RO82088B - Procedeu de preparare a acizilor 3-aril-4-izotiazolcarboxilici - Google Patents
Procedeu de preparare a acizilor 3-aril-4-izotiazolcarboxiliciInfo
- Publication number
- RO82088B RO82088B RO105454A RO10545478A RO82088B RO 82088 B RO82088 B RO 82088B RO 105454 A RO105454 A RO 105454A RO 10545478 A RO10545478 A RO 10545478A RO 82088 B RO82088 B RO 82088B
- Authority
- RO
- Romania
- Prior art keywords
- aryl
- preparation
- general formula
- formula
- isothiazolecarboxylic
- Prior art date
Links
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- MNOALXGAYUJNKX-UHFFFAOYSA-N s-chloro chloromethanethioate Chemical compound ClSC(Cl)=O MNOALXGAYUJNKX-UHFFFAOYSA-N 0.000 abstract 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D291/00—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms
- C07D291/02—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms not condensed with other rings
- C07D291/04—Five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
- C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
- C07D261/10—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D261/18—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D275/00—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
- C07D275/02—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings
- C07D275/03—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
- C07D295/14—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D295/145—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals with the ring nitrogen atoms and the carbon atoms with three bonds to hetero atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Inventia se refera la un procedeu de preparare a acizilor 3-eril-4-izotiazolcarboxilici cu formula generala I: (vezi formula) în care X si Y reprezinta independent unul de celalalt hidrogen, halogen, alchilinferior, alcoxiinferior, trifluormetil, cian sau nitro, constînd din aceea ca se trateaza o amida cu formula generala II: (vezi formula) în care X si Y au semnificatiile indicate mai sus, cu clorura de clorcarbonilsulfenil cu formula Cl-CO-C-Cl, eventual în exces, în solutie în toluen, la temperatura cuprinsa între 40 si 110 degree C, obtinîndu-se 5-aril-1, 3,4-oxatiazol-2-ona cu formula generala III: (vezi formula)....
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/852,165 US4144047A (en) | 1977-11-16 | 1977-11-16 | 3-Aryl-4-isoxazolecarboxylic acids as plant growth regulants |
Publications (2)
Publication Number | Publication Date |
---|---|
RO82088B true RO82088B (ro) | 1983-06-30 |
RO82088A RO82088A (ro) | 1983-07-07 |
Family
ID=25312632
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RO78105454A RO82088A (ro) | 1977-11-16 | 1978-11-15 | Procedeu de preparare a acizilor 3-aril-4-izotiazolcarboxilici |
RO7895686A RO77739A (ro) | 1977-11-16 | 1978-11-15 | Compozitie de reglare a cresterii plantelor leguminoase |
RO105455A RO82968B (ro) | 1977-11-16 | 1978-11-15 | Compozitie de reglare a cresterii plantelor leguminoase |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RO7895686A RO77739A (ro) | 1977-11-16 | 1978-11-15 | Compozitie de reglare a cresterii plantelor leguminoase |
RO105455A RO82968B (ro) | 1977-11-16 | 1978-11-15 | Compozitie de reglare a cresterii plantelor leguminoase |
Country Status (8)
Country | Link |
---|---|
US (1) | US4144047A (ro) |
JP (1) | JPS5479274A (ro) |
AR (1) | AR217878A1 (ro) |
BG (1) | BG32262A3 (ro) |
BR (1) | BR7807486A (ro) |
CA (1) | CA1111670A (ro) |
RO (3) | RO82088A (ro) |
ZA (1) | ZA786424B (ro) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4602454A (en) * | 1978-05-15 | 1986-07-29 | Monsanto Company | 2,4-disubstituted-5-thiazole-carboxylic acids and derivatives |
US4437876A (en) | 1980-04-14 | 1984-03-20 | Monsanto Company | 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives |
US4336389A (en) * | 1978-05-15 | 1982-06-22 | Monsanto Company | 2-Substituted-4-aryl-5-thiazolecarboxylic acids and their derivatives as safening agents |
US4437875A (en) | 1980-04-14 | 1984-03-20 | Monsanto Company | 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives |
US4602937A (en) * | 1978-05-15 | 1986-07-29 | Monsanto Company | 2,4-Disubstituted-5-thiazole-carboxylic acids and derivatives |
US4243406A (en) * | 1978-12-26 | 1981-01-06 | Monsanto Company | 5-Aryl-4-isoxazolecarboxylate-safening agents |
US4251261A (en) * | 1979-04-09 | 1981-02-17 | Monsanto Company | 2-Chloro-4-trifluoromethyl-5-thiazolecarboxylic acids and derivatives |
US4380465A (en) * | 1979-04-27 | 1983-04-19 | Monsanto Company | 5-Aryl-4-isothiazolecarboxylic acids and derivatives |
US4544752A (en) * | 1980-09-22 | 1985-10-01 | Eli Lilly And Company | 3-Aryl-5-isothiazolecarboxylic acids and related compounds used to lower uric acid levels |
US4586948A (en) * | 1981-04-22 | 1986-05-06 | Monsanto Company | 2,4-disubstituted-5-thiazole-carboxylic acids and derivatives |
DE3133418A1 (de) * | 1981-08-24 | 1983-03-10 | Basf Ag, 6700 Ludwigshafen | Thiazolyl- und isothiazolylcarbonsaeureanilide, verfahren zu ihrer herstellung und ihre verwendung als fungizide |
DE4026018A1 (de) * | 1990-08-17 | 1992-02-20 | Hoechst Ag | Isoxazoline oder isothiazoline enthaltende pflanzenschuetzende mittel und neue isoxazoline und isothiazoline |
DE59905341D1 (de) * | 1998-08-04 | 2003-06-05 | Ciba Sc Holding Ag | Verwendung von Oxathiazolonen als Mikrobizide |
JP2003533517A (ja) * | 2000-05-15 | 2003-11-11 | ビーエーエスエフ アクチェンゲゼルシャフト | 3−アリールイソチアゾール類及びその除草剤としての使用 |
GB0823000D0 (en) * | 2008-12-17 | 2009-01-28 | Syngenta Participations Ag | Isothiazole and pyrazole derivatives with plant growth regulating properties |
US8962883B2 (en) | 2009-05-29 | 2015-02-24 | Cargill, Incorporated | Levulinic acid from fungal biomass |
CN103140483B (zh) | 2010-07-15 | 2015-06-24 | 拜耳知识产权有限责任公司 | 作为杀虫剂的新杂环化合物 |
CA2822296A1 (en) | 2010-12-21 | 2012-06-28 | Bayer Cropscience Lp | Sandpaper mutants of bacillus and methods of their use to enhance plant growth, promote plant health and control diseases and pests |
EP2755485A1 (en) | 2011-09-12 | 2014-07-23 | Bayer Cropscience LP | Methods of enhancing health and/or promoting growth of a plant and/or of improving fruit ripening |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3155678A (en) * | 1961-11-14 | 1964-11-03 | Du Pont | Certain isothiazole compounds and their production |
US3403209A (en) * | 1965-06-08 | 1968-09-24 | Fmc Corp | Fungicidal and bactericidal compositions and methods employing isothiazolecarboxylate |
US3341518A (en) * | 1965-06-23 | 1967-09-12 | Bristol Banyu Res Inst Ltd | 6-[5'-loweralkyl-3'-phenylisothiazole-4'-carboxamido]penicillanic acids and salts thereof |
US3466296A (en) * | 1967-05-16 | 1969-09-09 | American Home Prod | Process for the preparation of alkyl 3,5-disubstituted-isoxazole-4-carboxylates |
US3699115A (en) * | 1969-11-25 | 1972-10-17 | Monsanto Co | 3-aryl-isothiazole-4,5-dicarboxylates |
-
1977
- 1977-11-16 US US05/852,165 patent/US4144047A/en not_active Expired - Lifetime
-
1978
- 1978-10-27 CA CA314,529A patent/CA1111670A/en not_active Expired
- 1978-11-14 BR BR7807486A patent/BR7807486A/pt unknown
- 1978-11-15 ZA ZA00786424A patent/ZA786424B/xx unknown
- 1978-11-15 RO RO78105454A patent/RO82088A/ro unknown
- 1978-11-15 AR AR274447A patent/AR217878A1/es active
- 1978-11-15 RO RO7895686A patent/RO77739A/ro unknown
- 1978-11-15 BG BG041400A patent/BG32262A3/xx unknown
- 1978-11-15 RO RO105455A patent/RO82968B/ro unknown
- 1978-11-15 JP JP13995378A patent/JPS5479274A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
JPS5479274A (en) | 1979-06-25 |
RO77739A (ro) | 1982-02-01 |
BR7807486A (pt) | 1979-07-24 |
RO82968B (ro) | 1984-01-30 |
BG32262A3 (en) | 1982-06-15 |
AR217878A1 (es) | 1980-04-30 |
CA1111670A (en) | 1981-11-03 |
US4144047A (en) | 1979-03-13 |
ZA786424B (en) | 1979-10-31 |
RO82088A (ro) | 1983-07-07 |
RO82968A (ro) | 1984-01-14 |
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