NZ211089A - Early high strength concrete compositions, containing a polysialatesiloxo material and blast furnace slag - Google Patents
Early high strength concrete compositions, containing a polysialatesiloxo material and blast furnace slagInfo
- Publication number
- NZ211089A NZ211089A NZ211089A NZ21108985A NZ211089A NZ 211089 A NZ211089 A NZ 211089A NZ 211089 A NZ211089 A NZ 211089A NZ 21108985 A NZ21108985 A NZ 21108985A NZ 211089 A NZ211089 A NZ 211089A
- Authority
- NZ
- New Zealand
- Prior art keywords
- slag
- strength concrete
- mixture
- reactant mixture
- psi
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 104
- 239000002893 slag Substances 0.000 title claims abstract description 49
- 239000011372 high-strength concrete Substances 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 title abstract description 4
- 229910001868 water Inorganic materials 0.000 claims abstract description 52
- 239000000376 reactant Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 24
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 14
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011591 potassium Substances 0.000 claims abstract description 11
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims abstract description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- KVLCHQHEQROXGN-UHFFFAOYSA-N aluminium(1+) Chemical compound [Al+] KVLCHQHEQROXGN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940007076 aluminum cation Drugs 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 52
- 229920000876 geopolymer Polymers 0.000 claims description 41
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 19
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 15
- 239000004576 sand Substances 0.000 claims description 13
- 238000006068 polycondensation reaction Methods 0.000 claims description 11
- 230000008859 change Effects 0.000 claims description 8
- 239000011398 Portland cement Substances 0.000 claims description 7
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 239000004567 concrete Substances 0.000 claims description 2
- 241001125671 Eretmochelys imbricata Species 0.000 claims 1
- 239000004568 cement Substances 0.000 description 23
- 229910052500 inorganic mineral Inorganic materials 0.000 description 18
- 239000011707 mineral Substances 0.000 description 18
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 9
- 239000002002 slurry Substances 0.000 description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 239000004927 clay Substances 0.000 description 8
- 239000000945 filler Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 8
- 229910001950 potassium oxide Inorganic materials 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 238000001723 curing Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000012190 activator Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910000805 Pig iron Inorganic materials 0.000 description 2
- 239000004111 Potassium silicate Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- 229910001948 sodium oxide Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910002656 O–Si–O Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 229910001588 amesite Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- -1 clinker Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 239000011178 precast concrete Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910021487 silica fume Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Civil Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Dental Preparations (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Lubricants (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Organic Insulating Materials (AREA)
- Gas Burners (AREA)
- Thermistors And Varistors (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)
- On-Site Construction Work That Accompanies The Preparation And Application Of Concrete (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/582,279 US4509985A (en) | 1984-02-22 | 1984-02-22 | Early high-strength mineral polymer |
Publications (1)
Publication Number | Publication Date |
---|---|
NZ211089A true NZ211089A (en) | 1987-09-30 |
Family
ID=24328526
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NZ211089A NZ211089A (en) | 1984-02-22 | 1985-02-11 | Early high strength concrete compositions, containing a polysialatesiloxo material and blast furnace slag |
Country Status (18)
Families Citing this family (115)
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DE3246621A1 (de) * | 1982-12-16 | 1984-06-20 | Dynamit Nobel Ag, 5210 Troisdorf | Bauteilverkleidungen aus anorganischen formmassen |
US4509985A (en) * | 1984-02-22 | 1985-04-09 | Pyrament Inc. | Early high-strength mineral polymer |
US4640715A (en) * | 1985-03-06 | 1987-02-03 | Lone Star Industries, Inc. | Mineral binder and compositions employing the same |
US4642137A (en) * | 1985-03-06 | 1987-02-10 | Lone Star Industries, Inc. | Mineral binder and compositions employing the same |
EP0288502B1 (fr) * | 1986-10-14 | 1991-07-24 | DAVIDOVITS, Nicolas | Materiau composite ceramique-ceramique et procede d'obtention |
US4917732A (en) * | 1986-12-22 | 1990-04-17 | Shell Oil Company | Flyash treatment |
US4859367A (en) * | 1987-10-02 | 1989-08-22 | Joseph Davidovits | Waste solidification and disposal method |
DE3832452A1 (de) * | 1988-09-23 | 1990-03-29 | Lothar Mansfeld | Anorganischer baustoff und dessen verwendung |
FR2657867B1 (fr) * | 1990-02-05 | 1994-01-14 | Joseph Davidovits | Ciment rapide geopolymerique a base de ciment portland et procede d'obtention. |
US5342595A (en) * | 1990-03-07 | 1994-08-30 | Joseph Davidovits | Process for obtaining a geopolymeric alumino-silicate and products thus obtained |
FR2659320B1 (fr) * | 1990-03-07 | 1992-07-03 | Davidovics Michel | Liant geopolymerique fluoro-alumino-silicate et procede d'obtention. |
US5637412A (en) * | 1990-05-18 | 1997-06-10 | E. Khashoggi Industries | Compressed hydraulically bonded composite articles |
US5169566A (en) * | 1990-05-18 | 1992-12-08 | E. Khashoggi Industries | Engineered cementitious contaminant barriers and their method of manufacture |
US5356579A (en) * | 1990-05-18 | 1994-10-18 | E. Khashoggi Industries | Methods of manufacture and use for low density hydraulically bonded cement compositions |
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US5100586A (en) * | 1990-07-20 | 1992-03-31 | E. Khashoggi Industries | Cementitious hazardous waste containers and their method of manufacture |
AU8422591A (en) * | 1990-09-03 | 1992-03-30 | Holderbank Financiere Glarus S.A. | Method for preparing a spherosilicate-type cement and cement thereby obtained |
FR2666253B1 (fr) * | 1990-09-04 | 1992-10-30 | Davidovits Joseph | Procede d'obtention d'un liant geopolymerique permettant la stabilisation, la solidification et la consolidation de dechets toxiques. |
FR2666328B1 (fr) * | 1990-09-04 | 1992-10-30 | Davidovits Joseph | Procede d'obtention d'une matrice geopolymere a durcissement rapide pour impregnation de materiaux composites et produits obtenus. |
FR2671343B1 (fr) * | 1991-01-03 | 1993-11-26 | Poudres Explosifs Ste Nale | Materiaux isolants thermiques a haute temperature et leur procede de fabrication. |
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FR2758323B1 (fr) * | 1997-01-15 | 1999-08-06 | Cordi Geopolymere Sa | Methodes de fabrication de ciments geopolymeriques et ciments obtenus par ces methodes |
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US6966945B1 (en) * | 2000-09-20 | 2005-11-22 | Goodrich Corporation | Inorganic matrix compositions, composites and process of making the same |
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US7732358B2 (en) * | 2000-09-20 | 2010-06-08 | Goodrich Corporation | Inorganic matrix compositions and composites incorporating the matrix composition |
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NL6711782A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1966-09-01 | 1968-03-04 | ||
DE3071695D1 (en) * | 1979-09-04 | 1986-09-18 | Joseph Davidovits | Synthetic inorganic polymer of the silicoaluminate family and process for the preparation thereof; moulded articles containing this polymer, and process for their preparation |
FR2464227B1 (fr) * | 1979-09-04 | 1985-09-20 | Cordi Coord Dev Innovation | Polymere mineral |
FR2489291A1 (fr) * | 1980-09-03 | 1982-03-05 | Davidovits Joseph | Compose polymerique mineral et procede d'obtention |
US4432798A (en) * | 1980-12-16 | 1984-02-21 | The Duriron Company, Inc. | Aluminosilicate hydrogel bonded aggregate articles |
US4509985A (en) * | 1984-02-22 | 1985-04-09 | Pyrament Inc. | Early high-strength mineral polymer |
-
1984
- 1984-02-22 US US06/582,279 patent/US4509985A/en not_active Expired - Lifetime
-
1985
- 1985-02-01 CA CA000473466A patent/CA1236858A/en not_active Expired
- 1985-02-07 DE DE8585300819T patent/DE3574695D1/de not_active Expired - Fee Related
- 1985-02-07 FI FI850514A patent/FI76780C/fi not_active IP Right Cessation
- 1985-02-07 EP EP19850300819 patent/EP0153097B1/en not_active Expired
- 1985-02-07 AT AT85300819T patent/ATE48586T1/de not_active IP Right Cessation
- 1985-02-08 DK DK60985A patent/DK160086C/da active
- 1985-02-10 JO JO19851387A patent/JO1387B1/en active
- 1985-02-11 NZ NZ211089A patent/NZ211089A/en unknown
- 1985-02-11 NO NO850511A patent/NO164232C/no unknown
- 1985-02-12 ZA ZA851043A patent/ZA851043B/xx unknown
- 1985-02-13 MX MX20431685A patent/MX164940B/es unknown
- 1985-02-19 AU AU39967/85A patent/AU3996785A/en not_active Abandoned
- 1985-02-19 WO PCT/US1985/000270 patent/WO1985003699A1/en unknown
- 1985-02-20 TR TR2217485A patent/TR22174A/xx unknown
- 1985-02-21 MA MA20582A patent/MA20358A1/fr unknown
- 1985-02-22 ES ES540652A patent/ES8605450A1/es not_active Expired
- 1985-05-28 IN IN428/DEL/85A patent/IN163449B/en unknown
Also Published As
Publication number | Publication date |
---|---|
US4509985A (en) | 1985-04-09 |
JO1387B1 (en) | 1986-11-30 |
IN163449B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-09-24 |
FI76780C (fi) | 1994-11-26 |
FI850514A0 (fi) | 1985-02-07 |
DK160086B (da) | 1991-01-28 |
ZA851043B (en) | 1985-09-25 |
EP0153097B1 (en) | 1989-12-13 |
WO1985003699A1 (en) | 1985-08-29 |
NO164232B (no) | 1990-06-05 |
MA20358A1 (fr) | 1985-10-01 |
MX164940B (es) | 1992-10-05 |
FI850514L (fi) | 1985-08-23 |
DK60985D0 (da) | 1985-02-08 |
ATE48586T1 (de) | 1989-12-15 |
DK160086C (da) | 1991-06-10 |
FI76780B (fi) | 1988-08-31 |
EP0153097A2 (en) | 1985-08-28 |
NO850511L (no) | 1985-08-23 |
NO164232C (no) | 1990-09-12 |
AU3996785A (en) | 1985-09-10 |
ES540652A0 (es) | 1986-04-01 |
TR22174A (tr) | 1986-07-29 |
CA1236858A (en) | 1988-05-17 |
DK60985A (da) | 1985-08-23 |
EP0153097A3 (en) | 1986-04-16 |
DE3574695D1 (de) | 1990-01-18 |
ES8605450A1 (es) | 1986-04-01 |
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