RU2015145461A - Смешаннооксидные материалы - Google Patents

Смешаннооксидные материалы Download PDF

Info

Publication number
RU2015145461A
RU2015145461A RU2015145461A RU2015145461A RU2015145461A RU 2015145461 A RU2015145461 A RU 2015145461A RU 2015145461 A RU2015145461 A RU 2015145461A RU 2015145461 A RU2015145461 A RU 2015145461A RU 2015145461 A RU2015145461 A RU 2015145461A
Authority
RU
Russia
Prior art keywords
mixed oxide
oxide material
material according
scintillator
mixed
Prior art date
Application number
RU2015145461A
Other languages
English (en)
Other versions
RU2666431C2 (ru
RU2015145461A3 (ru
Inventor
Корнелис Рейндер РОНДА
Якобус Герардус БУРЕКАМП
Даниэла БЮТТНЕР
Анн-Мари Андрее ВАН ДОНГЕН
Херфрид Карл ВЕЧОРЕК
Сандра Йоханна Мария Паула СПОР
Силван ДЬОХАН
Вильхельмус Корнелис КЕУР
Original Assignee
Конинклейке Филипс Н.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Конинклейке Филипс Н.В. filed Critical Конинклейке Филипс Н.В.
Publication of RU2015145461A publication Critical patent/RU2015145461A/ru
Publication of RU2015145461A3 publication Critical patent/RU2015145461A3/ru
Application granted granted Critical
Publication of RU2666431C2 publication Critical patent/RU2666431C2/ru

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/77Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals
    • C09K11/7766Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing rare earth metals containing two or more rare earth metals
    • C09K11/7774Aluminates
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B6/00Apparatus or devices for radiation diagnosis; Apparatus or devices for radiation diagnosis combined with radiation therapy equipment
    • A61B6/02Arrangements for diagnosis sequentially in different planes; Stereoscopic radiation diagnosis
    • A61B6/03Computed tomography [CT]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B6/00Apparatus or devices for radiation diagnosis; Apparatus or devices for radiation diagnosis combined with radiation therapy equipment
    • A61B6/02Arrangements for diagnosis sequentially in different planes; Stereoscopic radiation diagnosis
    • A61B6/03Computed tomography [CT]
    • A61B6/032Transmission computed tomography [CT]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B6/00Apparatus or devices for radiation diagnosis; Apparatus or devices for radiation diagnosis combined with radiation therapy equipment
    • A61B6/42Arrangements for detecting radiation specially adapted for radiation diagnosis
    • A61B6/4208Arrangements for detecting radiation specially adapted for radiation diagnosis characterised by using a particular type of detector
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/62Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing gallium, indium or thallium
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/67Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing refractory metals
    • C09K11/69Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing refractory metals containing vanadium
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01TMEASUREMENT OF NUCLEAR OR X-RADIATION
    • G01T1/00Measuring X-radiation, gamma radiation, corpuscular radiation, or cosmic radiation
    • G01T1/16Measuring radiation intensity
    • G01T1/20Measuring radiation intensity with scintillation detectors
    • G01T1/2006Measuring radiation intensity with scintillation detectors using a combination of a scintillator and photodetector which measures the means radiation intensity
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01TMEASUREMENT OF NUCLEAR OR X-RADIATION
    • G01T1/00Measuring X-radiation, gamma radiation, corpuscular radiation, or cosmic radiation
    • G01T1/16Measuring radiation intensity
    • G01T1/20Measuring radiation intensity with scintillation detectors
    • G01T1/2012Measuring radiation intensity with scintillation detectors using stimulable phosphors, e.g. stimulable phosphor sheets
    • G01T1/2016Erasing of stimulable sheets, e.g. with light, heat or the like
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01TMEASUREMENT OF NUCLEAR OR X-RADIATION
    • G01T1/00Measuring X-radiation, gamma radiation, corpuscular radiation, or cosmic radiation
    • G01T1/16Measuring radiation intensity
    • G01T1/20Measuring radiation intensity with scintillation detectors
    • G01T1/202Measuring radiation intensity with scintillation detectors the detector being a crystal
    • G01T1/2023Selection of materials
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21KTECHNIQUES FOR HANDLING PARTICLES OR IONISING RADIATION NOT OTHERWISE PROVIDED FOR; IRRADIATION DEVICES; GAMMA RAY OR X-RAY MICROSCOPES
    • G21K4/00Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Medical Informatics (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Optics & Photonics (AREA)
  • Animal Behavior & Ethology (AREA)
  • Biophysics (AREA)
  • Veterinary Medicine (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Public Health (AREA)
  • Pathology (AREA)
  • Radiology & Medical Imaging (AREA)
  • Biomedical Technology (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Surgery (AREA)
  • General Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Pulmonology (AREA)
  • Theoretical Computer Science (AREA)
  • Measurement Of Radiation (AREA)
  • Luminescent Compositions (AREA)
  • Apparatus For Radiation Diagnosis (AREA)

Claims (18)

1. Смешаннооксидный материал, имеющий формулу (YwTbx)3Al5-yGayO12:Cez, в которой 0,01 ≤ w ≤ 0,99, 0,01 ≤ x ≤ 0,99, 0 ≤ y ≤ 3,5 и 0,001 ≤ z ≤ 0,10 и в которой w + x + 3×z = 1, причем смешаннооксидный материал легирован по меньшей мере 10 млн-1 V.
2. Смешаннооксидный материал по п.1, причем материал легирован от 10 до 250 млн-1 V.
3. Смешаннооксидный материал по п.1, причем 0,1 ≤ w ≤ 0,9.
4. Смешаннооксидный материал по п.1, причем 0,1 ≤ x ≤ 0,9.
5. Смешаннооксидный материал по п.1, причем 1 ≤ y ≤ 3,5.
6. Смешаннооксидный материал по п.1, причем 0,005 ≤ z ≤ 0,05.
7. Смешаннооксидный материал по п.1, причем материал представляет собой монокристаллический или поликристаллический материал.
8. Способ получения смешаннооксидного материала по п.1, содержащий следующие этапы:
а) обеспечение Y2O3, CeO2, Tb4O7, Al2O3 и Ga2O3 в пропорциях, пригодных для получения требуемого смешанного оксида,
b) пропитывание одного или нескольких из твердых веществ по этапу а) источником V в требуемом количестве,
с) объединение и измельчение твердых веществ по этапу а) и этапу b) в присутствии подходящего диспергатора с получением суспензии,
d) высушивание суспензии по этапу с) с получением смешанного порошка, и
е) спекание смешанного порошка по этапу d) при температуре по меньшей мере 1400°С в течение по меньшей мере 1 ч.
9. Способ по п.8, причем на этапе с) при объединении твердых веществ по этапу а) и этапу b) добавляют флюс.
10. Сцинтиллятор, содержащий смешаннооксидный материал по п.1.
11. Детектор ионизирующего излучения, содержащий смешаннооксидный материал по п.1 или сцинтиллятор (32; 42; 62) по п.10 в комбинации с по меньшей мере одним фотодетектором (34; 44; 64).
12. Детектор по п.11, дополнительно содержащий второй смешаннооксидный материал или сцинтиллятор, причем второй смешаннооксидный материал или второй сцинтиллятор имеет более высокую плотность, чем смешаннооксидный материал по п.1 или сцинтиллятор по п.10.
13. КТ-сканер, содержащий по меньшей мере один детектор (18; 30; 40; 60) по п.11.
RU2015145461A 2013-03-26 2014-03-21 Смешаннооксидные материалы RU2666431C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201361805261P 2013-03-26 2013-03-26
US61/805,261 2013-03-26
PCT/IB2014/060019 WO2014155256A1 (en) 2013-03-26 2014-03-21 Mixed oxide materials

Publications (3)

Publication Number Publication Date
RU2015145461A true RU2015145461A (ru) 2017-05-16
RU2015145461A3 RU2015145461A3 (ru) 2018-03-22
RU2666431C2 RU2666431C2 (ru) 2018-09-07

Family

ID=50439449

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2015145461A RU2666431C2 (ru) 2013-03-26 2014-03-21 Смешаннооксидные материалы

Country Status (6)

Country Link
US (1) US9315726B2 (ru)
EP (1) EP2898043B1 (ru)
JP (1) JP5937287B1 (ru)
CN (1) CN105073949B (ru)
RU (1) RU2666431C2 (ru)
WO (1) WO2014155256A1 (ru)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6671839B2 (ja) * 2014-10-07 2020-03-25 キヤノン株式会社 放射線撮像装置及び撮像システム
CZ2015711A3 (cs) * 2015-10-09 2016-10-19 Crytur Spol S R O Způsob zkrácení scintilační odezvy zářivých center scintilátoru a materiál scintilátoru se zkrácenou scintilační odezvou
US11000701B2 (en) * 2017-08-01 2021-05-11 Varex Imaging Corporation Dual-layer detector for soft tissue motion tracking
CN108535770B (zh) * 2018-05-09 2024-01-02 同方威视技术股份有限公司 余辉检测装置和余辉检测方法
US11624126B2 (en) 2020-06-16 2023-04-11 Ohio State Innovation Foundation Deposition of single phase beta-(AlxGa1-x)2O3 thin films with 0.28< =x<=0.7 on beta Ga2O3(100) or (−201) substrates by chemical vapor deposition
CN114296124A (zh) * 2021-12-30 2022-04-08 上海联影医疗科技股份有限公司 闪烁体余辉测试系统、方法、装置和电子设备

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2834851B2 (ja) * 1990-06-05 1998-12-14 化成オプトニクス株式会社 タングステン酸カルシウム蛍光体及び該蛍光体を用いた放射線増感紙
US6168731B1 (en) 1997-02-24 2001-01-02 Superior Micropowders Llc Cathodoluminescent phosphor powders, methods for making phosphor powders and devices incorporating same
WO1999033934A1 (fr) * 1997-12-24 1999-07-08 Hitachi Medical Corporation Luminophores et detecteurs de rayonnement et unites de tomodensitometrie formes a partir de ces luminophores
US5938974A (en) 1998-09-10 1999-08-17 Osram Sylvania Inc. Yttrium tantalate x-ray phosphors with reduced persistence
JP4683719B2 (ja) * 2000-12-21 2011-05-18 株式会社日立メディコ 酸化物蛍光体及びそれを用いた放射線検出器、並びにx線ct装置
US7008558B2 (en) * 2001-10-11 2006-03-07 General Electric Company Terbium or lutetium containing scintillator compositions having increased resistance to radiation damage
US6630077B2 (en) 2001-10-11 2003-10-07 General Electric Company Terbium- or lutetium - containing garnet phosphors and scintillators for detection of high-energy radiation
JP4269880B2 (ja) * 2003-10-17 2009-05-27 日亜化学工業株式会社 蛍光ランプ及び蛍光ランプ用蛍光体
US7449128B2 (en) * 2004-06-21 2008-11-11 General Electric Company Scintillator nanoparticles and method of making
US7252789B2 (en) 2005-03-31 2007-08-07 General Electric Company High-density scintillators for imaging system and method of making same
CN101163774B (zh) 2005-04-19 2011-09-07 皇家飞利浦电子股份有限公司 获得用于具有非常短余辉的CT的Gd2O2S:Pr的方法
RU2009106671A (ru) 2006-07-26 2010-09-10 Конинклейке Филипс Электроникс Н.В. (Nl) Керамический гранатовый материал на основе аиг, содержащий по меньшей мере один многоузельный элемент
US7569109B2 (en) * 2006-08-23 2009-08-04 General Electric Company Single crystal scintillator materials and methods for making the same
WO2012066425A2 (en) 2010-11-16 2012-05-24 Saint-Gobain Cristaux Et Detecteurs Scintillation compound including a rare earth element and a process of forming the same
JP5548629B2 (ja) 2011-01-31 2014-07-16 古河機械金属株式会社 シンチレータ用ガーネット型結晶およびこれを用いる放射線検出器
JP5311241B2 (ja) 2011-02-16 2013-10-09 日立金属株式会社 多結晶シンチレータ及びその製造方法並びに放射線検出器
CN102241982B (zh) * 2011-05-20 2014-02-19 电子科技大学 一种led荧光粉及其制备方法
JP6066608B2 (ja) * 2011-07-27 2017-01-25 キヤノン株式会社 相分離構造を有するシンチレータおよびそれを用いた放射線検出器

Also Published As

Publication number Publication date
CN105073949B (zh) 2018-05-22
EP2898043A1 (en) 2015-07-29
WO2014155256A1 (en) 2014-10-02
EP2898043B1 (en) 2016-06-01
JP5937287B1 (ja) 2016-06-22
CN105073949A (zh) 2015-11-18
RU2666431C2 (ru) 2018-09-07
US9315726B2 (en) 2016-04-19
RU2015145461A3 (ru) 2018-03-22
US20160024380A1 (en) 2016-01-28
JP2016519183A (ja) 2016-06-30

Similar Documents

Publication Publication Date Title
RU2015145461A (ru) Смешаннооксидные материалы
Guss et al. Results for aliovalent doping of CeBr3 with Ca2+
RU2018106636A (ru) Способ производства полностью керамического микроинкапсулированного ядерного топлива
RU2006146017A (ru) Флюоресцентная керамика и способ ее получения
Seeley et al. Expanded phase stability of Gd-based garnet transparent ceramic scintillators
Li et al. Effective lattice stabilization of gadolinium aluminate garnet (GdAG) via Lu3+ doping and development of highly efficient (Gd, Lu) AG: Eu3+ red phosphors
Cherepy et al. Transparent ceramic scintillators for gamma spectroscopy and MeV imaging
FR2967421B1 (fr) Materiau luminescent comprenant un silicate de terre rare dope
MX2017002950A (es) Oxido que contiene cerio y zirconio de alta porosidad.
Watanabe et al. Luminescence and scintillation properties of La-and La, Ag-doped CsPbCl3 single crystals
US20170260448A1 (en) Transparent ceramic garnet scintillator detector for positron emission tomography
RU2016146155A (ru) Люминофор и детектор излучения
ATE477509T1 (de) Schneller szintillator mit hoher lichtausbeute
WO2012170390A3 (en) Scintillation crystal including a rare earth halide, and a radiation detection system including the scintillation crystal
Siqueira et al. Effect of the processing parameters on the crystalline structure of lanthanide orthotantalates
Takeda et al. A broadband-sensitive upconverter La (Ga0. 5Sc0. 5) O3: Er, Ni, Nb for crystalline silicon solar cells
Zhang et al. Raman spectroscopic investigation of lanthana‐doped neodymium‐yttria transparent ceramics
Hui et al. Bright green emission in Ho+ 3-Yb+ 3 Co-doped Bi1/2Na1/2TiO3 ferroelectric ceramics and the optical thermometry behavior
Babin et al. Effect of the Pr3+→ Gd3+ energy transfer in multicomponent garnet single crystal scintillators
Tu et al. Influence of H3BO3 addition on mechanoluminescence property of SrAl2O4: Eu2+
Huang et al. Antisite defect in nonstoichiometric yttrium aluminum garnet: Experimental and first-principles calculation
MX2018013711A (es) Materiales de fosforo dopados con manganeso para aplicaciones de alta densidad de potencia.
Guille et al. NaLaF4: Pr3+, Yb3+, an efficient blue to near infra-red quantum cutter
RU2010137080A (ru) Таблетка ядерного топлива и способ его изготовления
Barve et al. Synthesis and TL–OSL studies in Cu activated lithium silicate