RU2008135960A - PARAFFIN HYDROGENIZATION PROCESS AND FUEL BASIS PRODUCTION PROCESS - Google Patents

PARAFFIN HYDROGENIZATION PROCESS AND FUEL BASIS PRODUCTION PROCESS Download PDF

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Publication number
RU2008135960A
RU2008135960A RU2008135960/04A RU2008135960A RU2008135960A RU 2008135960 A RU2008135960 A RU 2008135960A RU 2008135960/04 A RU2008135960/04 A RU 2008135960/04A RU 2008135960 A RU2008135960 A RU 2008135960A RU 2008135960 A RU2008135960 A RU 2008135960A
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Russia
Prior art keywords
paraffin
catalyst
stage
hydrocracking
contacted
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RU2008135960/04A
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Russian (ru)
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RU2425092C2 (en
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Хироюки СЕКИ (JP)
Хироюки СЕКИ
Масахиро ХИГАСИ (JP)
Масахиро ХИГАСИ
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Ниппон Ойл Корпорейшн (Jp)
Ниппон Ойл Корпорейшн
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/06—Gasoil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

1. Способ гидроочистки парафина, отличающийся включением ! первого этапа, на котором парафин с содержанием С16 или выше нормальных парафинов 70 мас.% или больше используется в качестве исходного материала, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, катализатора, состоящего из металла VIII группы Периодической Таблицы, помещенного на носитель, содержащий аморфную твердую кислоту, ! второго этапа, на котором сырьевой материал временно переводится из парафина в легкий парафин с содержанием С9-21 парафинов 60 мас.% или больше, и легкий парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, и ! третьего этапа, на котором сырьевой материал переводится из легкого парафина в парафин, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга. ! 2. Способ гидроочистки парафина по п.1, отличающийся тем, что парафин производится синтезом Фишера-Тропша. ! 3. Способ гидроочистки парафина по п.1, отличающийся тем, что легкий парафин получается синтезом Фишера-Тропша. ! 4. Способ гидроочистки парафина по любому из пп.1-3, отличающийся тем, что второй этап проводится при реакционной температуре 150-320°С. ! 5. Способ получения материала топливной основы, отличающийся тем, что включает первый этап, на котором парафин с содержанием С16 или выше нормальных парафинов 70 мас.% или больше используется как сырьевой материал, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, катализатор, состоящий из металла VIII группы Периодической Таблицы, помещенного на I носитель, содержащий аморфную твердую кислоту, второй этап, на котором сырьевой мате1. The method of hydrotreating paraffin, characterized in inclusion! the first stage, in which paraffin with a content of C16 or higher of normal paraffins 70 wt.% or more is used as a starting material, and the paraffin is contacted with a catalyst in the presence of hydrogen for hydrocracking, a catalyst consisting of a metal of group VIII of the Periodic Table placed on a carrier, containing amorphous solid acid,! the second stage, in which the raw material is temporarily transferred from paraffin to light paraffin with a content of C9-21 paraffins of 60 wt.% or more, and light paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking, and! the third stage, in which the raw material is transferred from light paraffin to paraffin, and the paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking. ! 2. The method of hydrotreating paraffin according to claim 1, characterized in that the paraffin is produced by Fischer-Tropsch synthesis. ! 3. The method of hydrotreating paraffin according to claim 1, characterized in that the light paraffin is obtained by Fischer-Tropsch synthesis. ! 4. The method of hydrotreating paraffin according to any one of claims 1 to 3, characterized in that the second stage is carried out at a reaction temperature of 150-320 ° C. ! 5. A method of obtaining a fuel-based material, characterized in that it includes a first step in which paraffin with a content of C16 or higher of normal paraffins is used by weight of 70 wt.% Or more, and the paraffin is contacted with a catalyst in the presence of hydrogen for hydrocracking, a catalyst, consisting of a metal of group VIII of the Periodic Table placed on carrier I containing amorphous solid acid, the second stage, in which the raw material

Claims (5)

1. Способ гидроочистки парафина, отличающийся включением1. The method of hydrotreating paraffin, characterized by the inclusion первого этапа, на котором парафин с содержанием С16 или выше нормальных парафинов 70 мас.% или больше используется в качестве исходного материала, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, катализатора, состоящего из металла VIII группы Периодической Таблицы, помещенного на носитель, содержащий аморфную твердую кислоту,the first stage, in which paraffin with a content of C16 or higher of normal paraffins 70 wt.% or more is used as a starting material, and the paraffin is contacted with a catalyst in the presence of hydrogen for hydrocracking, a catalyst consisting of a metal of group VIII of the Periodic Table placed on a carrier, containing amorphous solid acid, второго этапа, на котором сырьевой материал временно переводится из парафина в легкий парафин с содержанием С9-21 парафинов 60 мас.% или больше, и легкий парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, иthe second stage, in which the raw material is temporarily transferred from paraffin to light paraffin with a C9-21 content of paraffins of 60 wt.% or more, and light paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking, and третьего этапа, на котором сырьевой материал переводится из легкого парафина в парафин, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга.the third stage, in which the raw material is transferred from light paraffin to paraffin, and the paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking. 2. Способ гидроочистки парафина по п.1, отличающийся тем, что парафин производится синтезом Фишера-Тропша.2. The method of hydrotreating paraffin according to claim 1, characterized in that the paraffin is produced by Fischer-Tropsch synthesis. 3. Способ гидроочистки парафина по п.1, отличающийся тем, что легкий парафин получается синтезом Фишера-Тропша.3. The method of hydrotreating paraffin according to claim 1, characterized in that the light paraffin is obtained by Fischer-Tropsch synthesis. 4. Способ гидроочистки парафина по любому из пп.1-3, отличающийся тем, что второй этап проводится при реакционной температуре 150-320°С.4. The method of hydrotreating paraffin according to any one of claims 1 to 3, characterized in that the second stage is carried out at a reaction temperature of 150-320 ° C. 5. Способ получения материала топливной основы, отличающийся тем, что включает первый этап, на котором парафин с содержанием С16 или выше нормальных парафинов 70 мас.% или больше используется как сырьевой материал, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, катализатор, состоящий из металла VIII группы Периодической Таблицы, помещенного на I носитель, содержащий аморфную твердую кислоту, второй этап, на котором сырьевой материал временно переводится из парафина в легкий парафин с содержанием С9-21 парафинов 60 мас.% или больше, и легкий парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, третий этап, на котором сырьевой материал переводится из легкого парафина в парафин, и парафин контактирует с катализатором в присутствии водорода для гидрокрекинга, и четвертый этап, на котором из обработанного продукта, получаемого на третьем этапе, получается среднедистиллятная фракция. 5. A method of obtaining a fuel-based material, characterized in that it includes a first step in which paraffin with a content of C16 or higher of normal paraffins is used by weight of 70 wt.% Or more, and the paraffin is contacted with a catalyst in the presence of hydrogen for hydrocracking, a catalyst, consisting of a metal of group VIII of the Periodic Table placed on carrier I containing amorphous solid acid, the second stage, in which the raw material is temporarily transferred from paraffin to light paraffin containing C9-21 paraffino 60 wt.% Or more, and light paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking, a third step in which the raw material is transferred from light paraffin to paraffin, and paraffin is contacted with the catalyst in the presence of hydrogen for hydrocracking, and a fourth step, in which from the processed product obtained in the third stage, the middle distillate fraction is obtained.
RU2008135960/04A 2006-02-07 2007-02-05 Paraffin hydrogenation process and process for obtaining fuel base RU2425092C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006030047A JP4714035B2 (en) 2006-02-07 2006-02-07 Method for hydrotreating wax
JP2006-030047 2006-02-07

Publications (2)

Publication Number Publication Date
RU2008135960A true RU2008135960A (en) 2010-03-20
RU2425092C2 RU2425092C2 (en) 2011-07-27

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RU2008135960/04A RU2425092C2 (en) 2006-02-07 2007-02-05 Paraffin hydrogenation process and process for obtaining fuel base

Country Status (6)

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JP (1) JP4714035B2 (en)
CN (1) CN101405372B (en)
AU (1) AU2007213211B2 (en)
MY (1) MY147199A (en)
RU (1) RU2425092C2 (en)
WO (1) WO2007091518A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5378123B2 (en) * 2009-09-07 2013-12-25 独立行政法人石油天然ガス・金属鉱物資源機構 Regeneration method of hydrotreating catalyst for Fischer-Tropsch synthetic oil
JP5737981B2 (en) * 2011-02-04 2015-06-17 独立行政法人石油天然ガス・金属鉱物資源機構 Method for producing hydrocarbon oil
KR101577617B1 (en) * 2012-03-30 2015-12-15 제이엑스 닛코닛세키에너지주식회사 Method for producing lubricant base oil

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2723946A (en) * 1950-05-29 1955-11-15 Universal Oil Prod Co Hydrocarbon conversion process
US3158563A (en) * 1962-03-27 1964-11-24 Standard Oil Co Process for rejuvenation of hydrocracking catalysts
US3376218A (en) * 1965-03-17 1968-04-02 Standard Oil Co Refining of lubricating oil and reactivation of the catalyst
JPS5670840A (en) * 1979-11-12 1981-06-13 Chiyoda Chem Eng & Constr Co Ltd Method of removing carbonaceous substances deposited on catalyst
GB9119504D0 (en) * 1991-09-12 1991-10-23 Shell Int Research Process for the preparation of naphtha
JPH05124350A (en) * 1991-11-05 1993-05-21 Mitsubishi Paper Mills Ltd Thermal recording material
JP4047206B2 (en) * 2003-03-20 2008-02-13 株式会社ジャパンエナジー Environment-friendly diesel oil and method for producing the same
US7150823B2 (en) * 2003-07-02 2006-12-19 Chevron U.S.A. Inc. Catalytic filtering of a Fischer-Tropsch derived hydrocarbon stream

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Publication number Publication date
JP4714035B2 (en) 2011-06-29
AU2007213211A1 (en) 2007-08-16
WO2007091518A1 (en) 2007-08-16
JP2007211057A (en) 2007-08-23
RU2425092C2 (en) 2011-07-27
MY147199A (en) 2012-11-14
CN101405372B (en) 2012-06-20
AU2007213211B2 (en) 2011-09-01
CN101405372A (en) 2009-04-08

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