NO320562B1 - Blandinger av polyolefin elastomerer og anvendelse derav - Google Patents
Blandinger av polyolefin elastomerer og anvendelse derav Download PDFInfo
- Publication number
- NO320562B1 NO320562B1 NO19983357A NO983357A NO320562B1 NO 320562 B1 NO320562 B1 NO 320562B1 NO 19983357 A NO19983357 A NO 19983357A NO 983357 A NO983357 A NO 983357A NO 320562 B1 NO320562 B1 NO 320562B1
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- Prior art keywords
- polymer
- component
- slep
- ethylene
- crystallinity
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- 239000000203 mixture Substances 0.000 title claims description 132
- 229920006124 polyolefin elastomer Polymers 0.000 title description 6
- 229920000642 polymer Polymers 0.000 claims description 128
- 229920000573 polyethylene Polymers 0.000 claims description 116
- 239000005977 Ethylene Substances 0.000 claims description 88
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 87
- 229920002959 polymer blend Polymers 0.000 claims description 85
- -1 1-isobutylene Natural products 0.000 claims description 75
- 229920001577 copolymer Polymers 0.000 claims description 39
- 239000004711 α-olefin Substances 0.000 claims description 34
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 239000000155 melt Substances 0.000 claims description 27
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 24
- 238000002844 melting Methods 0.000 claims description 24
- 238000001125 extrusion Methods 0.000 claims description 23
- 230000008018 melting Effects 0.000 claims description 23
- 238000007906 compression Methods 0.000 claims description 22
- 230000006835 compression Effects 0.000 claims description 22
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims description 21
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims description 21
- 238000009826 distribution Methods 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 150000001993 dienes Chemical class 0.000 claims description 14
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 12
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 12
- 229920001897 terpolymer Polymers 0.000 claims description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 10
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- 238000004132 cross linking Methods 0.000 claims description 10
- 238000005227 gel permeation chromatography Methods 0.000 claims description 10
- 238000000518 rheometry Methods 0.000 claims description 9
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 claims description 8
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 7
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 229920001567 vinyl ester resin Polymers 0.000 claims description 4
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 claims description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 3
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 claims description 3
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 3
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- UCKITPBQPGXDHV-UHFFFAOYSA-N 7-methylocta-1,6-diene Chemical compound CC(C)=CCCCC=C UCKITPBQPGXDHV-UHFFFAOYSA-N 0.000 claims description 2
- 238000000034 method Methods 0.000 description 71
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 46
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- 239000000523 sample Substances 0.000 description 34
- 239000000463 material Substances 0.000 description 31
- 238000002156 mixing Methods 0.000 description 30
- ZCBSOTLLNBJIEK-UHFFFAOYSA-N silane titanium Chemical compound [SiH4].[Ti] ZCBSOTLLNBJIEK-UHFFFAOYSA-N 0.000 description 27
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- 238000006116 polymerization reaction Methods 0.000 description 25
- 239000000178 monomer Substances 0.000 description 23
- 230000008569 process Effects 0.000 description 22
- 150000001875 compounds Chemical class 0.000 description 19
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
- 239000000243 solution Substances 0.000 description 18
- JFLKFZNIIQFQBS-FNCQTZNRSA-N trans,trans-1,4-Diphenyl-1,3-butadiene Chemical compound C=1C=CC=CC=1\C=C\C=C\C1=CC=CC=C1 JFLKFZNIIQFQBS-FNCQTZNRSA-N 0.000 description 18
- 239000003085 diluting agent Substances 0.000 description 17
- 125000001891 dimethoxy group Chemical group [H]C([H])([H])O* 0.000 description 17
- 125000005745 ethoxymethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])* 0.000 description 17
- 239000010410 layer Substances 0.000 description 17
- 239000002904 solvent Substances 0.000 description 17
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- 239000011347 resin Substances 0.000 description 15
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- 206010017076 Fracture Diseases 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- 208000010392 Bone Fractures Diseases 0.000 description 13
- 229920001684 low density polyethylene Polymers 0.000 description 13
- 239000004698 Polyethylene Substances 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 238000001816 cooling Methods 0.000 description 11
- 230000006872 improvement Effects 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
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- 239000002002 slurry Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 239000004702 low-density polyethylene Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000003431 cross linking reagent Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 9
- 238000001746 injection moulding Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 8
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 229920001903 high density polyethylene Polymers 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 229920000554 ionomer Polymers 0.000 description 8
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 8
- 229920000098 polyolefin Polymers 0.000 description 8
- 239000000454 talc Substances 0.000 description 8
- 229910052623 talc Inorganic materials 0.000 description 8
- 235000012222 talc Nutrition 0.000 description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 7
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 229920000092 linear low density polyethylene Polymers 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 7
- 239000004033 plastic Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 230000003213 activating effect Effects 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000005038 ethylene vinyl acetate Substances 0.000 description 6
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 6
- 239000004700 high-density polyethylene Substances 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 239000007924 injection Substances 0.000 description 6
- 238000002347 injection Methods 0.000 description 6
- 210000003739 neck Anatomy 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 5
- 239000004707 linear low-density polyethylene Substances 0.000 description 5
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 5
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- 238000004736 wide-angle X-ray diffraction Methods 0.000 description 5
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
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- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 4
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- 150000004696 coordination complex Chemical class 0.000 description 4
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 4
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- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1030396P | 1996-01-22 | 1996-01-22 | |
| US1343096P | 1996-03-14 | 1996-03-14 | |
| PCT/US1997/001180 WO1997026297A1 (en) | 1996-01-22 | 1997-01-22 | Polyolefin elastomer blends exhibiting improved properties |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO983357D0 NO983357D0 (no) | 1998-07-21 |
| NO983357L NO983357L (no) | 1998-09-22 |
| NO320562B1 true NO320562B1 (no) | 2005-12-19 |
Family
ID=26681013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19983357A NO320562B1 (no) | 1996-01-22 | 1998-07-21 | Blandinger av polyolefin elastomerer og anvendelse derav |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US6005053A (de) |
| EP (1) | EP0876427B1 (de) |
| JP (1) | JP3840499B2 (de) |
| KR (1) | KR100445310B1 (de) |
| CN (1) | CN1111563C (de) |
| AR (1) | AR012814A1 (de) |
| AT (1) | ATE224929T1 (de) |
| AU (1) | AU716317B2 (de) |
| BR (1) | BR9707298A (de) |
| CA (1) | CA2243852C (de) |
| CZ (1) | CZ230898A3 (de) |
| DE (2) | DE69715818T2 (de) |
| ES (1) | ES2123484T3 (de) |
| HU (1) | HUP9900394A3 (de) |
| MX (1) | MX9805832A (de) |
| NO (1) | NO320562B1 (de) |
| PL (1) | PL327988A1 (de) |
| PT (1) | PT876427E (de) |
| TR (1) | TR199801405T2 (de) |
| TW (1) | TW406107B (de) |
| WO (1) | WO1997026297A1 (de) |
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| US20020156536A1 (en) * | 1996-02-13 | 2002-10-24 | Harris William H. | Polyethylene hip joint prosthesis with extended range of motion |
| NZ331107A (en) | 1996-02-13 | 2000-04-28 | Gen Hospital Corp | Radiation and melt treated ultra high molecular weight polyethylene prosthetic devices |
| US8865788B2 (en) * | 1996-02-13 | 2014-10-21 | The General Hospital Corporation | Radiation and melt treated ultra high molecular weight polyethylene prosthetic devices |
| US8563623B2 (en) | 1996-02-13 | 2013-10-22 | The General Hospital Corporation | Radiation melt treated ultra high molecular weight polyethylene prosthetic devices |
| EP1795212A3 (de) | 1996-07-09 | 2007-09-05 | Orthopaedic Hospital | Vernetzung von Polyethylen für geringen Verschleiss mit Hilfe von Strahlen- und Wärmebehandlung |
| US6610408B1 (en) * | 1996-11-08 | 2003-08-26 | Solvay Engineered Polymers | TPO blends containing multimodal elastomers |
| US5928740A (en) * | 1997-02-28 | 1999-07-27 | Viskase Corporation | Thermoplastic C2 -α-olefin copolymer blends and films |
| EP0870803A1 (de) * | 1997-04-07 | 1998-10-14 | Phillips Petroleum Company | Ein Verfahren zur Herstellung von einer vernetzten Ethylen enthaltenden Polymer enthaltende Zusammensetzung und eine vernetzte Ethylen enthaltenden Polymer enthaltende Zusammensetzung |
| ES2247714T3 (es) * | 1997-08-07 | 2006-03-01 | Tarkett Sommer S.A. | Revestimiento de suelos, de paredes, o productos de insonorizacion obtenidos a partir de materiales plasticos cargados. |
| JP2001514273A (ja) | 1997-08-27 | 2001-09-11 | ザ ダウ ケミカル カンパニー | 改良された加工性を有するエラストマー |
| US6096668A (en) * | 1997-09-15 | 2000-08-01 | Kimberly-Clark Worldwide, Inc. | Elastic film laminates |
| US6909028B1 (en) * | 1997-09-15 | 2005-06-21 | Kimberly-Clark Worldwide, Inc. | Stable breathable elastic garments |
| US6313241B1 (en) * | 1997-10-01 | 2001-11-06 | Cryovac, Inc. | Narrow molecular weight distribution copolymers containing long chain branches and process to form same |
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| AR018359A1 (es) | 1998-05-18 | 2001-11-14 | Dow Global Technologies Inc | Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano |
| US6709742B2 (en) | 1998-05-18 | 2004-03-23 | Dow Global Technologies Inc. | Crosslinked elastic fibers |
| US6207237B1 (en) * | 1998-09-30 | 2001-03-27 | Kimberly-Clark Corporation | Elastic nonwoven webs and films |
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| US20100239796A1 (en) * | 2009-03-23 | 2010-09-23 | Gagne Joseph Donald | Lap sealable laminate and packaging made therefrom |
| EP2256159A1 (de) | 2009-05-26 | 2010-12-01 | Borealis AG | Polymerzusammensetzung für vernetzte Rohre |
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| CN109072051B (zh) | 2016-03-08 | 2023-12-26 | 霍尼韦尔国际公司 | 相变材料 |
| IL263812B2 (en) | 2016-06-20 | 2023-09-01 | Shionogi & Co | A process for the preparation of a polycyclic derivative of a modified pyridone and a hymane crystal |
| US10501671B2 (en) | 2016-07-26 | 2019-12-10 | Honeywell International Inc. | Gel-type thermal interface material |
| US11041103B2 (en) | 2017-09-08 | 2021-06-22 | Honeywell International Inc. | Silicone-free thermal gel |
| US10428256B2 (en) | 2017-10-23 | 2019-10-01 | Honeywell International Inc. | Releasable thermal gel |
| US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
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1997
- 1997-01-22 US US08/784,681 patent/US6005053A/en not_active Expired - Lifetime
- 1997-01-22 WO PCT/US1997/001180 patent/WO1997026297A1/en not_active Application Discontinuation
- 1997-01-22 AR ARP970100252A patent/AR012814A1/es unknown
- 1997-01-22 AU AU17095/97A patent/AU716317B2/en not_active Ceased
- 1997-01-22 HU HU9900394A patent/HUP9900394A3/hu unknown
- 1997-01-22 PT PT97903105T patent/PT876427E/pt unknown
- 1997-01-22 DE DE69715818T patent/DE69715818T2/de not_active Expired - Lifetime
- 1997-01-22 CA CA002243852A patent/CA2243852C/en not_active Expired - Fee Related
- 1997-01-22 TR TR1998/01405T patent/TR199801405T2/xx unknown
- 1997-01-22 DE DE0876427T patent/DE876427T1/de active Pending
- 1997-01-22 JP JP52630897A patent/JP3840499B2/ja not_active Expired - Lifetime
- 1997-01-22 AT AT97903105T patent/ATE224929T1/de active
- 1997-01-22 EP EP97903105A patent/EP0876427B1/de not_active Expired - Lifetime
- 1997-01-22 PL PL97327988A patent/PL327988A1/xx unknown
- 1997-01-22 BR BR9707298A patent/BR9707298A/pt not_active IP Right Cessation
- 1997-01-22 CZ CZ982308A patent/CZ230898A3/cs unknown
- 1997-01-22 KR KR10-1998-0705625A patent/KR100445310B1/ko not_active IP Right Cessation
- 1997-01-22 ES ES97903105T patent/ES2123484T3/es not_active Expired - Lifetime
- 1997-01-22 CN CN97191819A patent/CN1111563C/zh not_active Expired - Lifetime
- 1997-01-29 TW TW086101006A patent/TW406107B/zh not_active IP Right Cessation
-
1998
- 1998-07-20 MX MX9805832A patent/MX9805832A/es active IP Right Grant
- 1998-07-21 NO NO19983357A patent/NO320562B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR9707298A (pt) | 1999-07-20 |
| DE69715818D1 (de) | 2002-10-31 |
| MX9805832A (es) | 1998-10-31 |
| EP0876427B1 (de) | 2002-09-25 |
| CZ230898A3 (cs) | 1998-12-16 |
| JP3840499B2 (ja) | 2006-11-01 |
| PL327988A1 (en) | 1999-01-04 |
| EP0876427A1 (de) | 1998-11-11 |
| AU1709597A (en) | 1997-08-11 |
| DE69715818T2 (de) | 2003-06-18 |
| CA2243852C (en) | 2006-11-07 |
| CN1209828A (zh) | 1999-03-03 |
| TW406107B (en) | 2000-09-21 |
| AR012814A1 (es) | 2000-11-22 |
| KR19990081912A (ko) | 1999-11-15 |
| CN1111563C (zh) | 2003-06-18 |
| HUP9900394A2 (hu) | 1999-05-28 |
| WO1997026297A1 (en) | 1997-07-24 |
| HUP9900394A3 (en) | 2000-08-28 |
| US6005053A (en) | 1999-12-21 |
| DE876427T1 (de) | 1999-05-06 |
| ES2123484T1 (es) | 1999-01-16 |
| NO983357L (no) | 1998-09-22 |
| CA2243852A1 (en) | 1997-07-24 |
| TR199801405T2 (xx) | 1998-10-21 |
| ATE224929T1 (de) | 2002-10-15 |
| AU716317B2 (en) | 2000-02-24 |
| PT876427E (pt) | 2003-01-31 |
| JP2000503332A (ja) | 2000-03-21 |
| NO983357D0 (no) | 1998-07-21 |
| ES2123484T3 (es) | 2003-02-16 |
| KR100445310B1 (ko) | 2004-10-15 |
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| MM1K | Lapsed by not paying the annual fees |