PL447216A1 - Sposób otrzymywania kompozytowego materiału anodowego na bazie Sb dla ogniw galwanicznych, w szczególności sodowych - Google Patents

Sposób otrzymywania kompozytowego materiału anodowego na bazie Sb dla ogniw galwanicznych, w szczególności sodowych

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Publication number
PL447216A1
PL447216A1 PL447216A PL44721623A PL447216A1 PL 447216 A1 PL447216 A1 PL 447216A1 PL 447216 A PL447216 A PL 447216A PL 44721623 A PL44721623 A PL 44721623A PL 447216 A1 PL447216 A1 PL 447216A1
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Poland
Prior art keywords
weight
sbcl3
cells
anode material
composite anode
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PL447216A
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English (en)
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PL248941B1 (pl
Inventor
Justyna Płotek
Andrzej KULKA
Janina MOLENDA
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Akademia Górniczo-Hutnicza Im.Stanisława Staszica W Krakowie
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Priority to PL447216A priority Critical patent/PL248941B1/pl
Publication of PL447216A1 publication Critical patent/PL447216A1/pl
Publication of PL248941B1 publication Critical patent/PL248941B1/pl

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H01M4/13915—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H01M4/1315—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027—Negative electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Przedmiotem zgłoszenia jest sposób otrzymywania kompozytowego materiału anodowego na bazie Sb dla ogniw galwanicznych, w szczególności sodowych, który polega na tym, że rozpuszcza się SbCl3 w glikolu etylenowym w stosunku wagowym od 1:50 do 1:100, mieszając do całkowitego rozpuszczenia SbCl3, po czym nie przerywając mieszania dodaje się dodatek węglowy w ilości od 0,5% do 8,5% wagowych w stosunku do masy SbCl3. Następnie dodaje się cynk w stosunku molowym od 1,4 do 2,3 mola Zn na 1 mol SbCl3 i mieszaninę podgrzewa się do temperatury w zakresie od 150°C do 200°C oraz miesza z prędkością obrotową w zakresie od 100 do 600 obr./min, przy ciśnieniu nie wyższym niż 150 kPa, przez okres od 2 do 12 godzin. Mieszaninę chłodzi się do temperatury pokojowej i odwirowuje się kolejno: najpierw w etanolu, następnie w roztworze HCl, a na końcu w wodzie korzystnie co najmniej dwukrotnie, a każde odwirowanie prowadzi się przez okres od 5 do 20 minut przy prędkości obrotowej od 2000 do 5000 obr./min. Uzyskany kompozytowy materiał anodowy Sb/Sb4O5Cl2/C suszy się w suszarce pod ciśnieniem atmosferycznym przez okres od 2 do 10 godzin w temperaturze od 40°C do 80°C. Udział poszczególnych składników kompozytu wynosi: Sb>50% wagowych, Sb4O5Cl2>15% wagowych, C>1% wagowego.
PL447216A 2023-12-21 2023-12-21 Sposób otrzymywania kompozytowego materiału anodowego na bazie Sb dla ogniw galwanicznych, w szczególności sodowych PL248941B1 (pl)

Priority Applications (1)

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PL447216A PL248941B1 (pl) 2023-12-21 2023-12-21 Sposób otrzymywania kompozytowego materiału anodowego na bazie Sb dla ogniw galwanicznych, w szczególności sodowych

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PL447216A PL248941B1 (pl) 2023-12-21 2023-12-21 Sposób otrzymywania kompozytowego materiału anodowego na bazie Sb dla ogniw galwanicznych, w szczególności sodowych

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PL447216A1 true PL447216A1 (pl) 2025-06-23
PL248941B1 PL248941B1 (pl) 2026-02-16

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104617281B (zh) * 2015-02-12 2017-02-01 中南大学 一种钠离子电池锑/掺氮碳纳米片负极复合材料的制备方法
CN108448072A (zh) * 2018-01-24 2018-08-24 东北电力大学 一种基于二维三氧化二锑纳米片/还原氧化石墨烯气凝胶复合电极材料的制备方法及应用
CN108767223A (zh) * 2018-05-28 2018-11-06 福州大学 一种微纳结构氯氧化锑-碳复合物锂离子电池负极材料的制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104617281B (zh) * 2015-02-12 2017-02-01 中南大学 一种钠离子电池锑/掺氮碳纳米片负极复合材料的制备方法
CN108448072A (zh) * 2018-01-24 2018-08-24 东北电力大学 一种基于二维三氧化二锑纳米片/还原氧化石墨烯气凝胶复合电极材料的制备方法及应用
CN108767223A (zh) * 2018-05-28 2018-11-06 福州大学 一种微纳结构氯氧化锑-碳复合物锂离子电池负极材料的制备方法

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