NZ598158A - A process for producing unsaturated cyclic and/or aromatic compounds from 1,8-cineole, the process comprising pyrolysing 1,8-cineole in the presence of gamma-alumina - Google Patents
A process for producing unsaturated cyclic and/or aromatic compounds from 1,8-cineole, the process comprising pyrolysing 1,8-cineole in the presence of gamma-aluminaInfo
- Publication number
- NZ598158A NZ598158A NZ598158A NZ59815810A NZ598158A NZ 598158 A NZ598158 A NZ 598158A NZ 598158 A NZ598158 A NZ 598158A NZ 59815810 A NZ59815810 A NZ 59815810A NZ 598158 A NZ598158 A NZ 598158A
- Authority
- NZ
- New Zealand
- Prior art keywords
- cineole
- pyrolysing
- gamma
- aromatic compounds
- alumina
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
- C07C1/247—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by splitting of cyclic ethers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
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- B01J23/90—Regeneration or reactivation
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/20—Vanadium, niobium or tantalum
- C07C2523/22—Vanadium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/34—Manganese
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07—ORGANIC CHEMISTRY
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- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
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- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
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- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/48—Silver or gold
- C07C2523/50—Silver
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/48—Silver or gold
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2009903333A AU2009903333A0 (en) | 2009-07-16 | Cineole | |
| PCT/AU2010/000232 WO2011006183A1 (en) | 2009-07-16 | 2010-02-26 | Cineole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ598158A true NZ598158A (en) | 2012-12-21 |
Family
ID=43448784
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ598158A NZ598158A (en) | 2009-07-16 | 2010-02-26 | A process for producing unsaturated cyclic and/or aromatic compounds from 1,8-cineole, the process comprising pyrolysing 1,8-cineole in the presence of gamma-alumina |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8710287B2 (enExample) |
| EP (2) | EP2454221B1 (enExample) |
| JP (2) | JP5699144B2 (enExample) |
| KR (1) | KR20120073197A (enExample) |
| CN (2) | CN102482178B (enExample) |
| BR (1) | BR112012001054A2 (enExample) |
| CA (1) | CA2768259C (enExample) |
| EA (1) | EA020285B1 (enExample) |
| ES (1) | ES2523273T3 (enExample) |
| NZ (1) | NZ598158A (enExample) |
| WO (1) | WO2011006183A1 (enExample) |
| ZA (1) | ZA201201000B (enExample) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101843410B1 (ko) * | 2015-11-05 | 2018-03-29 | 한국과학기술연구원 | 천연 오일도료 |
| CN106542950B (zh) * | 2016-10-26 | 2019-03-26 | 梧州学院 | 一种通过3-蒈烯制备柠檬烯的方法 |
| CN107008499B (zh) * | 2017-04-13 | 2019-12-31 | 上海科技大学 | 可将萜类化合物转化为芳香烃的组合催化剂及方法 |
| KR102209357B1 (ko) | 2019-07-19 | 2021-01-29 | 주식회사 한국아트라스비엑스 | 프레스 금형 부식을 이용한 납축전지의 그리드 표면 돌기 생성 방법 |
| KR102209365B1 (ko) | 2019-07-30 | 2021-02-01 | 주식회사 한국아트라스비엑스 | 격리판 파손 방지와 전류 집진 효과를 증대시키기 위한 납축전지 기판 |
| KR102225211B1 (ko) | 2019-09-18 | 2021-03-09 | 주식회사 한국아트라스비엑스 | 납축전지 양극 그리드 성장에 의한 쇼트 방지가 가능한 납축전지용 양극 그리드 제조 방법 |
| KR102225220B1 (ko) | 2019-09-25 | 2021-03-09 | 주식회사 한국아트라스비엑스 | 저저항 와이어 패턴을 포함하고 있는 납축전지 기판 |
| JP7343044B2 (ja) * | 2020-03-31 | 2023-09-12 | 三菱ケミカル株式会社 | 触媒、イソブチレンの製造方法、メタクリル酸の製造方法及びメタクリル酸メチルの製造方法 |
| CN113980030A (zh) * | 2021-08-09 | 2022-01-28 | 江西农业大学 | 一种高选择性催化合成1,8-桉叶素的方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB789809A (en) | 1953-09-19 | 1958-01-29 | Hoechst Ag | Process for the manufacture of terephthalic acid |
| US2857439A (en) * | 1955-06-20 | 1958-10-21 | Hercules Powder Co Ltd | Dehydrogenation of sulfur-contaminated monocyclic terpenes |
| DE1003190B (de) * | 1955-09-22 | 1957-02-28 | Basf Ag | Vorrichtung zur Durchfuehrung endotherm ablaufender Umsetzungen im Wirbelschichtverfahren |
| JPS6010068B2 (ja) * | 1982-10-02 | 1985-03-14 | 本田技研工業株式会社 | テルペン系化合物の芳香族化法 |
| GB8705565D0 (en) * | 1987-03-10 | 1987-04-15 | Bp Chem Int Ltd | Chemical process |
| DE19521225A1 (de) * | 1995-06-14 | 1996-12-19 | Hoechst Ag | Verfahren zur Herstellung von p-Cymol |
| DE19521222A1 (de) * | 1995-06-14 | 1996-12-19 | Hoechst Ag | Verfahren zur Herstellung von Alkylbenzolen |
| DE19651330A1 (de) * | 1996-12-11 | 1998-06-18 | Hoechst Ag | Verfahren zur Herstellung von Alkylbenzolen |
| JP4652695B2 (ja) * | 2004-01-30 | 2011-03-16 | 千代田化工建設株式会社 | 水素化芳香族類の脱水素触媒及びその製造方法 |
| WO2006137358A1 (ja) * | 2005-06-20 | 2006-12-28 | Chiyoda Corporation | 均一型高分散金属触媒及びその製造方法 |
| DE102006037447A1 (de) * | 2006-08-10 | 2008-02-14 | Clariant Specialty Fine Chemicals (Deutschland) Gmbh | Katalytische Oxidation von Terpenen mit Edelmetallkatalysatoren |
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2010
- 2010-02-26 NZ NZ598158A patent/NZ598158A/xx not_active IP Right Cessation
- 2010-02-26 EA EA201270172A patent/EA020285B1/ru not_active IP Right Cessation
- 2010-02-26 EP EP10799266.1A patent/EP2454221B1/en not_active Not-in-force
- 2010-02-26 CN CN201080037225.4A patent/CN102482178B/zh not_active Expired - Fee Related
- 2010-02-26 WO PCT/AU2010/000232 patent/WO2011006183A1/en not_active Ceased
- 2010-02-26 BR BR112012001054A patent/BR112012001054A2/pt not_active IP Right Cessation
- 2010-02-26 CA CA2768259A patent/CA2768259C/en not_active Expired - Fee Related
- 2010-02-26 JP JP2012519847A patent/JP5699144B2/ja not_active Expired - Fee Related
- 2010-02-26 ES ES10799266.1T patent/ES2523273T3/es active Active
- 2010-02-26 US US13/383,948 patent/US8710287B2/en not_active Expired - Fee Related
- 2010-02-26 CN CN201410341215.XA patent/CN104193572A/zh active Pending
- 2010-02-26 KR KR1020127003970A patent/KR20120073197A/ko not_active Abandoned
- 2010-02-26 EP EP14173766.8A patent/EP2805934A1/en not_active Withdrawn
-
2012
- 2012-02-10 ZA ZA2012/01000A patent/ZA201201000B/en unknown
-
2014
- 2014-12-11 JP JP2014251230A patent/JP5989749B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR112012001054A2 (pt) | 2016-03-15 |
| EP2454221A4 (en) | 2012-05-23 |
| AU2010273157A1 (en) | 2012-03-01 |
| JP2012532893A (ja) | 2012-12-20 |
| EA020285B1 (ru) | 2014-10-30 |
| CN102482178B (zh) | 2014-07-30 |
| CN104193572A (zh) | 2014-12-10 |
| JP2015083588A (ja) | 2015-04-30 |
| CN102482178A (zh) | 2012-05-30 |
| EP2805934A1 (en) | 2014-11-26 |
| US20120264988A1 (en) | 2012-10-18 |
| EP2454221A1 (en) | 2012-05-23 |
| ZA201201000B (en) | 2013-05-29 |
| KR20120073197A (ko) | 2012-07-04 |
| JP5699144B2 (ja) | 2015-04-08 |
| US8710287B2 (en) | 2014-04-29 |
| CA2768259C (en) | 2016-11-29 |
| EA201270172A1 (ru) | 2012-07-30 |
| CA2768259A1 (en) | 2011-01-20 |
| WO2011006183A1 (en) | 2011-01-20 |
| ES2523273T3 (es) | 2014-11-24 |
| EP2454221B1 (en) | 2014-08-13 |
| JP5989749B2 (ja) | 2016-09-07 |
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