PL3445791T3 - Proces i katalizator do polimeryzacji z przeniesieniem łańcucha anionowego inicjowanej solnym wodorkiem w obecności wodoru - Google Patents

Proces i katalizator do polimeryzacji z przeniesieniem łańcucha anionowego inicjowanej solnym wodorkiem w obecności wodoru

Info

Publication number
PL3445791T3
PL3445791T3 PL17719094.9T PL17719094T PL3445791T3 PL 3445791 T3 PL3445791 T3 PL 3445791T3 PL 17719094 T PL17719094 T PL 17719094T PL 3445791 T3 PL3445791 T3 PL 3445791T3
Authority
PL
Poland
Prior art keywords
aniconic
catalyst
chain transfer
transfer polymerization
saline hydride
Prior art date
Application number
PL17719094.9T
Other languages
English (en)
Inventor
William J. Layman
Original Assignee
Albemarle Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Corporation filed Critical Albemarle Corporation
Publication of PL3445791T3 publication Critical patent/PL3445791T3/pl

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06Hydrocarbons
    • C08F12/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/461Catalysts containing at least two different components covered by the same or by different subgroups of group C08F4/46, e.g. butyllithium + propylrubidium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • C08K5/175Amines; Quaternary ammonium compounds containing COOH-groups; Esters or salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/56Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
    • C08K5/57Organo-tin compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01Additive used together with the catalyst, excluding compounds containing Al or B
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/02Low molecular weight, e.g. <100,000 Da.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
PL17719094.9T 2016-04-20 2017-04-06 Proces i katalizator do polimeryzacji z przeniesieniem łańcucha anionowego inicjowanej solnym wodorkiem w obecności wodoru PL3445791T3 (pl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662325149P 2016-04-20 2016-04-20
PCT/US2017/026340 WO2017184350A1 (en) 2016-04-20 2017-04-06 Process and catalyst for hydrogen mediated saline hydride initiated aniconic chain transfer polymerization

Publications (1)

Publication Number Publication Date
PL3445791T3 true PL3445791T3 (pl) 2025-06-09

Family

ID=58610013

Family Applications (1)

Application Number Title Priority Date Filing Date
PL17719094.9T PL3445791T3 (pl) 2016-04-20 2017-04-06 Proces i katalizator do polimeryzacji z przeniesieniem łańcucha anionowego inicjowanej solnym wodorkiem w obecności wodoru

Country Status (13)

Country Link
US (3) US11591420B2 (pl)
EP (1) EP3445791B1 (pl)
JP (1) JP7299703B2 (pl)
KR (1) KR102315747B1 (pl)
CN (2) CN116253819A (pl)
CA (1) CA3021383C (pl)
ES (1) ES3023743T3 (pl)
HU (1) HUE071619T2 (pl)
IL (1) IL262457B2 (pl)
MX (1) MX2018012827A (pl)
PL (1) PL3445791T3 (pl)
SG (1) SG11201809251PA (pl)
WO (1) WO2017184350A1 (pl)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
HUE071619T2 (hu) 2016-04-20 2025-09-28 Albemarle Corp Hidrogénnel közvetett, sóhidriddel kiváltott anionos lánc-transzfer polimerizációra szolgáló eljárás és katalizátor
CN116134076A (zh) 2020-08-07 2023-05-16 雅宝公司 阻燃聚烯烃添加剂
MX2023002225A (es) * 2020-09-01 2023-04-21 Albemarle Corp Proceso y catalizadores para la polimerización aniónica mediada por hidrógeno de dienos conjugados y polímeros líquidos de estos.
EP4486808A2 (en) * 2022-03-01 2025-01-08 Albemarle Corporation Process and catalysts for hydrogen mediated anionic copolymerization of conjugated dienes and liquid copolymers thereof

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2985594A (en) 1958-08-20 1961-05-23 Dow Chemical Co Alkali metal addition compounds of alpha-methyl styrene and method of making
GB923350A (en) 1961-03-27 1963-04-10 Dow Chemical Co Alkali metal addition compounds of alpha-methyl styrene and method of making
US3306949A (en) 1964-10-12 1967-02-28 Exxon Research Engineering Co Alkali metal polymerization of diolefins
US3352934A (en) 1964-11-06 1967-11-14 Exxon Research Engineering Co Use of hydrogen as a molecular weight control in alkali-metal polymerization of diolefins
US3716594A (en) 1969-04-01 1973-02-13 Nippon Soda Co Process for the production of living oligomer
DE19516563A1 (de) * 1995-05-05 1996-11-07 Basf Ag Verfahren zur Herstellung von Styrol-Oligomeren und deren Verwendung als Schmiermittel in Thermoplasten
US5771169A (en) 1996-08-29 1998-06-23 Case Corporation Site-specific harvest statistics analyzer
US5777169A (en) 1997-07-01 1998-07-07 Albemarle Corporation Production of high purity alkali metal diarylphosphide and cycloalkyldiarylphosphines
JPH11286507A (ja) 1998-03-31 1999-10-19 Kanagawa Prefecture アニオン重合開始剤
WO2003008470A1 (fr) 2001-07-16 2003-01-30 Societe De Technologie Michelin Elastomeres dieniques a unites vinyliques cycliques et procedes d'obtention
US6657028B1 (en) 2002-08-01 2003-12-02 Albemarle Corporation Anionic polymerization process
JP5226239B2 (ja) 2006-04-06 2013-07-03 日本曹達株式会社 スチレン系ポリマーの製造方法
KR101593236B1 (ko) 2007-06-07 2016-02-12 알베마를 코포레이션 저분자량의 브롬화 중합체 및 열가소성 배합물에서 이들의 용도
US8993684B2 (en) 2008-06-06 2015-03-31 Albemarle Corporation Low molecular weight brominated polymers, processes for their manufacture and their use in thermoplastic formulations
MX2010013175A (es) 2008-06-06 2011-02-22 Albemarle Corp Polimeros bromados de bajo peso molecular, procesos para su manufactura y su uso en formulaciones termoplasticas.
US8217120B2 (en) 2008-08-13 2012-07-10 Designer Molecules, Inc. Functionalized styrene oligomers and polymers
KR102481040B1 (ko) * 2016-04-05 2022-12-23 알베마를 코포레이션 수소 매개된 염유사 수소화물 개시된 음이온성 연쇄 이동 중합용 탄화수소 가용성 염유사 수소화물 촉매 및 방법 그리고 그로부터 생산된 폴리머 분포 조성물
HUE071619T2 (hu) 2016-04-20 2025-09-28 Albemarle Corp Hidrogénnel közvetett, sóhidriddel kiváltott anionos lánc-transzfer polimerizációra szolgáló eljárás és katalizátor

Also Published As

Publication number Publication date
EP3445791A1 (en) 2019-02-27
MX2018012827A (es) 2019-08-05
US20230227591A1 (en) 2023-07-20
EP3445791B1 (en) 2025-03-26
CN109415458A (zh) 2019-03-01
CA3021383C (en) 2024-06-18
ES3023743T3 (en) 2025-06-03
WO2017184350A1 (en) 2017-10-26
US20250179225A1 (en) 2025-06-05
IL262457B (en) 2022-12-01
HUE071619T2 (hu) 2025-09-28
IL262457A (en) 2018-12-31
SG11201809251PA (en) 2018-11-29
US12234304B2 (en) 2025-02-25
CN109415458B (zh) 2022-12-30
JP7299703B2 (ja) 2023-06-28
JP2019515065A (ja) 2019-06-06
CA3021383A1 (en) 2017-10-26
KR20180136509A (ko) 2018-12-24
IL262457B2 (en) 2023-04-01
US20190106517A1 (en) 2019-04-11
US11591420B2 (en) 2023-02-28
CN116253819A (zh) 2023-06-13
KR102315747B1 (ko) 2021-10-20

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