CN111483977B - 一种溶于水可瞬间产生高浓度氢的复合物及其制备方法 - Google Patents
一种溶于水可瞬间产生高浓度氢的复合物及其制备方法 Download PDFInfo
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Abstract
本发明属于制氢领域，具体涉及一种溶于水可瞬间产生高浓度氢的复合物，其制备方法包括以下步骤：将氢气通入装有纳米硅粉末的密闭容器中，在温度＜‑20℃、压强＞5Mpa的低温高压条件下固化1‑2h，即得溶于水可瞬间产生高浓度氢的复合物。该复合物可在水中快速溶解，在短时间内可释放出大量氢气，获得高浓度的富氢水。将其应用于食品、日化领域，可起到抑菌消炎、抗氧化、延缓衰老、清洁排毒、提高新陈代谢、促进血液循环的作用。
Description
技术领域
本发明属于制氢领域，具体涉及一种溶于水可瞬间产生高浓度氢的复合物及其制备方法和应用。
背景技术
富氢水即富含氢气分子的水，氢气分子作为自然界中最小的分子，具有极强穿透性，可通过皮肤、粘膜弥散进入细胞。研究表明，富氢水中的氢气极易被人体吸收利用，水中可有效清除体内活性自由基，安全无毒副作用。目前市面上具有抗氧化作用的富氢水产品浓度一般为2500ppb，含氢量较低，其生产方法主要是利用镁和水反应或电解水产生氢气，存在着产氢效率不稳定、氢气容易逃逸、使用携带不方便等问题。
发明内容
本发明所要解决的技术问题是提供一种溶于水可瞬间产生高浓度氢的复合物，该复合物可在水中快速溶解，在短时间内可释放出大量氢气，获得高浓度的富氢水，具有抑菌消炎、抗氧化、延缓衰老、清洁排毒、提高新陈代谢、促进血液循环的作用。将其制成粉剂或片剂的组合物，方便携带使用，可广泛应用于食品、日化领域。
本发明的技术方案如下：
一种溶于水可瞬间产生高浓度氢的复合物的制备方法，包括以下步骤：将氢气通入装有纳米硅粉末的密闭容器中，在温度＜-20℃、压强＞5Mpa的低温高压条件下固化1-2h，即得溶于水可瞬间产生高浓度氢的复合物。
进一步的，氢气与纳米硅粉末的质量比为1:8-10。
一种所述的溶于水可瞬间产生高浓度氢的复合物的制备方法制备而成的溶于水可瞬间产生高浓度氢的复合物。
一种所述的溶于水可瞬间产生高浓度氢的复合物在食品、日化领域的应用，所述溶于水可瞬间产生高浓度氢的复合物与水反应可产生氢气。
一种组合物，包括以下重量百分比计算的组分：所述的溶于水可瞬间产生高浓度氢的复合物16-30%、珊瑚藻粉13-24%、填充剂8-16%、崩解剂3-12%、缓冲剂6-28%。
进一步的，还包括以下重量百分比计算的组分：粘合剂1.5-6%、润滑剂0.5-30%、稀释剂0.1-1%。
进一步的，所述填充剂为微晶纤维素。
进一步的，所述崩解剂为交联聚维酮、麦芽糊精中的至少一种。
进一步的，所述缓冲剂为葡萄糖、氨基酸、水杨酸中的至少一种。
进一步的，所述粘合剂为羟丙基甲基纤维素、聚乙烯醇中的至少一种；润滑剂为硬脂富马酸钠、硬脂酸镁、硅酸镁、二氧化硅中的至少一种；稀释剂为癸酸甘油酯。
本发明具有如下有益效果：
本发明溶于水可瞬间产生高浓度氢的复合物，选用的纳米硅颗粒具有粒径小、表面积大、表面活性高、孔隙疏松、密度低的特点，可提高氢气固化在其上的负载量稳定性。该复合物在水中可快速溶解，纳米硅颗粒的空隙结构大大提高了氢气的释放速度，在短时间内即可产生大量氢气，获得高浓度的富氢水。将其应用于食品、日化领域，可起到消炎抑菌、抗氧化、延缓衰老、清洁排毒、提高新陈代谢、促进血液循环的作用。
本发明组合物含有溶于水可瞬间产生高浓度氢的复合物，其剂型为粉剂或片剂，方便携带使用。选用的崩解剂可使溶于水可瞬间产生高浓度氢的复合物与水反应更充分，提高氢气的释放速率，有效解决了溶于水可瞬间产生高浓度氢的复合物在与水反应过程中的生成物形成致密的隔离层，导致未反应的材料无法继续反应的问题。通过调整缓冲剂的用量可控制反应和释放氢气的速度，获得任意浓度的富氢水，以适应不同需求和应用场景。
具体实施方式
下面结合实施例对本发明进行详细的说明，实施例仅是本发明的优选实施方式，不是对本发明的限定。
本发明3个实施例中所用的溶于水可瞬间产生高浓度氢的复合物，其制备方法包括以下步骤：将氢气通入装有纳米硅粉末的密闭容器中，氢气与纳米硅粉末的质量比为1:8-10，在温度＜-20℃、压强＞5Mpa的低温高压条件下固化1-2h，即得溶于水可瞬间产生高浓度氢的复合物。
实施例1
一种组合物，包括以下重量百分比计算的组分：所述的溶于水可瞬间产生高浓度氢的复合物30%、珊瑚藻粉19.3%、微晶纤维素7.3%、麦芽糊精8%、交联聚维酮3.6%、葡萄糖12%、氨基酸16%、癸酸甘油酯0.7%、羟丙基甲基纤维素6%、烟酰胺2.1%、维生素2.6%、生物素0.6%、泛酸钙0.8%。
实施例1组合物可作为氢饮用片应用于食品领域，将0.7g的实施例1融于200ml20℃的水中可在2min内完全溶解，所得富氢水氢含量为13000ppb，用于日常饮用，可提高新陈代谢、促进血液循环、提高免疫力。
实施例2
一种组合物，包括以下重量百分比计算的组分：所述的溶于水可瞬间产生高浓度氢的复合物23.5%、珊瑚藻粉13%、葡萄糖5%、氨基酸18%、硬脂酸镁0.9%、微晶纤维素8.5%、烟酰胺6.2%、泛酸钙7.1%、交联聚维酮6%、生物素11.8%。
实施例2组合物可作为氢美容片应用于日化领域，将0.7g的实施例3融于200ml 20℃的水中可在2.5min内完全溶解，所得富氢水氢含量为11000ppb，用于清洁肌肤，具有抗氧化、延缓衰老功效。
实施例3
一种组合物，包括以下重量百分比计算的组分：所述的溶于水可瞬间产生高浓度氢的复合物16%、珊瑚藻粉24%、微晶纤维素14%、硬脂酸镁0.7%、聚乙烯醇1.5%、硅酸镁12%、交联聚维酮8.3%、水杨酸6%、二氧化硅13.2%、硬脂富马酸钠3.5%、芳香剂0.8%。
实施例3组合物可作为氢足浴片应用于日化领域，将0.7g的实施例3融于200ml 20℃的水中可在3min内完全溶解，所得富氢水氢含量为10000ppb，用于足浴，可抑菌消炎，缓解脚气。
Claims (5)
1.一种溶于水可瞬间产生高浓度氢的组合物，其特征在于，将氢气通入装有纳米硅粉末的密闭容器中，在温度＜-20℃、压强＞5MPa的低温高压条件下固化1-2h，即得溶于水可瞬间产生高浓度氢的复合物；
上述氢气与纳米硅粉末的质量比为1:8-10；
包括以下重量百分比计算的组分，溶于水可瞬间产生高浓度氢的复合物16-30%、珊瑚藻粉13-24%、填充剂8-16%、崩解剂交联聚维酮3-12%、缓冲剂6-28%、粘合剂1.5-6%、润滑剂0.5-30%、稀释剂0.1-1%。
2.一种权利要求1所述的溶于水可瞬间产生高浓度氢的组合物在食品、日化领域的应用，所述溶于水可瞬间产生高浓度氢的复合物与水反应可产生氢气。
3.根据权利要求1所述溶于水可瞬间产生高浓度氢的组合物，其特征在于，所述填充剂为微晶纤维素。
4.根据权利要求1所述溶于水可瞬间产生高浓度氢的组合物，其特征在于，所述缓冲剂为葡萄糖、氨基酸、水杨酸中的至少一种。
5.根据权利要求1所述溶于水可瞬间产生高浓度氢的组合物，其特征在于，所述粘合剂为羟丙基甲基纤维素、聚乙烯醇中的至少一种；润滑剂为硬脂富马酸钠、硬脂酸镁、硅酸镁、二氧化硅中的至少一种；稀释剂为癸酸甘油酯。
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