PL56362B1 - - Google Patents

Info

Publication number

PL56362B1

PL56362B1 PL119696A PL11969667A PL56362B1 PL 56362 B1 PL56362 B1 PL 56362B1 PL 119696 A PL119696 A PL 119696A PL 11969667 A PL11969667 A PL 11969667A PL 56362 B1 PL56362 B1 PL 56362B1

Authority

PL

Poland

Prior art keywords

keto

hexonic

anion exchanger

oxidation

acid

Prior art date

1967-03-28

Links

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• 239000002253 acid Substances 0.000 claims description 13
• 239000000243 solution Substances 0.000 claims description 12
• 239000007800 oxidant agent Substances 0.000 claims description 10
• 238000007254 oxidation reaction Methods 0.000 claims description 10
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
• 150000007513 acids Chemical class 0.000 claims description 8
• 238000000034 method Methods 0.000 claims description 8
• AEMOLEFTQBMNLQ-UHFFFAOYSA-N 3,4,5,6-tetrahydroxyoxane-2-carboxylic acid Chemical compound OC1OC(C(O)=O)C(O)C(O)C1O AEMOLEFTQBMNLQ-UHFFFAOYSA-N 0.000 claims description 7
• 230000003647 oxidation Effects 0.000 claims description 7
• 150000001450 anions Chemical class 0.000 claims description 6
• HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 5
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
• 239000007864 aqueous solution Substances 0.000 claims description 4
• 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
• 239000011707 mineral Substances 0.000 claims description 4
• 150000003839 salts Chemical class 0.000 claims description 4
• 239000000908 ammonium hydroxide Substances 0.000 claims description 3
• 239000012429 reaction media Substances 0.000 claims description 3
• 125000005587 carbonate group Chemical group 0.000 claims description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
• 239000003054 catalyst Substances 0.000 description 6
• BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
• 230000001590 oxidative effect Effects 0.000 description 4
• 229910052697 platinum Inorganic materials 0.000 description 3
• 239000000047 product Substances 0.000 description 3
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
• 239000003957 anion exchange resin Substances 0.000 description 2
• 239000011668 ascorbic acid Substances 0.000 description 2
• 229960005070 ascorbic acid Drugs 0.000 description 2
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
• 238000006243 chemical reaction Methods 0.000 description 2
• 239000007795 chemical reaction product Substances 0.000 description 2
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
• 150000002500 ions Chemical class 0.000 description 2
• 238000002955 isolation Methods 0.000 description 2
• 150000002574 ketohexoses Chemical class 0.000 description 2
• 239000007788 liquid Substances 0.000 description 2
• 238000004519 manufacturing process Methods 0.000 description 2
• 238000002156 mixing Methods 0.000 description 2
• 229910052760 oxygen Inorganic materials 0.000 description 2
• 239000001301 oxygen Substances 0.000 description 2
• 239000011347 resin Substances 0.000 description 2
• 229920005989 resin Polymers 0.000 description 2
• 239000000126 substance Substances 0.000 description 2
• NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
• VBUYCZFBVCCYFD-NUNKFHFFSA-N 2-dehydro-L-idonic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)C(=O)C(O)=O VBUYCZFBVCCYFD-NUNKFHFFSA-N 0.000 description 1
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
• 102000006786 Chloride-Bicarbonate Antiporters Human genes 0.000 description 1
• 108010086832 Chloride-Bicarbonate Antiporters Proteins 0.000 description 1
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
• VBUYCZFBVCCYFD-UHFFFAOYSA-N D-arabino-2-Hexulosonic acid Natural products OCC(O)C(O)C(O)C(=O)C(O)=O VBUYCZFBVCCYFD-UHFFFAOYSA-N 0.000 description 1
• ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
• DCNMIDLYWOTSGK-SRQIZXRXSA-N D-xylo-hexos-2-ulose Chemical compound OC[C@@H](O)[C@H](O)[C@@H](O)C(=O)C=O DCNMIDLYWOTSGK-SRQIZXRXSA-N 0.000 description 1
• LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 description 1
• CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
• 229930003268 Vitamin C Natural products 0.000 description 1
• 230000004913 activation Effects 0.000 description 1
• 150000003863 ammonium salts Chemical class 0.000 description 1
• 125000000129 anionic group Chemical group 0.000 description 1
• 239000008346 aqueous phase Substances 0.000 description 1
• 235000010323 ascorbic acid Nutrition 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 229910052802 copper Inorganic materials 0.000 description 1
• 150000001879 copper Chemical class 0.000 description 1
• 239000010949 copper Substances 0.000 description 1
• 230000007423 decrease Effects 0.000 description 1
• 230000001066 destructive effect Effects 0.000 description 1
• 238000006073 displacement reaction Methods 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 238000010438 heat treatment Methods 0.000 description 1
• 239000000543 intermediate Substances 0.000 description 1
• 238000005342 ion exchange Methods 0.000 description 1
• 239000003456 ion exchange resin Substances 0.000 description 1
• 229920003303 ion-exchange polymer Polymers 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 150000001451 organic peroxides Chemical class 0.000 description 1
• 238000006864 oxidative decomposition reaction Methods 0.000 description 1
• 229910052763 palladium Inorganic materials 0.000 description 1
• 230000000737 periodic effect Effects 0.000 description 1
• 239000011591 potassium Substances 0.000 description 1
• 229910052700 potassium Inorganic materials 0.000 description 1
• 238000002360 preparation method Methods 0.000 description 1
• 230000000750 progressive effect Effects 0.000 description 1
• 239000012063 pure reaction product Substances 0.000 description 1
• 238000000746 purification Methods 0.000 description 1
• 239000011541 reaction mixture Substances 0.000 description 1
• 239000011734 sodium Substances 0.000 description 1
• 229910052708 sodium Inorganic materials 0.000 description 1
• 238000001179 sorption measurement Methods 0.000 description 1
• 239000012086 standard solution Substances 0.000 description 1
• 239000000725 suspension Substances 0.000 description 1
• 238000003786 synthesis reaction Methods 0.000 description 1
• 239000011718 vitamin C Substances 0.000 description 1
• 235000019154 vitamin C Nutrition 0.000 description 1