RU2003127946A - Способ получения высокочистого диизобутена - Google Patents

Способ получения высокочистого диизобутена Download PDF

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Publication number
RU2003127946A
RU2003127946A RU2003127946/04A RU2003127946A RU2003127946A RU 2003127946 A RU2003127946 A RU 2003127946A RU 2003127946/04 A RU2003127946/04 A RU 2003127946/04A RU 2003127946 A RU2003127946 A RU 2003127946A RU 2003127946 A RU2003127946 A RU 2003127946A
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RU
Russia
Prior art keywords
diisobutene
metal ions
protons
isobutene
conversion
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RU2003127946/04A
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English (en)
Inventor
Андреас БЕКМАНН (DE) БЕКМАНН Андреас (DE)
Андреас БЕКМАНН
Франц НИРЛИХ (DE) НИРЛИХ Франц (DE)
Франц НИРЛИХ
Удо ПЕТЕРС (DE) ПЕТЕРС Удо (DE)
Удо ПЕТЕРС
Вилфрид БЮШКЕН (DE) БЮШКЕН Вилфрид (DE)
Вилфрид БЮШКЕН
Лотар КЕРКЕР (DE) КЕРКЕР Лотар (DE)
Лотар КЕРКЕР
Original Assignee
Оксено Олефинхеми ГмбХ (DE) Оксено Олефинхеми ГмбХ (DE)
Оксено Олефинхеми Гмбх
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Application filed by Оксено Олефинхеми ГмбХ (DE) Оксено Олефинхеми ГмбХ (DE), Оксено Олефинхеми Гмбх filed Critical Оксено Олефинхеми ГмбХ (DE) Оксено Олефинхеми ГмбХ (DE)
Publication of RU2003127946A publication Critical patent/RU2003127946A/ru

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/28—Catalytic processes with hydrides or organic compounds with ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • C07C2531/08—Ion-exchange resins
    • C07C2531/10—Ion-exchange resins sulfonated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (11)

1. Способ получения высокочистого диизобутена посредством превращения изобутена или изобутен-содержащих смесей углеводородов на твердой кислой ионообменной смоле, отличающийся тем, что кислая ионообменная смола содержит сульфокислотные группы, протоны которых частично обмениваются на ионы металла.
2. Способ по п.1, отличающийся тем, что от 30 до 90% протонов обмениваются на ионы металла.
3. Способ по п.1 или 2, отличающийся тем, что от 50 до 80% протонов обмениваются на ионы металла.
4. Способ по одному из пп.1-3, отличающийся тем, что ионами металла являются ионы щелочных металлов.
5. Способ по одному из пп.1-4, отличающийся тем, что ионами металла являются ионы натрия.
6. Способ по одному из пп.1-5, отличающийся тем, что превращение проводят при температуре от 20 до 120°С.
7. Способ по п.6, отличающийся тем, что превращение проводят при температуре от 40 до 100°С.
8. Способ по одному из пп.1-7, отличающийся тем, что превращение проводят в жидкой фазе в области давлений от 5 до 40 бар.
9. Применение диизобутена, полученного по пп.1-8, для получения 3,5,5-триметилгексановой кислоты посредством гидроформилирования и последующего окисления.
10. Применение диизобутена, полученного по пп.1-8, для получения 3,5,5-триметилгексанола посредством гидроформилирования и последующего гидрирования.
11. Применение диизобутена, полученного по пп.1-8, в качестве алкилирующего агента для фенолов и ароматических аминов.
RU2003127946/04A 2001-02-13 2001-12-28 Способ получения высокочистого диизобутена RU2003127946A (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10106593.0 2001-02-13
DE10106593 2001-02-13
DE10113381A DE10113381A1 (de) 2001-02-13 2001-03-20 Verfahren zur Herstellung von hochreinem Diisobuten
DE10113381.2 2001-03-20

Publications (1)

Publication Number Publication Date
RU2003127946A true RU2003127946A (ru) 2005-03-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2003127946/04A RU2003127946A (ru) 2001-02-13 2001-12-28 Способ получения высокочистого диизобутена

Country Status (15)

Country Link
US (1) US7002053B2 (ru)
EP (1) EP1360160B1 (ru)
JP (1) JP4076442B2 (ru)
KR (1) KR100763216B1 (ru)
CN (1) CN1213003C (ru)
AT (1) ATE425133T1 (ru)
BR (1) BR0116884A (ru)
CA (1) CA2435590C (ru)
CZ (1) CZ20032479A3 (ru)
DE (2) DE10113381A1 (ru)
ES (1) ES2322693T3 (ru)
HU (1) HUP0303274A2 (ru)
PL (1) PL362245A1 (ru)
RU (1) RU2003127946A (ru)
WO (1) WO2002064531A1 (ru)

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Publication number Priority date Publication date Assignee Title
CN110452083A (zh) * 2019-08-05 2019-11-15 中国石油天然气集团有限公司 二异丁烯的生产方法及装置

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Publication number Priority date Publication date Assignee Title
CN110452083A (zh) * 2019-08-05 2019-11-15 中国石油天然气集团有限公司 二异丁烯的生产方法及装置
CN110452083B (zh) * 2019-08-05 2021-11-30 中国石油天然气集团有限公司 二异丁烯的生产方法及装置

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Publication number Publication date
US7002053B2 (en) 2006-02-21
ATE425133T1 (de) 2009-03-15
CN1213003C (zh) 2005-08-03
EP1360160A1 (de) 2003-11-12
KR100763216B1 (ko) 2007-10-08
CA2435590C (en) 2009-06-02
CZ20032479A3 (cs) 2004-08-18
DE50114767D1 (de) 2009-04-23
CA2435590A1 (en) 2002-08-22
KR20040002865A (ko) 2004-01-07
BR0116884A (pt) 2004-06-22
JP4076442B2 (ja) 2008-04-16
WO2002064531A1 (de) 2002-08-22
EP1360160B1 (de) 2009-03-11
HUP0303274A2 (hu) 2004-01-28
JP2004529876A (ja) 2004-09-30
DE10113381A1 (de) 2002-08-14
PL362245A1 (en) 2004-10-18
US20040054246A1 (en) 2004-03-18
CN1489565A (zh) 2004-04-14
ES2322693T3 (es) 2009-06-25

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