NO306603B1 - Fremgangsmåte til å inhibere trimerisasjonskatalysatoraktivitet - Google Patents

Fremgangsmåte til å inhibere trimerisasjonskatalysatoraktivitet

Info

Publication number
NO306603B1
NO306603B1 NO950613A NO950613A NO306603B1 NO 306603 B1 NO306603 B1 NO 306603B1 NO 950613 A NO950613 A NO 950613A NO 950613 A NO950613 A NO 950613A NO 306603 B1 NO306603 B1 NO 306603B1
Authority
NO
Norway
Prior art keywords
trimerization catalyst
inhibiting
catalyst activity
aqueous
precipitate
Prior art date
Application number
NO950613A
Other languages
English (en)
Norwegian (no)
Other versions
NO950613D0 (no
NO950613L (no
Inventor
Mark E Lashier
Jeffrey W Freeman
Ronald D Knudsen
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Publication of NO950613D0 publication Critical patent/NO950613D0/no
Publication of NO950613L publication Critical patent/NO950613L/no
Publication of NO306603B1 publication Critical patent/NO306603B1/no

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122Metal aryl or alkyl compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223At least two oxygen atoms present in one at least bidentate or bridging ligand
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234Beta-dicarbonyl ligands, e.g. acetylacetonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40Regeneration or reactivation
    • B01J31/4015Regeneration or reactivation of catalysts containing metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/30Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/005Processes comprising at least two steps in series
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/148Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/14833Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with metals or their inorganic compounds
    • C07C7/1485Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with metals or their inorganic compounds oxides; hydroxides; salts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/148Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/17Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with acids or sulfur oxides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/148Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/17Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with acids or sulfur oxides
    • C07C7/171Sulfuric acid or oleum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20Olefin oligomerisation or telomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235Nitrogen containing compounds
    • B01J31/0244Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
NO950613A 1994-02-18 1995-02-17 Fremgangsmåte til å inhibere trimerisasjonskatalysatoraktivitet NO306603B1 (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US19986194A 1994-02-18 1994-02-18

Publications (3)

Publication Number Publication Date
NO950613D0 NO950613D0 (no) 1995-02-17
NO950613L NO950613L (no) 1995-08-21
NO306603B1 true NO306603B1 (no) 1999-11-29

Family

ID=22739331

Family Applications (1)

Application Number Title Priority Date Filing Date
NO950613A NO306603B1 (no) 1994-02-18 1995-02-17 Fremgangsmåte til å inhibere trimerisasjonskatalysatoraktivitet

Country Status (18)

Country Link
US (1) US5689028A (pt)
EP (1) EP0668106B1 (pt)
JP (1) JP3184724B2 (pt)
KR (1) KR100306559B1 (pt)
CN (1) CN1090535C (pt)
AT (1) ATE174890T1 (pt)
AU (1) AU664811B2 (pt)
BR (1) BR9405298A (pt)
CA (1) CA2134503C (pt)
DE (1) DE69506747T2 (pt)
DK (1) DK0668106T3 (pt)
ES (1) ES2125500T3 (pt)
HU (1) HU219364B (pt)
NO (1) NO306603B1 (pt)
RU (1) RU2131405C1 (pt)
SG (1) SG46243A1 (pt)
TW (1) TW303369B (pt)
ZA (1) ZA949493B (pt)

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US6455648B1 (en) 1999-12-29 2002-09-24 Chevron Phillips Chemical Company Lp Olefin production
RU2249585C2 (ru) * 1999-12-29 2005-04-10 Филлипс Петролеум Компани Способ олигомеризации (варианты) и способ предотвращения коррозии в процессе олигомеризации
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US20050187418A1 (en) * 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US7384886B2 (en) * 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) * 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) * 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7476775B2 (en) 2004-03-03 2009-01-13 Chevron Phillips Chemical Company Lp Method and system for separating an oligomerization reactor effluent
EP1752433B1 (en) * 2005-08-10 2012-10-03 Linde AG Improved drying process for linear alpha-olefins
US7858833B2 (en) 2006-02-03 2010-12-28 Exxonmobil Chemical Patents Inc. Process for generating linear alpha olefin comonomers
US7687672B2 (en) 2006-02-03 2010-03-30 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US9421534B2 (en) * 2006-12-28 2016-08-23 Mitsubishi Chemical Corporation Production method of α-olefin low polymer
JP2007314561A (ja) * 2007-07-24 2007-12-06 Mitsubishi Chemicals Corp α−オレフイン低重合体の製造方法
US7902415B2 (en) * 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
CA2639882C (en) * 2008-09-29 2016-07-12 Nova Chemicals Corporation Tetramerization
CA2639870A1 (en) * 2008-09-29 2010-03-29 Nova Chemicals Corporation Trimerization
US8471085B2 (en) * 2008-10-31 2013-06-25 Chevron Phillips Chemical Company Lp Oligomerization catalyst system and process for oligomerizing olefins
AU2009308790B2 (en) * 2008-10-31 2015-05-07 Chevron Phillips Chemical Company Lp Compositions and catalyst systems of metal precursors and olefinic diluents
US8227653B2 (en) 2009-03-27 2012-07-24 Exxonmobil Chemical Patents Inc. Olefin oligomerization reaction processes exhibiting reduced fouling
US20120142988A1 (en) * 2009-08-05 2012-06-07 Sumitomo Chemical Company, Limited Method of producing 1-hexene
EP2354113A1 (en) 2010-02-04 2011-08-10 Linde AG Method for deactivation of a catalyst
WO2011112184A1 (en) 2010-03-09 2011-09-15 Exxonmobil Chemical Patents Inc. System and method for selective trimerization
CN103260777B (zh) 2010-12-14 2015-04-01 沙索技术有限公司 工艺设备的清洗
RU2471762C1 (ru) * 2011-06-22 2013-01-10 Открытое акционерное общество "СИБУР Холдинг" (ОАО "СИБУР Холдинг") Способ выделения продуктов олигомеризации олефинов и разложения остатков катализатора олигомеризации
US8957235B2 (en) 2011-12-12 2015-02-17 Chevron Phillips Chemical Company Lp Preparation of transition metal carboxylates
US9956548B2 (en) 2011-12-12 2018-05-01 Chevron Phillips Chemical Company Lp Preparation of an olefin oligomerization catalyst
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
US8524972B1 (en) 2012-04-18 2013-09-03 Exxonmobil Chemical Patents Inc. Low temperature steam stripping for byproduct polymer and solvent recovery from an ethylene oligomerization process
US9175109B1 (en) 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
KR102113798B1 (ko) 2014-12-23 2020-05-21 퍼블릭 조인트 스톡 컴퍼니 “시부르 홀딩” 올레핀 올리고머화 반응에서 폴리머 및 불활성화된 유기금속 촉매의 침전 방법
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
WO2017010998A1 (en) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Olefin compositions
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
CN118767993A (zh) * 2015-09-16 2024-10-15 沙特基础工业全球技术有限公司 用于烯烃低聚催化剂的失活的方法
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US11878952B1 (en) 2022-11-14 2024-01-23 Chevron Phillips Chemical Company Lp Oligomerization catalyst system deactivation and related ethylene oligomerization processes

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DE3923256A1 (de) * 1989-07-14 1991-01-24 Hoechst Ag Verfahren zur herstellung von 1,1,1-trifluor-2-chlorethan
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CA2020509C (en) * 1989-08-10 1998-04-28 William K. Reagen Chromium compounds and uses thereof
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EP0433750B1 (de) * 1989-12-16 1993-12-01 Bayer Ag Verfahren zur Herstellung von Chromsäure
TW279167B (pt) * 1993-03-12 1996-06-21 Sumitomo Chemical Co

Also Published As

Publication number Publication date
JP3184724B2 (ja) 2001-07-09
CA2134503C (en) 2001-04-10
HU219364B (en) 2001-03-28
SG46243A1 (en) 1998-02-20
CN1107132A (zh) 1995-08-23
CN1090535C (zh) 2002-09-11
EP0668106B1 (en) 1998-12-23
BR9405298A (pt) 1996-12-24
AU664811B2 (en) 1995-11-30
TW303369B (pt) 1997-04-21
NO950613D0 (no) 1995-02-17
CA2134503A1 (en) 1995-08-19
HUT71640A (en) 1996-01-29
RU95102330A (ru) 1997-01-10
DE69506747T2 (de) 1999-05-20
AU8026194A (en) 1995-08-31
EP0668106A3 (en) 1996-01-31
DK0668106T3 (da) 1999-08-23
KR100306559B1 (ko) 2001-12-01
HU9500484D0 (en) 1995-04-28
RU2131405C1 (ru) 1999-06-10
JPH07242701A (ja) 1995-09-19
DE69506747D1 (de) 1999-02-04
ES2125500T3 (es) 1999-03-01
ZA949493B (en) 1995-08-14
NO950613L (no) 1995-08-21
ATE174890T1 (de) 1999-01-15
EP0668106A2 (en) 1995-08-23
KR950025014A (ko) 1995-09-15
US5689028A (en) 1997-11-18

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