS, MRE, MTT, MVY, MWW, NAB, NAT, NES, OBW, PAR, PCR, PON, PUN, RRO, RSN, SFF, SFG, STF, STI, STT, STW, SVR, SZR, TER, TON, TUN, UOS, VSV, WEI и WEN, и их смесей и/или сростков.
14. Каталитическое изделие по пп. 1-3, 5-6 и 13, где катализатор SCR содержит среднепористое молекулярное сито, выбранное из группы типов каркасных структур, состоящей из MFI, FER и STT.
15. Каталитическое изделие по пп. 1-3 и 5-6, где катализатор SCR содержит крупнопористое молекулярное сито, выбранное из группы типов каркасных структур, состоящей из AFI, AFR, AFS, AFY, ASV, ATO, ATS, BEA, BEC, BOG, BPH, BSV, CAN, CON, CZP, DFO, EMT, EON, EZT, FAU, GME, GON, IFR, ISV, ITG, IWR, IWS, IWV, IWW, JSR, LTF, LTL, MAZ, MEI, MOR, MOZ, MSE, MTW, NPO, OFF, OKO, OSI, RON, RWY, SAF, SAO, SBE, SBS, SBT, SEW, SFE, SFO, SFS, SFV, SOF, SOS, STO, SSF, SSY, USI, UWY и VET, и их смесей и/или сростков.
16. Каталитическое изделие по пп. 1-3, 5-6 и 15, где катализатор SCR содержит крупнопористое молекулярное сито, выбранное из группы типов каркасных структур, состоящей из MOR, OFF и BEA.
17. Каталитическое изделие по любому из предшествующих пунктов, где изделие превращает NOx в N2 с большей селективностью, чем сопоставимое изделие, содержащее подложку, имеющую пористость, меньшую чем пористость высокопористой подложки.
18. Способ очистки выхлопного газа, содержащего NOx, причем способ включает в себя приведение выхлопного газа, содержащего NOx, в контакт с каталитическим изделием по любому из предшествующих пунктов.
19. Способ по п. 18, где выхлопной газ, содержащий NOx, приводят в контакт с каталитическим изделием по пп. 1-17 при температуре от примерно 150°C до примерно 550°C.
20. Способ по пп. 18 или 19, где способ приводит к превращению NOx в N2, и селективность по N2 превышает селективность по N2 сопоставимого изделия, содержащего подложку, имеющую пористость, меньшую чем пористость высокопористой подложки.
RU2016147953A 2014-05-09 2015-05-08 Катализатор для уменьшения проскока аммиака, содержащий платину, пропитывающую высокопористые подложки RU2016147953A (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201461990963P 2014-05-09 2014-05-09
US61/990,963 2014-05-09
PCT/US2015/029852 WO2015172000A1 (en) 2014-05-09 2015-05-08 Ammonia slip catalyst having platinum impregnated on high porosity substrates

Publications (2)

Publication Number Publication Date
RU2016147953A true RU2016147953A (ru) 2018-06-13
RU2016147953A3 RU2016147953A3 (ru) 2018-11-14

Family

ID=53264787

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2016147953A RU2016147953A (ru) 2014-05-09 2015-05-08 Катализатор для уменьшения проскока аммиака, содержащий платину, пропитывающую высокопористые подложки

Country Status (9)

Country Link
US (1) US9757718B2 (ru)
EP (1) EP3140038A1 (ru)
JP (1) JP6585079B2 (ru)
KR (1) KR20170005455A (ru)
CN (1) CN106457216B (ru)
DE (1) DE112015002186T5 (ru)
GB (1) GB2544203B (ru)
RU (1) RU2016147953A (ru)
WO (1) WO2015172000A1 (ru)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102444558B1 (ko) * 2014-11-19 2022-09-20 존슨 맛쎄이 퍼블릭 리미티드 컴파니 저온 배출물 제어를 위한 scr과 pna의 조합
US9937489B2 (en) * 2015-06-18 2018-04-10 Johnson Matthey Public Limited Company Exhaust system without a DOC having an ASC acting as a DOC in a system with an SCR catalyst before the ASC
US10105692B2 (en) * 2015-09-29 2018-10-23 Johnson Matthey Public Limited Company Zoned ammonia slip catalyst for use in combustion turbines
GB2547288B (en) * 2016-02-03 2021-03-17 Johnson Matthey Plc Catalyst for oxidising ammonia
JP6925351B2 (ja) * 2016-02-03 2021-08-25 ビーエーエスエフ コーポレーション 内燃機関のための多層触媒組成物
BR112018074248A2 (pt) 2016-06-08 2019-03-06 Basf Corporation processo para a produção de um catalisador, catalisadores, método para a redução catalítica seletiva de nox e uso de um catalisador
TW201834543A (zh) * 2016-07-04 2018-09-16 托普索公司 過濾袋裝配
WO2018065354A1 (en) * 2016-10-03 2018-04-12 Umicore Ag & Co. Kg Catalyst article and method for the abatement of ammonia and nitrogen oxides
KR101846918B1 (ko) * 2016-11-16 2018-04-09 현대자동차 주식회사 Cu/LTA 촉매 및 이를 포함하는 배기 시스템, 그리고 Cu/LTA 촉매 제조 방법
BR112019015734A2 (pt) * 2017-02-08 2020-03-24 Basf Corporation Artigo catalítico, sistema de tratamento de gases de escape e método para o tratamento de uma corrente gasosa de escape
GB201705158D0 (en) * 2017-03-30 2017-05-17 Johnson Matthey Plc Catalyst article for use in a emission treatment system
EP3634626A2 (en) * 2017-06-09 2020-04-15 Basf Corporation Catalytic article and exhaust gas treatment systems
CN109126815B (zh) * 2017-06-27 2020-09-11 中国石油化工股份有限公司 一种低温脱硝催化剂及应用
CH713958A1 (de) * 2017-07-07 2019-01-15 Exentis Tech Ag System bestehend aus einem Träger mit Strömungskanälen und mindestens einer katalystisch wirksamen Substanz.
CN111683734A (zh) * 2018-02-05 2020-09-18 巴斯夫公司 具有改善的过滤性能的四效转化催化剂
CN111683733A (zh) * 2018-02-05 2020-09-18 巴斯夫公司 具有改善的过滤性能的四效转化催化剂
GB201805312D0 (en) * 2018-03-29 2018-05-16 Johnson Matthey Plc Catalyst article for use in emission treatment system
JP2020062627A (ja) * 2018-10-19 2020-04-23 東京濾器株式会社 アンモニア浄化触媒
EP3873666A4 (en) * 2018-10-31 2022-09-07 BASF Corporation CATALYTIC WASH COAT WITH ALUMINUM ADDED FOR NOX REDUCTION
EP3873664A4 (en) * 2018-10-31 2022-09-07 BASF Corporation CATALYTIC COMPOSITION WITH ADDED COPPER CAPTURE COMPONENTS FOR NOX REDUCTION
EP3782726A1 (en) 2019-08-20 2021-02-24 Umicore Ag & Co. Kg Catalyst for the abatement of ammonia and nitrogen oxide emissions from the exhaust gases of combustion engines
JP6921261B1 (ja) * 2020-03-26 2021-08-18 株式会社キャタラー 排ガス浄化触媒装置
DE102020207311B4 (de) 2020-06-11 2022-09-08 Volkswagen Aktiengesellschaft Ammoniak-Sperrkatalysator, Abgasnachbehandlungssystem und Verfahren zur Abgasnachbehandlung
WO2022175300A1 (en) 2021-02-17 2022-08-25 Basf Corporation An ammonia oxidation catalyst and methods for its preparation
WO2023285794A1 (en) * 2021-07-12 2023-01-19 Johnson Matthey Public Limited Company Anionic pgm carboxylate assisted pgm nanoparticle synthesis for exhaust gas treatment applications

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5523086B2 (ru) 1973-03-26 1980-06-20
US4085193A (en) 1973-12-12 1978-04-18 Mitsubishi Petrochemical Co. Ltd. Catalytic process for reducing nitrogen oxides to nitrogen
FR2873447B1 (fr) * 2004-07-23 2007-09-28 Alain Michel Rousseau Analyseur automatique pluridisciplinaire pour le diagnostic in vitro
CA2661783C (en) * 2006-08-19 2014-10-14 Umicore Ag & Co. Kg Catalytically coated diesel particle filter, process for producing it and its use
US7998423B2 (en) * 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
JP5110954B2 (ja) * 2007-05-09 2012-12-26 エヌ・イーケムキャット株式会社 選択還元型触媒を用いた排気ガス浄化触媒装置並びに排気ガス浄化方法
US8636959B2 (en) * 2007-05-09 2014-01-28 N.E. Chemcat Corporation Selective catalytic reduction type catalyst, and exhaust gas purification equipment and purifying process of exhaust gas using the same
JPWO2009118868A1 (ja) * 2008-03-27 2011-07-21 イビデン株式会社 ハニカム構造体
WO2010077843A2 (en) * 2008-12-29 2010-07-08 Basf Catalysts Llc Oxidation catalyst with low co and hc light-off and systems and methods
US9440192B2 (en) * 2009-01-16 2016-09-13 Basf Corporation Diesel oxidation catalyst and use thereof in diesel and advanced combustion diesel engine systems
US8637426B2 (en) * 2009-04-08 2014-01-28 Basf Corporation Zoned catalysts for diesel applications
US8246922B2 (en) * 2009-10-02 2012-08-21 Basf Corporation Four-way diesel catalysts and methods of use
RU2593989C2 (ru) * 2010-03-11 2016-08-10 Джонсон Мэттей Паблик Лимитед Компани НОСИТЕЛИ НА ОСНОВЕ НЕУПОРЯДОЧЕННЫХ МОЛЕКУЛЯРНЫХ СИТ ДЛЯ СЕЛЕКТИВНОГО КАТАЛИТИЧЕСКОГО ВОССТАНОВЛЕНИЯ NOx
US8293182B2 (en) * 2010-05-05 2012-10-23 Basf Corporation Integrated SCR and AMOx catalyst systems
KR101476901B1 (ko) * 2010-05-05 2014-12-26 바스프 코포레이션 촉매 매연 필터 및 배출물 처리 시스템 및 방법
US8057767B1 (en) * 2010-08-10 2011-11-15 GM Global Technology Operations LLC Base metal oxides oxidation catalyst
EP3103979B1 (de) * 2010-09-13 2018-01-03 Umicore AG & Co. KG Katalysator zur entfernung von stickoxiden aus dem abgas von dieselmotoren
US9120077B2 (en) * 2010-10-01 2015-09-01 Basf Corporation Surface-coated zeolite materials for diesel oxidation applications
US8101146B2 (en) 2011-04-08 2012-01-24 Johnson Matthey Public Limited Company Catalysts for the reduction of ammonia emission from rich-burn exhaust
KR101938432B1 (ko) * 2011-06-05 2019-01-14 존슨 맛쎄이 퍼블릭 리미티드 컴파니 배기 가스를 처리하기 위한 백금족 금속(ｐｇｍ) 촉매
GB2492175B (en) * 2011-06-21 2018-06-27 Johnson Matthey Plc Exhaust system for internal combustion engine comprising catalysed filter substrate
JP5964564B2 (ja) * 2011-09-05 2016-08-03 日本碍子株式会社 ウォールフロー型排ガス浄化フィルタ
US9163218B2 (en) * 2011-10-21 2015-10-20 Guangzhou Institutes of Biomedicine and Health Chinese Academy of Sciences Method for increasing the efficiency of inducing pluripotent stem cells
JPWO2014014059A1 (ja) * 2012-07-20 2016-07-07 住友化学株式会社 ハニカムフィルタ
US8568674B1 (en) * 2012-08-10 2013-10-29 Basf Corporation Diesel oxidation catalyst composites
BR112015011998A2 (pt) 2012-11-30 2017-07-11 Johnson Matthey Plc artigo catalisador, método e sistema para o tratamento de um gás de emissão, e, método para preparar um artigo catalisador
CN105358250A (zh) * 2013-01-29 2016-02-24 庄信万丰股份有限公司 氨氧化催化剂
EP2969206A4 (en) * 2013-03-14 2016-07-06 Basf Corp CATALYTIC ARTICLE HAVING A SEPARATE LAVIS LAYER, AND METHODS OF MAKING THE SAME
KR20160036586A (ko) * 2013-07-26 2016-04-04 존슨 맛쎄이 퍼블릭 리미티드 컴파니 텅스텐/티타니아 산화 촉매
KR102227267B1 (ko) 2013-07-30 2021-03-12 존슨 맛쎄이 퍼블릭 리미티드 컴파니 암모니아 슬립 촉매

Also Published As

Publication number Publication date
JP2017514683A (ja) 2017-06-08
US20150321184A1 (en) 2015-11-12
GB201620324D0 (en) 2017-01-11
GB2544203A (en) 2017-05-10
GB2544203B (en) 2020-09-09
US9757718B2 (en) 2017-09-12
WO2015172000A1 (en) 2015-11-12
DE112015002186T5 (de) 2017-01-19
EP3140038A1 (en) 2017-03-15
CN106457216B (zh) 2020-05-12
RU2016147953A3 (ru) 2018-11-14
KR20170005455A (ko) 2017-01-13
CN106457216A (zh) 2017-02-22
JP6585079B2 (ja) 2019-10-02

Similar Documents

Publication Publication Date Title
RU2016147953A (ru) Катализатор для уменьшения проскока аммиака, содержащий платину, пропитывающую высокопористые подложки
JP2017514683A5 (ru)
US10322372B2 (en) NH3 overdosing-tolerant SCR catalyst
RU2734384C2 (ru) Система выпуска отработавших газов без дизельного катализатора окисления (doc), имеющая катализатор проскока аммиака (asc), действующий, как doc, в системе с катализатором селективного каталитического восстановления (scr) перед asc
RU2723550C2 (ru) Катализатор, предотвращающий проскок аммиака, с низким образованием h2o
RU2715653C2 (ru) Катализатор, предотвращающий проскок аммиака, спроектированный в качестве первого в системе селективного каталитического восстановления (scr)
CN107847863B (zh) 分区的排气系统
KR20180020215A (ko) 단일 또는 이중 층 암모니아 슬립 촉매
RU2017121092A (ru) Объединение scr с pna для низкотемпературного контроля выхлопных газов
CN115023285A (zh) 具有原位Pt固定的氨漏失催化剂
RU2790665C2 (ru) Каталитический нейтрализатор проскока аммиака с закреплением pt in situ
RU2020131781A (ru) Каталитический нейтрализатор проскока аммиака с закреплением pt in situ
CN114761108A (zh) 提供经改善的选择性、活性和毒性耐受性的指定区域的氨漏失催化剂
BR112017027024B1 (pt) Artigo catalítico, e, métodos para melhorar o rendimento de n2 a partir de amônia e nox em um gás de escape e para tratar gás de escape

Legal Events

Date Code Title Description
FA92 Acknowledgement of application withdrawn (lack of supplementary materials submitted)

Effective date: 20190429