RU2012112434A - Способ получения биотоплива, где теплоту от реакций образования углерод-углеродных связей используют для проведения реакций газификации биомассы - Google Patents

Способ получения биотоплива, где теплоту от реакций образования углерод-углеродных связей используют для проведения реакций газификации биомассы Download PDF

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RU2012112434A
RU2012112434A RU2012112434/04A RU2012112434A RU2012112434A RU 2012112434 A RU2012112434 A RU 2012112434A RU 2012112434/04 A RU2012112434/04 A RU 2012112434/04A RU 2012112434 A RU2012112434 A RU 2012112434A RU 2012112434 A RU2012112434 A RU 2012112434A
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carbon
zeolite
gasification reaction
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Рэнди Д. КОРТРАЙТ
Джеймс А. ДУМЕСИК
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Висконсин Эламнай Рисерч Фаундейшн
Вайрент, Инк.
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Abstract

1. Способ получения углеводородов и кислородсодержащих углеводородов, включающий:а) проведение эндотермической реакции газификации с реагентом из биомассы при температуре менее или равной примерно 750 К с получением синтез-газа;б) проведение экзотермической реакции утилизации синтез-газа или реакции образования углерод-углеродных связей с синтез-газом стадии (а) при температуре выше или равной температуре реакции газификации, выполняемой на стадии (а), где реакция производит углеводороды или кислородсодержащие углеводороды и теплоту, ив) использование теплоты, выделяемой из реакции утилизации синтез-газа или реакции образования углерод-углеродных связей стадии (б), в эндотермической реакции газификации стадии (а).2. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации при температуре менее или равной примерно 625 К.3. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации при температуре менее или равной примерно 575 К.4. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации при температуре менее или разной примерно 550 К.5. Способ по п.1, включающий выполнение стадии (а) и стадии (б) одновременно в одном реакционном сосуде.6. Способ по п.5, включающий выполнение стадии (а) и стадии (б) с использованием более одного слоя катализатора.7. Способ по п.1, включающий выполнение стадии (а) перед стадией (б) и выполнение стадии (а) и стадии (б) последовательно в отдельных реакционных сосудах.8. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации с реагентом, включающим одно или более соед

Claims (18)

1. Способ получения углеводородов и кислородсодержащих углеводородов, включающий:
а) проведение эндотермической реакции газификации с реагентом из биомассы при температуре менее или равной примерно 750 К с получением синтез-газа;
б) проведение экзотермической реакции утилизации синтез-газа или реакции образования углерод-углеродных связей с синтез-газом стадии (а) при температуре выше или равной температуре реакции газификации, выполняемой на стадии (а), где реакция производит углеводороды или кислородсодержащие углеводороды и теплоту, и
в) использование теплоты, выделяемой из реакции утилизации синтез-газа или реакции образования углерод-углеродных связей стадии (б), в эндотермической реакции газификации стадии (а).
2. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации при температуре менее или равной примерно 625 К.
3. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации при температуре менее или равной примерно 575 К.
4. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации при температуре менее или разной примерно 550 К.
5. Способ по п.1, включающий выполнение стадии (а) и стадии (б) одновременно в одном реакционном сосуде.
6. Способ по п.5, включающий выполнение стадии (а) и стадии (б) с использованием более одного слоя катализатора.
7. Способ по п.1, включающий выполнение стадии (а) перед стадией (б) и выполнение стадии (а) и стадии (б) последовательно в отдельных реакционных сосудах.
8. Способ по п.1, в котором стадия (а) включает проведение эндотермической реакции газификации с реагентом, включающим одно или более соединений, выбираемых из группы, состоящей из полисахаридов, моносахаридов и полиолов.
9. Способ по п.8, в котором стадия (а) включает проведение эндотермической реакции газификации с реагентом, включающим глицерин.
10. Способ по п.1, в котором стадия (б) включает проведение реакции Фишера-Тропша.
11. Способ по п.1, в котором стадию (а) и стадию (б) выполняют, используя один или более катализаторов, включающих металл группы VIIIB (Fe, Со, Ni, Ru, Rh, Pd, Os, Ir и Pt).
12. Способ по п.11, в котором катализатор сплавляют, соединяют, или он дополнительно включает один или более элементов, выбираемых из группы, состоящей из Сu, К, Mn, La, Re, Zn, Si, Ag, Се, Gd, Th, Mn, Zr, Ti, Cr, V, Li, Na, Rb, Cs, Mo, Au, В и Cl, и их оксиды.
13. Способ по п.1, в котором стадию (а) и стадию (б) выполняют, используя один или более катализаторов, включающих платину, рутений, рений и их сочетания.
14. Способ по п.1, в котором стадию (а) и стадию (б) выполняют, используя один или более катализаторов, включающих металл группы VIIIB, расположенных на носителе.
15. Способ по п.14, в котором носитель выбирают из группы, состоящей из углерода и оксидов алюминия, церия, циркония и магния, и их сочетаний.
16. Способ по п.14, в котором носитель выбирают из группы, состоящей из TiO2, SiO2, Al2O3, MgO, ZrO2, ZrxTiyO2, ThO2, кизельгура, La2O3, MgCr2O4, TixSiyO2, TixZryO2,
ZnO, Cr2O3, MnO, Nb2O5, CeO2, цеолита Y, цеолита USY, цеолита ZSM-5, цеолита MCM-41, цеолита MCM-22, цеолита HZSM-5, цеолита H-BEA, цеолита HY, Fe-замещенного цеолита LTL, деламинированного цеолита ITQ-6, деламинированного цеолита ITQ-2, молекулярных сит HMS, монтмориллонита, макропористого стирол-дивинилбензола, 4-винилпридин-дивинилбензола, антрацена, карбонизированного хинолина и их сочетаний.
17. Способ по п.1, в котором стадию (а) и стадию (б) выполняют, используя по меньшей мере один катализатор, включающий платину, рутений, рений и их сочетания, и в котором катализатор размещают на носителе, выбираемом из группы, состоящей из углерода, Al2O3, CeO2, ZrO2, MgO, ZrO2 и их сочетаний.
18. Способ по п.1, в котором синтез-газ из стадии (а) вводят непосредственно в реакцию стадии (б), без какой-либо предварительной обработки.
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Families Citing this family (96)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090100752A1 (en) * 2004-06-26 2009-04-23 Sessa John P Device for converting carbonaceous matter into synthesis gas and associated methods
US7973086B1 (en) 2010-10-28 2011-07-05 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst and hydrocracking catalyst
US20090054711A1 (en) * 2005-05-04 2009-02-26 Tom Lawrence Pyrolysis Systems, Methods of Use Thereof, and Methods of Bio-Oil Transformation
US8084655B2 (en) * 2007-06-15 2011-12-27 E. I. Du Pont De Nemours And Company Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks
EP2167452A1 (en) * 2007-06-25 2010-03-31 Mcneff Research Consultants, Inc. Catalysts, systems and methods for ether synthesis
US7388034B1 (en) * 2007-07-03 2008-06-17 G.D.O. Production of methanol from the crude glycerol by-product of producing biodiesel
FI20085400A0 (fi) * 2007-11-09 2008-04-30 Upm Kymmene Oyj Menetelmä jäteveden integroidulle käsittelylle
US20090031615A1 (en) * 2007-08-01 2009-02-05 General Electric Company Integrated method for producing a fuel component from biomass and system therefor
US20090118561A1 (en) * 2007-11-02 2009-05-07 Plasma Waste Recycling, Inc. Method for Gasification of Carbonic Materials Using CO2 and Apparatus for Performing Same
FI20075794L (fi) * 2007-11-09 2009-05-10 Upm Kymmene Oyj Integroitu prosessi diesel-polttoaineen valmistamiseksi biologisesta materiaalista ja prosessiin liittyvät tuotteet, käyttötavat ja laitteisto
FR2926084B1 (fr) * 2008-01-04 2010-03-19 Inst Francais Du Petrole Procede ameliore de synthese fischer-tropsch par controle de la pression partielle d'eau dans la zone reactionnelle
US8470078B2 (en) 2008-03-12 2013-06-25 Ihi E&C International Corporation Process for removing tar from synthesis gas
EP2100972A1 (en) * 2008-03-13 2009-09-16 BIOeCON International Holding N.V. Process for converting polysaccharides in a molten salt hydrate
US20090246430A1 (en) 2008-03-28 2009-10-01 The Coca-Cola Company Bio-based polyethylene terephthalate polymer and method of making same
US20100028512A1 (en) * 2008-03-28 2010-02-04 The Coca-Cola Company Bio-based polyethylene terephthalate packaging and method of making thereof
US20090253947A1 (en) * 2008-04-06 2009-10-08 Brandvold Timothy A Production of Blended Fuel from Renewable Feedstocks
KR100970936B1 (ko) 2008-04-25 2010-07-20 한국에너지기술연구원 가스화장치를 이용한 바이오디젤 정제 잔여물의 가스화방법
EP2307524A1 (en) * 2008-06-17 2011-04-13 UPM-Kymmene Oyj An integrated process for producing diesel fuel from biological material and products and uses relating to said process
DE102008002514A1 (de) * 2008-06-18 2009-12-24 Federal-Mogul Nürnberg GmbH Kolben, Zylinderlaufbuchse oder sonstiges, den Brennraum eines Verbrennungsmotors begrenzendes Motorbauteil und Verfahren zur Herstellung derselben
WO2010002792A2 (en) 2008-06-30 2010-01-07 Kior, Inc. Co-processing solid biomass in a conventional petroleum refining process unit
FR2933391B3 (fr) * 2008-07-03 2012-02-03 Physiques Ecp Et Chimiques Conversion du glycerol en carburant liquide propre et renouvelable
WO2010033789A2 (en) 2008-09-18 2010-03-25 University Of Massachusetts Production of hydrogen, liquid fuels, and chemicals from catalytic processing of bio-oils
US7993546B2 (en) * 2008-09-23 2011-08-09 Plasma Waste Recycling, Inc. Method and apparatus for precipitation of nano-structured carbon solids
BRPI0919275A2 (pt) * 2008-09-24 2015-12-15 Fpinnovations processo para produzir dioxido de cloro, e, uso de um liquido residual contendo glicerol
US8137632B2 (en) * 2008-11-04 2012-03-20 Kior, Inc. Biomass conversion process
WO2010059223A1 (en) * 2008-11-19 2010-05-27 Global Energies, Llc Large scale green manufacturing of ethylene (ethene) using plasma
US8697893B2 (en) * 2008-12-22 2014-04-15 Sartec Corporation Systems and methods for producing fuels and fuel precursors from carbohydrates
US20100160464A1 (en) * 2008-12-24 2010-06-24 Chevron U.S.A. Inc. Zeolite Supported Cobalt Hybrid Fischer-Tropsch Catalyst
WO2010078371A2 (en) * 2008-12-29 2010-07-08 Chevron U.S.A. Inc. Preparation of cobalt-containing acidic support-based fischer-tropsch catalysts
WO2010078360A2 (en) * 2008-12-29 2010-07-08 Chevron U.S.A. Inc. Preparation of cobalt-containing fischer-tropsch catalysts
US20100187822A1 (en) * 2009-01-23 2010-07-29 Louisville Clean Energy, Llc Multi-process method of combined heat and power generation, biodiesel production, ethanol production, town gas production, methane production, and syngas production
US20100187818A1 (en) * 2009-01-23 2010-07-29 Louisville Clean Energy, Llc Multi-process method of combined heat and power generation, biodiesel production, ethanol production, town gas production and methane production
EP3130623A1 (en) 2009-03-03 2017-02-15 The Coca-Cola Company Bio-based polyethylene terephthalate packaging and method of making thereof
WO2010099626A1 (en) * 2009-03-05 2010-09-10 G4 Insights Inc. Process and system for thermochemical conversion of biomass
WO2010104467A1 (en) * 2009-03-10 2010-09-16 Agency For Science, Technology And Research Oxygenated hydrocarbon reforming
CN101555495B (zh) * 2009-05-18 2014-03-19 徐守才 乙醇导向秸秆生物炼制全封闭集成系统
ES2350076B1 (es) * 2009-05-26 2011-11-15 Fundacion Investigacion E Innovacion Para El Desarrollo Social Conversion de glicerina en metanol
US8241599B2 (en) * 2009-06-01 2012-08-14 Afton Chemical Corporation Method of using volatile organometallics as biomass gasification catalysts
US9181505B2 (en) 2009-06-03 2015-11-10 Texaco Inc. & Texaco Development Corporation Integrated biofuel process
US8440870B2 (en) * 2009-06-05 2013-05-14 The Penn State Research Foundation One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels
US8674150B2 (en) 2009-06-05 2014-03-18 Penn State Research Foundation One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels
CA2766990A1 (en) * 2009-07-01 2011-01-06 James Charles Juranitch High energy power plant fuel, and co or co2 sequestering process
US20110028631A1 (en) * 2009-08-03 2011-02-03 E. I. Du Pont De Nemours And Company Renewable Polyoxymethylene Compositions and Articles Therefrom
WO2011051902A1 (en) * 2009-10-28 2011-05-05 University Of The Witwatersrand, Johannesburg Conversion of carbon containing feedstock
WO2011060539A1 (en) 2009-11-18 2011-05-26 G4 Insights Inc. Method and system for biomass hydrogasification
EP2501788A4 (en) 2009-11-18 2013-12-04 G4 Insights Inc BY SORPTION REINFORCED METHANIZATION OF BIOMASS
ES2369684B1 (es) * 2010-01-12 2012-10-15 Fundación Investigación E Innovación Para El Desarrollo Social Proceso para la conversión de la glicerina en gas de síntesis.
BR112012032999B1 (pt) 2010-06-26 2022-11-29 Virdia, Llc Hidrolisado lignocelulósico e métodos de hidrólise ácida e desacidificação para gerar misturas de açúcar a partir de lignocelulose
IL206678A0 (en) 2010-06-28 2010-12-30 Hcl Cleantech Ltd A method for the production of fermentable sugars
CN102304380B (zh) * 2010-07-23 2014-01-29 中国科学技术大学 一种利用生物质和生物油制生物质基混合液体燃料的方法
US20150175896A1 (en) * 2010-07-26 2015-06-25 Uop Llc Methods for deoxygenating biomass-derived pyrolysis oils
IL207329A0 (en) 2010-08-01 2010-12-30 Robert Jansen A method for refining a recycle extractant and for processing a lignocellulosic material and for the production of a carbohydrate composition
IL207945A0 (en) 2010-09-02 2010-12-30 Robert Jansen Method for the production of carbohydrates
US8383871B1 (en) 2010-09-03 2013-02-26 Brian G. Sellars Method of hydrogasification of biomass to methane with low depositable tars
US8772556B2 (en) 2010-09-22 2014-07-08 Kior, Inc. Bio-oil production with optimal byproduct processing
US8362278B2 (en) 2010-10-01 2013-01-29 Chevron Phillips Chemical Company Lp Methods for the conversion of a substituted furan to a substituted pyrrole
US8519011B2 (en) 2010-10-28 2013-08-27 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using alternating layers of synthesis gas conversion catalyst, hydrocracking and hydroisomerization catalyst
JP2012116920A (ja) * 2010-11-30 2012-06-21 Polyplastics Co ポリオキシメチレン樹脂の製造方法
DE102011104006A1 (de) * 2010-12-10 2012-06-14 Süd-Chemie AG Granulierte Zeolithe mit hoher Adsorptionskapazität zur Adsorption von organischen Molekülen
KR101264021B1 (ko) 2011-03-11 2013-05-13 구자숭 바이오 매스를 이용한 바이오 오일 및 탄화물 제조 방법
US9512495B2 (en) 2011-04-07 2016-12-06 Virdia, Inc. Lignocellulose conversion processes and products
ES2944112T3 (es) 2011-04-18 2023-06-19 Upm Kymmene Corp Procedimiento catalítico para producir hidrocarburos a partir de bioaceites
US9212328B2 (en) 2011-05-02 2015-12-15 Virent, Inc. Apparatus and method for converting biomass to feedstock for biofuel and biochemical manufacturing processes
CA2839399C (en) 2011-06-15 2021-03-23 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to hydrocarbons
JP4814403B1 (ja) * 2011-06-17 2011-11-16 民朗 金辺 メタン製造装置
GB201113904D0 (en) * 2011-08-12 2011-09-28 Univ Cardiff Method of making alcohols
WO2013026752A1 (de) * 2011-08-22 2013-02-28 Smiths Heimann Gmbh Flüssiges gemisch zum testen und validieren von prüfgeräten
JP5812781B2 (ja) 2011-09-21 2015-11-17 三菱重工業株式会社 メタノールからガソリンと水素を製造する方法および装置
US9617608B2 (en) 2011-10-10 2017-04-11 Virdia, Inc. Sugar compositions
WO2013110716A1 (en) 2012-01-24 2013-08-01 Sge Scandgreen Energy Ab Process and system for producing a fuelm a carbon-containing material using a plasma gasifier
US9556391B2 (en) 2012-07-13 2017-01-31 Phillips 66 Company Method for producing renewable hydrogen from biomass derivatives using steam reforming technology
RU2497800C1 (ru) * 2012-10-09 2013-11-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Тверской государственный технический университет" Способ каталитической конверсии целлюлозы в гекситолы
US9302250B2 (en) 2012-11-15 2016-04-05 Phillips 66 Company Catalysts for renewable hydrogen production from oxygenated feedstocks
US9200209B2 (en) 2012-11-19 2015-12-01 Kior, Inc. Process of generating a renewable biofuel from a hydrotreated stream of condensed oxygenates
US9290423B2 (en) 2012-11-19 2016-03-22 Kior, Llc Process of generating a renewable biofuel from a hydrotreated stream of condensed oxygenates
US9434658B2 (en) 2013-03-06 2016-09-06 Ut-Battelle, Llc Catalytic conversion of alcohols to hydrocarbons with low benzene content
US20140275634A1 (en) 2013-03-15 2014-09-18 Gas Technologies Llc Ether Blends Via Reactive Distillation
US9255051B2 (en) 2013-03-15 2016-02-09 Gas Technologies Llc Efficiency, flexibility, and product value of a direct alkanes to oxygenates process
US9174903B2 (en) 2013-03-15 2015-11-03 Gas Technologies Llc Reactive scrubbing for upgrading product value, simplifying process operation and product handling
EP3016923B1 (en) 2013-07-02 2019-12-18 UT-Battelle, LLC Catalytic conversion of alcohols selected from n-heptanol and n-octanol to a hydrocarbon blendstock
WO2015050991A1 (en) 2013-10-01 2015-04-09 Gas Technologies L.L.C. Diesel fuel composition
CN112226466A (zh) 2015-01-07 2021-01-15 威尔迪亚公司 萃取和转化半纤维素糖的方法
CN105126901B (zh) * 2015-09-14 2017-05-03 青岛大学 一种应用在海藻液化反应的分子筛催化剂及其制备方法
US10696606B2 (en) 2016-06-09 2020-06-30 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to hydrocarbon fractions with reduced gaseous hydrocarbon content
CN108238846B (zh) * 2016-12-26 2021-07-27 高化学株式会社 一种乙醇合成用催化剂的制备方法及由此得到的催化剂和该催化剂的用途
US10239812B2 (en) 2017-04-27 2019-03-26 Sartec Corporation Systems and methods for synthesis of phenolics and ketones
CN109806908A (zh) * 2017-11-20 2019-05-28 中国科学院大连化学物理研究所 一种生物质基合成气制液体燃料的催化剂及其制备和应用
CN108285151B (zh) * 2018-01-10 2020-02-14 中科合成油技术有限公司 一种Ce同晶取代LTL分子筛及其制备方法
US10696923B2 (en) 2018-02-07 2020-06-30 Sartec Corporation Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids
US10544381B2 (en) 2018-02-07 2020-01-28 Sartec Corporation Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid
US11053181B2 (en) 2018-08-09 2021-07-06 Ut-Battelle, Llc Zeolitic catalytic conversion of alcohols to olefins
CN111495422B (zh) * 2020-04-22 2022-08-30 陕西延长石油（集团）有限责任公司 一种乙烷与丙烯共氧化制备环氧丙烷及乙酸的方法及催化剂
CN111483977B (zh) * 2020-05-06 2022-07-05 深圳市霍沃科技有限公司 一种溶于水可瞬间产生高浓度氢的复合物及其制备方法
EP4237515A1 (en) 2020-10-29 2023-09-06 Marathon Petroleum Company L.P. Systems and methods for separating water and removing solids from pre-treated and unfiltered feedstock
US11613715B1 (en) 2021-10-12 2023-03-28 Marathon Petroleum Company Lp Systems and methods of converting renewable feedstocks into intermediate hydrocarbon blend stocks and transportation fuels
CN115326971A (zh) * 2022-08-18 2022-11-11 中国核动力研究设计院 放射性有机废物蒸汽重整尾气分析系统

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE884720A (fr) * 1980-08-11 1981-02-11 Catalysts & Chem Europ Procede de reformage de methanol et dispositif mis en oeuvre
US4567205A (en) 1984-06-29 1986-01-28 Exxon Research And Engineering Co. Ruthenium catalysts, and use thereof for Fischer-Tropsch synthesis
EP0231401B1 (en) * 1984-06-29 1992-09-09 Exxon Research And Engineering Company Ruthenium-rhenium-titania catalysts, and use thereof for fischer-tropsch synthesis
IT1256800B (it) 1992-01-31 1995-12-15 Novamont Spa Procedimento per la produzione di polioli inferiori e nuovo catalizzatore a base di rutenio utilizzato in tale procedimento.
AU666752B2 (en) * 1992-06-05 1996-02-22 Battelle Memorial Institute Method for the catalytic conversion of organic materials into a product gas
US5997594A (en) * 1996-10-30 1999-12-07 Northwest Power Systems, Llc Steam reformer with internal hydrogen purification
EE04622B1 (et) 1998-07-13 2006-04-17 Norsk Hydro Asa Meetod elektrienergia, auru ja süsihappegaasi genereerimiseks süsivesiniktoorainest
NO311081B1 (no) * 1999-12-09 2001-10-08 Norske Stats Oljeselskap Optimalisert FT-syntese ved reformering og resirkulering av tail-gass fra FT-syntesen
US6291725B1 (en) 2000-03-03 2001-09-18 Board Of Trustees Operating Michigan State University Catalysts and process for hydrogenolysis of sugar alcohols to polyols
US6841085B2 (en) 2001-10-23 2005-01-11 Battelle Memorial Institute Hydrogenolysis of 6-carbon sugars and other organic compounds
US6699457B2 (en) 2001-11-29 2004-03-02 Wisconsin Alumni Research Foundation Low-temperature hydrogen production from oxygenated hydrocarbons
JP5081368B2 (ja) * 2001-11-29 2012-11-28 ウィスコンシン アルムニ リサーチ ファンデイション 酸化炭化水素からの低温水素生成
US6824682B2 (en) * 2001-12-18 2004-11-30 Best Biofuels Llc C/O Smithfield Foods, Inc. System and method for extracting energy from agricultural waste
NZ536672A (en) * 2002-05-10 2007-01-26 Wisconsin Alumni Res Found Low-temperature hydrocarbon production from oxygenated hydrocarbons
JP4745219B2 (ja) 2003-03-18 2011-08-10 ケロッグ ブラウン アンド ルート，インコーポレイテッド 水素製造用の自己熱改質装置−改質交換器の配置
WO2007027669A1 (en) * 2005-08-29 2007-03-08 Cps Biofuels, Inc. Improved biodiesel fuel, additives, and lubbricants
MY148259A (en) * 2005-12-21 2013-03-29 Virent Inc Catalysts and methods for reforming oxygenated compounds

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