PL2547639T3 - Wytwarzanie propylenu poprzez jednoczesne odwadnianie i izomeryzację szkieletu izobutanolu na katalizatorach kwasowych a następnie reakcję metatezy - Google Patents

Wytwarzanie propylenu poprzez jednoczesne odwadnianie i izomeryzację szkieletu izobutanolu na katalizatorach kwasowych a następnie reakcję metatezy

Info

Publication number
PL2547639T3
PL2547639T3 PL11708460T PL11708460T PL2547639T3 PL 2547639 T3 PL2547639 T3 PL 2547639T3 PL 11708460 T PL11708460 T PL 11708460T PL 11708460 T PL11708460 T PL 11708460T PL 2547639 T3 PL2547639 T3 PL 2547639T3
Authority
PL
Poland
Prior art keywords
metathesis
isobutanol
production
acid catalysts
via simultaneous
Prior art date
Application number
PL11708460T
Other languages
English (en)
Inventor
Walter Vermeiren
Cindy Adam
Delphine Minoux
Original Assignee
Total Research & Technology Feluy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP10156537A external-priority patent/EP2366682A1/en
Priority claimed from EP10159463A external-priority patent/EP2374781A1/en
Priority claimed from EP10159461A external-priority patent/EP2374780A1/en
Application filed by Total Research & Technology Feluy filed Critical Total Research & Technology Feluy
Publication of PL2547639T3 publication Critical patent/PL2547639T3/pl

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23—Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25—Migration of carbon-to-carbon double bonds
    • C07C5/2506—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/2708—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/14858—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with inorganic compounds not provided for before
    • C07C7/14866—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with inorganic compounds not provided for before water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/14875—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds
    • C07C7/14891—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/177—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by selective oligomerisation or polymerisation of at least one compound of the mixture
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
PL11708460T 2010-03-15 2011-03-15 Wytwarzanie propylenu poprzez jednoczesne odwadnianie i izomeryzację szkieletu izobutanolu na katalizatorach kwasowych a następnie reakcję metatezy PL2547639T3 (pl)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP10156537A EP2366682A1 (en) 2010-03-15 2010-03-15 Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts
EP10159463A EP2374781A1 (en) 2010-04-09 2010-04-09 Simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts
EP10159461A EP2374780A1 (en) 2010-04-09 2010-04-09 Production of propylene via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by metathesis
EP10160840 2010-04-23
EP10161125 2010-04-27

Publications (1)

Publication Number Publication Date
PL2547639T3 true PL2547639T3 (pl) 2017-02-28

Family

ID=44242821

Family Applications (1)

Application Number Title Priority Date Filing Date
PL11708460T PL2547639T3 (pl) 2010-03-15 2011-03-15 Wytwarzanie propylenu poprzez jednoczesne odwadnianie i izomeryzację szkieletu izobutanolu na katalizatorach kwasowych a następnie reakcję metatezy

Country Status (16)

Country Link
US (1) US9260355B2 (pl)
EP (1) EP2547639B1 (pl)
JP (2) JP5784647B2 (pl)
KR (1) KR101572714B1 (pl)
CN (1) CN102906053B (pl)
AR (1) AR080682A1 (pl)
BR (1) BR112012023261B1 (pl)
CA (1) CA2791219C (pl)
CO (1) CO6602153A2 (pl)
DK (1) DK2547639T3 (pl)
EA (1) EA025706B1 (pl)
ES (1) ES2604134T3 (pl)
MY (1) MY161426A (pl)
PE (1) PE20130760A1 (pl)
PL (1) PL2547639T3 (pl)
WO (1) WO2011113836A1 (pl)

Families Citing this family (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2415739A4 (en) * 2009-04-01 2014-01-08 Mitsui Chemicals Inc PROCESS FOR THE PRODUCTION OF OLEFIN
JP5784647B2 (ja) * 2010-03-15 2015-09-24 トタル リサーチ アンド テクノロジー フエリユイ 酸触媒上でイソブタノールを同時脱水・骨格異性化し、次いでメタセシス段階を行ってプロピレンを製造する方法
US20130150643A1 (en) * 2011-12-08 2013-06-13 Saudi Basic Industries Corporation Mixed-phase operation of butenes metathesis process for maximizing propylene production
FR2988717B1 (fr) * 2012-03-29 2014-04-11 IFP Energies Nouvelles Procede de deshydratation et d'isomerisation d'alcools utilisant un catalyseur a base d'un materiau mesostructure comprenant du silicium
US9688591B2 (en) 2013-01-10 2017-06-27 Equistar Chemicals, Lp Ethylene separation process
EP3067340B1 (en) * 2013-11-08 2019-12-25 Braskem S.A. Propene production method
EP3071538B1 (en) * 2013-11-20 2021-02-17 Lummus Technology LLC Olefin double bond isomerization catalyst with high poison resistance
FR3015514B1 (fr) 2013-12-23 2016-10-28 Total Marketing Services Procede ameliore de desaromatisation de coupes petrolieres
KR101747501B1 (ko) * 2014-12-05 2017-06-14 주식회사 엘지화학 부타디엔 제조용 복합산화물 촉매 및 이의 제조방법
KR101966773B1 (ko) 2015-05-13 2019-04-08 주식회사 엘지화학 이성질화 반응을 이용한 노말부텐의 분리방법 및 노말부텐을 분리하기 위한 공정시스템
CN109364983A (zh) 2015-07-02 2019-02-22 沙特阿拉伯石油公司 用于丙烯生产的双重催化剂体系
US20170022125A1 (en) * 2015-07-21 2017-01-26 Uop Llc Processes for producing polymer grade light olefins from mixed alcohols
CN106467450B (zh) * 2015-08-19 2020-05-12 中国石油化工股份有限公司 一种制备异丁烯的方法
SG11201903179WA (en) 2016-10-14 2019-05-30 Gevo Inc Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols
FR3058413A1 (fr) * 2016-11-08 2018-05-11 IFP Energies Nouvelles Procede de deshydratation isomerisante d'une charge d'un monoalcool primaire non lineaire sur un catalyseur comprenant une zeolithe de type fer et un alcalin
US10934231B2 (en) 2017-01-20 2021-03-02 Saudi Arabian Oil Company Multiple-stage catalyst systems and processes for propene production
US10329225B2 (en) 2017-01-20 2019-06-25 Saudi Arabian Oil Company Dual catalyst processes and systems for propylene production
CN107118069A (zh) * 2017-06-17 2017-09-01 安徽海德石油化工有限公司 一种利用异丁醇脱水制备异丁烯的方法
US11505516B2 (en) 2017-07-19 2022-11-22 Sabic Global Technologies B.V. Use of MTBE raffinate in the production of propylene
FR3074802B1 (fr) 2017-12-13 2019-12-06 IFP Energies Nouvelles Procede d'elimination simultanee d'isobutanal et d'acetone de charges olefiniques par adsorption sur un materiau zeolithique
FR3074803B1 (fr) * 2017-12-13 2019-11-29 IFP Energies Nouvelles Procede d’elimination simultanee d’isobutanal et d’ethanol de charges olefiniques par adsorption sur un materiau a base d’oxyde refractaire poreux
FR3077818B1 (fr) 2018-02-09 2020-02-28 IFP Energies Nouvelles Procede de separation d'olefines non lineaires d'une charge olefinique par distillation reactive
US10961171B2 (en) 2018-10-10 2021-03-30 Saudi Arabian Oil Company Catalysts systems that include metal co-catalysts for the production of propylene
CN111013639A (zh) * 2018-10-10 2020-04-17 中国石油化工股份有限公司 丁烯双键异构化催化剂及其用途
US11242299B2 (en) * 2018-10-10 2022-02-08 Saudi Arabian Oil Company Catalyst systems that include metal oxide co-catalysts for the production of propylene
CN111116282B (zh) * 2018-10-30 2022-07-08 中国石油化工股份有限公司 叔丁醇制烯烃的方法
US11192090B2 (en) * 2019-03-25 2021-12-07 Korea Institute Of Energy Research Alcohol dehydration catalyst, preparation method the same and method for preparing alpha-olefins using the same
EP3946731A1 (en) * 2019-03-29 2022-02-09 ExxonMobil Chemical Patents Inc. Mel-type zeolite for converting aromatic hydrocarbons, process for making and catalytic composition comprising said zeolite
CN112209790B (zh) * 2019-07-12 2023-08-29 中国石油化工股份有限公司 叔丁醇直接转化生产丙烯的方法
CN112209791B (zh) * 2019-07-12 2023-08-04 中国石油化工股份有限公司 一种叔丁醇转化生产丙烯的方法
CN114929653A (zh) * 2019-09-30 2022-08-19 吉沃公司 C2-c5醇的同时脱水、二聚和复分解
CN112679295B (zh) * 2019-10-18 2022-11-04 中国石油化工股份有限公司 叔丁醇转化生产丙烯的方法
WO2021099534A1 (en) 2019-11-22 2021-05-27 Total Se Alkyl halides conversion into c3-c5 alpha olefins
WO2021099551A1 (en) 2019-11-22 2021-05-27 Total Se Process for converting one or more methyl halides into c3-c5 alpha olefins
US11185850B2 (en) 2019-12-02 2021-11-30 Saudi Arabian Oil Company Dual functional composite catalyst for olefin metathesis and cracking
US11339332B2 (en) 2020-01-29 2022-05-24 Saudi Arabian Oil Company Systems and processes integrating fluidized catalytic cracking with metathesis for producing olefins
US11572516B2 (en) 2020-03-26 2023-02-07 Saudi Arabian Oil Company Systems and processes integrating steam cracking with dual catalyst metathesis for producing olefins
CN115135625A (zh) * 2020-03-31 2022-09-30 三菱化学株式会社 催化剂、异丁烯的制造方法、甲基丙烯酸的制造方法及甲基丙烯酸甲酯的制造方法
WO2021198479A1 (en) 2020-04-03 2021-10-07 Total Se Production of light olefins via oxychlorination
US11845705B2 (en) 2021-08-17 2023-12-19 Saudi Arabian Oil Company Processes integrating hydrocarbon cracking with metathesis for producing propene
US11827589B2 (en) * 2021-10-04 2023-11-28 Lyondell Chemical Technology, L.P. Methods for isobutylene conversion to C5+ compounds
CN114849679B (zh) * 2022-04-01 2024-02-02 万华化学集团股份有限公司 一种固体超强酸负载催化剂以及β-苯乙醇的制备方法
CN115141086A (zh) * 2022-06-30 2022-10-04 浙江美福石油化工有限责任公司 一种甲基叔丁基醚回炼工艺

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US488760A (en) 1892-12-27 Philetus warren gates
US615933A (en) 1898-12-13 Gutter-former
DE890953C (de) * 1938-08-21 1953-10-29 Basf Ag Verfahren zur Herstellung von Butylen-Isobutylen-Gemischen
GB1064829A (en) 1964-11-19 1967-04-12 British Petroleum Co Olefin preparation
FR91345E (pl) 1965-11-22 1968-09-09
US3658927A (en) 1969-09-02 1972-04-25 Phillips Petroleum Co Olefin conversion and catalysts therefor
US4469911A (en) 1980-10-23 1984-09-04 Petro Tex Chemical Corporation Isobutene removal from C4 streams
US4568788A (en) 1980-11-17 1986-02-04 Phillips Petroleum Company Olefin disproportionation and catalyst therefor
EP0304515B1 (en) 1983-03-10 1991-12-04 The Dow Chemical Company A process for the disproportionation of alkenes
US4575575A (en) 1984-04-05 1986-03-11 Phillips Petroleum Company Catalysts and process for olefin conversion
US4754098A (en) 1986-02-24 1988-06-28 Phillips Petroleum Company Catalyst compositions useful for olefin isomerization and disproportionation
US4684760A (en) 1986-02-24 1987-08-04 Phillips Petroleum Company Catalyst compositions useful for olefin isomerization and disproportionation
FR2606669B1 (fr) 1986-11-18 1989-02-17 Inst Francais Du Petrole Procede de preparation d'un catalyseur renfermant du rhenium, catalyseur obtenu et utilisation de ce catalyseur pour la production d'olefines par metathese
FR2608595B1 (fr) 1986-12-17 1989-04-28 Inst Francais Du Petrole Procede de metathese d'olefines
US6495732B1 (en) 1992-02-10 2002-12-17 Catalytic Distillation Technologies Olefin isomerization process
FR2709125B1 (fr) 1993-08-20 1995-10-06 Inst Francais Du Petrole Procédé de métathèse des oléfines mettant en Óoeuvre un catalyseur au rhénium amélioré.
US6159433A (en) 1995-05-11 2000-12-12 Institut Francais Du Petrole Plant for the conversion of olefinic C4 and C5 cuts to an ether and to propylene
FR2733986B1 (fr) * 1995-05-11 1997-06-13 Inst Francais Du Petrole Procede et installation pour la conversion de coupes c4 olefiniques en polyisobutenes et en propylene
ZA966107B (en) * 1995-07-21 1997-02-03 Shell Int Research Dehydration of primary alcohols.
FR2740056B1 (fr) * 1995-10-20 1997-12-05 Inst Francais Du Petrole Catalyseur supporte contenant du rhenium et de l'aluminium, procede de preparation et application a la metathese des olefines
US5895830A (en) 1995-12-15 1999-04-20 Uop Llc Process for oligomer production and saturation
US5877372A (en) 1997-11-21 1999-03-02 Arco Chemical Technology, L.P. Isobutylene oligomerization using isooctane diluent
FR2802921B1 (fr) 1999-12-24 2002-08-23 Inst Francais Du Petrole Production d'isobutene de haute purete et de propylene a partir de coupes d'hydrocarbures a quatre atomes de carbone
US6616910B2 (en) * 2000-05-05 2003-09-09 Institut Francais Du Petrole Process for preparation of an EUO-structural-type zeolite, the zeolite that is obtained and its use as catalyst for isomerization of C8-aromatic compounds
US6689927B1 (en) 2001-05-07 2004-02-10 Uop Lcc Process for oligomer production and saturation
US20050124839A1 (en) 2001-06-13 2005-06-09 Gartside Robert J. Catalyst and process for the metathesis of ethylene and butene to produce propylene
US6768035B2 (en) * 2002-01-31 2004-07-27 Chevron U.S.A. Inc. Manufacture of high octane alkylate
US6777582B2 (en) * 2002-03-07 2004-08-17 Abb Lummus Global Inc. Process for producing propylene and hexene from C4 olefin streams
DE10302457B3 (de) 2003-01-23 2004-10-07 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen
US6977318B2 (en) 2004-05-04 2005-12-20 Equistar Chemicals, Lp Propylene production
US7220886B2 (en) 2004-10-27 2007-05-22 Catalytic Distillation Technologies Olefin metathesis
WO2006093058A1 (ja) * 2005-03-03 2006-09-08 Mitsui Chemicals, Inc. オレフィン類の製造方法
US20080132741A1 (en) 2006-06-16 2008-06-05 D Amore Michael B Process for making butenes from dry isobutanol
US20080154077A1 (en) * 2006-12-21 2008-06-26 Bozzano Andrea G Oxygenate conversion to olefins with metathesis
NZ579780A (en) 2007-04-18 2012-07-27 Butamax Advanced Biofuels Llc Fermentive production of isobutanol using highly active ketol-acid reductoisomerase enzymes
US8013200B2 (en) * 2007-04-27 2011-09-06 Mitsui Chemicals, Inc. Process for producing olefins
US8178737B2 (en) * 2007-06-14 2012-05-15 Lyondell Chemical Technology, L.P. Propylene production
KR20100095004A (ko) 2007-12-03 2010-08-27 게보 인코포레이티드 재생 조성물
AU2009211364B2 (en) * 2008-02-07 2012-01-19 Total Petrochemicals Research Feluy Dehydration of alcohols on crystalline silicates
EP2238093A1 (en) * 2008-02-07 2010-10-13 Total Petrochemicals Research Feluy Dehydration of alcohols in the presence of an inert component
EP2090561A1 (en) 2008-02-07 2009-08-19 Total Petrochemicals Research Feluy Dehydration of alcohols on crystalline silicates
EP2108634A1 (en) * 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Dehydration of alcohols on crystalline silicates
JP5784647B2 (ja) * 2010-03-15 2015-09-24 トタル リサーチ アンド テクノロジー フエリユイ 酸触媒上でイソブタノールを同時脱水・骨格異性化し、次いでメタセシス段階を行ってプロピレンを製造する方法

Also Published As

Publication number Publication date
CA2791219C (en) 2015-11-24
EA025706B1 (ru) 2017-01-30
EA201270740A1 (ru) 2013-02-28
CA2791219A1 (en) 2011-09-22
WO2011113836A1 (en) 2011-09-22
KR20120135905A (ko) 2012-12-17
AR080682A1 (es) 2012-05-02
EP2547639A1 (en) 2013-01-23
US20130245348A1 (en) 2013-09-19
DK2547639T3 (en) 2016-12-19
ES2604134T3 (es) 2017-03-03
KR101572714B1 (ko) 2015-11-27
JP2015042677A (ja) 2015-03-05
EP2547639B1 (en) 2016-08-24
CN102906053B (zh) 2015-06-03
US9260355B2 (en) 2016-02-16
JP2013522271A (ja) 2013-06-13
CN102906053A (zh) 2013-01-30
MY161426A (en) 2017-04-14
CO6602153A2 (es) 2013-01-18
BR112012023261B1 (pt) 2018-09-18
JP5784647B2 (ja) 2015-09-24
PE20130760A1 (es) 2013-06-21

Similar Documents

Publication Publication Date Title
PL2547639T3 (pl) Wytwarzanie propylenu poprzez jednoczesne odwadnianie i izomeryzację szkieletu izobutanolu na katalizatorach kwasowych a następnie reakcję metatezy
PL2547638T3 (pl) Jednoczesne odwadnianie i izomeryzacja szkieletu izobutanolu na katalizatorach kwasowych
HK1214277A1 (zh) 生產異源多聚體蛋白質
IL225549A (en) Production of alkanes by combined enzymatic conversion of 3-hydroxyalkanoic acids
ZA201302599B (en) Sintering-stable heterogeneous catalysts
EP2545178A4 (en) ACIDIFICATION BY FERMENTATION
ZA201300146B (en) Process for the production of para-xylene
HK1190980A1 (zh) 以還原性有機物為原料的芬頓反應催化劑
AU2012257130A1 (en) Fenton reaction catalyst produced using reducing organic substance as raw material
SG184282A1 (en) Cumene production with high selectivity
EP2526109A4 (en) ISOMERIZATION OF SUGARS
EP2727184A4 (en) ACTIVE ANTENNA subarray STRUCTURES
IL224946B (en) Synthesis of h[gly2]glp–2 using solid phase
EP2552871A4 (en) CONVERSION OF BUTYLENE TO PROPYLENE IN OETFIN METATHESIS CONDITIONS
HK1191546A1 (zh) 皮膚膠原產生促進劑
EP2539071A4 (en) PROCESS FOR PRODUCING CATALYSTS BASED ON HETEROPOLYACID COMPOUNDS
ZA201305373B (en) Isomerization catalysts
EP2561869A4 (en) PROMOTER PRODUCING COLLAGEN THROUGH THE SKIN
SG11201402880TA (en) Preparation method of polyester synthesis composite catalyst
PT2597593T (pt) Estrutura de antena plana aperfeiçoada para mobiliário
EP2534963A4 (en) PROTEIN SYNTHESIS PROMOTERS
EP2513019A4 (en) ALKYLATION METHODS WITH CATALYSTS WITH LOW OLEFINSKELETTISOMERIZATION ACTIVITY
EP2907283A4 (en) PHASE SECTOR BASED ON RF SIGNAL ACQUISITION
PL2809430T3 (pl) Sposoby elektrochemiczne do rozdzielania produktów pochodzących z konwersji biologicznych
TWM405171U (en) Structure of shoe product