PL825B1 - - Google Patents
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- Publication number
- PL825B1 PL825B1 PL825A PL82522A PL825B1 PL 825 B1 PL825 B1 PL 825B1 PL 825 A PL825 A PL 825A PL 82522 A PL82522 A PL 82522A PL 825 B1 PL825 B1 PL 825B1
- Authority
- PL
- Poland
- Prior art keywords
- action
- dioxydiminoarsenobenzole
- stable base
- obtaining
- soluble stable
- Prior art date
Links
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 6
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 2
- 239000008101 lactose Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 6
- 238000006386 neutralization reaction Methods 0.000 claims 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- JIADKDBYMRAFHF-UHFFFAOYSA-N [As].C1=CC=CC=C1 Chemical compound [As].C1=CC=CC=C1 JIADKDBYMRAFHF-UHFFFAOYSA-N 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
Celem stosowania dwuoksydwuamino- areenobenzolu w roztworze obojetnym wpro--* wadzano do .niego lancuchy boczne w rodza¬ ju CH2—SO* Na, laczac bezposrednio z azo¬ tem1. Zwiazki te sa nader nietrwale i nie mozna przechowywac ich w roztworze. Usu¬ wa sie te niedogodnosc przez zastapieinie lancucha lub lancuchów w rodzaju CH2 SO Na reszta jakiegokolwiek: badz cukru cdtle- niajacego, np. glukoza lub laktoza.Zwiazek tak otrzymany rozpuszcza sie w wodzie, jest silnie odtleniajacy i posiada charakter kwasny dzieki temu, ze dzialai jak fenol wolny. Mozna usunac te wlasnosc dzia¬ laniem silnej zasady (lugu sodowego) lecz korzystniej stosowac w tym celu taka zasa¬ de jak np. piperazyne. Produkt polaczenia, otrzymanego ostatecznie dzialaniem glukozy na dwuoksydwuaminoarsenobenzol, a na¬ stepnie dzialaniem piperazyny jest latwo roz¬ puszczalny i trwaly, wytrzymuje, nie roz¬ kladajac sie, temperature wyzsza; mozna go równiez doprowadzic nawet do wrzenia, w wypadku, gdy nalezy go wyjalowic (ste¬ rylizowac). PL PLFor the use of the dioxydiamine-areenobenzole in an inert solution, side chains of the CH2-SO * Na type were introduced into it by direct linking with nitrogen. These compounds are very unstable and cannot be stored in solution. This inconvenience is removed by replacing a chain or chains such as CH2 SO For the rest of any: or an oxidizing sugar, e.g. glucose or lactose. The compound thus obtained dissolves in water, is strongly deoxidizing and has an acidic character due to the fact that acts as free phenol. This property can be removed by the action of a strong base (sodium hydroxide), but more preferably a base such as, for example, piperazine is used for this purpose. The product of the combination finally obtained by the action of glucose on the dioxydiamino arsenobenzole and then by the action of piperazine is easily soluble and stable, withstands, without decomposition, the temperature is higher; it can also be brought to a boil in case it needs to be sterilized. PL PL
Claims (5)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL825B1 true PL825B1 (en) | 1924-11-29 |
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