PL95234B1 - - Google Patents
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- Publication number
- PL95234B1 PL95234B1 PL1972159067A PL15906772A PL95234B1 PL 95234 B1 PL95234 B1 PL 95234B1 PL 1972159067 A PL1972159067 A PL 1972159067A PL 15906772 A PL15906772 A PL 15906772A PL 95234 B1 PL95234 B1 PL 95234B1
- Authority
- PL
- Poland
- Prior art keywords
- catalyst
- isoprene
- temperature
- molecular weight
- weight
- Prior art date
Links
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 16
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 claims description 11
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 9
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 230000003197 catalytic effect Effects 0.000 claims description 6
- -1 inorganic acid halide Chemical class 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 4
- 229940050176 methyl chloride Drugs 0.000 claims description 4
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 239000003054 catalyst Substances 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 6
- 229920005549 butyl rubber Polymers 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229960003750 ethyl chloride Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 1
- OIXYALOFXKMPMT-UHFFFAOYSA-N 3-(chloromethylidene)pentane Chemical group CCC(CC)=CCl OIXYALOFXKMPMT-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 101150095461 Tfrc gene Proteins 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000010538 cationic polymerization reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/14—Monomers containing five or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
- C08F210/12—Isobutene with conjugated diolefins, e.g. butyl rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT31722/71A IT946098B (it) | 1971-11-26 | 1971-11-26 | Procedimento per la produzione di polimeri e copolimeri dell isobuti lene e composti ottenuti |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL95234B1 true PL95234B1 (en:Method) | 1977-09-30 |
Family
ID=11234269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1972159067A PL95234B1 (en:Method) | 1971-11-26 | 1972-11-24 |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US3850896A (en:Method) |
| JP (1) | JPS543505B2 (en:Method) |
| AT (1) | AT316861B (en:Method) |
| AU (1) | AU476644B2 (en:Method) |
| BE (1) | BE791407A (en:Method) |
| CA (1) | CA1011499A (en:Method) |
| CH (1) | CH562267A5 (en:Method) |
| CS (1) | CS182775B2 (en:Method) |
| DD (1) | DD103648A5 (en:Method) |
| DE (1) | DE2257466A1 (en:Method) |
| FR (1) | FR2160849B1 (en:Method) |
| GB (1) | GB1407415A (en:Method) |
| IT (1) | IT946098B (en:Method) |
| LU (1) | LU66537A1 (en:Method) |
| NL (1) | NL154227B (en:Method) |
| PL (1) | PL95234B1 (en:Method) |
| RO (1) | RO63402A (en:Method) |
| ZA (1) | ZA727773B (en:Method) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4107417A (en) * | 1971-11-26 | 1978-08-15 | Snamprogetti, S.P.A. | Process for the production of polymers and copolymers of isobutylene |
| US3965078A (en) * | 1971-11-26 | 1976-06-22 | Snam Progetti S.P.A. | Procedure for the production of polymers and copolymers of isobutylene |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT556483A (en:Method) * | 1955-07-16 | |||
| BE604435A (en:Method) * | 1960-06-03 |
-
0
- BE BE791407D patent/BE791407A/xx unknown
-
1971
- 1971-11-26 IT IT31722/71A patent/IT946098B/it active
-
1972
- 1972-11-01 AU AU48388/72A patent/AU476644B2/en not_active Expired
- 1972-11-01 ZA ZA727773A patent/ZA727773B/xx unknown
- 1972-11-08 RO RO7200072748A patent/RO63402A/ro unknown
- 1972-11-14 FR FR7240268A patent/FR2160849B1/fr not_active Expired
- 1972-11-15 US US00306902A patent/US3850896A/en not_active Expired - Lifetime
- 1972-11-16 CS CS7200007780A patent/CS182775B2/cs unknown
- 1972-11-20 CH CH1684372A patent/CH562267A5/xx not_active IP Right Cessation
- 1972-11-21 NL NL727215723A patent/NL154227B/xx unknown
- 1972-11-23 DE DE2257466A patent/DE2257466A1/de active Pending
- 1972-11-24 LU LU66537A patent/LU66537A1/xx unknown
- 1972-11-24 AT AT1005372A patent/AT316861B/de not_active IP Right Cessation
- 1972-11-24 PL PL1972159067A patent/PL95234B1/pl unknown
- 1972-11-24 CA CA157,504A patent/CA1011499A/en not_active Expired
- 1972-11-24 GB GB5452472A patent/GB1407415A/en not_active Expired
- 1972-11-24 DD DD167137A patent/DD103648A5/xx unknown
- 1972-11-27 JP JP11812872A patent/JPS543505B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL7215723A (en:Method) | 1973-05-29 |
| BE791407A (fr) | 1973-03-01 |
| US3850896A (en) | 1974-11-26 |
| AU476644B2 (en) | 1976-09-30 |
| DD103648A5 (en:Method) | 1974-02-05 |
| CA1011499A (en) | 1977-05-31 |
| AT316861B (de) | 1974-07-25 |
| NL154227B (nl) | 1977-08-15 |
| JPS543505B2 (en:Method) | 1979-02-23 |
| CS182775B2 (en) | 1978-05-31 |
| AU4838872A (en) | 1974-05-02 |
| RO63402A (fr) | 1978-05-15 |
| DE2257466A1 (de) | 1973-05-30 |
| CH562267A5 (en:Method) | 1975-05-30 |
| GB1407415A (en) | 1975-09-24 |
| FR2160849B1 (en:Method) | 1975-09-12 |
| FR2160849A1 (en:Method) | 1973-07-06 |
| ZA727773B (en) | 1973-09-26 |
| LU66537A1 (en:Method) | 1973-02-01 |
| JPS4860786A (en:Method) | 1973-08-25 |
| IT946098B (it) | 1973-05-21 |
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