NZ581037A - Grain puffing apparatus - Google Patents

Grain puffing apparatus

Info

Publication number
NZ581037A
NZ581037A NZ581037A NZ58103708A NZ581037A NZ 581037 A NZ581037 A NZ 581037A NZ 581037 A NZ581037 A NZ 581037A NZ 58103708 A NZ58103708 A NZ 58103708A NZ 581037 A NZ581037 A NZ 581037A
Authority
NZ
New Zealand
Prior art keywords
screw
grain
cylinder
puffing
spiral
Prior art date
Application number
NZ581037A
Inventor
Ki Hong Choi
Original Assignee
Ki Hong Choi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ki Hong Choi filed Critical Ki Hong Choi
Publication of NZ581037A publication Critical patent/NZ581037A/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/30Puffing or expanding
    • A23P30/32Puffing or expanding by pressure release, e.g. explosion puffing; by vacuum treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B11/00Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
    • B30B11/22Extrusion presses; Dies therefor
    • B30B11/24Extrusion presses; Dies therefor using screws or worms
    • B30B11/248Means preventing the material from turning with the screw or returning towards the feed hopper
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/161Puffed cereals, e.g. popcorn or puffed rice
    • A23L7/174Preparation of puffed cereals from wholegrain or grain pieces without preparation of meal or dough
    • A23L7/178Preparation of puffed cereals from wholegrain or grain pieces without preparation of meal or dough by pressure release with or without heating
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/20Extruding
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P30/00Shaping or working of foodstuffs characterised by the process or apparatus
    • A23P30/30Puffing or expanding
    • A23P30/32Puffing or expanding by pressure release, e.g. explosion puffing; by vacuum treatment
    • A23P30/34Puffing or expanding by pressure release, e.g. explosion puffing; by vacuum treatment by extrusion-expansion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B30PRESSES
    • B30BPRESSES IN GENERAL
    • B30B11/00Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
    • B30B11/22Extrusion presses; Dies therefor
    • B30B11/24Extrusion presses; Dies therefor using screws or worms
    • B30B11/246Screw constructions

Abstract

A grain puffing apparatus comprises a motor 10, a screw 20 coupled to the motor 10 which transfers and compresses grain while rotating, a first screw spiral 21 formed on the outer circumferential surface of the screw 20 in a certain direction, a second screw spiral 22 which is formed from the central portion of a first pitch of the first screw spiral 21 on the outer circumferential surface of the screw 20 and in the same direction as the first screw spiral 21, a thread hitch 23 that is formed on the other end of the screw 20 and connects the threads forming the first screw spiral 21 and the second screw spiral 22, a screw groove 24 formed on the other end of the screw 20 and along the circumferential direction of the screw 20, a cylinder 30 that surrounds the outer circumferential surface of the screw 20 and compresses and heats the grain when the screw 20 pushes the grain against it thus changing the grain into a gel state, first and second cylinder spirals 31, 32 which are formed on the inner circumferential surface of the cylinder 30 in correspondence to the first screw spiral 21 and the second screw spiral 22 respectively, a grain inlet 33 formed at the motor end of the cylinder 20, and a puffing unit 40 which puffs the gelled grains produced by the screw 20 and the cylinder 30. The puffing unit 40 comprises a main body 41 with an open side and comprises a first space portion 411accommodating the other end of the screw 20 and a second space portion 412 accommodating the other end of the cylinder 30 and part of the screw 20, a cover 23 which closes the open side of the main body 41 and in which a grain outlet 42 is formed, and a clamp 43 which attaches the cover 23 to the main body 41.

Description

WO 2008/123746 PCT/KR2008/002001 GRAIN PUFFING APPARATUS Technical Field The present invention relates to a grain puffing apparatus which puffs grains such as uncleaned rices, rices, corns, and beans in an extrusion method without a special heating apparatus, and more particularly to a grain puffing apparatus which efficiently discharges heat generated in the inside of the grain puffing apparatus and enables puffing of grains without stopping of operation 10 due to excessive heating of the grain puffing apparatus.
Background Art A grain puffing apparatus stands for an apparatus which inputs grains : such as uncleaned rices, rices, corns, and beans through an inlet of a vessel 15 having a closed space together with air while heightening the inner pressure of the vessel and then opens the outlet of the vessel all at once to then be expanded. A conventional grain puffing apparatus has a structure of heating and cooking grains which have been input into a closed space, heightening the inner pressure of the closed space by vapor exhausted from the cooked grains, 20 and extruding and puffing the grains to the outside at the state where the inner pressure of the closed space has been heightened.
In the case of the conventional grain puffing apparatus, when grains are processed at the state where the grains are heated at about 280°C or so. Since there is a problem that the nutrient of grains is destroyed if the grains are 25 heated at 150°C or more, it is not so appropriate to use the conventional grain ■ puffing apparatus as an apparatus for making foods good for health.
WO 2008/123746 PCT/KR2008/002001 In addition, there is a problem that an energy efficiency drops because the conventional grain puffing apparatus should be heated by a special heating source. Further, there is a problem that the conventional grain puffing apparatus is complicated due to the special heating source. Further, since a 5 degree of heating grains differs at the respective steps in the process of processing the grains, there is a problem that a separate circuit for controlling the temperature of the conventional grain puffing apparatus should be essentially added.
Disclosure of the Invention To solve the above problems, it is an object of the present invention to provide a grain puffing apparatus which can enable puffing of grains without using a heating source, and efficiently discharge heat which is generated during puffing, to thereby prevent vapor from flowing backward and enable a 15 continuous operation of the grain puffing apparatus.
To accomplish the above objects of the present invention, according to an aspect of the present invention, there is provided a grain puffing apparatus comprising: a motor; a screw whose one end is coupled to the motor, and thus which transfers and compresses grain while rotating; a first screw spiral formed on the outer circumferential surface of the screw in a certain direction; a second screw spiral which is formed from the central portion of a first 25 pitch of the first screw spiral on the outer circumferential surface of the screw WO 2008/123746 PCT/KR2008/002001 O and in the same direction as that of the first screw spiral; at least one thread hitch that is formed on the other end of the screw and that connects threads forming the first screw spiral and the second screw spiral; a screw groove that is formed on the other end of the screw, and is formed along the circumferential direction of the screw; a cylinder that surrounds the outer circumferential surface of the screw and compresses grain with the screw, and thus which heats the grain by the compression and changes the grain into a gel state; first and second cylinder spirals which are formed on the inner circumferential surface of the cylinder, in correspondence to the first screw spiral and the second screw spiral, respectively; a grain inlet unit formed at the end of the motor of the cylinder; and a puffing unit which rapidly gushes grains that are changed into the gel 15 state by the screw and the cylinder so as to be puffed, wherein the puffing unit comprises: a main body which comprises a first space portion accommodating the other end of the screw and a second space portion accommodating the other end of the cylinder and part of the screw, and whose one side is opened; 20 a cover which closes the opened one side of the main body and in which a grain outlet is formed; and a clamp which fixes the cover and the main body.
Preferably but not necessarily, the inner diameter of the cylinder becomes smaller from the motor to the puffing unit.
Preferably but not necessarily, the minimum inner diameter of the 4 portion where the threads on the inner circumferential surface of the cylinder are formed is larger than the outer diameter of the thread portion of the screw.
Preferably but not necessarily, the grain puffing apparatus further comprises a cutter which cuts grain which is discharged through the grain outlet 5 of the cover into a certain length, and which rotates at a constant speed at the outer portion of the cover.
Brief Description of the Drawings The above and other objects and advantages of the present invention 10 will become more apparent by describing the preferred embodiments thereof in detail with reference to the accompanying drawings in which: FIG. 1 is a schematic diagram for explaining a grain puffing apparatus -according to an embodiment of the present invention; FIG. 2 is an explosive perspective view of a motor, a screw, a cylinder, a 15 puffing unit which are illustrated in FIG. 1; and FIG. 3 is a cross-sectional view of FIG. 2.
Best Mode for Carrying out the Invention The above and/or other objects and/or advantages of the present 20 invention will become more apparent by the following description.
Hereinbelow, a grain puffing apparatus according to an embodiment of the present invention will be described with reference to the accompanying drawing.
As shown in FIG. 1, a grain puffing apparatus according to an 25 embodiment of the present invention includes a motor 10, a screw 20, a cylinder 30, a puffing unit 40, and a cutter 50.
The motor 10 rotates the screw 20.
As the screw 20 rotates according to rotation of the motor 10, grains gl are transferred and compressed. In FIG. 1, a reference alphanumeric designation gl stand for grains which should be puffed or in the process of 5 puffing, and a reference alphanumeric designation g2 stands for grains in which puffing has been ended.
A first screw spiral 21 and a second screw spiral 22 are formed on the outer circumferential surface of the screw 20 in a certain direction, respectively.
The second screw spiral 22 is started and spirally formed from the central portion of the first pitch of the first screw spiral 21, and is formed in the same pitch as the pitch of the first screw spiral 21. Therefore, the pitch * between the first screw spiral 21 and the second screw spiral 22 becomes half • the pitch of the first screw spiral 21. The screw 20 has a double spiral 15 structure of the first screw spiral 21 and the second screw spiral 22. The reason why the screw 20 has a double spiral structure is to intercept heat which is generated when grains gl are transferred from one end of the screw 20 to the other end thereof from flowing backward, that is, toward the one end of the screw 20 from the other end thereof.
At least one thread hitch 23 that connects threads forming the first screw spiral 21 and the second screw spiral 22 is formed on the other end of the screw 20. As illustrated in FIG. 2, a pair of the thread hitches 23 are provided, and form an angle of about 180°to face each other on the outer circumferential surface of the screw 20. A compression degree of the grains gl increases at 25 the other end of the screw 20 and frictional heat due to friction between the WO 2008/123746 „ PCT/KR2008/002001 D grains gl and the respective inner surfaces of the screw 20, the cylinder 30, and the puffing unit 40 further increases. Preferably, it is required that the grains gl be compressed at a state where the grains gl are made into a gel state. A thermal conductivity increases at the other end of the screw 20 by the thread 5 hitches 23. Accordingly, the heating value or calorific value in the puffing unit 40 becomes much larger, to thereby provide an advantage of maintaining the optimum puffing temperature of the grains gl.
A screw groove 24 is formed along the circumference of the screw spiral, at the other end of the screw 20, that is, at the side of the thread hitch 23. 10 The screw groove 24 may be formed on the thread portions of the first screw spiral 21 and the second screw spiral 22 and the thread hitch 23 between the first screw spiral 21 and the second screw spiral 22. The outer diameter of the screw groove 24 is preferably formed a-little smaller- than the outer, diameter of the screw vale portion of the screw 20.
The cylinder 30 compresses the grains gl that is transferred by the screw 20 in a form of surrounding the outer circumferential surface of the screw 20, and makes the grains gl self-generate heat by themselves and changes the grains gl in a gel state by the compression action.
A first cylinder spiral 31 and a second cylinder spiral 32 are formed on 20 the inner circumferential surface of the cylinder 30, in correspondence to the first screw spiral 21 and the second screw spiral 22, respectively.
The pitch of the first screw spiral 21 equals the pitch of the first cylinder spiral 31, and the pitch of the second screw spiral 22 equals the pitch of the second cylinder spiral 32.
A grain inlet 33 is formed at one end of the cylinder 30, that is, at the end WO 2008/123746 PCT/KR2008/002001 of the motor 10. Accordingly, grains gl are input into a space that is formed by the screw 20 and the cylinder 30 through the grain inlet 33.
The inner diameter of the cylinder 30 becomes smaller as it goes from the motor 10 to the puffing unit 40. Accordingly, distances dl, d2, d3, and d4 5 between the screw spirals 21 and 22 and the cylinder spirals 31 and 32 become gradually smaller. This is, dl is bigger than d2, d2 is bigger than d3, and d3 is bigger than d4.
Here, the minimum inner diameter of the portion where the threads on the inner circumferential surface of the cylinder 30 are formed is larger than the 10 outer diameter of the thread portion of the screw 20.
The puffing unit 40 includes a main body 41, a cover 42 and a clamp 43.
A first space portion 411 accommodating the other end of the screw 20 .. and a .second space portion 412 accommodating the other end of the cylinder 30 ? and part of the screw 20 are formed in the main body 41. The other end of the 15 motor 10 is opened.
The cover 42 closes the opened portion of the main body 41. A grain outlet 421 through which puffed grains are discharged is formed on the cover 42.
The clamp 43 has a structure of clamping the main body 41 and the cover 20 42, and can be deformed to a degree by heat and pressure that are generated from the inside of the puffing unit 40.
The cutter 50 cuts grains g2 which are discharged through the grain outlet 421 of the cover 42 after puffing has been ended. The cutter 50 rotates at a given speed at the outside of the cover 42, and cuts the puffed grains g2 in 25 desired size. A reference numeral 55 in FIG. 1 denotes a motor for making the 8 cutter 50 rotate.
Hereinbelow, a process of puffing grains will be described, and simultaneously the operation, function, and effect of the respective components of the grain puffing apparatus according to the embodiment of the present 5 invention will be described in detail with reference to FIGS. 1 to 3.
In FIG. 1, a fixed amount of grains gl per unit time is input into a space that is formed by the screw 20 and the cylinder 30 through a hopper "H" and through the grain inlet 33 of the cylinder 30.
If grains gl are input through the hopper "H" and through the grain inlet 10 33 of the cylinder 30, the grains gl are moved to the puffing unit 40 while the screw 20 rotates by the motor 10. The grains gl make a friction with one another during the process that grains gl move to the puffing unit 40, and the, grains gl make a friction with the outer circumferential surface of the screw 20 and the inner circumferential surface of the cylinder 30, to thereby generate 15 frictional heat. The grains gl are changed into a gel state by the frictional heat, as the grains gl moves from the grain inlet 33 to the puffing unit 40. Accordingly, water existing in the inside of the grains gl evaporates, and the pressure in a space (hereinafter referred to as a puffing space) which is formed by the screw 20 and the cylinder 30 increases together.
Grains gl move toward the puffing unit 40 continuously at the high temperature and high pressure state.
Meanwhile, when grains gl move at the state where proper temperature and pressure are kept, puffing is attained properly. The internal temperature and pressure of the puffing space are sensitive to react to the temperature of 25 the input grains, the water included in the grains, and the external temperature 9 of the grain puffing apparatus.
The temperature in the puffing space should be kept at 130°C or so, in this invention. This is because nutrients of grains are destroyed in the case that the temperature in the puffing space becomes 150°C or higher, as 5 described above.
In the case that the temperature in the puffing space is a certain temperature or high, vapor that is evaporated from the grains gl flows backward, and heats the grains gl which are input into the grain inlet 33. Accordingly, as soon as the grains gl are input, the grains gl are changed into a 10 gel state. As a result, there is a problem that it is difficult to make the grains gl transferred. Since the temperature of grains is lower than that of the puffing space, the grain puffing apparatus is cooled by the grains. Thus, if input grains . are immediately heated, there is a problem that a cooling effect of the grain, puffing apparatus by grains cannot be expected.
In order to prevent vapor from flowing backward, a screw groove 24 is formed. Since grains of a gel state is engaged with the screw groove 24 in a ring shape, a kind of a wall is formed to prevent vapor from flowing backward toward the grain inlet 33.
Meanwhile, since vapor does not flow backward by the grains filled in the 20 screw groove 24, the vapor in the puffing space is discharged through the grain inlet 421. Here, in the case that the vapor pressure in the puffing space is very high, the temperature in the puffing space rises up, to thereby make an influence upon an efficiency of puffing. Accordingly, in the case that the vapor pressure in the puffing space becomes a certain pressure or high, it is necessary to 25 discharge vapor through a path other than the grain outlet 421.
For this reason, the puffing unit 40 includes a main body 41, a cover 42 and a clamp 43. As described above, the main body 41 and the cover 42 are fixed by the clamp 43, and the clamp 43 is of a mechanically deformable structure. Accordingly, in the case that the vapor pressure in the puffing space 5 becomes a certain pressure or high, vapor is discharged through a minute gap between the main body 41 and the cover 42 by the vapor pressure.
By this configuration, the temperature and pressure in the puffing space are kept constant.
The grains gl which have been transferred toward the cover 42 through 10 the puffing space are discharged through the grain outlet 421. Here, since the atmospheric pressure is relatively smaller than the pressure in the puffing space, the puffing space is expanded.
Meanwhile, since.the .inner circumferential surface of the cylinder 30 is gradually reduced lengthily, the puffing space is gradually reduced during the 15 transfer of the grains gl. Accordingly, the friction between the grains gl increases, to thus provide an effect of increasing a self-generation of heat as the grains gl are transferred toward the puffing unit 40.
If the puffed grains g2 are discharged through the grain outlet 421, it should be easy to cut the puffed grains g2 into a desired size and package the 20 cut grains g2, to commercialize the puffed grains g2.
Accordingly, the cutter 50 is rotated using the motor 55 for the cutter 50, in order to cut the puffed grains g2 into a desired size.
As described above, the grain puffing apparatus according to an embodiment of the present invention which has a structure that the inner 25 diameter of the cylinder decreases gradually, has been described, but even in 11 the case that the inner diameter of the cylinder is kept equally can achieve an objective that the present invention attains. It is apparent to one skilled in the art that such a modification or variation should be included in the technological thought of this invention.
As described above, the grain puffing apparatus according to an embodiment of the present invention which has a cutter has been described, but the objective of the present invention may be accomplished although the grain puffing apparatus does not include the cutter. It is apparent to one skilled in the art that such a modification or variation should be included in the 10 technological thought of this invention, even in the case that the grain puffing apparatus does not include any cutter.
As described above, the grain puffing apparatus according to the preferable embodimentof the,present invention has been described.... However, the present invention is not limited to the above embodiment, and it is possible 15 for one who has an ordinary skill in the art to make various modifications and variations of the grain puffing apparatus, without departing off the spirit of the present invention.
As described above, the present invention provided a grain puffing apparatus which can enable puffing of grains without using a heating source, and 20 efficiently discharge heat which is generated during puffing, to thereby prevent vapor from flowing backward and enable a continuous operation of the grain puffing apparatus.
Industrial Applicability 25 As described above, a grain puffing apparatus according to the present 12 invention puffs grains such as uncleaned rices, rices, corns, and beans in an extrusion method without a special heating apparatus, and efficiently discharges heat generated in the inside of the grain puffing apparatus and enables puffing of grains without stopping of operation due to excessive heating of the grain puffing apparatus. 13

Claims (4)

What is claimed is:
1. A grain puffing apparatus comprising: a motor; a screw whose one end is coupled to the motor, and thus which transfers 5 and compresses grain while rotating; a first screw spiral formed on the outer circumferential surface of the screw in a certain direction; a second screw spiral which is formed from the central portion of a first pitch of the first screw spiral on the outer circumferential surface of the screw 10 and in the same direction as that of the first screw spiral; a thread hitch that is formed on the other end of the screw and that connects threads forming the first screw spiral and the second screw spiral; a screw groove that is. formed on the other end of the screw, and >is formed along the circumferential direction of the screw; 15 a cylinder that surrounds the outer circumferential surface of the screw and compresses grain with the screw, and thus which heats the grain by the compression and changes the grain into a gel state; first and second cylinder spirals which are formed on the inner circumferential surface of the cylinder, in correspondence to the first screw 20 spiral and the second screw spiral, respectively! a grain inlet unit formed at the end of the motor of the cylinder; and a puffing unit which rapidly gushes grains that are changed into the gel state by the screw and the cylinder so as to be puffed, wherein the puffing unit comprises: 25 a main body which comprises a first space portion accommodating the WO 2008/123746 14 PCT/KR2008/002001 other end of the screw and a second space portion accommodating the other end of the cylinder and part of the screw, and whose one side is opened; a cover which closes the opened one side of the main body and in which a grain outlet is formed; and 5 a clamp which fixes the cover and the main body.
2. The grain puffing apparatus according to claim 1, wherein the inner diameter of the cylinder becomes smaller from the motor side to the puffing unit. 10
3. The grain puffing apparatus according to claim 2, wherein the minimum inner diameter of the portion where the threads on the inner circumferential surface of the-cylinder are formed, is larger than the outer diameter of the thread portion of the screw. 15
4. The grain puffing apparatus according to claim 3, further comprising a cutter which cuts grain which is discharged through the grain outlet of the cover into a certain length, and which rotates at a constant speed at the outer portion of the cover. 20 25
NZ581037A 2007-04-10 2008-04-10 Grain puffing apparatus NZ581037A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020070035152A KR100807527B1 (en) 2007-04-10 2007-04-10 Apparatus for puffing grains
PCT/KR2008/002001 WO2008123746A1 (en) 2007-04-10 2008-04-10 Grain puffing apparatus

Publications (1)

Publication Number Publication Date
NZ581037A true NZ581037A (en) 2011-05-27

Family

ID=39383386

Family Applications (1)

Application Number Title Priority Date Filing Date
NZ581037A NZ581037A (en) 2007-04-10 2008-04-10 Grain puffing apparatus

Country Status (11)

Country Link
EP (1) EP2173192A4 (en)
JP (1) JP5149374B2 (en)
KR (1) KR100807527B1 (en)
CN (1) CN101730480B (en)
AU (1) AU2008236966B2 (en)
BR (1) BRPI0813082A8 (en)
CO (1) CO6260026A2 (en)
IL (1) IL201301A0 (en)
NZ (1) NZ581037A (en)
WO (1) WO2008123746A1 (en)
ZA (1) ZA200907801B (en)

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KR101296847B1 (en) * 2011-04-06 2013-08-14 주식회사델리스 Apparatus for puffing grains
KR101498261B1 (en) * 2013-07-15 2015-03-06 서강대학교산학협력단 Apparatus for puffing grain
KR101396423B1 (en) 2013-09-16 2014-05-20 장성신 Grain snack puffer
CN109717378A (en) * 2019-02-26 2019-05-07 顾健健 Rice deep-processing system and its processing technology
KR102212437B1 (en) * 2020-07-08 2021-02-04 주식회사 자인 Apparatus for puffing grains

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Also Published As

Publication number Publication date
CN101730480A (en) 2010-06-09
EP2173192A1 (en) 2010-04-14
WO2008123746A1 (en) 2008-10-16
EP2173192A4 (en) 2010-11-03
KR100807527B1 (en) 2008-02-26
ZA200907801B (en) 2010-07-28
IL201301A0 (en) 2010-05-31
CO6260026A2 (en) 2011-03-22
AU2008236966B2 (en) 2011-12-01
BRPI0813082A8 (en) 2016-08-02
AU2008236966A1 (en) 2008-10-16
CN101730480B (en) 2013-03-27
JP5149374B2 (en) 2013-02-20
BRPI0813082A2 (en) 2014-12-30
JP2010523143A (en) 2010-07-15

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