NO300071B1 - Eventuelt fornettede, partielt eller totalt vannopplöselige akrylkopolymerer og deres anvendelse - Google Patents
Eventuelt fornettede, partielt eller totalt vannopplöselige akrylkopolymerer og deres anvendelse Download PDFInfo
- Publication number
- NO300071B1 NO300071B1 NO931692A NO931692A NO300071B1 NO 300071 B1 NO300071 B1 NO 300071B1 NO 931692 A NO931692 A NO 931692A NO 931692 A NO931692 A NO 931692A NO 300071 B1 NO300071 B1 NO 300071B1
- Authority
- NO
- Norway
- Prior art keywords
- weight
- monomer
- ethylenically unsaturated
- acrylic
- copolymer according
- Prior art date
Links
- 229920006243 acrylic copolymer Polymers 0.000 title 1
- 229920001577 copolymer Polymers 0.000 claims description 83
- 239000000178 monomer Substances 0.000 claims description 71
- 125000004432 carbon atom Chemical group C* 0.000 claims description 54
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 43
- 125000000217 alkyl group Chemical group 0.000 claims description 38
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 36
- 239000000725 suspension Substances 0.000 claims description 34
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 20
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- 238000009472 formulation Methods 0.000 claims description 13
- 230000002209 hydrophobic effect Effects 0.000 claims description 11
- 238000000518 rheometry Methods 0.000 claims description 10
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 239000003973 paint Substances 0.000 claims description 8
- 239000003381 stabilizer Substances 0.000 claims description 8
- 239000004753 textile Substances 0.000 claims description 8
- 239000010457 zeolite Substances 0.000 claims description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 238000005553 drilling Methods 0.000 claims description 7
- -1 allylic ethers Chemical class 0.000 claims description 6
- 239000013049 sediment Substances 0.000 claims description 6
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 6
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 5
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 5
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 5
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 5
- 239000002453 shampoo Substances 0.000 claims description 5
- FXNDIJDIPNCZQJ-UHFFFAOYSA-N 2,4,4-trimethylpent-1-ene Chemical group CC(=C)CC(C)(C)C FXNDIJDIPNCZQJ-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 claims description 4
- BXAAQNFGSQKPDZ-UHFFFAOYSA-N 3-[1,2,2-tris(prop-2-enoxy)ethoxy]prop-1-ene Chemical compound C=CCOC(OCC=C)C(OCC=C)OCC=C BXAAQNFGSQKPDZ-UHFFFAOYSA-N 0.000 claims description 4
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 claims description 4
- KBIWOJBFYNSQKW-UHFFFAOYSA-N 3-ethenylphthalic acid Chemical class OC(=O)C1=CC=CC(C=C)=C1C(O)=O KBIWOJBFYNSQKW-UHFFFAOYSA-N 0.000 claims description 4
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims description 4
- QISOBCMNUJQOJU-UHFFFAOYSA-N 4-bromo-1h-pyrazole-5-carboxylic acid Chemical compound OC(=O)C=1NN=CC=1Br QISOBCMNUJQOJU-UHFFFAOYSA-N 0.000 claims description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 150000008064 anhydrides Chemical class 0.000 claims description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- 235000013985 cinnamic acid Nutrition 0.000 claims description 4
- WBYWAXJHAXSJNI-UHFFFAOYSA-N cinnamic acid group Chemical class C(C=CC1=CC=CC=C1)(=O)O WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 4
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims description 4
- 229940018557 citraconic acid Drugs 0.000 claims description 4
- 150000007973 cyanuric acids Chemical class 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000600 sorbitol Substances 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 3
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 3
- 229930016911 cinnamic acid Natural products 0.000 claims description 3
- 239000002537 cosmetic Substances 0.000 claims description 3
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 3
- 239000003599 detergent Substances 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 claims description 3
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- DOEXKUOGPAEBAD-UHFFFAOYSA-N ethyl n-(2-methylprop-2-enoyl)carbamate Chemical compound CCOC(=O)NC(=O)C(C)=C DOEXKUOGPAEBAD-UHFFFAOYSA-N 0.000 claims description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 2
- 239000012764 mineral filler Substances 0.000 claims description 2
- 239000012766 organic filler Substances 0.000 claims description 2
- OCAAZRFBJBEVPS-UHFFFAOYSA-N prop-2-enyl carbamate Chemical compound NC(=O)OCC=C OCAAZRFBJBEVPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000000375 suspending agent Substances 0.000 claims description 2
- 150000003673 urethanes Chemical class 0.000 claims description 2
- 125000000391 vinyl group Chemical class [H]C([*])=C([H])[H] 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims description 2
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 claims 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 34
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 30
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 30
- 238000000034 method Methods 0.000 description 26
- 238000004062 sedimentation Methods 0.000 description 16
- 238000003756 stirring Methods 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 229910000019 calcium carbonate Inorganic materials 0.000 description 15
- 238000005259 measurement Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000008719 thickening Effects 0.000 description 9
- 239000002562 thickening agent Substances 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002270 dispersing agent Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000006071 cream Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 239000004927 clay Substances 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000003139 biocide Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000005429 oxyalkyl group Chemical group 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 101000670226 Homo sapiens Threonine synthase-like 2 Proteins 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 102100039276 Threonine synthase-like 2 Human genes 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- OPVLOHUACNWTQT-UHFFFAOYSA-N azane;2-dodecoxyethyl hydrogen sulfate Chemical compound N.CCCCCCCCCCCCOCCOS(O)(=O)=O OPVLOHUACNWTQT-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
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- Veterinary Medicine (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Birds (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Epidemiology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
- Detergent Compositions (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
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Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9208399A FR2693203B1 (fr) | 1992-07-01 | 1992-07-01 | Copolymère acrylique partiellement ou totalement hydrosoluble, réticulé ou non et son utilisation. |
Publications (3)
Publication Number | Publication Date |
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NO931692D0 NO931692D0 (no) | 1993-05-10 |
NO931692L NO931692L (no) | 1994-01-03 |
NO300071B1 true NO300071B1 (no) | 1997-04-01 |
Family
ID=9431654
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO931692A NO300071B1 (no) | 1992-07-01 | 1993-05-10 | Eventuelt fornettede, partielt eller totalt vannopplöselige akrylkopolymerer og deres anvendelse |
Country Status (10)
Country | Link |
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US (2) | US5294693A (zh) |
EP (3) | EP1997838A3 (zh) |
CA (1) | CA2096083C (zh) |
DE (2) | DE69332494T2 (zh) |
DK (1) | DK0577526T3 (zh) |
ES (2) | ES2315336T3 (zh) |
FI (2) | FI933006A (zh) |
FR (1) | FR2693203B1 (zh) |
HK (1) | HK1052362B (zh) |
NO (1) | NO300071B1 (zh) |
Families Citing this family (95)
Publication number | Priority date | Publication date | Assignee | Title |
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US5759962A (en) * | 1992-01-31 | 1998-06-02 | Institut Francais Du Petrole | Method for inhibiting reactive argillaceous formations and use thereof in a drilling fluid |
US5599784A (en) * | 1994-03-04 | 1997-02-04 | National Starch And Chemical Investment Holding Corporation | Aqueous lamellar detergent compositions with hydrophobically capped hydrophilic polymers |
US5489397A (en) * | 1994-03-04 | 1996-02-06 | National Starch And Chemical Investment Holding Corporation | Aqueous lamellar detergent compositions with hydrophobically terminated hydrophilic polymer |
CA2157691C (en) † | 1994-09-29 | 1998-08-18 | Joseph Doolan | High performance alkali-swellable rheological additives for aqueous systems |
US5874495A (en) * | 1994-10-03 | 1999-02-23 | Rhodia Inc. | Polymers useful as PH responsive thickeners and monomers therefor |
US5639841A (en) * | 1995-02-28 | 1997-06-17 | Union Carbide Chemicals & Plastics Technology Corporation | Polymers containing macromonomer mixtures |
FR2739023B1 (fr) * | 1995-09-21 | 1997-10-31 | Oreal | Composition aqueuse pour le maintien et/ou la fixation des cheveux comprenant un oligomere acrylique filmogene, soluble ou dispersible dans les milieux aqueux et utilisations |
FR2746304B1 (fr) * | 1996-03-21 | 2001-09-07 | Oreal | Compositions cosmetiques detergentes contenant un polyacrylamide epaississant |
US5804207A (en) * | 1996-03-21 | 1998-09-08 | L'oreal | Detergent cosmetic compositions containing a thickening polyacrylamide |
US5798324A (en) * | 1996-04-05 | 1998-08-25 | S.C. Johnson & Son, Inc. | Glass cleaner with adjustable rheology |
NZ328554A (en) * | 1996-08-16 | 1999-01-28 | Nat Starch & Chemical Investme | A polymeric rheology modifier useful in cosmetic compositions |
SG67989A1 (en) * | 1996-08-16 | 1999-10-19 | Nat Starch Chem Invest | Thickened personal care composition |
DE69703427T2 (de) * | 1996-08-16 | 2001-06-13 | National Starch And Chemical Investment Holding Corp., Wilmington | Wässrige zusammensetzungen verdicht mit polymeren rheologiemodifizierern auf acrylatbasis |
US5849674A (en) * | 1996-10-15 | 1998-12-15 | Phillips Petroleum Company | Compositions and processes for oil field applications |
FR2766107B1 (fr) * | 1997-07-18 | 1999-08-20 | Pluss Stauffer Ag | Suspensions aqueuses de matieres minerales et leurs utilisations |
FR2766106B1 (fr) * | 1997-07-18 | 2001-09-07 | Coatex Sa | Utilisation d'un copolymere a structure tensio-active comme agent dispersant et/ou d'aide au broyage |
KR19980018663A (ko) * | 1997-08-14 | 1998-06-05 | 해밀톤 데이비드 엘. | 농후 퍼스널케어조성물 |
US6165454A (en) * | 1997-09-18 | 2000-12-26 | Colgate-Palmolive Company | Stabilized hair care products |
US6159906A (en) * | 1997-10-01 | 2000-12-12 | Rheox, Inc. | Oil well drilling fluids with improved anti-settling properties and methods of providing anti-settling properties to oil well drilling fluids |
FR2773159B1 (fr) * | 1997-12-29 | 2000-03-24 | Rhodia Chimie Sa | Copolymere alcalisoluble associatif diol et son utilisation comme agent epaississant pour le couchage papier |
FR2779647B1 (fr) | 1998-06-15 | 2000-08-04 | Oreal | Composition cosmetique contenant un polymere anionique et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques |
FR2779640B1 (fr) | 1998-06-15 | 2000-08-04 | Oreal | Composition cosmetique contenant un polymere cationique et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques |
FR2779637B1 (fr) * | 1998-06-15 | 2000-09-01 | Oreal | Compositions cosmetiques photoprotectrices, contenant un nanopigment d'oxyde metallique et un terpolymere acrylique et utilisation de ces compositions pour proteger les matieres keratiniques contre le rayonnement ultraviolet |
FR2779638B1 (fr) | 1998-06-15 | 2000-08-04 | Oreal | Composition cosmetique contenant un polysaccharide et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques |
FR2779639B1 (fr) † | 1998-06-15 | 2000-08-04 | Oreal | Composition cosmetique contenant un polyorganosiloxane et un terpolymere acrylique et utilisation de cette composition pour le traitement des matieres keratiniques |
US6762269B1 (en) * | 1998-08-13 | 2004-07-13 | National Starch And Chemical Investment Holding Corporation | High temperature viscosity stable thickener |
FR2792932B1 (fr) * | 1999-04-30 | 2001-07-06 | Coatex Sa | Nouveaux agents de type copolymeres acryliques a base d'urethanne pour ameliorer la maniabilite des liants hydrauliques, leur procede de preparation, les liants les contenant et leurs applications |
US6869996B1 (en) | 1999-06-08 | 2005-03-22 | The Sherwin-Williams Company | Waterborne coating having improved chemical resistance |
WO2000075206A1 (en) * | 1999-06-08 | 2000-12-14 | Union Carbide Chemicals & Plastics | Waterborne thickeners and dispersants having improved chemical resistance |
FR2796403B1 (fr) * | 1999-07-16 | 2001-09-28 | Coatex Sa | Nouvel agent de retention d'eau hydrosoluble en milieu neutre ou alcalin de type copolymere vinylique-acrylique, applications aux sauces de couchage pour papier et carton, et sauces de couchage et papiers et cartons ainsi obtenus |
US20020022585A1 (en) * | 2000-05-30 | 2002-02-21 | The Procter & Gamble Company | Detergent compositions with improved whitening benefits and methods and articles employing same |
FR2810261B1 (fr) * | 2000-06-15 | 2002-08-30 | Coatex Sa | Utilisation de copolymeres faiblement anioniques comme agent dispersant et/ou d'aide au broyage de suspension aqueuse de matieres minerales, suspensions aqueuses obtenues et leurs utilisations |
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DE2758122A1 (de) * | 1977-12-24 | 1979-07-05 | Basf Ag | Wasserloesliche copolymerisate auf der basis von hydrophilen aethylenisch ungesaettigten monomeren |
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DE3311752A1 (de) * | 1983-03-31 | 1984-10-04 | Hoechst Ag, 6230 Frankfurt | Crotonesterhaltige copolymerisate, verfahren zu ihrer herstellung und ihre verwendung als verdicker in waessrigen systemen sowie als schlichtemittel |
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-
1992
- 1992-07-01 FR FR9208399A patent/FR2693203B1/fr not_active Expired - Lifetime
-
1993
- 1993-05-10 NO NO931692A patent/NO300071B1/no not_active IP Right Cessation
- 1993-05-12 CA CA002096083A patent/CA2096083C/fr not_active Expired - Lifetime
- 1993-06-11 DK DK93420239T patent/DK0577526T3/da active
- 1993-06-11 ES ES02076892T patent/ES2315336T3/es not_active Expired - Lifetime
- 1993-06-11 EP EP08013582A patent/EP1997838A3/fr not_active Withdrawn
- 1993-06-11 DE DE69332494T patent/DE69332494T2/de not_active Expired - Lifetime
- 1993-06-11 EP EP02076892A patent/EP1270617B1/fr not_active Expired - Lifetime
- 1993-06-11 ES ES93420239T patent/ES2185622T3/es not_active Expired - Lifetime
- 1993-06-11 DE DE69334245T patent/DE69334245D1/de not_active Expired - Lifetime
- 1993-06-11 EP EP93420239A patent/EP0577526B1/fr not_active Revoked
- 1993-06-29 US US08/083,257 patent/US5294693A/en not_active Expired - Lifetime
- 1993-06-30 FI FI933006A patent/FI933006A/fi not_active Application Discontinuation
- 1993-10-15 US US08/136,282 patent/US5362415A/en not_active Expired - Lifetime
-
2003
- 2003-06-26 HK HK03104597.6A patent/HK1052362B/zh not_active IP Right Cessation
-
2006
- 2006-10-16 FI FI20060912A patent/FI121144B/fi not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
FI121144B (fi) | 2010-07-30 |
EP1270617A3 (fr) | 2003-08-06 |
DE69332494T2 (de) | 2003-10-09 |
FR2693203B1 (fr) | 1994-08-26 |
EP1270617B1 (fr) | 2008-10-22 |
DE69332494D1 (de) | 2003-01-02 |
DE69334245D1 (de) | 2008-12-04 |
ES2315336T3 (es) | 2009-04-01 |
EP0577526A1 (fr) | 1994-01-05 |
CA2096083C (fr) | 2004-08-31 |
FI933006A0 (fi) | 1993-06-30 |
HK1052362B (zh) | 2008-12-12 |
EP0577526B1 (fr) | 2002-11-20 |
NO931692D0 (no) | 1993-05-10 |
US5294693A (en) | 1994-03-15 |
ES2185622T3 (es) | 2003-05-01 |
DK0577526T3 (da) | 2003-03-17 |
EP1270617A2 (fr) | 2003-01-02 |
FI20060912A (fi) | 2006-10-16 |
EP1997838A2 (fr) | 2008-12-03 |
CA2096083A1 (fr) | 1994-01-02 |
FR2693203A1 (fr) | 1994-01-07 |
NO931692L (no) | 1994-01-03 |
HK1052362A1 (en) | 2003-09-11 |
EP1997838A3 (fr) | 2009-04-15 |
US5362415A (en) | 1994-11-08 |
FI933006A (fi) | 1994-01-02 |
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