NO119705B - - Google Patents
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- Publication number
- NO119705B NO119705B NO168087A NO16808767A NO119705B NO 119705 B NO119705 B NO 119705B NO 168087 A NO168087 A NO 168087A NO 16808767 A NO16808767 A NO 16808767A NO 119705 B NO119705 B NO 119705B
- Authority
- NO
- Norway
- Prior art keywords
- residue
- hydrogen
- toothpaste
- formula
- compounds
- Prior art date
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- 239000000606 toothpaste Substances 0.000 claims description 19
- 229940034610 toothpaste Drugs 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000006071 cream Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000006072 paste Substances 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 150000003973 alkyl amines Chemical class 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229940112822 chewing gum Drugs 0.000 claims description 2
- 235000015218 chewing gum Nutrition 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000686 essence Substances 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 108010039491 Ricin Proteins 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000551 dentifrice Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- -1 oleyl tyrosinate Chemical compound 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 235000015424 sodium Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 235000019830 sodium polyphosphate Nutrition 0.000 description 1
- RZLORCNPOWHAMO-FYZYNONXSA-M sodium;(2s)-2-(dodecanoylamino)-3-(4-hydroxyphenyl)propanoate Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CC1=CC=C(O)C=C1 RZLORCNPOWHAMO-FYZYNONXSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-L tyrosinate(2-) Chemical compound [O-]C(=O)C(N)CC1=CC=C([O-])C=C1 OUYCCCASQSFEME-UHFFFAOYSA-L 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/12—Unsaturated polyimide precursors
- C08G73/125—Unsaturated polyimide precursors the unsaturated precursors containing atoms other than carbon, hydrogen, oxygen or nitrogen in the main chain
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/07—Glass compositions containing silica with less than 40% silica by weight containing lead
- C03C3/072—Glass compositions containing silica with less than 40% silica by weight containing lead containing boron
- C03C3/074—Glass compositions containing silica with less than 40% silica by weight containing lead containing boron containing zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/36—Amides or imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1039—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors comprising halogen-containing substituents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/12—Unsaturated polyimide precursors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/12—Unsaturated polyimide precursors
- C08G73/124—Unsaturated polyimide precursors the unsaturated precursors containing oxygen in the form of ether bonds in the main chain
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31721—Of polyimide
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Cosmetics (AREA)
Description
Tannpussemiddel.
Det har allerede lenge vært kjent tannpussemidler som i tillegg til de vanlige in-gredienser inneholder vannoppløselige sal-
ter av overflatespenningsaktive forbindel-
ser med høy molekylarvekt. Slike tannpussemidler er f. eks. beskrevet i det tyske patent nr. 675 837 hvor det anbefales å føre inn i tannpussemidlene kjemiske forbindel-
ser med formelen
eller visse salter av forbindelser med formelen (1). I denne formel (1) representerer R-CO en høyere (alifatisk) fettsyrefest med minst 8 kullstoffatomer, Ri består av et alkylradikal eller hydrogen og X repre-, senterer en -SO3H-, -COOH- eller -O-SO3H-rest som er bundet til nitrogenatomet gjen-nom en alkylengruppe: (CHa).m hvor m representerer et helt positivt tall. Det lar seg ikke nekte at kjemiske forbindelser méd formel (1) eller deres salter, spesielt alkali-, kalsium- eller magnesium^ saltene har en uomtvistelig betydning ved fremstillingen av tannpussemidler som kan gi effektiv pleie av tennene. Etter lang-; varige undersøkelser med det formål å finne stoffer som er enda mer effektive enn de forbindelser som svarer til formel (1) og deres; salter, f. eks. med hensyn på deres skumme- og renseegenskaper, har det vist seg at visse forbindelser som ligner forbindelsene med formelen (1) har forbed-rede egenskaper. Det er først-og fremst lagt merke til at de forbindelser som inneholder minst én oksy-aryl- eller oksy-polyaryl gruppe gir utmerkede egenskaper til de tannpussemidler som de tilsettes når •det gjelder frembringelse av skum og rensevirkning og sikrer en bedre pleie av tennene. Foreliggende oppfinnelse går ut på å erstatte et vilkårlig hydrogenatom (h) i alkylengruppen (CH^),,, i formel (1) med en kjede med formelen
hvor m' er et helt positivt tall eller null og A og X' har de betydninger som er an-
gitt nedenfor.
Foreliggende oppfinnelse angår tannpussemiddel av krem, pasta, væske, såpe, essens, pulver eller tyggegummi hvis sær-egne trekk består i at det inneholder 0,5—
5 % av en eller flere av forbindelsene med den generelle formel
som fremstilles ved kondensering av høy-
ere fettsyrederivater med en primær eller sekundær amin av den generelle formel
idet R-CO betyr en mettet eller umettet rest av en høyere fettsyre, som eventuelt kan inneholde en eller flere hydroksygrup-per, X betyr en -SO3H-, -COOH- eller -O-SO3H- rest, hvor det sure hydrogen kan være erstattet av et alkalimetall, ammo-nium, kalsium, magnesium eller alkylamin, A betyr aryl, alkylaryl, polyaryl eller alkyl-polyaryl og X' hydrogen, alkalimetall, am-monium eller en alkanolaminrest, for-trinnsvis en mono-, di- eller trietanolamin-rest, og n og n' betyr null eller hele tall, som kan være like eller forskjellige.
Etter fremstilling og prøving i kjemisk ren tilstand av et visst antall stoffer som svarer til formlene (1) og (2), er det fun-ent at det oppnås tannpussemidler med en bemerkelsesverdig virkningsgrad og det endog med doser som ofte er mindre enn tidligere når det brukes forbindelser som er fremstillet i nesten ren tilstand og til-svarende formel (2).
Det var ikke til å forutsi at en fenol-eller oksypolyaromatisk erstatning som med hensikt ble ført inn i så sammensatte molekyler som de finnes i formel (1) ville bevare sine egenskaper samtidig som de ville miste sin irriterende evne likeoverfor slimhinnene. En erstatning av et vannstoff-atom i alkylen-kjeden i formel (1) med en substituent, som inneholder et fenol eller fenolderivat, f. eks. en alkylfenol eller en alkylnaftol, lar dessuten skumme- og renseevnen for de kjemiske forbindelser bestå eller endog øker den.
Blant de natriumforbindelser som sær-lig egner seg kan nevnes: natrium-N-n-dodekanoyl-amino-2-parahydroksyfenyl-3-propionat eller natrium-N-lauroyl-amino-2-parahydroksyfenyl-3-propionat eller natrium-N-lauroyl-tyrosinat, natrium-N-olelyl-amino-2-parahydroksyfenyl-3-propionat eller natrium-N-olelyl-tyrosinat, natrium-N-ricin-oleyl-amino-2-parahydroksy-fenyl-3-propionat eller natrium-N-ricin-oleyl-tyrosinat.
Når det gjelder en tannkrem eller tann-pasta i henhold til oppfinnelsen, benyttes det ved fremstillingen av denne følgende bestanddeler: a) et bløtt slipe- eller polermiddel, f.
eks. utfelt kalsiumkarbonat, bikalsiumfos-fat osv. i en mengde på mellom ca. 25 og 50 %, b) et vandig viskost medium som skal holde slipemidlet i suspensjon og sikre at tannpussemassen holder seg praktisk.'Dette vandige medium består stort sett av en blanding av glyserol, sorbitol eller propy-len-glykol (mindre enn 40 % i forhold til den endelige tannpussemasse) og en gel av et stoff som svulmer opp i vann (0,5— 5 %) som kan være tragant-gummi, na-triumalginat, natrium karragenat, kar-boksymetylcellulose osv. c) søtningsstoffer, f. eks. natriumsak-karinat, sammen med et luktestoff, f. eks. mentolessens, fargestoffer og et preserve-ringsstoff, • . d) et rense- og skumme-stoff med formel (2) i en mengde på mellom 0,5 og 5 %, eventuelt sammen med et vanlig skumme-eller fuktestoff, f .eks. såpe eller et sulfat av laurinsyrealkohol,
e) eventuelt et avsondringsmiddel, f. eks. natriumpolyfosfat som er oppløselig i
vann som tjener til å sikre at tannrense-massen holder seg stabil.
, For å vise hvorledes oppfinnelsen kan bringes til utførelse skal det nå gis noen ikke begrensende eksempler på tannpussemidler som har vist seg helt tilfredsstil-lende for pleie av tennene. I eksemplene er de forskjellige mengder angitt i vekts-deler.
Eksempel 1:
Sammensetning av krem- eller pasta-formet tannpussemiddel:
Hvis det ønskes å tilsette et preserve-ringsmiddel, minskes vanninnholdet med samme verdi som verdien av det tilsatte middel.
Eksempel 2:
Tannpussekrem eller -pasta.
Eksempel 3: Tannpusspulver. Formelen for den aktive substans i
dette pulver er
hvor R-CO betegner lauroyl.
Eksempel 4:
Tannpusse-essens.
Eksempel 5: Tannpusspulver. Formelen for den aktive substans i
dette pulver er
hvor R-CO betegner ricinoleylgruppen.
Det er klart at det i de eksempler som er beskrevet kan foretas forskjellige en-dringer, tilføyelser eller erstatninger av visse stoffer.
Claims (1)
- Tannpussemiddel i form av krem, pasta, såpe, væske, essens, pulver, tyggegummi karakterisert ved at det inneholder 0,5—5 % av en eller flere av forbindelsene med den generelle formel:som fremstilles ved kondensering av høyere fettsyrederivater med en primær eller sekundær amin av den generelle formel: idet R-CO betyr en mettet eller umettet rest av en høyere fettsyre, som eventuelt kan inneholde en eller flere hydroksygrup-per, X betyr en -SOsH-, -COOH- eller -0-SO:iH- rest, hvor det sure hydrogen kan være erstattet av et alkalimetall, ammo-nium, kalsium, magnesium eller alkylamin, Ri betyr et alkyl-radikal eller hydrogen, A betyr aryl, alkylaryl, polyaryl eller alkyl-polyaryl, og X' hydrogen, alkalimetall, am-monium eller en alkanolaminrest, for-trinnsvis en mono-, di- eller tri-etanol-aminrest, og n og n' betyr null eller hele tall, som kan være like eller forskjellige.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1483864A CH430220A (fr) | 1964-11-13 | 1964-11-13 | Procédé de fabrication d'une résine polyimide réticulée |
| CH686366A CH466929A (fr) | 1964-11-13 | 1966-05-11 | Procédé de fabrication d'une résine polyimide réticulée |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO119705B true NO119705B (no) | 1970-06-22 |
Family
ID=25700296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO168087A NO119705B (no) | 1964-11-13 | 1967-05-10 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US3380964A (no) |
| BE (2) | BE672266A (no) |
| DE (2) | DE1645302A1 (no) |
| FR (1) | FR92323E (no) |
| GB (2) | GB1066390A (no) |
| LU (1) | LU53637A1 (no) |
| NL (2) | NL6514767A (no) |
| NO (1) | NO119705B (no) |
| SE (1) | SE316011B (no) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL6601893A (no) * | 1966-02-15 | 1967-08-16 | ||
| AT279169B (de) * | 1967-01-26 | 1970-02-25 | Rhodiaceta | Verfahren zur herstellung eines vernetzten polyamidharzes |
| US3619259A (en) * | 1967-04-04 | 1971-11-09 | Gen Electric | Photopolymerized film, composite thereof, and method of forming |
| USRE29316E (en) * | 1967-07-13 | 1977-07-19 | Rhone-Poulenc S.A. | Cross-linked resins |
| US3625912A (en) * | 1968-07-26 | 1971-12-07 | Desota Inc | Polyimide lacquers |
| US4581396A (en) * | 1968-09-18 | 1986-04-08 | Raychem Corporation | Flame retardants and compositions containing them |
| US4535170A (en) * | 1968-09-18 | 1985-08-13 | Raychem Corporation | Flame retardants and compositions containing them |
| US4644066A (en) * | 1968-09-18 | 1987-02-17 | Raychem Corporation | Flame retardants and compositions containing them |
| US4374220A (en) * | 1968-09-18 | 1983-02-15 | Raychem Corporation | Imide flame retardants and compositions containing them |
| DE1954878B2 (de) * | 1968-11-05 | 1972-03-02 | Toray Industries, Ine , Tokio | Verfahren zur herstellung von formkoerpern auf der basis von imidgruppen enthaltenden polykondensaten |
| US3878172A (en) * | 1968-12-19 | 1975-04-15 | Rhone Poulenc Sa | Process for preparing heat resistant resin from unsaturated bis-imide and diamine |
| US3717615A (en) * | 1969-04-25 | 1973-02-20 | Gen Electric | Polyimides |
| US3678015A (en) * | 1970-04-06 | 1972-07-18 | Gen Electric | Process for making polyimide prepolymer with mixture of phenolic and hydrocarbon solvents |
| US3610994A (en) * | 1970-08-31 | 1971-10-05 | Sheldon Edward E | Cathode-ray tubes of television type for x-rays protection |
| US3789052A (en) * | 1971-04-30 | 1974-01-29 | Gen Electric | Imido-alkylene substituted aromatic carbocyclic polymers |
| US3855180A (en) * | 1971-07-21 | 1974-12-17 | Gen Electric | Curable compositions from blend of maleimido compound and vinyl ether |
| US3742089A (en) * | 1971-07-21 | 1973-06-26 | Gen Electric | Curable compositions of maleimide substituted aromatic material |
| US4110294A (en) * | 1974-04-08 | 1978-08-29 | Ciba-Geigy Corporation | Processing aids for high temperature polymers |
| CH617447A5 (no) | 1975-06-18 | 1980-05-30 | Ciba Geigy Ag | |
| CH619694A5 (no) * | 1975-12-19 | 1980-10-15 | Ciba Geigy Ag | |
| CH624391A5 (no) * | 1976-12-14 | 1981-07-31 | Ciba Geigy Ag | |
| FR2444667A2 (fr) * | 1978-12-19 | 1980-07-18 | Rhone Poulenc Ind | Preparation d'oligoimides |
| FR2400014A1 (fr) * | 1977-08-09 | 1979-03-09 | Rhone Poulenc Ind | Preparation d'oligoimides |
| US4110274A (en) * | 1977-10-17 | 1978-08-29 | The Dow Chemical Company | Method for making crosslinked resin foams from an ethylenically unsaturated dicarboxylic acid anhydride and a polyisocyanate |
| US4108810A (en) * | 1977-10-17 | 1978-08-22 | The Dow Chemical Company | Method for making crosslinked resin foams from at least one dicarboxylic acid, at least one ethylenically unsaturated dicarboxylic acid anhydride and a polyisocyanate |
| CA1111997A (en) * | 1977-10-17 | 1981-11-03 | John M. Corbett | Imide-crosslinked ethylenic polymer resin foams |
| JPS5611917A (en) * | 1979-07-10 | 1981-02-05 | Mitsui Toatsu Chem Inc | Thermosetting resin composition |
| US4351932A (en) * | 1980-03-27 | 1982-09-28 | Hitco | Bis-maleimide/divinyl aryl crosslinking agent resin system |
| US4468497A (en) * | 1981-03-30 | 1984-08-28 | Hitco | Elastomer modified bis-maleimide resin |
| US4454283A (en) * | 1981-03-30 | 1984-06-12 | Hitco | Bis-maleimide resin with inhibitor |
| US4354012A (en) * | 1981-06-12 | 1982-10-12 | United Technologies Corporation | Aliphatic diene bis-imide polymers |
| US4412884A (en) * | 1981-06-12 | 1983-11-01 | United Technologies Corporation | Adhesive bonding method employing diene bis-imide polymers |
| US4520145A (en) * | 1982-07-21 | 1985-05-28 | The Boots Company Plc | Modified thermosetting imide resins with improved fracture toughness |
| US4464520A (en) * | 1982-08-12 | 1984-08-07 | The United States Of America As Represented By The United States Department Of Energy | Delayed cure bismaleimide resins |
| US4454257A (en) * | 1983-04-06 | 1984-06-12 | The Dow Chemical Company | Isocyanurate/imide cross-linked resins and foams |
| US4598115A (en) * | 1983-09-14 | 1986-07-01 | Hitachi Chemical Company, Ltd. | Polyamino-bis-maleimide prepolymer, method for manufacture thereof, and method for manufacture of laminate using said prepolymer |
| US5719233A (en) * | 1984-05-21 | 1998-02-17 | General Electric Company | Modified polyphenylene ether-polyamide compositions and process |
| DE3582911D1 (de) * | 1984-09-14 | 1991-06-27 | Ciba Geigy Ag | Substituierte bicyclo(2.2.1)hept-5-en-2,3-dicarbonsaeureimide und polymaleinimide enthaltende heisshaertbare stoffgemische und deren verwendung. |
| US4678849A (en) * | 1986-02-21 | 1987-07-07 | Ciba-Geigy Corporation | Heat-curable mixture containing substituted bicyclo(2.2.1)hept-5-ene-2,3-dicarboximide and polymaleimide |
| EP0292434B1 (de) * | 1987-05-22 | 1992-07-08 | Ciba-Geigy Ag | Ungesättigte Bisimide und deren Polymeren |
| AT388915B (de) * | 1987-11-18 | 1989-09-25 | Chemie Holding Ag | Bismaleinimide, sowie daraus hergestellte polyimide |
| US5194545A (en) * | 1987-11-18 | 1993-03-16 | Petrochemie Danubia Gesellschaft M.B.H. | Bismaleimides and polyimides prepared therefrom |
| US5244999A (en) * | 1988-02-26 | 1993-09-14 | Petrochemie Danubia Gesellschaft M.B.H. | Polyimide from diamine and bismaleimide having azole ring |
| AT390059B (de) | 1988-02-26 | 1990-03-12 | Danutec Werkstoff | Diamine und bismaleinimide, sowie daraus hergestellte polyimide |
| WO1991002013A1 (en) * | 1989-08-03 | 1991-02-21 | Akzo N.V. | Biscitraconimide copolymers with olefinically unsaturated materials |
| US5386002A (en) * | 1993-12-03 | 1995-01-31 | The Dow Chemical Company | Fluorene based bisimides and thermoplastic polymers thereof |
| KR19990061716A (ko) * | 1997-12-31 | 1999-07-26 | 윤종용 | 비스(디알킬말레이미드) 유도체 및 이로부터 형성된 광통신용 폴리에테르이미드 |
| WO2015164601A1 (en) * | 2014-04-25 | 2015-10-29 | Polyone Corporation | Aliphatic polyimides from a 1:2 molar ratio of diamine and unsaturated monoanhydride or unsaturated diacid |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1248070A (fr) * | 1959-10-29 | 1960-12-09 | Saint Gobain | Procédé de polymérisation de l'imide maléique et produits obtenus par ce procédé |
-
1965
- 1965-11-01 SE SE1408365A patent/SE316011B/xx unknown
- 1965-11-11 DE DE19651645302 patent/DE1645302A1/de active Pending
- 1965-11-12 BE BE672266D patent/BE672266A/xx unknown
- 1965-11-12 NL NL6514767A patent/NL6514767A/xx unknown
- 1965-11-12 GB GB4824065A patent/GB1066390A/en not_active Expired
- 1965-11-15 US US50765665 patent/US3380964A/en not_active Expired - Lifetime
-
1967
- 1967-05-08 DE DE19671745383 patent/DE1745383A1/de active Pending
- 1967-05-08 GB GB2130167A patent/GB1181255A/en not_active Expired
- 1967-05-09 US US63705467 patent/US3406148A/en not_active Expired - Lifetime
- 1967-05-09 FR FR105753A patent/FR92323E/fr not_active Expired
- 1967-05-10 BE BE698308D patent/BE698308A/xx unknown
- 1967-05-10 NO NO168087A patent/NO119705B/no unknown
- 1967-05-10 LU LU53637D patent/LU53637A1/xx unknown
- 1967-05-11 NL NL6706592A patent/NL6706592A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BE698308A (no) | 1967-11-10 |
| SE316011B (no) | 1969-10-13 |
| GB1181255A (en) | 1970-02-11 |
| GB1066390A (en) | 1967-04-26 |
| US3380964A (en) | 1968-04-30 |
| US3406148A (en) | 1968-10-15 |
| DE1745383A1 (de) | 1971-09-02 |
| NL6514767A (no) | 1966-05-16 |
| LU53637A1 (no) | 1967-09-11 |
| DE1645302A1 (de) | 1970-09-17 |
| BE672266A (no) | 1966-05-12 |
| FR92323E (fr) | 1968-10-25 |
| NL6706592A (no) | 1967-11-13 |
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