RU2006121130A - METHOD FOR PRODUCING (MET) ACRYLIC ACID OR (MET) ACROLEIN - Google Patents

METHOD FOR PRODUCING (MET) ACRYLIC ACID OR (MET) ACROLEIN Download PDF

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Publication number
RU2006121130A
RU2006121130A RU2006121130/04A RU2006121130A RU2006121130A RU 2006121130 A RU2006121130 A RU 2006121130A RU 2006121130/04 A RU2006121130/04 A RU 2006121130/04A RU 2006121130 A RU2006121130 A RU 2006121130A RU 2006121130 A RU2006121130 A RU 2006121130A
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RU
Russia
Prior art keywords
reaction
temperature
coolant
control
acrolein
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RU2006121130/04A
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Russian (ru)
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RU2370483C2 (en
Inventor
Сухеи ЯДА (JP)
Сухеи Яда
Ясуси ОГАВА (JP)
Ясуси Огава
Йосиро СУЗУКИ (JP)
Йосиро Сузуки
Кимикацу ДЗИННО (JP)
Кимикацу Дзинно
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Мицубиси Кемикал Корпорейшн (Jp)
Мицубиси Кемикал Корпорейшн
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Claims (5)

1. Способ получения (мет)акриловой кислоты или (мет)акролеина реакцией газофазного каталитического окисления, по меньшей мере, одного окисляемого вещества, выбранного из пропилена, пропана, изобутилена и (мет)акролеина, молекулярным кислородом или газом, который содержит молекулярный кислород, с использованием многотрубного реактора, имеющего такую конструкцию, что имеется множество реакционных труб, снабженные одним (или несколькими) каталитическим слоем (каталитическими слоями) в направлении оси трубы, и снаружи указанных реакционных труб может течь теплоноситель для регулирования температуры реакции, отличающийся тем, что изменение по повышению температуры указанной реакции газофазного каталитического окисления проводится путем изменения температуры теплоносителя на впуске для регулирования температуры реакции, наряду с тем, что (1) изменение температуры теплоносителя на впуске для регулирования температуры реакции проводится не более, чем на 2°C для каждой операции изменения как таковой, и (2) когда операция изменения проводится непрерывно, операция изменения проводится так, что интервал времени от операции изменения, непосредственно предшествующей данной, составляет не менее 10 мин.1. The method of obtaining (meth) acrylic acid or (meth) acrolein by gas-phase catalytic oxidation of at least one oxidizable substance selected from propylene, propane, isobutylene and (meth) acrolein, molecular oxygen or a gas that contains molecular oxygen, using a multi-tube reactor having such a design that there are many reaction tubes provided with one (or several) catalytic layer (s) in the direction of the axis of the pipe, and outside of said reaction pipes can flow coolant to control the reaction temperature, characterized in that a change in temperature increase of the specified gas-phase catalytic oxidation reaction is carried out by changing the temperature of the coolant at the inlet to control the reaction temperature, along with the fact that (1) a change in the temperature of the coolant at the inlet to control the temperature the reaction is carried out no more than 2 ° C for each change operation as such, and (2) when the change operation is continuous, the change operation is It is found so that the time interval from the changing operation immediately prior art, is not less than 10 minutes. 2. Способ по п.1, в котором разность между максимальным значением пиковой температуры реакции каталитического слоя реакционной трубы и температурой теплоносителя на впуске для регулирования температуры реакции составляет не менее 20°C.2. The method according to claim 1, in which the difference between the maximum value of the peak reaction temperature of the catalytic layer of the reaction tube and the temperature of the coolant at the inlet to control the reaction temperature is at least 20 ° C. 3. Способ по п.1 или 2, в котором активность каждого каталитического слоя реакционной трубы регулируется путем смешивания с инертным веществом.3. The method according to claim 1 or 2, in which the activity of each catalytic layer of the reaction tube is controlled by mixing with an inert substance. 4. Способ по п.1 или 2, в котором число каталитических слоев реакционной трубы составляет от 1 до 10.4. The method according to claim 1 or 2, in which the number of catalytic layers of the reaction tube is from 1 to 10. 5. Способ по п.3, в котором число каталитических слоев реакционной трубы составляет от 1 до 10.5. The method according to claim 3, in which the number of catalytic layers of the reaction tube is from 1 to 10.
RU2006121130/04A 2003-12-15 2004-10-27 Method of producing (meth)acrylic acid or (meth)acrolein RU2370483C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003-416718 2003-12-15
JP2003416718A JP4867129B2 (en) 2003-12-15 2003-12-15 Method for producing (meth) acrylic acid or (meth) acrolein

Publications (2)

Publication Number Publication Date
RU2006121130A true RU2006121130A (en) 2007-12-27
RU2370483C2 RU2370483C2 (en) 2009-10-20

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RU2006121130/04A RU2370483C2 (en) 2003-12-15 2004-10-27 Method of producing (meth)acrylic acid or (meth)acrolein

Country Status (10)

Country Link
US (1) US20070043238A1 (en)
EP (1) EP1695954B1 (en)
JP (1) JP4867129B2 (en)
CN (1) CN100335455C (en)
AU (1) AU2004299367A1 (en)
BR (1) BRPI0417591B1 (en)
ES (1) ES2429440T3 (en)
RU (1) RU2370483C2 (en)
WO (1) WO2005058785A1 (en)
ZA (1) ZA200604662B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2621715C2 (en) * 2012-07-20 2017-06-07 Ниппон Каяку Кабусики Кайся Method of obtaining an unsaturated aldehyde and/or unsaturated carboxylic acid

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008058918A1 (en) * 2006-11-15 2008-05-22 Basf Se Process for conducting an exothermic heterogeneously catalyzed partial gas phase oxidation of an organic starting compound to an organic target compound
DE102007014603A1 (en) 2007-03-23 2008-09-25 Basf Se Method of transporting a withdrawn from a storage container liquid monomer phase in the tank of a tanker or a tanker
DE102007014606A1 (en) 2007-03-23 2008-09-25 Basf Se Process for the storage of a monomer phase which is liquid under the conditions of storage
DE102007019597A1 (en) * 2007-04-24 2008-05-15 Basf Ag Partial gas phase oxidation of acrolein to acrylic acid or methacrolein to methacrylic acid, useful e.g. as monomer to prepare polymers, comprises using a tube bundle reactor in reaction tube of a vertically arranged reaction tubes
DE102007025869A1 (en) 2007-06-01 2008-07-03 Basf Se To service tube bundle of gas-phase hydrocarbon oxidation reactor immediately prior to re-charging with fresh bed of catalyst solids, they are brushed internally
DE102007028333A1 (en) 2007-06-15 2008-12-18 Basf Se Method for introducing a subset taken from at least one production batch of annular shell catalysts K into a reaction tube of a tube bundle reactor
JP5107084B2 (en) * 2008-02-12 2012-12-26 三菱レイヨン株式会社 Method for producing methacrylic acid
JP5479803B2 (en) * 2009-07-29 2014-04-23 三菱レイヨン株式会社 Method for producing (meth) acrolein or (meth) acrylic acid
JP5852134B2 (en) * 2010-12-29 2016-02-03 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ Reactor and process for propane oxidation
EP2671862B1 (en) * 2011-02-02 2018-01-10 Nipponkayaku Kabushikikaisha Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
JP2016106082A (en) * 2015-11-24 2016-06-16 日本化薬株式会社 Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
CN109153627B (en) * 2016-04-21 2022-08-02 罗门哈斯公司 Method for using macroporous inert materials in monomer production
KR102084768B1 (en) * 2016-11-01 2020-03-04 주식회사 엘지화학 Method of producing unsaturated aldehyde and unsaturated caboxylic acid
CN107388036A (en) * 2017-08-30 2017-11-24 湖南申鑫能源科技有限公司 Energy conserving system and its application process based on compressed natural gas
WO2022250030A1 (en) * 2021-05-25 2022-12-01 三菱ケミカル株式会社 Method of producing (meth)acrolein and/or (meth)acrylic acid
CN114225884A (en) * 2021-12-29 2022-03-25 江苏吉华化工有限公司 Continuous nitration reaction device

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2056614C3 (en) 1970-11-18 1981-04-16 Basf Ag, 6700 Ludwigshafen Process for the production of acrylic acid from propylene
IN142430B (en) 1975-04-21 1977-07-09 Standard Oil Co
JPH0638918B2 (en) 1986-02-27 1994-05-25 三菱油化株式会社 Method for producing complex oxide catalyst
JPH0613096B2 (en) 1986-08-23 1994-02-23 三菱油化株式会社 Method for producing complex oxide catalyst
JPH0613097B2 (en) 1986-08-23 1994-02-23 三菱油化株式会社 Method for producing complex oxide catalyst
JPH0294239A (en) 1988-09-30 1990-04-05 Toshiba Corp Scanning type electron microscope
JP3287066B2 (en) 1993-06-28 2002-05-27 住友化学工業株式会社 Method for producing acrylic acid
DE4431957A1 (en) 1994-09-08 1995-03-16 Basf Ag Process for the catalytic gas-phase oxidation of propene to acrolein
DE4431949A1 (en) * 1994-09-08 1995-03-16 Basf Ag Process for the catalytic gas-phase oxidation of acrolein to acrylic acid
JP3559456B2 (en) * 1998-09-18 2004-09-02 株式会社日本触媒 Catalytic gas phase oxidation method and multitubular reactor
US6384274B1 (en) * 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
JP2003252820A (en) * 2001-12-27 2003-09-10 Mitsubishi Chemicals Corp Method for producing (meth)acrolein or (meth)acrylic acid
JP4163021B2 (en) * 2002-02-14 2008-10-08 三菱化学株式会社 Vapor phase catalytic oxidation method using multi-tube heat exchanger type reactor
JP4325146B2 (en) * 2002-03-11 2009-09-02 三菱化学株式会社 Method for producing (meth) acrylic acids
EP1484299B1 (en) * 2002-03-11 2014-10-15 Mitsubishi Chemical Corporation Process for catalytic vapor phase oxidation
JP4163895B2 (en) * 2002-04-30 2008-10-08 三菱化学株式会社 Method for producing (meth) acrolein and (meth) acrylic acid

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2621715C2 (en) * 2012-07-20 2017-06-07 Ниппон Каяку Кабусики Кайся Method of obtaining an unsaturated aldehyde and/or unsaturated carboxylic acid

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Publication number Publication date
ES2429440T3 (en) 2013-11-14
JP2005170909A (en) 2005-06-30
WO2005058785A1 (en) 2005-06-30
CN1697813A (en) 2005-11-16
RU2370483C2 (en) 2009-10-20
EP1695954A1 (en) 2006-08-30
AU2004299367A1 (en) 2005-06-30
EP1695954A4 (en) 2007-10-10
JP4867129B2 (en) 2012-02-01
BRPI0417591A (en) 2007-03-20
EP1695954B1 (en) 2013-09-18
ZA200604662B (en) 2007-10-31
BRPI0417591B1 (en) 2020-12-01
US20070043238A1 (en) 2007-02-22
CN100335455C (en) 2007-09-05

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