NL8104299A - Werkwijze voor het bereiden van polyisobutenen. - Google Patents
Werkwijze voor het bereiden van polyisobutenen. Download PDFInfo
- Publication number
- NL8104299A NL8104299A NL8104299A NL8104299A NL8104299A NL 8104299 A NL8104299 A NL 8104299A NL 8104299 A NL8104299 A NL 8104299A NL 8104299 A NL8104299 A NL 8104299A NL 8104299 A NL8104299 A NL 8104299A
- Authority
- NL
- Netherlands
- Prior art keywords
- aluminum oxide
- weight
- alumina
- chlorinated
- polyisobutenes
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 34
- 239000003054 catalyst Substances 0.000 claims description 39
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 37
- 239000011148 porous material Substances 0.000 claims description 23
- 229920002367 Polyisobutene Polymers 0.000 claims description 22
- 230000008569 process Effects 0.000 claims description 20
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052801 chlorine Inorganic materials 0.000 claims description 12
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 11
- 239000000460 chlorine Substances 0.000 claims description 11
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 9
- 238000005660 chlorination reaction Methods 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 24
- 239000000463 material Substances 0.000 description 13
- 150000001336 alkenes Chemical class 0.000 description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 230000000379 polymerizing effect Effects 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000539 dimer Substances 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 3
- 239000013638 trimer Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- -1 extrudate Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/10—Catalytic processes with metal oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/08—Butenes
- C08F110/10—Isobutene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polymerization Catalysts (AREA)
- Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18942980 | 1980-09-22 | ||
| US06/189,429 US4306105A (en) | 1980-09-22 | 1980-09-22 | Process for the production of polyisobutenes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8104299A true NL8104299A (nl) | 1982-04-16 |
Family
ID=22697289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8104299A NL8104299A (nl) | 1980-09-22 | 1981-09-17 | Werkwijze voor het bereiden van polyisobutenen. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US4306105A (it) |
| JP (1) | JPS5782325A (it) |
| AR (1) | AR226482A1 (it) |
| BE (1) | BE890409A (it) |
| CA (1) | CA1157485A (it) |
| DE (1) | DE3137500A1 (it) |
| FR (1) | FR2490652A1 (it) |
| GB (1) | GB2085467B (it) |
| IN (1) | IN154457B (it) |
| IT (1) | IT1139965B (it) |
| NL (1) | NL8104299A (it) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IN154458B (it) * | 1980-09-22 | 1984-10-27 | Cosden Technology | |
| DE3336355A1 (de) * | 1983-10-06 | 1985-04-18 | Basf Ag, 6700 Ludwigshafen | Verfahren zur qualitaetsverbesserung von polymerisaten des isobutens |
| DE69409512T2 (de) * | 1993-05-20 | 1998-09-24 | Exxon Chemical Patents Inc | Lewis-säure-katalysatoren auf einem porösen polymersubstrat |
| WO1994028036A1 (en) * | 1993-05-20 | 1994-12-08 | Exxon Chemical Patents Inc. | Heterogeneous lewis acid-type catalysts |
| US5691431A (en) * | 1996-01-18 | 1997-11-25 | Exxon Chemical Patents Inc. | Cationic polymerization catalyzed by lewis acid catalysts supported on porous polymer substrate |
| DE10148284A1 (de) * | 2001-09-29 | 2003-04-17 | Basf Ag | Verfahren zur Herstellung von Raffinaten und Extrakten von Polymerisaten |
| US7638573B2 (en) * | 2006-04-07 | 2009-12-29 | Exxonmobil Chemical Patents Inc. | Butyl nanocomposite via low Mw elastomer pre-blend |
| JP5410150B2 (ja) * | 2009-05-08 | 2014-02-05 | 出光興産株式会社 | ヘテロポリ酸のアルカリ金属塩及びそれからなるオレフィンオリゴマー化用触媒 |
| US9040645B2 (en) | 2010-03-11 | 2015-05-26 | Petrochemical Supply, Inc. | Catalyst system for heterogenous catalysis of an isobutylene polymerization reaction |
| JP2016065128A (ja) * | 2014-09-24 | 2016-04-28 | Ｊｘ日鉱日石エネルギー株式会社 | ポリイソブチレンの製造方法、高反応性ポリイソブチレンの生成率向上方法、及びポリイソブチレンの製造装置 |
| EP3585822A4 (en) | 2017-02-21 | 2021-03-03 | NTP Tec, LLC | PROCESS FOR THE PREPARATION OF POLYISOBUTYLENE COMPOSITIONS |
| WO2020006437A1 (en) | 2018-06-29 | 2020-01-02 | Ntp Tec, Llc | Processes for the manufacture of isobutylene, polyisobutylene, and derivatives thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE632378A (it) * | 1962-05-15 | 1900-01-01 | ||
| US3607959A (en) * | 1967-06-16 | 1971-09-21 | Texaco Inc | Catalyst for hydrocarbon conversion |
| US3558737A (en) * | 1968-07-26 | 1971-01-26 | Texas Dev Corp | Olefin polymerization |
| US3600129A (en) * | 1969-06-17 | 1971-08-17 | Universal Oil Prod Co | Manufacture of low bulk density high strength spherical alumina particles |
| US4288649A (en) * | 1979-08-23 | 1981-09-08 | Standard Oil Company (Indiana) | Isobutylene polymerization process |
-
1980
- 1980-09-22 US US06/189,429 patent/US4306105A/en not_active Expired - Lifetime
-
1981
- 1981-09-02 IN IN986/CAL/81A patent/IN154457B/en unknown
- 1981-09-11 IT IT23902/81A patent/IT1139965B/it active
- 1981-09-15 GB GB8127809A patent/GB2085467B/en not_active Expired
- 1981-09-17 NL NL8104299A patent/NL8104299A/nl not_active Application Discontinuation
- 1981-09-17 JP JP56145657A patent/JPS5782325A/ja active Granted
- 1981-09-18 BE BE0/205998A patent/BE890409A/fr not_active IP Right Cessation
- 1981-09-21 AR AR286819A patent/AR226482A1/es active
- 1981-09-21 DE DE19813137500 patent/DE3137500A1/de active Granted
- 1981-09-21 CA CA000386276A patent/CA1157485A/en not_active Expired
- 1981-09-22 FR FR8118062A patent/FR2490652A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AR226482A1 (es) | 1982-07-15 |
| BE890409A (fr) | 1982-03-18 |
| JPH0323566B2 (it) | 1991-03-29 |
| FR2490652A1 (fr) | 1982-03-26 |
| US4306105A (en) | 1981-12-15 |
| DE3137500C2 (it) | 1991-05-29 |
| FR2490652B1 (it) | 1984-05-04 |
| IN154457B (it) | 1984-10-27 |
| JPS5782325A (en) | 1982-05-22 |
| IT1139965B (it) | 1986-09-24 |
| CA1157485A (en) | 1983-11-22 |
| GB2085467B (en) | 1984-08-08 |
| DE3137500A1 (de) | 1982-06-24 |
| IT8123902A0 (it) | 1981-09-11 |
| GB2085467A (en) | 1982-04-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A85 | Still pending on 85-01-01 | ||
| BA | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| BC | A request for examination has been filed | ||
| BV | The patent application has lapsed |