RU2008143259A - METHOD FOR WATER TREATMENT OF PARAFFIN AND METHOD FOR PRODUCING BASIC FUEL - Google Patents

METHOD FOR WATER TREATMENT OF PARAFFIN AND METHOD FOR PRODUCING BASIC FUEL Download PDF

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Publication number
RU2008143259A
RU2008143259A RU2008143259/04A RU2008143259A RU2008143259A RU 2008143259 A RU2008143259 A RU 2008143259A RU 2008143259/04 A RU2008143259/04 A RU 2008143259/04A RU 2008143259 A RU2008143259 A RU 2008143259A RU 2008143259 A RU2008143259 A RU 2008143259A
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Russia
Prior art keywords
paraffin
stage
hydrocracking
feedstock
contacted
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RU2008143259/04A
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Russian (ru)
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RU2443757C2 (en
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Хироюки СЕКИ (JP)
Хироюки СЕКИ
Масахиро ХИГАСИ (JP)
Масахиро ХИГАСИ
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Ниппон Ойл Корпорейшн (Jp)
Ниппон Ойл Корпорейшн
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

1. Способ гидрообработки парафина, отличающийся тем, что он содержит ! первую стадию, на которой парафин, произведенный посредством синтеза Фишера-Тропша, используется, как исходное сырье, и парафин контактирует с катализатором, содержащим металл Группы VIII Периодической Таблицы, нанесенный на содержащий цеолит носитель в присутствии водорода для гидрокрекинга, ! вторую стадию, на которой исходное сырье временно переключается от парафина к перегнанной нефти, полученной посредством перегонки смеси, содержащей продукт гидрокрекинга парафина, полученный на первой стадии, и продукт гидрокрекинга средней перегонной фракции, произведенный посредством синтеза Фишера-Тропша, и перегнанная нефть контактирует с катализатором в условиях с температурой реакции 160-330°С в присутствии водорода для гидрокрекинга, и ! третью стадию, на которой исходное сырье переключается обратно от перегнанной нефти к парафину, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга. ! 2. Способ гидрообработки парафина по п.1, отличающийся тем, что цеолит представляет собой сверхстабильный Y-цеолит. ! 3. Способ изготовления базового топлива, отличающийся тем, что он содержит ! первую стадию, на которой парафин, произведенный посредством синтеза Фишера-Тропша, используется, как исходное сырье, и парафин контактирует с катализатором, содержащим металл Группы VIII Периодической Таблицы, нанесенный на содержащий цеолит носитель в присутствии водорода для гидрокрекинга, ! вторую стадию, на которой исходное сырье временно переключается от парафина к перегнанной нефти, полученной посредством перегонки смеси, содержаще� 1. The method of hydroprocessing paraffin, characterized in that it contains! the first stage, in which the paraffin produced by Fischer-Tropsch synthesis is used as a feedstock and the paraffin is contacted with a catalyst containing a Group VIII metal of the Periodic Table, supported on a zeolite-containing carrier in the presence of hydrogen for hydrocracking,! the second stage, in which the feedstock is temporarily switched from paraffin to distilled oil obtained by distillation of the mixture containing the paraffin hydrocracking product obtained in the first stage, and the medium distillation hydrocracking product produced by Fischer-Tropsch synthesis, and the distilled oil is contacted with the catalyst in conditions with a reaction temperature of 160-330 ° C in the presence of hydrogen for hydrocracking, and! the third stage, in which the feedstock is switched back from distilled oil to paraffin, and the paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking. ! 2. The method of hydroprocessing paraffin according to claim 1, characterized in that the zeolite is an ultra-stable Y-zeolite. ! 3. A method of manufacturing a base fuel, characterized in that it contains! the first stage, in which the paraffin produced by Fischer-Tropsch synthesis is used as a feedstock and the paraffin is contacted with a catalyst containing a Group VIII metal of the Periodic Table, supported on a zeolite-containing carrier in the presence of hydrogen for hydrocracking,! the second stage, in which the feedstock is temporarily switched from paraffin to distilled oil obtained by distillation of a mixture containing

Claims (3)

1. Способ гидрообработки парафина, отличающийся тем, что он содержит1. The method of hydroprocessing of paraffin, characterized in that it contains первую стадию, на которой парафин, произведенный посредством синтеза Фишера-Тропша, используется, как исходное сырье, и парафин контактирует с катализатором, содержащим металл Группы VIII Периодической Таблицы, нанесенный на содержащий цеолит носитель в присутствии водорода для гидрокрекинга,the first stage, in which the paraffin produced by Fischer-Tropsch synthesis is used as a feedstock and the paraffin is contacted with a catalyst containing a Group VIII metal of the Periodic Table, supported on a zeolite-containing carrier in the presence of hydrogen for hydrocracking, вторую стадию, на которой исходное сырье временно переключается от парафина к перегнанной нефти, полученной посредством перегонки смеси, содержащей продукт гидрокрекинга парафина, полученный на первой стадии, и продукт гидрокрекинга средней перегонной фракции, произведенный посредством синтеза Фишера-Тропша, и перегнанная нефть контактирует с катализатором в условиях с температурой реакции 160-330°С в присутствии водорода для гидрокрекинга, иthe second stage, in which the feedstock is temporarily switched from paraffin to distilled oil obtained by distillation of the mixture containing the paraffin hydrocracking product obtained in the first stage, and the medium distillation hydrocracking product produced by Fischer-Tropsch synthesis, and the distilled oil is contacted with the catalyst in conditions with a reaction temperature of 160-330 ° C in the presence of hydrogen for hydrocracking, and третью стадию, на которой исходное сырье переключается обратно от перегнанной нефти к парафину, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга.the third stage, in which the feedstock is switched back from distilled oil to paraffin, and the paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking. 2. Способ гидрообработки парафина по п.1, отличающийся тем, что цеолит представляет собой сверхстабильный Y-цеолит.2. The method of hydroprocessing paraffin according to claim 1, characterized in that the zeolite is an ultra-stable Y-zeolite. 3. Способ изготовления базового топлива, отличающийся тем, что он содержит3. A method of manufacturing a base fuel, characterized in that it contains первую стадию, на которой парафин, произведенный посредством синтеза Фишера-Тропша, используется, как исходное сырье, и парафин контактирует с катализатором, содержащим металл Группы VIII Периодической Таблицы, нанесенный на содержащий цеолит носитель в присутствии водорода для гидрокрекинга,the first stage, in which the paraffin produced by Fischer-Tropsch synthesis is used as a feedstock and the paraffin is contacted with a catalyst containing a Group VIII metal of the Periodic Table, supported on a zeolite-containing carrier in the presence of hydrogen for hydrocracking, вторую стадию, на которой исходное сырье временно переключается от парафина к перегнанной нефти, полученной посредством перегонки смеси, содержащей продукт гидрокрекинга парафина, полученный на первой стадии, и продукт гидрокрекинга средней перегонной фракции, произведенный посредством синтеза Фишера-Тропша, и перегнанная нефть контактирует с катализатором в условиях температуры реакции 160-330°С в присутствии водорода для гидрокрекинга,the second stage, in which the feedstock is temporarily switched from paraffin to distilled oil obtained by distillation of the mixture containing the paraffin hydrocracking product obtained in the first stage, and the medium distillation hydrocracking product produced by Fischer-Tropsch synthesis, and the distilled oil is contacted with the catalyst under conditions of a reaction temperature of 160-330 ° C in the presence of hydrogen for hydrocracking, третью стадию, на которой исходное сырье переключается обратно от перегнанной нефти к парафину, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, иa third stage in which the feedstock is switched back from the distilled oil to paraffin, and the paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking, and четвертую стадию, на которой средняя перегонная фракция получается из обработанного продукта, полученного на стадиях от первой до третьей. the fourth stage, in which the average distillation fraction is obtained from the processed product obtained in stages from the first to the third.
RU2008143259/04A 2006-03-31 2007-03-01 Paraffin hydrotreatment method and base fuel production method RU2443757C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-100177 2006-03-31
JP2006100177A JP4714066B2 (en) 2006-03-31 2006-03-31 Method for hydrotreating wax

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RU2008143259A true RU2008143259A (en) 2010-05-10
RU2443757C2 RU2443757C2 (en) 2012-02-27

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JP (1) JP4714066B2 (en)
CN (1) CN101410487B (en)
AU (1) AU2007232010B2 (en)
MY (1) MY146925A (en)
RU (1) RU2443757C2 (en)
WO (1) WO2007113962A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5737981B2 (en) 2011-02-04 2015-06-17 独立行政法人石油天然ガス・金属鉱物資源機構 Method for producing hydrocarbon oil
MY167590A (en) * 2012-03-30 2018-09-20 Jx Nippon Oil & Energy Corp Method for producing lubricant base oil

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2723946A (en) * 1950-05-29 1955-11-15 Universal Oil Prod Co Hydrocarbon conversion process
US3158563A (en) * 1962-03-27 1964-11-24 Standard Oil Co Process for rejuvenation of hydrocracking catalysts
US3376218A (en) * 1965-03-17 1968-04-02 Standard Oil Co Refining of lubricating oil and reactivation of the catalyst
JPS5670840A (en) * 1979-11-12 1981-06-13 Chiyoda Chem Eng & Constr Co Ltd Method of removing carbonaceous substances deposited on catalyst
GB9119504D0 (en) * 1991-09-12 1991-10-23 Shell Int Research Process for the preparation of naphtha
MY139353A (en) * 2001-03-05 2009-09-30 Shell Int Research Process to prepare a lubricating base oil and a gas oil
US6583186B2 (en) * 2001-04-04 2003-06-24 Chevron U.S.A. Inc. Method for upgrading Fischer-Tropsch wax using split-feed hydrocracking/hydrotreating
WO2004028688A1 (en) * 2002-09-24 2004-04-08 Nippon Oil Corporation Hydrocracking catalyst and process for production of liquid hydrocarbons
US7150823B2 (en) * 2003-07-02 2006-12-19 Chevron U.S.A. Inc. Catalytic filtering of a Fischer-Tropsch derived hydrocarbon stream

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MY146925A (en) 2012-10-15
AU2007232010A1 (en) 2007-10-11
AU2007232010B2 (en) 2011-09-01
RU2443757C2 (en) 2012-02-27
WO2007113962A1 (en) 2007-10-11
JP4714066B2 (en) 2011-06-29
CN101410487A (en) 2009-04-15
CN101410487B (en) 2012-06-27
JP2007270060A (en) 2007-10-18

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