NO327829B1 - Anvendelse av et ekstraheringsmiddel som et antiskummiddel ved fremstilling av vannfri maursyre - Google Patents
Anvendelse av et ekstraheringsmiddel som et antiskummiddel ved fremstilling av vannfri maursyre Download PDFInfo
- Publication number
- NO327829B1 NO327829B1 NO20023513A NO20023513A NO327829B1 NO 327829 B1 NO327829 B1 NO 327829B1 NO 20023513 A NO20023513 A NO 20023513A NO 20023513 A NO20023513 A NO 20023513A NO 327829 B1 NO327829 B1 NO 327829B1
- Authority
- NO
- Norway
- Prior art keywords
- extractant
- distillation
- formic acid
- carrying
- distillation device
- Prior art date
Links
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title claims abstract description 102
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 235000019253 formic acid Nutrition 0.000 title claims abstract description 51
- 239000002518 antifoaming agent Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title description 2
- 238000004821 distillation Methods 0.000 claims abstract description 76
- 238000000034 method Methods 0.000 claims abstract description 39
- 125000003118 aryl group Chemical group 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 7
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- 125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 6
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract description 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims abstract description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 42
- 238000006460 hydrolysis reaction Methods 0.000 claims description 42
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 42
- 230000007062 hydrolysis Effects 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 238000000605 extraction Methods 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 13
- 150000003254 radicals Chemical class 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 238000003786 synthesis reaction Methods 0.000 claims description 7
- 150000003857 carboxamides Chemical class 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- NZMAJUHVSZBJHL-UHFFFAOYSA-N n,n-dibutylformamide Chemical compound CCCCN(C=O)CCCC NZMAJUHVSZBJHL-UHFFFAOYSA-N 0.000 claims description 4
- 238000007700 distillative separation Methods 0.000 claims description 3
- 238000000622 liquid--liquid extraction Methods 0.000 claims description 3
- FWHFWYKSIPTXBJ-UHFFFAOYSA-N n-butyl-n-cyclohexylformamide Chemical compound CCCCN(C=O)C1CCCCC1 FWHFWYKSIPTXBJ-UHFFFAOYSA-N 0.000 claims description 3
- HPWNCPYWUHXVNZ-UHFFFAOYSA-N n-butyl-n-ethylheptanamide Chemical compound CCCCCCC(=O)N(CC)CCCC HPWNCPYWUHXVNZ-UHFFFAOYSA-N 0.000 claims description 3
- GBDYFPAHVXJQEP-UHFFFAOYSA-N n-ethyl-n-phenylformamide Chemical compound CCN(C=O)C1=CC=CC=C1 GBDYFPAHVXJQEP-UHFFFAOYSA-N 0.000 claims description 3
- LYELEANKTIGQME-UHFFFAOYSA-N n-heptan-2-yl-n-methylformamide Chemical compound CCCCCC(C)N(C)C=O LYELEANKTIGQME-UHFFFAOYSA-N 0.000 claims description 3
- 238000000638 solvent extraction Methods 0.000 claims description 3
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 238000010626 work up procedure Methods 0.000 abstract 1
- 238000005187 foaming Methods 0.000 description 12
- 238000000926 separation method Methods 0.000 description 8
- 238000009835 boiling Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- KIZCCPGSHHAFRX-UHFFFAOYSA-N 1-hydroxybutyl formate Chemical compound CCCC(O)OC=O KIZCCPGSHHAFRX-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000895 extractive distillation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- MEXKFCWMWJZDMF-UHFFFAOYSA-N n,n-dibutylacetamide Chemical compound CCCCN(C(C)=O)CCCC MEXKFCWMWJZDMF-UHFFFAOYSA-N 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
- C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Medicinal Preparation (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10002793A DE10002793A1 (de) | 2000-01-24 | 2000-01-24 | Verwendung eines Extraktionsmittels bei der Herstellung von wasserfreier Ameisensäure |
| PCT/EP2001/000749 WO2001055071A1 (fr) | 2000-01-24 | 2001-01-24 | Utilisation d'un agent d'extraction en tant qu'agent anti-mousse lors de la production d'acide formique anhydre |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20023513D0 NO20023513D0 (no) | 2002-07-23 |
| NO20023513L NO20023513L (no) | 2002-08-26 |
| NO327829B1 true NO327829B1 (no) | 2009-10-05 |
Family
ID=7628464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20023513A NO327829B1 (no) | 2000-01-24 | 2002-07-23 | Anvendelse av et ekstraheringsmiddel som et antiskummiddel ved fremstilling av vannfri maursyre |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6838579B2 (fr) |
| EP (1) | EP1250307B1 (fr) |
| JP (1) | JP4746242B2 (fr) |
| KR (1) | KR100771709B1 (fr) |
| CN (1) | CN1271033C (fr) |
| AT (1) | ATE396167T1 (fr) |
| AU (1) | AU2001228487A1 (fr) |
| BR (1) | BR0107822B1 (fr) |
| DE (2) | DE10002793A1 (fr) |
| MY (1) | MY136296A (fr) |
| NO (1) | NO327829B1 (fr) |
| WO (1) | WO2001055071A1 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1517978A1 (fr) * | 2002-06-26 | 2005-03-30 | Dorf Ketal Chemicals India Pvt. Ltd. | Procede d'elimination de composes carbonyle et de gaz acides a partir de gaz de craquage dans une operation utilisant de l'ethylene |
| US7906012B2 (en) | 2002-07-16 | 2011-03-15 | Dorf Ketal Chemicals India Pvt. Ltd. | Method for reducing foam in a primary fractionator |
| CN101391945B (zh) * | 2008-10-27 | 2012-01-11 | 浙江工业大学 | 一种甲酸提纯的新方法 |
| DE102011075777A1 (de) * | 2011-05-13 | 2012-11-15 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Isophoron in Gegenwart mindestens eines Entschäumers in der Abwasserkolonne im Aufarbeitungsteil |
| CN109234530B (zh) * | 2018-09-11 | 2023-12-08 | 福建紫金选矿药剂有限公司 | 一种高性能萃取稀释剂 |
| CN115353450A (zh) * | 2022-09-26 | 2022-11-18 | 河北康壮环保科技股份有限公司 | 一种稀甲酸浓缩的工艺 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2545658C2 (de) * | 1975-10-11 | 1985-12-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Gewinnung von Carbonsäuren aus ihren wäßrigen Lösungen |
| DE2914671A1 (de) * | 1979-04-11 | 1980-10-23 | Basf Ag | Verfahren zur gewinnung von wasserfreier oder weitgehend wasserfreier ameisensaeure |
| DE3319651A1 (de) * | 1983-05-31 | 1984-12-06 | Basf Ag, 6700 Ludwigshafen | Verfahren zur destillativen gewinnung von ameisensaeure |
| DE3411384A1 (de) | 1984-03-28 | 1985-10-10 | Basf Ag, 6700 Ludwigshafen | Verfahren zur gewinnung von wasserfreier oder weitgehend wasserfreier ameisensaeure durch hydrolyse von methylformiat |
-
2000
- 2000-01-24 DE DE10002793A patent/DE10002793A1/de not_active Withdrawn
-
2001
- 2001-01-17 MY MYPI20010197A patent/MY136296A/en unknown
- 2001-01-24 KR KR1020027009418A patent/KR100771709B1/ko not_active IP Right Cessation
- 2001-01-24 US US10/181,460 patent/US6838579B2/en not_active Expired - Lifetime
- 2001-01-24 EP EP01946840A patent/EP1250307B1/fr not_active Expired - Lifetime
- 2001-01-24 CN CNB018040632A patent/CN1271033C/zh not_active Expired - Fee Related
- 2001-01-24 DE DE50113988T patent/DE50113988D1/de not_active Expired - Lifetime
- 2001-01-24 WO PCT/EP2001/000749 patent/WO2001055071A1/fr active IP Right Grant
- 2001-01-24 BR BRPI0107822-4A patent/BR0107822B1/pt not_active IP Right Cessation
- 2001-01-24 AT AT01946840T patent/ATE396167T1/de not_active IP Right Cessation
- 2001-01-24 JP JP2001555015A patent/JP4746242B2/ja not_active Expired - Fee Related
- 2001-01-24 AU AU2001228487A patent/AU2001228487A1/en not_active Abandoned
-
2002
- 2002-07-23 NO NO20023513A patent/NO327829B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR0107822A (pt) | 2002-10-29 |
| WO2001055071A1 (fr) | 2001-08-02 |
| ATE396167T1 (de) | 2008-06-15 |
| US20030009057A1 (en) | 2003-01-09 |
| KR100771709B1 (ko) | 2007-10-30 |
| MY136296A (en) | 2008-09-30 |
| BR0107822B1 (pt) | 2011-07-12 |
| US6838579B2 (en) | 2005-01-04 |
| EP1250307A1 (fr) | 2002-10-23 |
| JP4746242B2 (ja) | 2011-08-10 |
| NO20023513L (no) | 2002-08-26 |
| NO20023513D0 (no) | 2002-07-23 |
| EP1250307B1 (fr) | 2008-05-21 |
| JP2003520834A (ja) | 2003-07-08 |
| CN1395553A (zh) | 2003-02-05 |
| DE10002793A1 (de) | 2001-07-26 |
| AU2001228487A1 (en) | 2001-08-07 |
| DE50113988D1 (de) | 2008-07-03 |
| CN1271033C (zh) | 2006-08-23 |
| KR20020070350A (ko) | 2002-09-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP1117629B1 (fr) | Purification de l'acetate d'ethyle de melanges qui contiennent de l'ethanol et de l'eau par distillation a pression alternee | |
| FI80218C (fi) | Foerfarande och anlaeggning foer rening av en tvaokomponentvaetskeblandning medelst destillering. | |
| JP4908712B2 (ja) | 無水ギ酸の製造方法 | |
| US10508074B2 (en) | Method for purifying (meth)acrylic esters | |
| NO327831B1 (no) | Behandling av avlopsvann i en fremgangsmate for fremstilling av vannfri maursyre | |
| GB958828A (en) | Purification of synthetic methanol | |
| NO327829B1 (no) | Anvendelse av et ekstraheringsmiddel som et antiskummiddel ved fremstilling av vannfri maursyre | |
| US6673955B2 (en) | Preparation of triethyl phosphate | |
| KR100830758B1 (ko) | 폐가스 흐름의 세정 방법 | |
| JP2004149421A (ja) | ジメチルアミド化合物とカルボン酸を蒸留分離する方法及びその装置 | |
| BR112020022956B1 (pt) | Processo para a recuperação/purificação de acrilatos leves a partir de uma mistura de reação resultante da esterificação de ácido acrílico com metanol ou etanol | |
| US9133094B2 (en) | Apparatus and process for nitration selectivity flexibility enabled by azeotropic distillation | |
| CN112430185B (zh) | 一种用于蒸馏纯化2,2,4-三甲基-1,3-戊二醇单异丁酸酯的方法 | |
| CN113698275A (zh) | 一种从碳酸二甲酯、乙酸甲酯、甲醇体系中回收甲醇的装置与方法 | |
| WO2024126086A1 (fr) | Procédé amélioré pour préparer des composés d'alcoxyde métallique | |
| WO2017174463A8 (fr) | Procédé de préparation d'acétate de vinyle |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |