NO180260B - Vannlöselig trebeskyttelsesmiddel - Google Patents
Vannlöselig trebeskyttelsesmiddel Download PDFInfo
- Publication number
- NO180260B NO180260B NO914101A NO914101A NO180260B NO 180260 B NO180260 B NO 180260B NO 914101 A NO914101 A NO 914101A NO 914101 A NO914101 A NO 914101A NO 180260 B NO180260 B NO 180260B
- Authority
- NO
- Norway
- Prior art keywords
- acid
- water
- compounds
- wood
- copper
- Prior art date
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- 239000003171 wood protecting agent Substances 0.000 title claims description 6
- 239000002253 acid Substances 0.000 claims abstract description 19
- 229910017464 nitrogen compound Inorganic materials 0.000 claims abstract description 11
- 150000002830 nitrogen compounds Chemical class 0.000 claims abstract description 11
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 5
- 150000001412 amines Chemical class 0.000 claims description 17
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- 229920002873 Polyethylenimine Polymers 0.000 claims description 7
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 claims description 3
- 239000005749 Copper compound Substances 0.000 claims 1
- 150000001880 copper compounds Chemical class 0.000 claims 1
- 239000002023 wood Substances 0.000 abstract description 29
- 239000003755 preservative agent Substances 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 7
- 230000000536 complexating effect Effects 0.000 abstract description 3
- -1 polypropylene Polymers 0.000 description 24
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 23
- 229910052802 copper Inorganic materials 0.000 description 23
- 239000010949 copper Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 14
- 229920000768 polyamine Polymers 0.000 description 13
- 150000007513 acids Chemical class 0.000 description 11
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- 235000008504 concentrate Nutrition 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 8
- 238000005470 impregnation Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000002386 leaching Methods 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 6
- 235000011613 Pinus brutia Nutrition 0.000 description 6
- 241000018646 Pinus brutia Species 0.000 description 6
- 238000007792 addition Methods 0.000 description 6
- 230000035515 penetration Effects 0.000 description 6
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 description 6
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 4
- YTOPFCCWCSOHFV-UHFFFAOYSA-N 2,6-dimethyl-4-tridecylmorpholine Chemical compound CCCCCCCCCCCCCN1CC(C)OC(C)C1 YTOPFCCWCSOHFV-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 241000790917 Dioxys <bee> Species 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 3
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 3
- 150000003752 zinc compounds Chemical class 0.000 description 3
- RYAUSSKQMZRMAI-ALOPSCKCSA-N (2S,6R)-4-[3-(4-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine Chemical compound C=1C=C(C(C)(C)C)C=CC=1CC(C)CN1C[C@H](C)O[C@H](C)C1 RYAUSSKQMZRMAI-ALOPSCKCSA-N 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical class C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 2
- ZAXCZCOUDLENMH-UHFFFAOYSA-N 3,3,3-tetramine Chemical compound NCCCNCCCNCCCN ZAXCZCOUDLENMH-UHFFFAOYSA-N 0.000 description 2
- IJFXRHURBJZNAO-UHFFFAOYSA-N 3-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1 IJFXRHURBJZNAO-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- 239000005778 Fenpropimorph Substances 0.000 description 2
- 206010041662 Splinter Diseases 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 2
- OTBHHUPVCYLGQO-UHFFFAOYSA-N bis(3-aminopropyl)amine Chemical compound NCCCNCCCN OTBHHUPVCYLGQO-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 150000001869 cobalt compounds Chemical class 0.000 description 2
- DDISVBZQSSOXFA-UHFFFAOYSA-L copper carbonate dihydrate Chemical compound O.O.[Cu++].[O-]C([O-])=O DDISVBZQSSOXFA-UHFFFAOYSA-L 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002815 nickel Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 229920000962 poly(amidoamine) Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- KEUPLGRNURQXAR-UHFFFAOYSA-N (4-chlorophenyl) acetate Chemical compound CC(=O)OC1=CC=C(Cl)C=C1 KEUPLGRNURQXAR-UHFFFAOYSA-N 0.000 description 1
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 description 1
- WIZMVGOIBVVWHI-UHFFFAOYSA-N 1-[[2-(2,4-dichlorophenyl)-4-ethyl-1,3-dioxolan-2-yl]methyl]imidazole Chemical compound O1C(CC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1C=NC=C1 WIZMVGOIBVVWHI-UHFFFAOYSA-N 0.000 description 1
- NMAWVAOKKSGWHX-UHFFFAOYSA-N 1-[[2-(2,4-dichlorophenyl)-4-methyl-1,3-dioxolan-2-yl]methyl]-1,2,4-triazole Chemical compound O1C(C)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 NMAWVAOKKSGWHX-UHFFFAOYSA-N 0.000 description 1
- LRZAKZPYSBPLLA-UHFFFAOYSA-N 1-[[2-(2,4-dichlorophenyl)-4-pentyl-1,3-dioxolan-2-yl]methyl]-1,2,4-triazole Chemical compound O1C(CCCCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 LRZAKZPYSBPLLA-UHFFFAOYSA-N 0.000 description 1
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 1
- SNUSZUYTMHKCPM-UHFFFAOYSA-N 1-hydroxypyridin-2-one Chemical compound ON1C=CC=CC1=O SNUSZUYTMHKCPM-UHFFFAOYSA-N 0.000 description 1
- DDHUNHGZUHZNKB-UHFFFAOYSA-N 2,2-dimethylpropane-1,3-diamine Chemical compound NCC(C)(C)CN DDHUNHGZUHZNKB-UHFFFAOYSA-N 0.000 description 1
- VTUMIXJWXJGPJW-UHFFFAOYSA-N 2,5-dimethyl-3h-furan-2-carboxylic acid Chemical compound CC1=CCC(C)(C(O)=O)O1 VTUMIXJWXJGPJW-UHFFFAOYSA-N 0.000 description 1
- GDMDOMRUYVLLHM-UHFFFAOYSA-N 2-(1-iodoethyl)pentyl carbamate Chemical compound CCCC(C(C)I)COC(N)=O GDMDOMRUYVLLHM-UHFFFAOYSA-N 0.000 description 1
- QZQNMMLYACBCMJ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octyl)amino]ethanol Chemical compound CCCCCCCCN(CCO)CCO QZQNMMLYACBCMJ-UHFFFAOYSA-N 0.000 description 1
- NJORESDPPZFURG-UHFFFAOYSA-N 2-[3-[2-(4-chlorophenyl)ethyl]-1,2,4-triazol-1-yl]ethanol Chemical compound OCCN1C=NC(CCC2=CC=C(Cl)C=C2)=N1 NJORESDPPZFURG-UHFFFAOYSA-N 0.000 description 1
- RILZRCJGXSFXNE-UHFFFAOYSA-N 2-[4-(trifluoromethoxy)phenyl]ethanol Chemical class OCCC1=CC=C(OC(F)(F)F)C=C1 RILZRCJGXSFXNE-UHFFFAOYSA-N 0.000 description 1
- HZTPKMIMXLTOSK-UHFFFAOYSA-N 2-bromohexanoic acid Chemical compound CCCCC(Br)C(O)=O HZTPKMIMXLTOSK-UHFFFAOYSA-N 0.000 description 1
- GTGTXZRPJHDASG-UHFFFAOYSA-N 2-bromooctanoic acid Chemical compound CCCCCCC(Br)C(O)=O GTGTXZRPJHDASG-UHFFFAOYSA-N 0.000 description 1
- SMNDYUVBFMFKNZ-UHFFFAOYSA-N 2-furoic acid Chemical compound OC(=O)C1=CC=CO1 SMNDYUVBFMFKNZ-UHFFFAOYSA-N 0.000 description 1
- RXFCIXRFAJRBSG-UHFFFAOYSA-N 3,2,3-tetramine Chemical compound NCCCNCCNCCCN RXFCIXRFAJRBSG-UHFFFAOYSA-N 0.000 description 1
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 1
- CDIJOYCNNFLOAX-UHFFFAOYSA-N 4-(trichloromethylsulfanyl)isoindole-1,3-dione Chemical compound ClC(Cl)(Cl)SC1=CC=CC2=C1C(=O)NC2=O CDIJOYCNNFLOAX-UHFFFAOYSA-N 0.000 description 1
- WUBBRNOQWQTFEX-UHFFFAOYSA-N 4-aminosalicylic acid Chemical compound NC1=CC=C(C(O)=O)C(O)=C1 WUBBRNOQWQTFEX-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 1
- AWQSAIIDOMEEOD-UHFFFAOYSA-N 5,5-Dimethyl-4-(3-oxobutyl)dihydro-2(3H)-furanone Chemical compound CC(=O)CCC1CC(=O)OC1(C)C AWQSAIIDOMEEOD-UHFFFAOYSA-N 0.000 description 1
- QTZBTBLHYPSFMG-UHFFFAOYSA-N 5-chloro-3-methylpyridin-2-amine Chemical class CC1=CC(Cl)=CN=C1N QTZBTBLHYPSFMG-UHFFFAOYSA-N 0.000 description 1
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 description 1
- XZOYHFBNQHPJRQ-UHFFFAOYSA-N 7-methyloctanoic acid Chemical compound CC(C)CCCCCC(O)=O XZOYHFBNQHPJRQ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 239000005892 Deltamethrin Substances 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- QTDRLOKFLJJHTG-UHFFFAOYSA-N Furmecyclox Chemical compound C1=C(C)OC(C)=C1C(=O)N(OC)C1CCCCC1 QTDRLOKFLJJHTG-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- YJLYANLCNIKXMG-UHFFFAOYSA-N N-Methyldioctylamine Chemical compound CCCCCCCCN(C)CCCCCCCC YJLYANLCNIKXMG-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000005822 Propiconazole Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- FHKPLLOSJHHKNU-INIZCTEOSA-N [(3S)-3-[8-(1-ethyl-5-methylpyrazol-4-yl)-9-methylpurin-6-yl]oxypyrrolidin-1-yl]-(oxan-4-yl)methanone Chemical compound C(C)N1N=CC(=C1C)C=1N(C2=NC=NC(=C2N=1)O[C@@H]1CN(CC1)C(=O)C1CCOCC1)C FHKPLLOSJHHKNU-INIZCTEOSA-N 0.000 description 1
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- BAZMYXGARXYAEQ-UHFFFAOYSA-N alpha-ethyl valeric acid Chemical compound CCCC(CC)C(O)=O BAZMYXGARXYAEQ-UHFFFAOYSA-N 0.000 description 1
- JTXJZBMXQMTSQN-UHFFFAOYSA-N amino hydrogen carbonate Chemical compound NOC(O)=O JTXJZBMXQMTSQN-UHFFFAOYSA-N 0.000 description 1
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 1
- 229960004909 aminosalicylic acid Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- AKNQMEBLVAMSNZ-UHFFFAOYSA-N azaconazole Chemical compound ClC1=CC(Cl)=CC=C1C1(CN2N=CN=C2)OCCO1 AKNQMEBLVAMSNZ-UHFFFAOYSA-N 0.000 description 1
- AGLSQWBSHDEAHB-UHFFFAOYSA-N azane;boric acid Chemical compound N.OB(O)O AGLSQWBSHDEAHB-UHFFFAOYSA-N 0.000 description 1
- LJOZMWRYMKECFF-UHFFFAOYSA-N benodanil Chemical compound IC1=CC=CC=C1C(=O)NC1=CC=CC=C1 LJOZMWRYMKECFF-UHFFFAOYSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 150000001639 boron compounds Chemical class 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011093 chipboard Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910000009 copper(II) carbonate Inorganic materials 0.000 description 1
- JJLJMEJHUUYSSY-UHFFFAOYSA-L copper(II) hydroxide Inorganic materials [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 1
- AEJIMXVJZFYIHN-UHFFFAOYSA-N copper;dihydrate Chemical compound O.O.[Cu] AEJIMXVJZFYIHN-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- GEQHKFFSPGPGLN-UHFFFAOYSA-N cyclohexane-1,3-diamine Chemical compound NC1CCCC(N)C1 GEQHKFFSPGPGLN-UHFFFAOYSA-N 0.000 description 1
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- KOLPCQCPJGFOMY-UHFFFAOYSA-M decyl(triethyl)phosphanium;bromide Chemical compound [Br-].CCCCCCCCCC[P+](CC)(CC)CC KOLPCQCPJGFOMY-UHFFFAOYSA-M 0.000 description 1
- MKFWXFCYOUBNSN-UHFFFAOYSA-M decyl(trihexyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC MKFWXFCYOUBNSN-UHFFFAOYSA-M 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- WHUHHXPFENAYSA-UHFFFAOYSA-M dodecyl(trimethyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[P+](C)(C)C WHUHHXPFENAYSA-UHFFFAOYSA-M 0.000 description 1
- ZOKWYSXFTXBLSG-UHFFFAOYSA-M dodecyl(triphenyl)phosphanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CCCCCCCCCCCC)C1=CC=CC=C1 ZOKWYSXFTXBLSG-UHFFFAOYSA-M 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- DWRKFAJEBUWTQM-UHFFFAOYSA-N etaconazole Chemical compound O1C(CC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 DWRKFAJEBUWTQM-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- JLYXXMFPNIAWKQ-GNIYUCBRSA-N gamma-hexachlorocyclohexane Chemical compound Cl[C@H]1[C@H](Cl)[C@@H](Cl)[C@@H](Cl)[C@H](Cl)[C@H]1Cl JLYXXMFPNIAWKQ-GNIYUCBRSA-N 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000003977 halocarboxylic acids Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- ZPFZPVSJKFXPAT-UHFFFAOYSA-M hexadecyl-tris(hydroxymethyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[P+](CO)(CO)CO ZPFZPVSJKFXPAT-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229940079865 intestinal antiinfectives imidazole derivative Drugs 0.000 description 1
- 229940102253 isopropanolamine Drugs 0.000 description 1
- 229960002809 lindane Drugs 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- DECZQJJTUZWGMA-UHFFFAOYSA-N methyl-(2-propoxyphenyl)carbamic acid Chemical compound CCCOC1=CC=CC=C1N(C)C(O)=O DECZQJJTUZWGMA-UHFFFAOYSA-N 0.000 description 1
- JWZXKXIUSSIAMR-UHFFFAOYSA-N methylene bis(thiocyanate) Chemical compound N#CSCSC#N JWZXKXIUSSIAMR-UHFFFAOYSA-N 0.000 description 1
- NYNKJVPRTLBJNQ-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCN(CCCN)CCCN NYNKJVPRTLBJNQ-UHFFFAOYSA-N 0.000 description 1
- RVRMXANSMFGKHA-UHFFFAOYSA-N n,n'-didodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCNCCCNCCCCCCCCCCCC RVRMXANSMFGKHA-UHFFFAOYSA-N 0.000 description 1
- RHFUXPCCELGMFC-UHFFFAOYSA-N n-(6-cyano-3-hydroxy-2,2-dimethyl-3,4-dihydrochromen-4-yl)-n-phenylmethoxyacetamide Chemical class OC1C(C)(C)OC2=CC=C(C#N)C=C2C1N(C(=O)C)OCC1=CC=CC=C1 RHFUXPCCELGMFC-UHFFFAOYSA-N 0.000 description 1
- ATBNMWWDBWBAHM-UHFFFAOYSA-N n-decyl-n-methyldecan-1-amine Chemical compound CCCCCCCCCCN(C)CCCCCCCCCC ATBNMWWDBWBAHM-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- PHZYYSZIFIULKU-UHFFFAOYSA-M octadecyl(triphenyl)phosphanium;chloride Chemical compound [Cl-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CCCCCCCCCCCCCCCCCC)C1=CC=CC=C1 PHZYYSZIFIULKU-UHFFFAOYSA-M 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- CETWGWHVAKIHPW-UHFFFAOYSA-N pentadecane-2,3-diamine Chemical compound CCCCCCCCCCCCC(N)C(C)N CETWGWHVAKIHPW-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- STJLVHWMYQXCPB-UHFFFAOYSA-N propiconazole Chemical compound O1C(CCC)COC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 STJLVHWMYQXCPB-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- YBBJKCMMCRQZMA-UHFFFAOYSA-N pyrithione Chemical compound ON1C=CC=CC1=S YBBJKCMMCRQZMA-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- NASFKTWZWDYFER-UHFFFAOYSA-N sodium;hydrate Chemical compound O.[Na] NASFKTWZWDYFER-UHFFFAOYSA-N 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229940042055 systemic antimycotics triazole derivative Drugs 0.000 description 1
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
- 235000019157 thiamine Nutrition 0.000 description 1
- 150000003544 thiamines Chemical class 0.000 description 1
- FUTRAFMCQUHVQM-UHFFFAOYSA-M tributyl(decyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCC[P+](CCCC)(CCCC)CCCC FUTRAFMCQUHVQM-UHFFFAOYSA-M 0.000 description 1
- ABJGUZZWSKMTEI-UHFFFAOYSA-M tributyl(dodecyl)phosphanium;bromide Chemical compound [Br-].CCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC ABJGUZZWSKMTEI-UHFFFAOYSA-M 0.000 description 1
- RYVBINGWVJJDPU-UHFFFAOYSA-M tributyl(hexadecyl)phosphanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC RYVBINGWVJJDPU-UHFFFAOYSA-M 0.000 description 1
- AKUNSPZHHSNFFX-UHFFFAOYSA-M tributyl(tetradecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC AKUNSPZHHSNFFX-UHFFFAOYSA-M 0.000 description 1
- FUMBGFNGBMYHGH-UHFFFAOYSA-M triphenyl(tetradecyl)phosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CCCCCCCCCCCCCC)C1=CC=CC=C1 FUMBGFNGBMYHGH-UHFFFAOYSA-M 0.000 description 1
- VJXUBPISGAQTRI-UHFFFAOYSA-M tripropyl(tetradecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[P+](CCC)(CCC)CCC VJXUBPISGAQTRI-UHFFFAOYSA-M 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
- DYWSVUBJGFTOQC-UHFFFAOYSA-N xi-2-Ethylheptanoic acid Chemical compound CCCCCC(CC)C(O)=O DYWSVUBJGFTOQC-UHFFFAOYSA-N 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/22—Compounds of zinc or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/343—Heterocyclic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
- C08L79/02—Polyamines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pest Control & Pesticides (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Materials Engineering (AREA)
- Plant Pathology (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Vannloselige trebeskyttelsesmidler , som inneholder blandinger av en metallforbindelse, en syre som fikserer metaller og en kompleksdannende, polymer nitrogenforbindelse, samt fremgangsmåte for beskyttelse av tre med denne blanding.
Description
Foreliggende oppfinnelse angår vannløselige trebeskyttelsesmidler som inneholder en metallforbindelse, en syre som fikserer metallet, og polymere, kompleksdannende nitrogenforbindelser, samt eventuelt vannløselige aminer og/eller poly-aminer.
Vannløselige trebeskyttelsesmidler på basis av kobber-og/eller sinkforbindelser, C5-C20-karboksylsyrer og alifatiske polyaminer er kjente (EP 270 848 og 320 786). Som alifatiske polyaminer er f.eks. alkylenpolyaminer med 2-4 N-atomer egnede. Alt etter arten av de polyaminer som anvendes, oppstår forskjellige ulemper.
Ved anvendelse av polypropylen-polyaminer, dvs. f.eks. 1,3-diaminopropan, dipropylentriamin (3,3'-diaminodipropyl-amin), tripropylentetramin, er ved impregnering av heltre i stor teknisk målestokk, f.eks. ved kjeletrykkmetoden, inn-tregningsdybden og fordelingen av kobberet ikke alltid tilstrekkelig til å sikre en dyptgående trebeskyttelse, f.eks.
når det gjelder rundtre, så som master og palisader, spesielt ved anvendelse med jordkontakt, dvs. når en del av treet er nedgravet i jorden.
De alkaliske, vandige løsninger av kobber- og/eller sinkforbindelser (gjennomsnittlig pH-verdi 8-10) reagerer med de sure trebestanddeler på en slik måte at kobberet og/eller sinken i nærvær av karboksylsyrene faller ut allerede i de ytre områder i treet, slik at kobberet og/eller sinken f.eks. i et furutre ikke mer når treets kjerne ved en splint-tykkelse på mer enn 2 cm, spesielt dersom furutreet oppviser smale årringer og høye harpiksinnhold.
Kobberutvaskingen ved anvendelse av disse trebeskyttelse-smidler, spesielt ved anvendelse ved hjelp av overhetet damp, er dessuten for høy. For eksempel kan over 20% av det kobber som befinner seg i treet vaskes ut etter fiksering med overhetet damp (overhetet damp ca. 100°C, 1-2 timer).
Ved anvendelse av polyetylen-polyaminer, f.eks. etylendiamin, dietylentriamin, trietylentetramin; aminoetyletanol-amin [2-(2-aminoetyl)-amino]etanol; 1,2-propandiamin, sikres riktignok en forbedret inntregningsevne; trebeskyttelsesmid-lets fiksering er imidlertid ikke tilstrekkelig hverken ved normalfiksering eller ved hurtigfiksering. Kobberutvaskingen fra treet ligger eksempelvis over 25%.
Det ble nå funnet at de forannevnte ulemper ikke opptrer ved vannløselige trebeskyttelsesmidler på basis av 2,5-40 vekt% metallforbindelser, 10-40 vekt% syrer som fikserer disse metaller og 5-50 vekt% kompleksdannende, polymere nitrogenforbindelser og eventuelt i tillegg vannløselige aminer og/eller polyaminer.
Kompleksdannende, polymere nitrogenforbindelser er f . eks . polyetyl<3Tiaminer, polyamidoaminer (kondensasjonsprodukter av polyaminer med adipinsyre), kondensasjonsprodukter f.eks. på basis av dietylentriamin/trietanolamin og/eller dietanolamin/dietylentriamin. Polyetyleniminer foretrekkes.
Polyetyleniminer (PEI) er kjente, og oppstår ved poly-merisasjon av 1,2-etylenimin. I disse iminer foreligger nitr-ogenet primært (endegruppe), sekundært og tertiært (forgrening) . Polyetyleniminer med n større enn 10 er egnede; svært gode resultater oppnås ved anvendelse av PEI med en polymeri-sasjonsgrad n mellom 50 og 1000.
Polyamidoaminer oppstår eksempelvis ved omsetning av dietylentriamin med adipinsyre ved 150 - 200°C.
Ytterligere kondensasjonsprodukter oppstår eksempelvis ved oppvarming av dietanolamin eller trietanolamin på 200 - 220°C i nærvær av fosfonsyre (H3P03) .
Metallforbindelser er f.eks. kobber-, sink-, nikkel-eller koboltforbindelser eller blandinger av disse. De kan anvendes som vannløselige eller vannuløselige forbindelser, f.eks. kobber- og/eller sinksalter, som sulfater, acetater, hydroksyder, oksyder, borater, fluorider, kobberhydroksydkarbonat, sinkkarbonat. De tilsvarende nikkel- og/eller koboltforbindelser kan også anvendes. Kobberforbindelser foretrekkes.
Metallf ikserende syrer er f . eks . alifatiske C5-C20-karboksylsyrer, så som heksansyre, heptansyre, oktansyre, forgrenede karboksylsyrer, 2-etylpentansyre, 2-etylheksansyre, 2-etylheptansyre, isooktansyre, isononansyre, karboksylsyrer med sterkere forgrening, så som neokarboksylsyrer, versatic-syrer, di-n-alkyleddiksyre, di-n-alkylpropionsyre, substi-tuerte C5-C20-karboksylsyrer, f . eks . halogenkarboksylsyrer
(2-bromheksansyre, 2-bromoktansyre); eterkarboksylsyrer, aminokarboksylsyrer; alifatiske dikarboksylsyrer, f.eks. sebacinsyre, cykloalkylkarboksylsyrer, som f.eks. cyklohek-sankarboksylsyre; cykloarylkarboksylsyrer; som f.eks. ftal-syre; salicylsyre, 3- eller 4-hydroksy-benzosyre; amino-hydroksykarboksylsyre, som f.eks. aminosalicylsyre; polykar-boksylsyrer, som f.eks. polyakrylsyrer og/eller andre metallfikserende syrer, som f.eks. 2-merkaptopyridin-N-oksyd, 2-hydroksypyridin-N-oksyd; dehydracetsyre, heterocykliske karboksylsyrer, f.eks. furankarboksylsyre, 2,5-dimetylfuran-karboksylsyre.
De tilsvarende alkali- og/eller amin- og/eller kobber-, sink-, kobolt- eller nikkelsalter av de metallfikserende syrer kan også komme til anvendelse.
Kobber-, sink-, kobolt-, nikkelsaltene av de ovenfor nevnte syrer er vannuløselige; de overføres i vannløselige forbindelser ved hjelp av de kompleksdannende, polymere nitrogenforbindelser .
Av formuleringstekniske og økonomiske grunner er det som oftest fordelaktig å erstatte en del av de kompleksdannende, polymere nitrogenforbindelser med vannløselige aminer og/eller polyaminer eller ammoniakk. Det kan f.eks. anvendes alifatiske, lineære eller forgrenede polyaminer, som f.eks. etylendiamin, dietylentriamin, trietylentetramin, aminoetyl-etanolamin, 1,2-diaminopropan, 1,3-diaminopropan, dipropylentriamin, tripropylentetramin, neopentandiamin, N,N'-bis(3-aminopropyl)etylendiamin (N4-amin), vannløselige aminer, som f.eks. alkanolaminer som etanolamin, dietanolamin, trietanolamin, isopropanolamin; polyeterdiaminer, f.eks. forbindelser med den generelle formel
H2N(CH2)n= (CH2CH20)m(CH2)nNH2
n; m = 1 - 6
og/eller di- eller polyaminer av cykliske forbindelser,
f.eks. 1,3-diaminocykloheksan, N-aminoetylpiperazin.
Mengden av disse vannløselige aminer som tilsettes be-grenses eksempelvis på en slik måte at hverken inntregningen av trebeskyttelsesmidlet påvirkes eller utvaskingen av metallene forhøyes. Mengden av polymere, kompleksdannende nitrogenforbindelser er alltid i overskudd i forhold til aminen<
Ettersom et bredt virkningsspektrum mot treødeleggende dyr eller skadelige planter i de fleste tilfeller første oppnås ved høyere anvendelsesmengder (mer enn 3 0 kg trebeskyttelsesmiddel pr. m3) , er det eksempelvis fordelaktig å fullstendiggjøre og å forbedre virkningen av trebeskyttelsesmidlene ifølge oppfinnelsen ved tilsetning av ytterligere fungicider eller insekticider.
Egnet er spesielt tilsetninger av f.eks. N-organo-di-azeniumdioksy-forbindelser (HDO-forbindelser), som f.eks. N-cykloheksyl-, N-C4-10-alkyl-, spesielt N-C6-C8-alkyl-, N-aryl-, spesielt N-fenyldiazeniumdioksy-forbindelser og blandinger av disse. Som salter av organodiazeniumdioksyforbindelsene kan eksempelvis såvel de vannløselige' alkali- og/eller ammonium-salter, som også de vannuløselige metallsalter, som f.eks. kobber-, sink-, nikkel- og/eller koboltsalter, anvendes.
Også blanding med fettaminer (primære, sekundære, terti-ære) som minst inneholder én hydrofil rest med minst 6 C-atomer, muliggjør en forbedring av virkningsspekteret mot treødeleggende og tremisfarvende sopptyper, samt mot treøde-leggende insekter.
Disse aminer tilsvarer f.eks. den generelle formel
hvor R betyr R6-C20-alkyl og/eller hydroksyalkyl,
R1, R2, R3 betyr uavhengig av hverandre hydrogen eller C-l-
til C4-alkyl, eller en C6- til C30-alkyl- eller hydroksyalkylrest tilsvarende R, eller eventuelt en benzylrest som er substituert med halogen.
Fettaminene kan i samsvar med de egenskaper de har, innarbeides i de nye konsentrater eller løsninger i form av ami-nenes salter, f.eks. helt eller delvis som salter av karboksylsyrer som eddiksyre, propionsyre, 2-etylheksansyre, eventuelt under tilsetning av emulgatorer.
Egnede fettaminer er f . eks . dimetyl-(C10-C18)-alkylamin, spesielt dimetyl-C12/C14-alkylamin, metyldioktylamin, metyl-didecylamin, oktyldietanolamin, didodecyl-1,3-propylendiamin, C13/C15-alkyltrimetylen-diamin, laurylpropylendiamin, N,N-bis-(3-aminopropyl)-laurylamin.
Det kan videre tilsettes kvaternære ammoniumforbindelser eller fosfoniumforbindelser.
En kvaternær ammoniumforbindelse er f.eks. en forbindelse som tilsvarer den generelle formel R^R^ISTZ"' idet R<1> betyr en alkylrest med 8 til 20 karbonatomer, spesielt en alkylrest med 12 til 20 karbonatomer, eller en benzylrest, som eventuelt er substituert med Cx- til C20-alkyl eller halogen,
R<2> betyr C1- til C6-alkyl, C3- til C9-alkoksyalkyl, polymert etylenoksyd (EO) eller propylenoksyd (PO), med EO, hhv.
PO n = 2 til 50,
R<3> betyr Cx- til C6-alkyl, C3- til C4-alkoksy, polymert etylenoksyd (EO) eller propylenoksyd (PO), med EO, hhv. PO
n = 2 til 50.
R<4> betyr CV til C20-alkyl,
eller to av restene R<1> til R4 danner i hvert tilfelle sammen med nitrogenatomet en heterocyklisk rest som inneholder 4 til 5 C-atomer, 1 til 2 N-atomer og 1, 2 eller 3 dobbeltbin-dinger, idet karbonatomene eventuelt er substituert med Cx-til C4-alkyl eller halogen, og Z betyr en syrerest, f.eks. halogenid.
Spesielt egnet som virksom fosfoniumforbindelse er forbindelser med formelen
<R1>3R<2p+Y>"
hvor
R<1> betyr en alkylrest med 1 til 6 karbonatomer, en hydroksyalkylrest med 1 til 6 karbonatomer, eller en
fenylrest,
R<2> betyr en alkylrest med 8 til 18 karbonatomer, og
Y betyr en syrerest, spesielt et halogenidanion.
Restene R<1> og R2 er fortrinnsvis rettkjedede.
De kvaternære fosfoniumforbindelser kan være til stede i de nye konsentrater enkeltvis eller som blandinger. Eksempler på slike fosfoniumforbindelser er trimetyl-n-dodecyl-fos-foniumklorid, trietyl-n-decylfosfoniumbromid, tri-n-propyl-n-tetradecyl-fosfoniumklorid, trimetylol-n-heksadecyl-fos-fonium-klorid, tri-n-butyl-n-tetradecylfosfoniumklorid, tri-n-butyl-n-dodecylfosfoniumbromid, tri-n-butyl-n-decylfos-foniumklorid, tri-n-butyl-n-heksadecylfosfoniumbromid, tri-n-heksyl-n-decylfosfoniumklorid, trifenyl-n-dodecylfosfonium-klorid, trifenyl-n-tetradecylfosfoniumbromid, trifenyl-n-oktadecylfosfoniumklorid.
Det er også mulig å tilsette ytterligere fungicider, f.eks. i emulgert form, så som
N-tridecyl-2,6-dimetylmorfolin (tridemorf) og/eller 4-(3-para-tertiær-butylfenyl)-2-metyl-propyl-2,6-cis-di-metylmorfolin (fenpropimorf) og/eller
triazol- og/eller imidazolforbindelser som
1-(2-(2,4-diklorfenyl)-4-metyl-1,3-dioksolan-2-ylmetyl)-1H-1,2,4-triazol,
1-(2-(2,4-diklorfenyl)-1,3-dioksolan-2-ylmetyl)-1H-1,2,4-triazol,
1-(2-(2,4-diklorfenyl)-4-etyl-1,3-dioksolan-2-ylmetyl)-1H-1,2,4-triazol,
1-(2-(2,4-diklorfenyl)-4-propyl-l,3-dioksolan-2-ylmetyl)-1H-' 1,2,4-triazol (propiconazol),
1-(2-(2,4-diklorfenyl)-4-pentyl-l,3-dioksolan-2-ylmetyl)-1H-1,2,4-triazol,
1-(2-(2,4-diklorfenyl)-4-etyl-l,3-dioksolan-2-ylmetyl)-1H-imidazol,
Qf-ter-t-butyl-a (p-klorf enyletyl) -1H-1, 2 , 4-triazol-1-etanol, 1-(S-alkyloksy-2,4-diklorfenetyl)imidazol og/eller organiske tinnforbindelser, spesielt tributyltinn(TBT)- forbindelser, som f.eks. TBT-oksyd, TBT-versatoat, TBT-benzoat, TBT-naftenat, TBT-HDO og/eller
isotiazolinforbindelser med følgende formal
hvor
R<1> er hydrogen, en alkyl-, alkenyl-, alkinylrest med 1 til 18 karbonatomer, en cykloalkylrest med en
C3- til C6-ring og med inntil 12 karbonatomer, en
aralkyl- eller arylrest med inntil 19 karbonatomer, R<2>, R<3> er uavhengig av hverandre, hydrogen, halogen eller en Cx- til C4-alkylrest, evt. kan R2 og R3 være
en del av en aromatrest,
og/eller hydroksamsyrer med den generelle formel
hvor R<1> for eks. er en cykloalkyl-, (cykloheksyl-), arylrest (fenylrest) eller en heterocyklisk rest, og R<2> for eks. er hydrogen-, en C^- C4-alkyl-, C5- C8-cykloalkyl- eller en arylrest (fenyl).
Som emulgatorer, evt. under tilsetning av polare løs-emidler, kan fremfor alt de forannevnte fettaminer og salter av disse, kvaternære ammonium-/fosfoniumforbindelser og f.eks. andre ioniske og ikke-ioniske emulgatorer finne anvendelse .
Trebeskyttelsesmidlene kan eventuelt inneholde ytterligere forbindelser, f.eks. en forbindelse med et fungicid anion, eksempelvis en borforbindelse, f.eks. alkaliborat, aminborat, borsyre; borsyreester; fluorider, f.eks. kalium-fluorid; og/eller salter av fluorborsyre og/eller fluorfos-forsyre og/eller difluorfosforsyre.
Inntrengningen av vandige løsninger av de nye trebeskyttelsesmidler er ved impregnering ved hjelp av f.eks. kjele-trykkfremgangsmåten svært god. Løsningene trenger godt inn i treet. Fordelingen av virksomme stoffer i treet er i samsvar med de praktiske krav. Ved impregnering av rundtre oppnås også ved bredt, splinttre kjernetreets ytterste grense. Først etter impregneringen begynner utfellingen av metallsaltene; de fikseres (påføres) på trefibrene og de stoffer treet inneholder ved hjelp av de polymere nitrogenforbindelser.
En fiksering av trebeskyttelsesmidlene ifølge oppfinnelsen er ved ca. 20°C eksempelvis avsluttet etter 1-2 uker. Ved behandling med overhetet damp (over 100°C) kan fikseringsreaksjonen i betydelig grad gjøres hurtigere; den er da avsluttet allerede etter 1-2 timer, hhv. 12 - 24 timer. Utvaskingen forminskes i forhold til anvendelse av kjente trebeskyttelsesmidler.
pH-verdien av de vandige impregneringsløsninger ligger generelt mellom 4 og 11, spesielt mellom 6 og 9. Fremfor alt er det mulig ved innstilling av pH-verdier under ca. 7,5 også å innarbeide fungicider og insekticider i konsentratene og løsningene, som i det alkaliske område ved høyere pH-verdier ikke er stabile. Således kan det f.eks. for økning av virkningsspektret eller for oppnåelse av spesielle effekter i tillegg også anvendes følgende forbindelser, eventuelt under anvendelse av hjelpemidler, som ioniske eller ikke-ioniske emulgatorer, og/eller organiske løsemidler:
metylenbistiocyanat,
klorerte fenoler,
tetraklorisoftalsyre-dinitril,
N-cykloheksyl-N-metoksy-2,5-dimetyl-furan-3-karboksylsyre-amid,
N-dimetyl-N'-fenyl-(N-fluormetyltio)-sulfamid, N, N-dimetyl-N'-toluyl-(N-fluormetyltio)-sulfamid, benzimidazol-2-karbaminsyre-metylester,
2-tiocyanometyl-tioberizotiazol,
2-j odbenzosyreanilid,
1-(1 ',2 ',4 '-triazolyl-1 ')-(1-(4'-klorfenoksy)-3,3-dimetyl-butan-2-on,
1- (1 ',2 ',4 ' - triazolyl-1 ')-(1-(4'-klorfenoksy)-3,3-dimetyl-butan-2-ol,
heksaklorcykloheksan,
0,O-dietyl-ditio-fosforyl-metyl-6-klorbenoksalon, 2- (1,3-tiazol-4-yl)-benzimidazol,
N-triklormetyltio-3,6,7,8-tetrahydroftalimid, N-(1,1,2,2-tetrakloretyltio)-3,6,7, 8-tetrahydroftalimid, N-triklormetyltioftalimid, 3 -j od-2-propylbutylkarbamat,
0,O-dimetyl-S-(2-metylamin-2-oksoetyl)-ditiofosfat, 0,O-dietyl-0-(3,5,6-triklor-2-pyridyl)-tiofosfat, 0,O-dimetyl-S-(N-ftalimid)-metylditiofosfat,
0, O-dietyl-0- (a-cyanbenzyliden-amin) -tiof osf at,
6,7,8,9,10-heksaklor-l,5,5a,6,9,9a-heksahydro-6,9-metan-2,3,4-benzodioksotiepien-3-oksyd,
(4-etoksyfenyl)-(dimetyl)-(3-(4-fluor-3-fenoksy-fenyl)-pro-pyl-silan,
2 -sek.-butyl-fenyl-N-metylkarbamat, 2 -i-propoksyfenyl-N-metyl-karbamat, N-metyl-1-naftyl-karbamat, norbonen-dimetanneksa-klorcyklosulfitt, 1-(4-klorfenyl)-3-)2,6-di-fluorbenzoyl)-urea;
syntetiske pyretroider, som (+)-3-(2,2-diklorvinyl-2,2-dimetyl)cyklopropan-1-karboksyl-syre-3- fenoksy-benzylester, 3-(2,2-diklorvinyl-2,2-dimetyl)-cyklopropan-1-karboksyl-syre-a-cyano-3,3-f enoksybenzylester, 3 -(2,2-dibromvinyl-2,2-dimetyl)-a-cyano-m-fenoksybenzyl-1R,3R)-cyklopropankarboksylat (deltametrin),
a-cyano-3-fenoksybenzyl-isopropyl-2,4-klorfenylacetat.
De midler som kan fortynnes med vann, inneholder - i konsentrert form - kobberet og/eller sinken og/eller nikkelen og/eller kobolten, beregnet som metall, vanligvis f.eks. i en mengde på 1,0 - 12,5 vekt%.
Egnede konsentrater består f.eks. av: (vekt%)
2,5 - 4 0% kobber- og/eller sink- og/eller kobolt og/eller nikkel-forbindelser
10 - 4 0% av en syre som fikserer metallene
5 - 5 0% av en kompleksdannende, polymer nitrogenforbindelse, spesielt polyetylenimin
0 - 25% av et vannløselig amin og/eller polyamin 0 - 4 0% av forbindelse med et fungicid virkende anion 0 -- 25% N-organodiazeniumdioksyforbindelser 0 - 40% av et fettamin og/eller et fettaminsalt eller
blandinger av slike
0 - 50% av en kvaternær ammoniumforbindelse eller en
kvaternær fosfoniumforbindelse
0 - 20% tridemorf, fenpropimorf, triazol- og/eller imidazolderivater, tributyltinnforbindelser og/eller isotiazolinonforbindelser og/eller hydroksamsyrer
0 2% syntetiske pyretroider
idet summen alltid utgjør 100 vekt%, samt eventuelt under-ordnede mengder av andre bestanddeler, som ammoniakk, korro-sjonsinhibitorer, kompleksdannende syrer (f.eks. nitrilo-eddiksyre, etylendiamintetraeddiksyre når det anvendes vann med høyere hardhetsgrader) og om nødvendig vann og/eller polare løsemidler som kan blandes med vann, idet disse ande-ler som i det vesentlige tjener til underletting av hånd-teringen, vanligvis kan holdes på et lavt nivå.
Oppfinnelsen omfatter imidlertid også de impregnerings-løsninger som kan fremstilles ved fortynning med vann, og som har tilsvarende lavere konsentrasjon av de enkelte bestanddeler. Anvendelseskonsentrasjonen er f.eks. 0,01 - 1,50 vekt% metall, f.eks. kobber, i den vandige impregneringsløsning, alt etter impregneringens art og graden av fare for treet som skal impregneres.
Ved oppløsning av metallsaltene, eventuelt under til-førsel av varme, spesielt kobber- og/eller sinkforbindelsene, i de polymere, kompleksdannende nitrogenforbindelser, eventuelt under tilsetning av amin og vann, oppstår høykonsen-trerte vannløselige pastaer og flytende konsentrater, som etter fortynning med vann kan anvendes for impregnering av tre.
Anvendelsen av impregneringsløsningene for beskyttelse av treet kan gjennomføres på håndtverksmessig måte, som f.eks. ved sprøyting, påstrykning, neddykking, impregnering i trau, eller ved hjelp av fremgangsmåter i stor teknisk målestokk, som f.eks. kjeletrykkprosesser, vekseltrykkprosesser, dobbelvakuumprosesser. Med "tre" skal det forstås såvel massivt tre som råmaterialer av tre, f.eks. sponplater, finer-; i dette tilfelle kan trebeskyttelsesmidlet eventuelt tilføres under prosessen for innblanding av lim.
Konsentratene eller løsningene kan farves ved hjelp av vannløselige farvestoffer eller farvestoff- og/eller pigment-preparater. En tilsetning av voks-, paraffin- og/eller akrylatdispersjoner for å oppnå en vannawisende virkning eller forbedring av fikseringen er mulig.
Konsentratene kan eventuelt også innarbeides i binde-middelholdige systemer (grunninger, lasurer) som kan fortynnes med vann.
Oppfinnelsen skal forklares med grunnlag i følgende eksempler:
Konsentratet fortynnes med vann i forholdet 2 deler konsentrat og 98 deler vann, dvs. at anvendelseskonsentrasjonen er 2%.
Det ble i hvert tilfelle impregnert 2 0 stk. furusplint-treklosser (15 x 25 x 50 mm), og for hver 10
I etter 4 ukers fiksering ved normaltemperatur (20°C),
II etter varmebehandling med overhetet damp (1 time,
100°C) og 4 timers avkjølingstid,
ble det foretatt flere utvaskinger med vann, vaskevannet ble samlet opp, og kobberinnholdet i vaskevannet ble bestemt.
Ved behandlingen med overhetet damp ble i tillegg kob-bermengden i kondensatvannet (kondensert overhetet damp på klossens overflate) analysert, lagt til vaskevannets kob-berinnhold, og fra dette ble den samlede utvasking beregnet.
Mengden av utvasket kobber ble satt i forhold til den samlede mengde av kobber i treet før utvaskingen. (Ingen utvasking = 0%, fullstendig utvasking = 100%).
Kobberutvasking:
10,0% kobberhydroksydkarbonat Cu(OH)2 • CuC03 Anvendelseskonsentrasjon: 2%
For bestemmelse av inntrengningsdybden ble 5 furupali-sader (lengde 1,50 m, diameter 0,20 m, fra samme vekstområde; med i lufttørket tilstand forholdsvis trange årringer og med en midlere splintbredde på mer enn 3 cm) oppskåret i for hvert tilfelle 6 rundtreavsnitt med lengde 24 cm, og snitt-flatene ble tettet til ved påstrykning av epoksyharpiksbe-legg. Fra hver palisade ble det i hvert tilfelle tatt ut et avsnitt, slik at 5 fururundtreavsnitt kunne impregneres sam-tidig (1 time vakuum: under 0,1 bar; 2 timer trykk: 8 bar).
For bestemmelse av kobberets inntregningsdybde ble de impregnerte fururundtreavsnitt kuttet opp i midten, kuttfla-tene ble behandlet med 4-(pyridyl-(2)-azo)-resorcin-monona-triumsalt(monohydrat) (rødfarving med kobber og sink), og kobberets inntregningsdybde ble bestemt.
Eksempler ifølge oppfinnelsen
Eksempel 1
Eksempel 2
Eksempel 3
Eksempel 4
Eksempel 5
Eksempel 6
Eksempel 7
Eksempel 8 Eksempel 9
Eksempel 10
Eksempel 11
Eksempel 12 Eksempel 13
Eksempel 14 Eksempel 15
Eksempel 16 Eksempel 17
Eksempel 18
Eksempel 19 Eksempel 20
Eksempel 21
Eksempel 22
Eksempel 23 Eksempel 24
Eksempel 25
Eksempel 26 Eksempel 27
Eksempel 2 8
Claims (5)
1. vannløselig trebeskyttelsesmiddel, karakterisert ved at det inneholder 2,5-40 vekt% av en metallforbindelse, 10-40 vekt% av en syre som fikserer metaller og 5-50 vekt% av en kompleksdannende, polymer nitrogenforbindelse.
2. Middel ifølge krav 1,
karakterisert ved at det inneholder en kobberforbindelse.
3. Middel ifølge krav 1,
karakterisert ved at det inneholder polyetylenimin.
4. Middel ifølge krav 1,
karakterisert ved at det inneholder 2-etylheksansyre.
5. Middel ifølge krav 1,
karakterisert ved at det i tillegg inneholder et vannløselig amin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4033419A DE4033419A1 (de) | 1990-10-20 | 1990-10-20 | Polymere stickstoffverbindungen und metall fixierende saeuren enthaltende holzschutzmittel |
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| Publication Number | Publication Date |
|---|---|
| NO914101D0 NO914101D0 (no) | 1991-10-18 |
| NO914101L NO914101L (no) | 1992-04-21 |
| NO180260B true NO180260B (no) | 1996-12-09 |
| NO180260C NO180260C (no) | 1997-03-19 |
Family
ID=6416728
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| NO914101A NO180260C (no) | 1990-10-20 | 1991-10-18 | Vannlöselig trebeskyttelsesmiddel |
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| US (1) | US5186947A (no) |
| EP (1) | EP0482433B1 (no) |
| JP (1) | JP3115376B2 (no) |
| AT (1) | ATE117618T1 (no) |
| AU (1) | AU638873B2 (no) |
| CA (1) | CA2053698C (no) |
| CZ (1) | CZ280408B6 (no) |
| DE (2) | DE4033419A1 (no) |
| DK (1) | DK0482433T3 (no) |
| ES (1) | ES2067827T3 (no) |
| FI (1) | FI114619B (no) |
| MY (1) | MY110256A (no) |
| NO (1) | NO180260C (no) |
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| US5578323A (en) | 1992-06-15 | 1996-11-26 | Emisphere Technologies, Inc. | Proteinoid carriers and methods for preparation and use thereof |
| US5714167A (en) | 1992-06-15 | 1998-02-03 | Emisphere Technologies, Inc. | Active agent transport systems |
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| US5643957A (en) | 1993-04-22 | 1997-07-01 | Emisphere Technologies, Inc. | Compounds and compositions for delivering active agents |
| DE69434418T2 (de) | 1993-04-22 | 2005-12-22 | Emisphere Technologies, Inc. | Orale Dareichungsform |
| US5709861A (en) * | 1993-04-22 | 1998-01-20 | Emisphere Technologies, Inc. | Compositions for the delivery of antigens |
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| DE4339701A1 (de) * | 1993-11-22 | 1995-05-24 | Bayer Ag | Holzschutzmittel enthaltend eine Kupferverbindung |
| DE4403291C2 (de) * | 1994-02-03 | 1998-09-03 | Kurt Obermeier Gmbh & Co Kg | Zinkhaltiges Holzschutzmittel |
| US5426121A (en) * | 1994-10-04 | 1995-06-20 | Akzo Nobel N.V. | Wood preservation formulation comprising complex of a copper cation and alkoxylated diamine |
| DE4441672A1 (de) * | 1994-11-23 | 1996-05-30 | Basf Ag | Holzschutzmittel |
| US5965121A (en) | 1995-03-31 | 1999-10-12 | Emisphere Technologies, Inc. | Compounds and compositions for delivering active agents |
| WO1997036480A1 (en) * | 1996-03-29 | 1997-10-09 | Emisphere Technologies, Inc. | Compounds and compositions for delivering active agents |
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-
1990
- 1990-10-20 DE DE4033419A patent/DE4033419A1/de not_active Withdrawn
-
1991
- 1991-09-19 US US07/762,369 patent/US5186947A/en not_active Expired - Lifetime
- 1991-10-01 NZ NZ240048A patent/NZ240048A/xx not_active IP Right Cessation
- 1991-10-10 EP EP91117261A patent/EP0482433B1/de not_active Expired - Lifetime
- 1991-10-10 AT AT91117261T patent/ATE117618T1/de not_active IP Right Cessation
- 1991-10-10 DK DK91117261.7T patent/DK0482433T3/da active
- 1991-10-10 DE DE59104396T patent/DE59104396D1/de not_active Expired - Lifetime
- 1991-10-10 ES ES91117261T patent/ES2067827T3/es not_active Expired - Lifetime
- 1991-10-14 MY MYPI91001890A patent/MY110256A/en unknown
- 1991-10-14 FI FI914834A patent/FI114619B/fi not_active IP Right Cessation
- 1991-10-18 AU AU85964/91A patent/AU638873B2/en not_active Expired
- 1991-10-18 NO NO914101A patent/NO180260C/no not_active IP Right Cessation
- 1991-10-18 JP JP03271170A patent/JP3115376B2/ja not_active Expired - Lifetime
- 1991-10-18 CZ CS913165A patent/CZ280408B6/cs not_active IP Right Cessation
- 1991-10-18 CA CA002053698A patent/CA2053698C/en not_active Expired - Lifetime
- 1991-10-18 PL PL91292098A patent/PL168277B1/pl unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO180260C (no) | 1997-03-19 |
| FI114619B (fi) | 2004-11-30 |
| NO914101D0 (no) | 1991-10-18 |
| NO914101L (no) | 1992-04-21 |
| JP3115376B2 (ja) | 2000-12-04 |
| DE59104396D1 (de) | 1995-03-09 |
| ATE117618T1 (de) | 1995-02-15 |
| EP0482433B1 (de) | 1995-01-25 |
| EP0482433A1 (de) | 1992-04-29 |
| CA2053698A1 (en) | 1992-04-21 |
| FI914834A0 (fi) | 1991-10-14 |
| AU8596491A (en) | 1992-04-30 |
| DK0482433T3 (da) | 1995-04-10 |
| CS316591A3 (en) | 1992-05-13 |
| JPH04339602A (ja) | 1992-11-26 |
| ES2067827T3 (es) | 1995-04-01 |
| MY110256A (en) | 1998-03-31 |
| PL292098A1 (en) | 1992-06-01 |
| CZ280408B6 (cs) | 1996-01-17 |
| US5186947A (en) | 1993-02-16 |
| FI914834A (fi) | 1992-04-21 |
| CA2053698C (en) | 2001-02-06 |
| PL168277B1 (en) | 1996-01-31 |
| AU638873B2 (en) | 1993-07-08 |
| DE4033419A1 (de) | 1992-04-23 |
| NZ240048A (en) | 1992-11-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK1K | Patent expired |