NO119525B - - Google Patents
Download PDFInfo
- Publication number
- NO119525B NO119525B NO159432A NO15943265A NO119525B NO 119525 B NO119525 B NO 119525B NO 159432 A NO159432 A NO 159432A NO 15943265 A NO15943265 A NO 15943265A NO 119525 B NO119525 B NO 119525B
- Authority
- NO
- Norway
- Prior art keywords
- ethylene
- trichloro
- denotes
- halogen
- general formula
- Prior art date
Links
- -1 alkyl radicals Chemical class 0.000 claims description 17
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 125000005843 halogen group Chemical group 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 125000004434 sulfur atom Chemical group 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 150000005840 aryl radicals Chemical class 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000000725 suspension Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 201000010099 disease Diseases 0.000 description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 3
- 244000046052 Phaseolus vulgaris Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 125000001174 sulfone group Chemical group 0.000 description 2
- 150000003457 sulfones Chemical class 0.000 description 2
- 150000003462 sulfoxides Chemical class 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- WETIYFGBOOVJPD-UHFFFAOYSA-N 1-methyl-4-(1,2,2-trichloroethenylsulfanyl)benzene Chemical group CC1=CC=C(SC(Cl)=C(Cl)Cl)C=C1 WETIYFGBOOVJPD-UHFFFAOYSA-N 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 241000222199 Colletotrichum Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 241000250507 Gigaspora candida Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 241000228143 Penicillium Species 0.000 description 1
- ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical compound CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 description 1
- 241000233626 Plasmopara Species 0.000 description 1
- 241001516100 Puccinia menthae Species 0.000 description 1
- 206010039509 Scab Diseases 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 241000317942 Venturia <ichneumonid wasp> Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- 229940031826 phenolate Drugs 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C9/00—Methods specially adapted for the making of beerwort
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C1/00—Preparation of malt
- C12C1/18—Preparation of malt extract or of special kinds of malt, e.g. caramel, black malt
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C11/00—Fermentation processes for beer
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C12/00—Processes specially adapted for making special kinds of beer
- C12C12/04—Beer with low alcohol content
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C3/00—Treatment of hops
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C5/00—Other raw materials for the preparation of beer
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C7/00—Preparation of wort
- C12C7/20—Boiling the beerwort
- C12C7/205—Boiling with hops
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C9/00—Methods specially adapted for the making of beerwort
- C12C9/02—Beerwort treatment; Boiling with hops; Hop extraction
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12H—PASTEURISATION, STERILISATION, PRESERVATION, PURIFICATION, CLARIFICATION OR AGEING OF ALCOHOLIC BEVERAGES; METHODS FOR ALTERING THE ALCOHOL CONTENT OF FERMENTED SOLUTIONS OR ALCOHOLIC BEVERAGES
- C12H1/00—Pasteurisation, sterilisation, preservation, purification, clarification, or ageing of alcoholic beverages
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C12/00—Processes specially adapted for making special kinds of beer
Landscapes
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Food Science & Technology (AREA)
- General Health & Medical Sciences (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Genetics & Genomics (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Microbiology (AREA)
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Fremgangsmåte til å bekjempe skadelige organismer.
Oppfinnelsen går ut på en fremgangsmåte til å bekjempe skadelige organismer,
bestående i at der til dette formål anvendes et trihalogenetylenderivat med den
generelle formel:
hvor Ar betegner et arylradikal, som eventuelt er substituert, særlig med halogen-atomer, akylradikaler, alkoksyradikaler
eller med nitrogengrupper, A betegner
en enkel binding eller et alifatisk, mettet,
toverdig kullvannstoffradikal som inneholder 1—3 kullstoffatomer, X betegner et
svovelatom eller en So- eller SOa-gruppe
og Y et halogenatom, fortrinnsvis klor eller
brom.
Disse forbindelser kan fås ved tilføyel-sen av et molekyl halogen til et molekyl av
et dikloretylen med den generelle formel:
og avspaltning av halogenvannstoff fra den
således oppnådde tetrahalogenforbindelse,
samt eventuelt oksydasjon av svovelet i
trihalogenforbindelsen til sulfoksyd eller
sulfon.
Tilføyelsen av halogen til dikloretylenet med formelen (II) skjer hensiktsmessig ved en temperatur mellom — 20° C og
-|-20<o> C, f. eks. ved gjennomledning av en
klorgass-strøm gjennom eller tilsetning av
brom til en oppløsning av dikloretylenet i
ett eller annet hensiktsmessig oppløsnings-middel, som kloroform, kulldisulfid, eddik-
syre eller eter. Man anvender reaksjons-komponentene i hovedsakelig ekvimoleky-lære proporsjoner. Sollys eller kunstig lys kan i visse tilfeller fremme reaksjonen, men er i almindelighet overflødig.
Avspaltningen av halogenvannstoff fra den oppnådde tetrahalogenforbindelse til-veiebringes ved hjelp av ett eller annet basisk reaksjonsmiddel, som et hydroksyd, et alkoholat eller fenolat av et alkalimetall, eller en heterosyklisk base (f. eks. pyridin eller piperidin). Reaksjonen kan gjennom-føres ved vanlig eller forhøyet temperatur ved innvirkning av et basisk reaksjonsmiddel på en oppløsning eller suspensjon av tetrahalogenf orbindelsen.
Når man ønsker å få sulfoksydene eller sulfonene, underkaster men svovelet en oksydasjon ved kjente midler for oksydasjon av et svovelatom til sulfoksyd eller sulfon, som surstoffholdig vann, peroksyder, per-salter (f. eks. alkalipermanganater), per-syrer etc. Det er hensiktsmessig å utføre oksydasjonen i et organisk oppløsningsmid-del, f. eks. aceton eller eddiksyre. Hvis man ønsker å få sulfoksydene, arbeider man hensiktsmessig med et lite overskudd av ok-sydasjonsmiddelet og ved vanlig temperatur, men hvis man ønsker å få sulfonene, er det hensiktsmessig å anvende et stort overskudd av oksydasjonsmiddel og arbeide ved sterkt forhøyet temperatur. Fremstillingen av forbindelsene med formelen (I) kan skje i ett eller flere trinn, beroende på om man ønsker å isolere mel-lomproduktene eller ikke.
De produkter som anvendes ifølge oppfinnelsen, særlig de hvor X = SO eller S02
i den generelle formel (I), har bemerkelses-verdige fungiside egenskaper. Deres akti-vitet har vært fastslått med hensyn på for-skjellige grupper av sopper, dels slike som
fremkaller sykdommer med stor spredning
blandt kulturvekster, f. eks. Botrytis cine-rea, Colletotrichum , lindemuthanium
(fremkaller bønneflekksyke), Venturia
anaequalis (fremkaller lepleskurv), Pucci-nia menthae (fremkaller rust hos mynte)
og Plasmopora viticola (fremkaller falsk
meldugg hos vinranker);, dels saprofyter, f.
eks. Aspergillus niger ogj Penicillium ansari
modifi, og dels slike som er parasitter hos
mennesker, f. eks. Candida albicans (fremkaller såkalt hudsopp). Deres virkning er helt jevngod med, for ikke å si helt over-legen i forhold til virkningen av klassiske fungisider, og de er i almindelighet meget mindre .giftige ved den dosering som nor-malt brukes (250 g aktivt materiale pr. 100 1 vann), og endog ved høyere doser.
Dette fremgår av følgende sammen-lignende forsøk som har vært utført under
anvendelse av l,l,2-triklor-2-(p-klor-ben-solsulfonyl)-etylen i form av et pulver som inneholdt 25 pst. virksomt produkt, som ble påført ved sprøytning av en suspensjon av pulveret i vann.
Fem behandlinger ble utført fra begyn- nelsen av juni til slutten av juli på plante-skolevinranker.
Der ble utført tre påføringer av 1,1,2-triklor-2-(p-klorbensolsulfonyl)-etylen i en konsentrasjon av 250 g pr. 100 1. fra mid-ten av juni til slutten av juli, og der ble ikke fremkalt noen senkning av utbyttet, mens fire kobberpreparater som ble brukt til stammenligning, gjennomsnittlig min-sket vekten av de høstede poteter med 11,4 pst.
Som ytterligere eksempler på aktive forbindelser kan nevnes: l,l,2-triklor-2-(p-klorfenyltio)-etylen 1,1,2-triklor-2- (p-klorf enylsulf oxy) -
etylen
l,l,2-triklor-2-(p-metylfenyltio)-etylen 1,1,2-triklor-2- (p-metylf enylsulf oxy) -
etylen
l,l,2-triklor-2-(p-metylf enylsulf onyl)-etylen
1,1,2-triklor-2- (p-isopropylf enyltio) -
etylen
l,l,2-triklor-2-(p-isopropylfenylsulfoxy)-etylen l,l,2-triklor-2-(p-isopropylf enylsulfonyl)-etylen
l,2-diklor-l-brom-2- (p-klorfenyltio) -
etylen
l,2-diklor-l-brom-2-(p-klorf enylsul-foxy) -etylen
l,2-diklor-l-brom-2-(p-klorf enylsulf o-nyl)-etylen
l,l,2-triklbr-2-(3',4'-dimetylfenyltio)-etylen
l,l,2-triklor-2-(3',4'-dimetylfenylsul-foxy)-etylen
l,l,2-triklor-2-(4'-klor-l'-naftyltio)-etylen
l,l,2-triklor-2-(4'-klor-l'-naftylsulfoxy)-etylen
l,l,2-triklor-2- (3',4'-diklorf enyltio) -
etylen
1,1,2-triklor-2- (3',4'-diklorf enylsulf oxy) -
etylen
l,l,2-triklor-2-(3',4'-diklorfenylsulfonyl)-etylen
l,l,2-triklor-2-(3'-metyl-4'-klorfenyltio)-etylen
l,l,2-triklor-2-(3'-metyl-4'-klorfenylsul-foxy)-etylen
l,l,2-triklor-2-(3'-metyl-4'-klorfenylsul-fonyl)-etylen
Eksempel 1.
En blanding tilberedt av 200 g 1,1,2-triklor-2- (p-klorbensolsulfonyl) -etylen, 500 ml xyien og 500 ml Tween 80 omrøres kraftig. Den oppnådde fine suspensjon spes opp med vann under kraftig omrør-ing inntil der fås et endelig volum av 200 1. Suspensjonen benyttes til behandling av bønner mot flekksyke.
Eksempel 2.
Man tilbereder en oppløsning av 200 g l,l,2-triklor-2-(3'4'-dimetylbensolsul-fonyl)-etylen i 500 ml xylen. Til denne opp-løsning setter man 500 ml Tween 80. Den blanding man således får, spes opp med vann under kraftig omrøring slik at der fås en finfordelt suspensjon som benyttes til å beskytte bønner mot flekksyke.
Claims (1)
- Fremgangsmåte til å bekjempe skadelige organismer, karakterisert ved at der til dette anvendes et trihalogenetylen-derivat med den generelle formel:hvor Ar betegner et arylradikal, som eventuelt er substituert, særlig med halogen-atomer, alkylradikaler, alkoksyradikaler eller med nitrogrupper, A betegner en enkel binding eller et alifatisk, mettet, toverdig kullvannstoffradikal som inneholder 1—3 kullstoffatomer, X betegner et svovelatom eller en SO- eller S02-gruppe og Y et halogenatom, fortrinnsvis klor eller brom.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEB78344A DE1263662B (de) | 1964-09-01 | 1964-09-01 | Verfahren zur Herstellung eines alkoholarmen Vollbieres |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO119525B true NO119525B (no) | 1970-06-01 |
Family
ID=6979839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO159432A NO119525B (no) | 1964-09-01 | 1965-08-21 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3402048A (no) |
| AT (1) | AT267451B (no) |
| BE (1) | BE668608A (no) |
| CH (1) | CH494816A (no) |
| DE (1) | DE1263662B (no) |
| DK (1) | DK111952B (no) |
| FI (1) | FI43583C (no) |
| FR (1) | FR1456768A (no) |
| GB (1) | GB1125466A (no) |
| LU (1) | LU49338A1 (no) |
| MC (1) | MC547A1 (no) |
| NL (1) | NL6510531A (no) |
| NO (1) | NO119525B (no) |
| SE (1) | SE323945B (no) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4957766A (en) * | 1987-09-08 | 1990-09-18 | Heineken Technisch Beheer B.V. | Process for making beer containing an unfermented beer product |
| US20090324783A1 (en) * | 2006-03-16 | 2009-12-31 | Heineken Supply Chain B.V. | Package for carbonated beverage |
| ITMI20110803A1 (it) * | 2011-05-10 | 2012-11-11 | Claber Spa | Impianto di irrigazione a controllo remoto. |
| CN107828571A (zh) * | 2017-08-03 | 2018-03-23 | 广东俊粤生物技术科技有限公司 | 富硒啤酒生产工艺 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE290075C (no) * | ||||
| US159716A (en) * | 1875-02-09 | Improvement in brewing beer | ||
| US1163454A (en) * | 1911-10-11 | 1915-12-07 | Carl Rach | Process of making beer. |
| AT124263B (de) * | 1929-05-28 | 1931-08-25 | Albrecht Haselbach | Verfahren zur Herstellung alkoholarmer Biere. |
| DE558552C (de) * | 1929-05-29 | 1932-09-08 | Euros Akt Ges | Verfahren zur Herstellung alkoholarmer, obergaeriger Biere |
| US1994494A (en) * | 1932-01-18 | 1935-03-19 | Wallerstein Leo | Process of preparing beers and ales |
| US2442806A (en) * | 1943-03-25 | 1948-06-08 | Alvin C Gluek | Manufacture of a new malt liquor from cereal products |
| GB737004A (en) * | 1953-01-14 | 1955-09-21 | Albrecht Haselbach | Improvements in or relating to the production of low alcoholic beers |
-
1964
- 1964-09-01 DE DEB78344A patent/DE1263662B/de active Pending
-
1965
- 1965-07-12 AT AT639565A patent/AT267451B/de active
- 1965-08-12 NL NL6510531A patent/NL6510531A/xx unknown
- 1965-08-17 LU LU49338A patent/LU49338A1/xx unknown
- 1965-08-18 MC MC579A patent/MC547A1/xx unknown
- 1965-08-20 BE BE668608A patent/BE668608A/xx unknown
- 1965-08-20 CH CH1176965A patent/CH494816A/de not_active IP Right Cessation
- 1965-08-21 NO NO159432A patent/NO119525B/no unknown
- 1965-08-23 GB GB36022/65A patent/GB1125466A/en not_active Expired
- 1965-08-24 SE SE11064/65A patent/SE323945B/xx unknown
- 1965-08-30 US US483782A patent/US3402048A/en not_active Expired - Lifetime
- 1965-08-30 FI FI652080A patent/FI43583C/fi active
- 1965-08-31 DK DK447365AA patent/DK111952B/da unknown
- 1965-09-01 FR FR30139A patent/FR1456768A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1125466A (en) | 1968-08-28 |
| FR1456768A (fr) | 1966-07-08 |
| AT267451B (de) | 1968-12-27 |
| SE323945B (no) | 1970-05-19 |
| BE668608A (no) | 1965-12-16 |
| MC547A1 (fr) | 1966-04-06 |
| LU49338A1 (no) | 1965-10-18 |
| FI43583B (no) | 1971-02-01 |
| DE1263662B (de) | 1968-03-21 |
| US3402048A (en) | 1968-09-17 |
| NL6510531A (no) | 1966-03-02 |
| DK111952B (da) | 1968-10-28 |
| CH494816A (de) | 1970-08-15 |
| FI43583C (fi) | 1971-05-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3296272A (en) | Sulfinyl- and sulfonylpyridines | |
| KR0120739B1 (ko) | 살균제 | |
| NL8006170A (nl) | Werkwijzen voor het bereiden en toepassen van organische verbinding. | |
| JPH02188565A (ja) | プロペン酸誘導体、その製造法及びそれを含有する殺菌剤、殺虫剤又は殺ダニ剤組成物 | |
| US3501578A (en) | Fungicidal composition containing phenyl - mercaptomethane-sulfonamide and method of using the same | |
| CZ282929B6 (cs) | Semikarbazidy, thiosemikarbazidy a isothiosemikarbazidy, způsob jejich výroby a herbicidní prostředek s jejich obsahem | |
| NO119525B (no) | ||
| DE68923124T2 (de) | Schimmelbekämpfungsmittel. | |
| US3639446A (en) | 4 4'-dibromo- and 4-chloro-4'-bromobenzilic acid esters | |
| EP0004129B1 (en) | Thiazolidinone derivatives, their preparation, their pesticidal compositions and processes for treating plants | |
| US3901935A (en) | Cyanophenyl sulfoxides and sulfones | |
| US2766274A (en) | Organic sulfides and their preparation | |
| US3346605A (en) | Ammonia complex manganese salt of ethylenebisdithiocarbamic acid | |
| EP0025773B1 (de) | Schwefelhaltige Alkancarbonsäurederivate mit herbizider und den Pflanzenwuchs regulierender Wirkung, deren Herstellung und Verwendung | |
| US3549647A (en) | Bis- and tris-(thio-,sulfinyl- and sulfonyl)pyridines | |
| US3397274A (en) | Method for the control of fungi | |
| HU206331B (en) | Fungicide composition containing 2,5-disubstituted 1,3,4-thiadiazol derivatives and process for producing the active components | |
| US2875126A (en) | New esters of 5-acyl-8-hydroxyquinolines and their use for the control of fungi | |
| US3736328A (en) | Certain 3-halo-5-sulfinyl-1,2,4-thiadiazoles | |
| US3920832A (en) | N-chloro carbamates as insecticides and fungicides | |
| US3542865A (en) | Ethylenic sulfilimines | |
| US3371011A (en) | Sulfinyl-and sulfonylpyridine pesticidal compositions and method of use | |
| KR800000903B1 (ko) | 프로파길(또는 알케닐) 페닐에테르 유도체의 제조방법 | |
| US2579429A (en) | Sulfur composition | |
| US3337396A (en) | Method of combatting fungi |