NO333033B1 - Fremgangsmate for polymerisering for okt polymerisasjonsreaktorutbytte ved bruk av et spesifikt initiatorsystem - Google Patents
Fremgangsmate for polymerisering for okt polymerisasjonsreaktorutbytte ved bruk av et spesifikt initiatorsystemInfo
- Publication number
- NO333033B1 NO333033B1 NO20055661A NO20055661A NO333033B1 NO 333033 B1 NO333033 B1 NO 333033B1 NO 20055661 A NO20055661 A NO 20055661A NO 20055661 A NO20055661 A NO 20055661A NO 333033 B1 NO333033 B1 NO 333033B1
- Authority
- NO
- Norway
- Prior art keywords
- polymerization
- initiator
- temperature
- monomer
- amount
- Prior art date
Links
- 239000003999 initiator Substances 0.000 title claims abstract description 135
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 123
- 238000000034 method Methods 0.000 title claims abstract description 86
- 239000000178 monomer Substances 0.000 claims abstract description 44
- 238000001816 cooling Methods 0.000 claims abstract description 21
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000084 colloidal system Substances 0.000 claims description 21
- 230000001681 protective effect Effects 0.000 claims description 20
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 abstract description 20
- 150000002978 peroxides Chemical class 0.000 description 35
- 239000000203 mixture Substances 0.000 description 29
- 239000011541 reaction mixture Substances 0.000 description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 description 14
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 230000007062 hydrolysis Effects 0.000 description 9
- 238000006460 hydrolysis reaction Methods 0.000 description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 description 8
- 239000006185 dispersion Substances 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000000725 suspension Substances 0.000 description 7
- 230000000379 polymerizing effect Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- -1 ethylene, propylene, acrylonitrile Chemical class 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000002516 radical scavenger Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- NUIZZJWNNGJSGL-UHFFFAOYSA-N 2-phenylpropan-2-yl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)c1ccccc1 NUIZZJWNNGJSGL-UHFFFAOYSA-N 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- JHJSICJSIOGNMW-UHFFFAOYSA-N [2-(2,2-dimethylpropanoylperoxy)-4-methylpentan-2-yl] 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(CC(C)C)OOC(=O)C(C)(C)C JHJSICJSIOGNMW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- BSVQJWUUZCXSOL-UHFFFAOYSA-N cyclohexylsulfonyl ethaneperoxoate Chemical compound CC(=O)OOS(=O)(=O)C1CCCCC1 BSVQJWUUZCXSOL-UHFFFAOYSA-N 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- MVELOSYXCOVILT-UHFFFAOYSA-N (4-hydroxy-2-methylpentan-2-yl) 7,7-dimethyloctaneperoxoate Chemical compound CC(O)CC(C)(C)OOC(=O)CCCCCC(C)(C)C MVELOSYXCOVILT-UHFFFAOYSA-N 0.000 description 1
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 description 1
- HXDFVLSNQZTNEL-UHFFFAOYSA-N 2,2-dimethylpropanoyl hexaneperoxoate Chemical compound CCCCCC(=O)OOC(=O)C(C)(C)C HXDFVLSNQZTNEL-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- ZACVGCNKGYYQHA-UHFFFAOYSA-N 2-ethylhexoxycarbonyloxy 2-ethylhexyl carbonate Chemical compound CCCCC(CC)COC(=O)OOC(=O)OCC(CC)CCCC ZACVGCNKGYYQHA-UHFFFAOYSA-N 0.000 description 1
- RAWISQFSQWIXCW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethyloctaneperoxoate Chemical compound CCCCCCC(C)(C)C(=O)OOC(C)(C)CC RAWISQFSQWIXCW-UHFFFAOYSA-N 0.000 description 1
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 1
- RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 1
- GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical group CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 230000002292 Radical scavenging effect Effects 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- IQARRNIZJJVLPF-UHFFFAOYSA-N [2-(2,2-dimethylpropanoylperoxy)-4-methylpentan-2-yl] 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)C(=O)OOC(C)(CC(C)C)OOC(=O)C(C)(C)C IQARRNIZJJVLPF-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000012674 dispersion polymerization Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- UPWGQKDVAURUGE-UHFFFAOYSA-N glycerine monooleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC(CO)CO UPWGQKDVAURUGE-UHFFFAOYSA-N 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- VNJISVYSDHJQFR-UHFFFAOYSA-N tert-butyl 4,4-dimethylpentaneperoxoate Chemical compound CC(C)(C)CCC(=O)OOC(C)(C)C VNJISVYSDHJQFR-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/38—Mixtures of peroxy-compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03076390 | 2003-05-01 | ||
| PCT/EP2004/004500 WO2004096871A1 (en) | 2003-05-01 | 2004-04-27 | Increased polymerization reactor output by using a specific initiator system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO20055661L NO20055661L (no) | 2005-11-30 |
| NO333033B1 true NO333033B1 (no) | 2013-02-18 |
Family
ID=33395907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20055661A NO333033B1 (no) | 2003-05-01 | 2005-11-30 | Fremgangsmate for polymerisering for okt polymerisasjonsreaktorutbytte ved bruk av et spesifikt initiatorsystem |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US8283431B2 (th) |
| EP (1) | EP1618137B1 (th) |
| JP (1) | JP4896709B2 (th) |
| KR (1) | KR101144881B1 (th) |
| CN (1) | CN100347203C (th) |
| AT (1) | ATE398143T1 (th) |
| AU (1) | AU2004234056B2 (th) |
| BR (1) | BRPI0409857B1 (th) |
| CA (1) | CA2524135C (th) |
| DE (1) | DE602004014359D1 (th) |
| ES (1) | ES2307011T3 (th) |
| MX (1) | MXPA05011727A (th) |
| MY (1) | MY136934A (th) |
| NO (1) | NO333033B1 (th) |
| PL (1) | PL1618137T3 (th) |
| RU (1) | RU2349603C2 (th) |
| SA (1) | SA04250201B1 (th) |
| TW (2) | TW200424217A (th) |
| WO (1) | WO2004096871A1 (th) |
| ZA (1) | ZA200509705B (th) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7173095B2 (en) † | 2003-06-20 | 2007-02-06 | Akzo Nobel N. V. | Polymerization process involving the dosing initiators |
| KR101359595B1 (ko) | 2006-03-24 | 2014-02-07 | 아크조 노벨 엔.브이. | 비닐 클로라이드 (코)폴리머의 연속 제조 방법 |
| USRE45940E1 (en) | 2006-03-24 | 2016-03-22 | Akzo Nobel N.V. | Continuous process for the production of vinyl chloride (co)polymers |
| EP1849804A1 (en) * | 2006-04-27 | 2007-10-31 | Arkema France | Process of free-radical polymerization or crosslinking in the presence of an organic peroxide by an ex situ process |
| EP1852418A1 (en) | 2006-04-27 | 2007-11-07 | Arkema France | Process for synthesizing selected organic peroxides |
| KR100899985B1 (ko) * | 2006-06-12 | 2009-05-28 | 주식회사 엘지화학 | 현탁 중합에 의한 염화 비닐계 중합체의 제조 방법 |
| KR100983702B1 (ko) * | 2006-08-22 | 2010-09-24 | 주식회사 엘지화학 | 가공성이 우수한 염화비닐계 중합체의 제조방법 |
| DE102008008421B4 (de) | 2008-02-09 | 2014-06-26 | Celanese Emulsions Gmbh | Verfahren zur Herstellung von Polymerdispersionen, die damit enthaltenen Dispersionen und deren Verwendung |
| CN105367688B (zh) | 2009-08-06 | 2018-07-06 | 阿克佐诺贝尔化学国际公司 | 具有高活性氧含量的储存稳定且安全的过氧化物乳液 |
| AR081664A1 (es) * | 2010-06-30 | 2012-10-10 | Akzo Nobel Chemicals Int Bv | Proceso de polimerizacion con formacion in-situ del iniciador |
| EP3708591A1 (de) * | 2019-03-15 | 2020-09-16 | Hilti Aktiengesellschaft | Beschleuniger-kombination |
| CN111718439A (zh) * | 2020-06-19 | 2020-09-29 | 宁波南大光电材料有限公司 | 甲基丙烯酸树脂及其制备方法和应用 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3451985A (en) | 1964-03-26 | 1969-06-24 | Monsanto Co | Method of polymerizing vinyl monomers |
| US3778422A (en) * | 1971-05-17 | 1973-12-11 | Tenneco Chem | Process for the production of vinyl halide polymers |
| DE3029211A1 (de) * | 1980-08-01 | 1982-03-18 | Hoechst Ag, 6000 Frankfurt | Verfahren zur herstellung von polymerisaten des vinylchlorids |
| EP0096365A1 (en) * | 1982-06-07 | 1983-12-21 | Air Products And Chemicals, Inc. | Shortened reaction cycle times in vinyl chloride-propylene copolymerization |
| US4727110A (en) | 1984-04-19 | 1988-02-23 | Union Carbide Corporation | Process for the polymerization of shear-stable water-in-oil emulsions |
| JPH0782304A (ja) * | 1993-09-13 | 1995-03-28 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| JP3326956B2 (ja) * | 1994-04-05 | 2002-09-24 | 三菱化学株式会社 | 塩化ビニル系重合体の製造方法 |
| JP3388528B2 (ja) * | 1994-12-15 | 2003-03-24 | 信越化学工業株式会社 | ビニル系重合体の製造方法 |
| JPH09157308A (ja) * | 1995-07-05 | 1997-06-17 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| HU230607B1 (hu) | 1998-09-21 | 2017-03-28 | Akzo Nobel N.V. | Nagyon gyors iniciátorok folytonos adagolása polimerizációs reakciók során |
| US6274690B1 (en) * | 1999-08-11 | 2001-08-14 | Shin-Etsu Chemical Co., Ltd. | Preparation of vinyl chloride polymer |
| UA77245C2 (uk) | 2001-12-21 | 2006-11-15 | Акцо Нобель Н.В. | Спосіб полімеризації суміші, яка містить вінілхлоридний мономер |
| CA2470817C (en) | 2001-12-21 | 2011-03-15 | Akzo Nobel Nv | Addition of organic initiators during the pressure drop in vinyl chloride monomer polymerization reactions |
| WO2003087168A1 (en) | 2002-04-12 | 2003-10-23 | Akzo Nobel N.V. | Co-metering of organic initiators and protective colloids during polymerization reactions |
-
2003
- 2003-06-10 TW TW092115675A patent/TW200424217A/zh unknown
-
2004
- 2004-04-27 MX MXPA05011727A patent/MXPA05011727A/es active IP Right Grant
- 2004-04-27 BR BRPI0409857-9A patent/BRPI0409857B1/pt active IP Right Grant
- 2004-04-27 AT AT04729652T patent/ATE398143T1/de not_active IP Right Cessation
- 2004-04-27 ES ES04729652T patent/ES2307011T3/es not_active Expired - Lifetime
- 2004-04-27 EP EP04729652A patent/EP1618137B1/en not_active Expired - Lifetime
- 2004-04-27 DE DE602004014359T patent/DE602004014359D1/de not_active Expired - Lifetime
- 2004-04-27 US US10/553,971 patent/US8283431B2/en active Active
- 2004-04-27 WO PCT/EP2004/004500 patent/WO2004096871A1/en active IP Right Grant
- 2004-04-27 RU RU2005137324/04A patent/RU2349603C2/ru active
- 2004-04-27 JP JP2006505306A patent/JP4896709B2/ja not_active Expired - Lifetime
- 2004-04-27 CN CNB2004800117908A patent/CN100347203C/zh not_active Expired - Lifetime
- 2004-04-27 PL PL04729652T patent/PL1618137T3/pl unknown
- 2004-04-27 KR KR1020057020643A patent/KR101144881B1/ko active IP Right Grant
- 2004-04-27 AU AU2004234056A patent/AU2004234056B2/en not_active Ceased
- 2004-04-27 CA CA2524135A patent/CA2524135C/en not_active Expired - Fee Related
- 2004-04-30 MY MYPI20041652A patent/MY136934A/en unknown
- 2004-05-03 TW TW093112405A patent/TWI346668B/zh not_active IP Right Cessation
- 2004-07-03 SA SA04250201A patent/SA04250201B1/ar unknown
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2005
- 2005-11-30 ZA ZA200509705A patent/ZA200509705B/en unknown
- 2005-11-30 NO NO20055661A patent/NO333033B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR101144881B1 (ko) | 2012-05-14 |
| US8283431B2 (en) | 2012-10-09 |
| PL1618137T3 (pl) | 2008-11-28 |
| EP1618137A1 (en) | 2006-01-25 |
| MY136934A (en) | 2008-11-28 |
| SA04250201B1 (ar) | 2009-02-07 |
| TW200500380A (en) | 2005-01-01 |
| AU2004234056A1 (en) | 2004-11-11 |
| RU2005137324A (ru) | 2006-05-27 |
| JP2006525389A (ja) | 2006-11-09 |
| DE602004014359D1 (de) | 2008-07-24 |
| CN100347203C (zh) | 2007-11-07 |
| MXPA05011727A (es) | 2006-01-23 |
| ATE398143T1 (de) | 2008-07-15 |
| US20060149014A1 (en) | 2006-07-06 |
| NO20055661L (no) | 2005-11-30 |
| JP4896709B2 (ja) | 2012-03-14 |
| CA2524135C (en) | 2012-07-24 |
| CN1780861A (zh) | 2006-05-31 |
| WO2004096871A1 (en) | 2004-11-11 |
| RU2349603C2 (ru) | 2009-03-20 |
| CA2524135A1 (en) | 2004-11-11 |
| ZA200509705B (en) | 2006-12-27 |
| BRPI0409857B1 (pt) | 2014-12-02 |
| BRPI0409857A (pt) | 2006-05-16 |
| AU2004234056B2 (en) | 2008-10-02 |
| EP1618137B1 (en) | 2008-06-11 |
| KR20060015564A (ko) | 2006-02-17 |
| TW200424217A (en) | 2004-11-16 |
| ES2307011T3 (es) | 2008-11-16 |
| TWI346668B (en) | 2011-08-11 |
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