NO122961B - - Google Patents

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Publication number
NO122961B
NO122961B NO156410A NO15641065A NO122961B NO 122961 B NO122961 B NO 122961B NO 156410 A NO156410 A NO 156410A NO 15641065 A NO15641065 A NO 15641065A NO 122961 B NO122961 B NO 122961B
Authority
NO
Norway
Prior art keywords
fillers
mixture
powdered
softeners
powdered mixture
Prior art date
Application number
NO156410A
Other languages
English (en)
Inventor
C Kilham
C Rossitto
R Hill
A Chaplick
Original Assignee
United Shoe Machinery Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US338705A external-priority patent/US3316573A/en
Priority claimed from US356218A external-priority patent/US3277867A/en
Application filed by United Shoe Machinery Corp filed Critical United Shoe Machinery Corp
Publication of NO122961B publication Critical patent/NO122961B/no

Links

Classifications

    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B23/00Uppers; Boot legs; Stiffeners; Other single parts of footwear
    • A43B23/08Heel stiffeners; Toe stiffeners
    • A43B23/081Toe stiffeners
    • A43B23/086Toe stiffeners made of impregnated fabrics, plastics or the like
    • A43B23/087Toe stiffeners made of impregnated fabrics, plastics or the like made of plastics
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B23/00Uppers; Boot legs; Stiffeners; Other single parts of footwear
    • A43B23/08Heel stiffeners; Toe stiffeners
    • A43B23/16Heel stiffeners; Toe stiffeners made of impregnated fabrics, plastics or the like
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43DMACHINES, TOOLS, EQUIPMENT OR METHODS FOR MANUFACTURING OR REPAIRING FOOTWEAR
    • A43D11/00Machines for preliminary treatment or assembling of upper-parts, counters, or insoles on their lasts preparatory to the pulling-over or lasting operations; Applying or removing protective coverings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/12Applying particulate materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/26Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C31/00Handling, e.g. feeding of the material to be shaped, storage of plastics material before moulding; Automation, i.e. automated handling lines in plastics processing plants, e.g. using manipulators or robots
    • B29C31/04Feeding of the material to be moulded, e.g. into a mould cavity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/48Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding
    • B29C65/4805Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using adhesives, i.e. using supplementary joining material; solvent bonding characterised by the type of adhesives
    • B29C65/481Non-reactive adhesives, e.g. physically hardening adhesives
    • B29C65/4815Hot melt adhesives, e.g. thermoplastic adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/553Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G67/00Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing oxygen or oxygen and carbon, not provided for in groups C08G2/00 - C08G65/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/121Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/836Moving relative to and tangentially to the parts to be joined, e.g. transversely to the displacement of the parts to be joined, e.g. using a X-Y table
    • B29C66/8362Rollers, cylinders or drums moving relative to and tangentially to the parts to be joined

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Robotics (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)

Description

Fremgangsmåte for fremstilling av sparkel- henh. fyllmasser.
Nærværende oppfinnelse angår en fremgangsmåte for fremstilling av sparkel-henh. fyllmasser særlig for metall, tre, betong, kunststoffer og liknende.
For dette formål anvendtes tidligere
f. eks. ved bulker i bilskjermer foruten sparkelmasser metaller, som tinn eller bly henh. legeringer av myke metaller. Med dette er det dog forbundet mange ulemper. Anvendelsen av metaller eller deres legeringer forutsetter at disse smeltes og videre en særlig behandling av grunnen i det hulrom som skal utfylles bortsett fra at disse fyllmasser på grunn av sin høye spesifikke vekt i statisk henseende fremkaller ugunstige bivirkninger. Ikke mindre om-stendelig og dyrt er arbeidsmåten ved anvendelse av vanlige sparkelmasser, da disse for at ingen sprekker skal oppstå, bare kan påføres i tynne sjikt på inntil 1 mm pr. arbeidsgang.
Det er også tidligere foreslått sparkelmasser, som kan finne anvendelse ved overflateforedling ved fuger og bulker ved gjenstander av blikk og som er fremstilt på basis av umettede polyesterharpikser. Ved dette finner fyllmidler som metallpul-ver anvendelse og som polymerisasjonska-talysatorer peroksyder i forbindelse med mykningsmidler. Disse sparkelmasser har imidlertid den store ulempe at en slutt-polymerisasjon bare kan oppnås etter len-gre tilførsel av varme inntil endelig herdning.
Videre er det tidligere foreslått fyllmasser, som består av oppløsningsmiddel-frie blandinger og som har tiksotrope egen-skaper. For det meste dreier det seg her om såkalte oppløsningsmiddelfrie påstryk-ningsmidler, bestående av en polyester, et polymeriserbart oppløsningsmiddel i forbindelse med fyllstoffer og peroksyder. Og-så ved disse masser kan en sluttpolymerisa-sjon til herdning bare oppnåes ved tilfør-sel av ytre varme.
Disse fyllmasser skal nå tjene til utfylling av ujevnheter, kontraksjonshuller osv. i maskinindustrien, til limning og til utfylling av kvisthull i treindustrien og for utformning av overflater i de forskjelligste industrigrener. Alle hittil kjente fyllmasser hadde nå den store ulempe, at det i de forskjellige industrier ikke var mulig under arbeide å avmåle eller avveie den nødven-dige lille mengde (1—4%) av en organisk peroksydisk katalysator som anvendes for å bringe polymerisasjonen til ende ved en umettet polyester. Ved underdosering inn-traff derfor ingen fullstendig polymerisa-sjon og ved over dosering av katalysatoren kunne termiske spenningsriss opptre.
Ved oppfinnelsen fjernes de nevnte ulemper. Ifølge oppfinnelsen gås der slik frem ved fremstilling av sparkel- henh. fyllmasser ,at der først dannes en pulverformet blanding av fyll- og farvestoffer, mykningsmidler og organiske peroksydiske katalysatorer, som umiddelbart før bruken blandes med en flytende oppløsning av en umettet polyesterharpiks i styrol, eventuelt under tilsetning av mykningsmidler, og karakteristisk for fremgangsmåten er at den pulverformede blanding tilsettes ytterligere pulverformede polyvinyl- henh. polyakrylharpikser.
En slik i pulverform brakt blanding blir bare utrørt inntil deigliknende kon-sistens med et oppløsningsmiddel, hen-siktsmessig med den til grunning anvendte oppløsning, og innføres i en eneste arbeidsgang i det hulrom som skal utfylles. Etter at fyllmassen er stivnet er den oppnådde flate uten videre slipbar og kan derpå på vanlig måte overstrykes med vanlige på-strykningsmidler. Den nye fyllmasse kle-ber så godt til underlaget, at den bare kan fjernes med makt og fremkaller som følge av sin lave spesifikke vekt ingen statiske forandringer.
For oppfinnelsens formål kan man og-så gå ut fra en delvis polymerisert forbindelse, som lar seg videre polymerisere til endelig herdning.
I det følgende skal et eksempel gjen-gis: A. ) 70 deler av en blanding av mineralske fyll- og farvelegemer som bariumsulfat, magnesiumsilikat, krystallinsk jernoksyd, titandioksyd,
sinkoksyd,
sinksulfid,
blandes med 15 vektsdeler av en vinyl-henh. akrylforbindelse i pulverform. Denne blanding blandes med 1—4 vektsdeler av kjente organiske peroksydiske katalysatorer i en oppløsning på 10—15 deler av en av de allerede foran nevnte flytende mykningsmidler.
B. ) Denne blanding røres kort før bruken ut til en deig med en flytende oppløsning av en polyester tilsatt alt etter sin viskosi-tetsgrad inntil 10 deler monomer styrol og inntil 10 deler av et mykningsmiddel som trikresylfosfat eller difenylkresylfosfat. Denne to-komponente form må opprett-holdes i alle tilfeller og da på den måte at først umiddelbart før det egentlige arbeide med utfylling av hulrommene blandes en tilsvarende mengde av disse 2 komponen-ter med hverandre hvorpå de innføres. Herdningen skjer ved videre polymerisa-sjon av denne blanding og da ved normal-temperatur i løpet av 10—30 minutter eller ved tilsvarende oppvarmning i betraktelig kortere tid.
I det angitte eksempel kan selvfølgelig mengdeforholdene av de enkelte produk-ter variere uten at det derved fravikes fra oppfinnelsestanken.

Claims (1)

  1. Fremgangsmåte for fremstilling av sparkel- henholdsvis fyllmasser for metall, tre, betong og kunststoff, hvorved først fremstilles en pulverformet blanding av fyll- og fargestoffer, mykningsmidler og organiske peroksydiske katalysatorer, som umiddelbart før bruken blandes med en flytende oppløsning av en umettet polyesterharpiks i styrol, eventuelt under tilsetning av mykningsmidler, karakterisert ved at til den pulverformede blanding tilsettes ytterligere pulverformede polyvinyl henholdsvis polyakrylharpikser.
NO156410A 1964-01-20 1965-01-19 NO122961B (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US338705A US3316573A (en) 1964-01-20 1964-01-20 Shoe manufacture
US356218A US3277867A (en) 1964-03-31 1964-03-31 Machines for applying molten thermoplastic material

Publications (1)

Publication Number Publication Date
NO122961B true NO122961B (no) 1971-09-06

Family

ID=26991324

Family Applications (1)

Application Number Title Priority Date Filing Date
NO156410A NO122961B (no) 1964-01-20 1965-01-19

Country Status (10)

Country Link
JP (1) JPS4928139B1 (no)
AT (1) AT291051B (no)
BE (1) BE658568A (no)
CH (1) CH427570A (no)
DE (3) DE1794338A1 (no)
FR (1) FR1424629A (no)
GB (2) GB1096793A (no)
NL (2) NL128102C (no)
NO (1) NO122961B (no)
SE (1) SE322440B (no)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4255877A (en) * 1978-09-25 1981-03-17 Brs, Inc. Athletic shoe having external heel counter
GB2361198A (en) * 2000-04-12 2001-10-17 Magna Interior Sys Ltd Producing leather covered articles
CN103251174A (zh) * 2013-05-07 2013-08-21 苏州卫鹏机电科技有限公司 一种新型真空箱放空消声音和电极绝缘装置
TWI587706B (zh) * 2014-06-04 2017-06-11 佳世達科技股份有限公司 顯示器及其控制方法
CN113475819B (zh) * 2021-07-24 2022-06-28 福建省华宝智能科技有限公司 一种用于鞋底高温模压的自动加工设备

Also Published As

Publication number Publication date
NL6500738A (no) 1965-07-21
CH427570A (de) 1966-12-31
AT291051B (de) 1971-06-25
DE1629803A1 (de) 1971-02-04
NL128102C (no) 1970-02-16
SE322440B (no) 1970-04-06
BE658568A (no) 1965-05-17
FR1424629A (fr) 1966-01-14
NL142901B (nl) 1974-08-15
DE1794338A1 (de) 1973-04-19
DE1629803C3 (de) 1979-10-31
NL6908010A (no) 1969-08-25
GB1096792A (en) 1967-12-29
DE1945349U (de) 1966-09-01
GB1096793A (en) 1967-12-29
DE1629803B2 (de) 1979-03-15
JPS4928139B1 (no) 1974-07-24

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