RU2016116302A - Полиэтилен для литья под давлением - Google Patents

Полиэтилен для литья под давлением Download PDF

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RU2016116302A
RU2016116302A RU2016116302A RU2016116302A RU2016116302A RU 2016116302 A RU2016116302 A RU 2016116302A RU 2016116302 A RU2016116302 A RU 2016116302A RU 2016116302 A RU2016116302 A RU 2016116302A RU 2016116302 A RU2016116302 A RU 2016116302A
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polyethylene
ethylene
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polyethylene according
determined
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RU2016116302A
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RU2635568C2 (ru
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Бернд ХЁКЕР
Томас ЛИНДНЕР
Петер БИССОН
Герд МАННЕБАХ
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Базелл Полиолефин Гмбх
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/05—Bimodal or multimodal molecular weight distribution
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/13—Environmental stress cracking resistance
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7039—Tridentate ligand
    • C08F4/7067—Dianionic ligand
    • C08F4/7072—NNO
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/08—Polymer mixtures characterised by way of preparation prepared by late transition metal, i.e. Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru or Os, single site catalyst

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Claims (12)

1. Полиэтилен, содержащий сополимеры этилена с 1-алкенами или смесь гомополимеров этилена и указанными сополимерами этилена с 1-алкенами, отличающийся тем, что полиэтилен имеет: молекулярно-массовое распределение (MWD) Mw/Mn от 7 до 15; плотность от 0,942 до 0,954 г/см3, предпочтительнее от 0,942 до 0,944 г/см3, определенную в соответствии с ISO 1183 при 23°С; среднемассовую молекулярную массу Mw от 20000 до 500000 г/моль; MIE от 1,0 до 3,0 г/10 мин; MIF от 100 до 200 г/10 мин, предпочтительнее от 110 до 150 г/10 мин; а отношение MIF/MIE от 40 до 50, где MIE представляет собой скорость течения расплава при 190°C с массой груза 2,16 кг, а MIF представляет собой индекс текучести расплава при 190°С с массой груза 21,6 кг, определенных в соответствии с ISO 1133.
2. Полиэтилен по п.1, содержащий от 0,7 до 20 CH3/1000 атомов углерода, определенных способом ядерного магнитного резонанса 13С.
3. Полиэтилен по п.1, содержащий, по меньшей мере, один из типов C3-C20-альфа-олефинового мономера в количестве > 3,5% в расчете на общую массу указанного полиэтилена.
4. Полиэтилен по любому из пп. 1–3, содержащий винильную группу в количестве, по меньшей мере, равном 0,6 винильных групп/1000 атомов углерода, предпочтительнее от 0,9 до 10 винильных групп, и предпочтительно отличающийся тем, что количество полиэтилена с молекулярной массой ниже 1 млн г/моль, определенное методом ГПХ, превышает 95,5% в расчете на общую массу полиэтилена.
5. Полиэтилен по любому из пп. 1–4, имеющий значение η (вязкость) от 0,3 до 7 дл/г, отличающийся тем, что η (вязкость) представляет собой характеристическую вязкость, определенную в декалине при 135°C в соответствии с ISO 1628-1 и -3.
6. Полиэтилен по любому из пп. 1–5, получаемый в одном реакторе за одну стадию полимеризации с использованием смешанной каталитической системы, содержащей, по меньшей мере, один металлоцен.
7. Полиэтилен по п.6, получаемый путем полимеризации в присутствии состава катализатора, содержащего, по меньшей мере, два различных катализатора полимеризации с единственным активным центром, предпочтительно содержащим, по меньшей мере, один гафноцен (А) и, по меньшей мере, один компонент железа (В), включая тридентатный лиганд, несущий, по меньшей мере, два арильных радикала, предпочтительно каждый из указанных арильных радикалов несет галоген или трет-алкильный заместитель в ортоположении.
8. Полиэтилен по п.7, получаемый путем сополимеризации этилена с одним или несколькими типами C3-C20-альфа-олефинового мономера при температуре от 20 до 200°С и при давлении от 0,05 до 10 МПа.
9. Полиэтилен по любому из предыдущих пунктов, дополнительно содержащий неполимерные добавки, такие как смазывающие вещества, антиоксиданты и/или стабилизаторы.
10. Изделие, изготовленное литьем под давлением, содержащее полиэтилен по одному из предыдущих пунктов.
11. Изделие, изготовленное литьем под давлением по п.10, отличающееся тем, что представляет собой контейнер емкостью, по меньшей мере, 5 л, предпочтительнее от 5 до 100 л, более предпочтительно от 10 до 100 л.
12. Изделие, изготовленное литьем под давлением по п.10, отличающееся тем, что представляет собой внутреннюю деталь резервуара, например гаситель динамических перемещений топлива.
RU2016116302A 2013-10-15 2014-09-24 Полиэтилен для литья под давлением RU2635568C2 (ru)

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Application Number Priority Date Filing Date Title
EP13188689.7 2013-10-15
EP13188689 2013-10-15
PCT/EP2014/070319 WO2015055393A1 (en) 2013-10-15 2014-09-24 Polyethylene for injection moulding

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US (1) US9580584B2 (ru)
EP (1) EP3058026B2 (ru)
JP (1) JP6147922B2 (ru)
KR (1) KR101764555B1 (ru)
CN (2) CN110982164A (ru)
BR (1) BR112016007006B1 (ru)
MX (1) MX2016004152A (ru)
RU (1) RU2635568C2 (ru)
WO (1) WO2015055393A1 (ru)

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US20240093009A1 (en) * 2022-09-15 2024-03-21 Basell Polyolefine Gmbh Polyethylene composition for blow molding having an improved swell behavior

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BR112016007006A2 (pt) 2017-08-01
WO2015055393A1 (en) 2015-04-23
EP3058026A1 (en) 2016-08-24
RU2635568C2 (ru) 2017-11-14
KR101764555B1 (ko) 2017-08-02
JP2016533411A (ja) 2016-10-27
EP3058026B1 (en) 2017-06-28
EP3058026B2 (en) 2020-04-15
US9580584B2 (en) 2017-02-28
KR20160057487A (ko) 2016-05-23
CN110982164A (zh) 2020-04-10
JP6147922B2 (ja) 2017-06-14
MX2016004152A (es) 2016-07-07
US20160280896A1 (en) 2016-09-29
CN105579514A (zh) 2016-05-11
BR112016007006B1 (pt) 2021-11-09

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