RO92361B - PROCEDEU PENTRU POLIMERIZAREA îN SUSPENSIE A CLORURII DE VINIL - Google Patents
PROCEDEU PENTRU POLIMERIZAREA îN SUSPENSIE A CLORURII DE VINILInfo
- Publication number
- RO92361B RO92361B RO119360A RO11936085A RO92361B RO 92361 B RO92361 B RO 92361B RO 119360 A RO119360 A RO 119360A RO 11936085 A RO11936085 A RO 11936085A RO 92361 B RO92361 B RO 92361B
- Authority
- RO
- Romania
- Prior art keywords
- polymerization
- suspension
- monomer
- polyvinyl chloride
- conversion
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 229920000915 polyvinyl chloride Polymers 0.000 title 1
- 239000004800 polyvinyl chloride Substances 0.000 title 1
- 239000000725 suspension Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 239000002609 medium Substances 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000003505 polymerization initiator Substances 0.000 abstract 1
- 238000010557 suspension polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Inventia se refera la un procedeu pentru polimelizarea în suspensie a clorurii de vinil în mediu apos, continand un agent tensioactiv neionic si în prezenta unui initiator de polimerizare solubil în monomer, care sonsta în aceea ca în mediul de polimerizare se introduce o cantitate de 0,01..2 parti în greutate fata de 100 parti monomer, un agent de reticulare avand formula generala : CH2=CR-CH2-(O-CH2)P-(-O-CH2-CHME)q-(-O-CH2-CHEt)r-O-CH2-CR=CH2 în care Me reprezina o grupa metil, Et este o grupa etil, R este un atom de hidrogen sau o grupa metil, p, q si r sunt fiecare zero sau un numar întreg pozitiv, cu mentiunea ca p+q+r sa fie mai mic de 500, adaugarea facandu-se în întregime la o conversie a monomerului de 1..20% sau în portiuni, prima portiune în cantitate de 1..30% adaugandu-se înainte de începerea reactiei de polimerizare iar restul într-o a doua portiune la o conversie a monomerului de 1..20%.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13417684A JPS6114204A (ja) | 1984-06-29 | 1984-06-29 | 塩化ビニル系重合体の製造方法 |
| JP59203712A JPS6181411A (ja) | 1984-09-28 | 1984-09-28 | 塩化ビニル系重合体の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RO92361A RO92361A (ro) | 1987-09-30 |
| RO92361B true RO92361B (ro) | 1987-10-01 |
Family
ID=26468351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RO119360A RO92361B (ro) | 1984-06-29 | 1985-06-29 | PROCEDEU PENTRU POLIMERIZAREA îN SUSPENSIE A CLORURII DE VINIL |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US4694055A (ro) |
| EP (1) | EP0166430B1 (ro) |
| KR (1) | KR890002929B1 (ro) |
| BR (1) | BR8503127A (ro) |
| CA (1) | CA1250086A (ro) |
| DE (1) | DE3574258D1 (ro) |
| ES (1) | ES8700278A1 (ro) |
| HK (1) | HK71190A (ro) |
| HU (1) | HU202255B (ro) |
| MX (1) | MX164430B (ro) |
| NO (1) | NO164601C (ro) |
| NZ (1) | NZ212604A (ro) |
| PL (1) | PL254242A1 (ro) |
| PT (1) | PT80734B (ro) |
| RO (1) | RO92361B (ro) |
| YU (1) | YU108485A (ro) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6191205A (ja) * | 1984-10-12 | 1986-05-09 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| US4742085A (en) * | 1987-04-14 | 1988-05-03 | The B. F. Goodrich Company | Crosslinked porous skinless particles of PVC resin and process for producing same |
| JP2875408B2 (ja) * | 1991-04-08 | 1999-03-31 | 信越化学工業株式会社 | ビニル系重合体製造時の未反応単量体の回収方法 |
| US5347464A (en) * | 1992-09-22 | 1994-09-13 | Basic Measuring Instruments | High-pass filter for enhancing the resolution of AC power line harmonic measurements |
| US5808902A (en) * | 1996-05-23 | 1998-09-15 | Basic Measuring Instruments | Power quality transducer for use with supervisory control systems |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2772258A (en) * | 1953-08-13 | 1956-11-27 | Monsanto Chemicals | Process for polymerizing vinyl chloride |
| US2886552A (en) * | 1954-06-10 | 1959-05-12 | Diamond Alkali Co | Polymerization employing polyvinyl alkyl ethers as suspension stabilizers |
| GB1150488A (en) * | 1966-05-30 | 1969-04-30 | Shinetsu Chem Ind Co | Process for the Suspension Polymerisation of Vinyl Chloride |
| US3907730A (en) * | 1973-09-27 | 1975-09-23 | Goodrich Co B F | Resinous initiator suspension for olefinic polymerization reactions |
| JPS5427872B2 (ro) * | 1974-03-09 | 1979-09-12 | ||
| JPS5253991A (en) * | 1975-10-28 | 1977-04-30 | Nissan Chem Ind Ltd | Suspension polymerization of vinyl chloride |
| DE2911333A1 (de) * | 1979-03-22 | 1980-10-02 | Wacker Chemie Gmbh | Verfahren zur polymerisation von vinylchlorid nach dem mikrosuspensionsverfahren |
| US4360651A (en) * | 1980-05-19 | 1982-11-23 | The B. F. Goodrich Company | Process for preparing spherical and porous vinyl resin particles |
| JPH044321B2 (ro) * | 1980-05-19 | 1992-01-28 |
-
1985
- 1985-06-25 US US06/748,432 patent/US4694055A/en not_active Ceased
- 1985-06-25 EP EP85107874A patent/EP0166430B1/en not_active Expired
- 1985-06-25 DE DE8585107874T patent/DE3574258D1/de not_active Expired
- 1985-06-26 CA CA000485257A patent/CA1250086A/en not_active Expired
- 1985-06-27 ES ES544635A patent/ES8700278A1/es not_active Expired
- 1985-06-27 NO NO852581A patent/NO164601C/no unknown
- 1985-06-28 PL PL25424285A patent/PL254242A1/xx unknown
- 1985-06-28 MX MX205834A patent/MX164430B/es unknown
- 1985-06-28 YU YU01084/85A patent/YU108485A/xx unknown
- 1985-06-28 PT PT80734A patent/PT80734B/pt not_active IP Right Cessation
- 1985-06-28 KR KR1019850004646A patent/KR890002929B1/ko not_active Expired
- 1985-06-28 HU HU852547A patent/HU202255B/hu not_active IP Right Cessation
- 1985-06-28 BR BR8503127A patent/BR8503127A/pt not_active IP Right Cessation
- 1985-06-29 RO RO119360A patent/RO92361B/ro unknown
- 1985-07-01 NZ NZ212604A patent/NZ212604A/en unknown
-
1987
- 1987-12-07 US US07/129,665 patent/USRE32813E/en not_active Expired - Lifetime
-
1990
- 1990-09-13 HK HK711/90A patent/HK71190A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RO92361A (ro) | 1987-09-30 |
| MX164430B (es) | 1992-08-12 |
| CA1250086A (en) | 1989-02-14 |
| HU202255B (en) | 1991-02-28 |
| BR8503127A (pt) | 1986-03-18 |
| ES544635A0 (es) | 1986-10-16 |
| PT80734B (pt) | 1987-08-19 |
| EP0166430B1 (en) | 1989-11-15 |
| NO164601C (no) | 1990-10-24 |
| US4694055A (en) | 1987-09-15 |
| PL254242A1 (en) | 1986-06-17 |
| HK71190A (en) | 1990-09-21 |
| NO164601B (no) | 1990-07-16 |
| KR860000318A (ko) | 1986-01-28 |
| DE3574258D1 (en) | 1989-12-21 |
| EP0166430A2 (en) | 1986-01-02 |
| KR890002929B1 (ko) | 1989-08-12 |
| YU108485A (en) | 1987-06-30 |
| HUT39196A (en) | 1986-08-28 |
| EP0166430A3 (en) | 1987-01-14 |
| PT80734A (en) | 1985-12-06 |
| ES8700278A1 (es) | 1986-10-16 |
| USRE32813E (en) | 1988-12-27 |
| NO852581L (no) | 1985-12-30 |
| NZ212604A (en) | 1987-11-27 |
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