MX9307322A - Copolimeros de bloque, resinosos, acoplados, polimodales, de dieno y monovinilareno y metodo para su preparacion. - Google Patents
Copolimeros de bloque, resinosos, acoplados, polimodales, de dieno y monovinilareno y metodo para su preparacion.Info
- Publication number
- MX9307322A MX9307322A MX9307322A MX9307322A MX9307322A MX 9307322 A MX9307322 A MX 9307322A MX 9307322 A MX9307322 A MX 9307322A MX 9307322 A MX9307322 A MX 9307322A MX 9307322 A MX9307322 A MX 9307322A
- Authority
- MX
- Mexico
- Prior art keywords
- monovinylaromatic
- monomers
- conjugated diene
- mixture
- block copolymers
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
Abstract
En la presente invención se describe un método para preparar copolímeros de bloques ahusados. polimodales, en un proceso de polimerización, al cargar en forma secuencial: (a) un iniciador y monómeros monovinilaromáticos en la presencia de un agente de aleatoriedad; (b) un iniciador y monómeros monovinilaromáticos; (c) una mezcla de monómeros de dieno conjugado y de monovinilaromáticos; (d) una mezcla de monómeros de dieno conjugado y de monovinilaromáticos; (e) un iniciador y monómeros monovinilaromáticos; (f) una mezcla de monómeros de dieno conjugado, y de monovinilaromáticos; (g) una mezcla de monómeros de dieno conjugado, y de monovilaromáticos; (h) monómeros de dieno conjugado; y (i) un agente de acoplamiento. Los copolímeros son útiles particularmente para aplicaciones en envases, que requieren buena resistencia al agrietamiento por fatiga ambiental.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/982,938 US5290875A (en) | 1992-11-30 | 1992-11-30 | Conjugated diene/monovinylarene block copolymers with multiple tapered blocks |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9307322A true MX9307322A (es) | 1994-06-30 |
Family
ID=25529665
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9307322A MX9307322A (es) | 1992-11-30 | 1993-11-23 | Copolimeros de bloque, resinosos, acoplados, polimodales, de dieno y monovinilareno y metodo para su preparacion. |
Country Status (10)
Country | Link |
---|---|
US (2) | US5290875A (es) |
EP (1) | EP0600405B1 (es) |
JP (1) | JP2935796B2 (es) |
KR (1) | KR100251074B1 (es) |
AT (1) | ATE147412T1 (es) |
CA (1) | CA2105157C (es) |
DE (1) | DE69307284T2 (es) |
ES (1) | ES2096186T3 (es) |
MX (1) | MX9307322A (es) |
TW (1) | TW268954B (es) |
Families Citing this family (64)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5436298A (en) * | 1993-09-30 | 1995-07-25 | Phillips Petroleum Company | Block copolymers of monovinylarenes and conjugated dienes and preparation thereof |
CA2134026C (en) * | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
US6265484B1 (en) * | 1993-11-15 | 2001-07-24 | Phillips Petroleum Company | Tapered block copolymers of monovinylarenes and conjugated dienes |
US5399628A (en) * | 1993-12-02 | 1995-03-21 | Phillips Petroleum Company | Block copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks |
FR2714384B1 (fr) * | 1993-12-29 | 1996-02-02 | Atochem Elf Sa | Copolymère bloc étoile d'un monomère vinylaromatique et d'un diène conjugué, son procédé d'obtention, et les compositions comprenant ledit copolymère et du polystyrène cristal. |
US5438103A (en) * | 1994-03-23 | 1995-08-01 | Phillips Petroleum Company | Block copolymers of monovinylaromatic and conjugated diene monomers |
DE19523585A1 (de) * | 1995-06-29 | 1997-01-02 | Basf Ag | Schlagzähe Formmasse aus Styrolpolymeren |
CN1036346C (zh) * | 1995-08-04 | 1997-11-05 | 中国石油化工总公司 | 丁苯嵌段共聚物热塑弹性体及制法 |
US6096828A (en) * | 1995-08-29 | 2000-08-01 | Phillips Petroleum Company | Conjugated diene/monovinylarene block copolymers, methods for preparing same, and polymer blends |
US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
US6127487A (en) * | 1998-10-14 | 2000-10-03 | Phillips Petroleum Company | Process to produce coupled block copolymers and said copolymers |
US6956084B2 (en) * | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
US7141621B2 (en) * | 2002-02-07 | 2006-11-28 | Kraton Polymers U.S. Llc | Gels from controlled distribution block copolymers |
US20040138371A1 (en) * | 2002-02-07 | 2004-07-15 | St. Clair David John | Gels from controlled distribution block copolymers |
US20040115381A1 (en) * | 2002-12-12 | 2004-06-17 | Chevron Phillips Chemical Company, Lp | Method for manufacturing articles with materials containing tapered polymers |
JP4683928B2 (ja) * | 2002-12-18 | 2011-05-18 | 株式会社ブリヂストン | クレイの剥離方法、該方法から得られた組成物、及び該組成物を含む変性ゴム |
US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
US7714067B2 (en) * | 2003-03-19 | 2010-05-11 | Denki Kagaku Kogyo Kabushiki Kaisha | Block copolymer mixture containing star-branched block copolymer |
KR100984995B1 (ko) * | 2003-03-19 | 2010-10-04 | 덴끼 가가꾸 고교 가부시키가이샤 | 선형 블록 공중합체 조성물 |
US7037980B2 (en) * | 2003-11-10 | 2006-05-02 | Chevron Phillips Chemical Company, Lp | Monovinylarene/conjugated diene copolymers having lower glass transition temperatures |
US7205370B2 (en) * | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
US7718737B2 (en) * | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
US7112369B2 (en) * | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
US20050215693A1 (en) * | 2004-03-29 | 2005-09-29 | Xiaorong Wang | Clay modified rubber composition and a method for manufacturing same |
US20050228074A1 (en) * | 2004-04-05 | 2005-10-13 | Bridgestone Corporation | Amphiphilic polymer micelles and use thereof |
US20050282956A1 (en) * | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
US7998554B2 (en) * | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
US7579398B2 (en) * | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
US7659342B2 (en) * | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
US20070066753A1 (en) * | 2005-09-16 | 2007-03-22 | Ehrlich Martin L | Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers |
US9061900B2 (en) * | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
US7538159B2 (en) | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
US8288473B2 (en) * | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
US8697775B2 (en) * | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
US7601772B2 (en) * | 2005-12-20 | 2009-10-13 | Bridgestone Corporation | Nano-composite and method thereof |
US8877250B2 (en) | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
US7935184B2 (en) | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
JP6096398B2 (ja) | 2006-07-28 | 2017-03-15 | 株式会社ブリヂストン | 重合体ナノ粒子、ゴム組成物及び使用 |
US8415429B2 (en) * | 2006-12-11 | 2013-04-09 | Chervron Phillips Chemical Company LP | Styrene butadiene block copolymers for film applications |
US7597959B2 (en) * | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
US7649049B2 (en) * | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
US7829624B2 (en) * | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
CN101628959A (zh) * | 2008-07-15 | 2010-01-20 | 中国石油化工集团公司 | 一种可发泡苯乙烯属单体-二烯烃共聚物、其制备方法和用途 |
JP5620405B2 (ja) | 2008-12-31 | 2014-11-05 | 株式会社ブリヂストン | 最初にコアを形成するナノ粒子形成プロセス、ナノ粒子、及び組成物 |
US9062144B2 (en) * | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
US20100272975A1 (en) * | 2009-04-23 | 2010-10-28 | Chevron Phillips Chemical Company Lp | System and method for the production and use of lamination films |
US20110172364A1 (en) * | 2009-12-29 | 2011-07-14 | Chen Yaohong | Charged Nanoparticles And Method Of Controlling Charge |
US9115222B2 (en) * | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
US9428604B1 (en) | 2011-12-30 | 2016-08-30 | Bridgestone Corporation | Nanoparticle fillers and methods of mixing into elastomers |
CN104271666B (zh) * | 2012-05-08 | 2018-11-13 | 电化株式会社 | 嵌段共聚物组合物及片材 |
TWI458768B (zh) | 2012-12-28 | 2014-11-01 | Chi Mei Corp | 橡膠組成及其製造方法 |
US9441090B1 (en) | 2015-03-12 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Methods for controlling hardness of styrene-butadiene block copolymers |
KR102641191B1 (ko) * | 2015-03-12 | 2024-02-26 | 이네오스 스티롤루션 그룹 게엠베하 | 튜빙 적용을 위한 스티렌-부타디엔 블록 공중합체 |
US9598524B1 (en) | 2015-09-18 | 2017-03-21 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications |
US9540475B2 (en) | 2015-03-12 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers for tubing applications |
US9738781B2 (en) | 2015-09-03 | 2017-08-22 | Ineos Styrolution Group Gmbh | Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications |
US10023676B2 (en) | 2016-02-24 | 2018-07-17 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
US9828455B2 (en) | 2016-02-24 | 2017-11-28 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4054616A (en) * | 1973-09-29 | 1977-10-18 | Sumitomo Chemical Company, Limited | Process for producing transparent block copolymer resins |
US4208356A (en) * | 1974-09-17 | 1980-06-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing mixture of block copolymers |
US4167545A (en) * | 1975-11-08 | 1979-09-11 | Basf Aktiengesellschaft | Branched block copolymers and their manufacture |
US4248981A (en) * | 1979-04-30 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
DE2940861A1 (de) * | 1979-10-09 | 1981-04-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen linearer dreiblockcopolymerisate sowie formteile aus diesen |
US4390663A (en) * | 1981-02-17 | 1983-06-28 | Atlantic Richfield Company | Semi-continuous process for making star-block copolymers |
US4584346A (en) * | 1984-02-29 | 1986-04-22 | Phillips Petroleum Company | Craze-resistant transparent resinous polymodal block copolymers |
US4704435A (en) * | 1986-03-24 | 1987-11-03 | Phillips Petroleum Company | Craze-resistant polymodal linear block copolymers with resinous terminal blocks |
US4704434A (en) * | 1986-03-24 | 1987-11-03 | Phillips Petroleum Company | Craze-resistant polymodal linear block copolymers with terminal tapered blocks |
IT1196517B (it) * | 1986-07-17 | 1988-11-16 | Montedipe Spa | Copolimeri a blocco radiali e bimodali aventi ottime proprieta' ottiche e reistenza agli urti e processo per la loro preparazione |
CA2028410C (en) * | 1990-01-02 | 1996-09-17 | William J. Trepka | Tapered block styrene/butadiene copolymers |
US5227419A (en) * | 1990-12-20 | 1993-07-13 | Phillips Petroleum Company | Tapered block styrene/butadiene copolymers |
US5256736A (en) * | 1991-05-08 | 1993-10-26 | Phillips Petroleum Company | Tapered block copolymers of conjugated dienes and monovinylarenes |
-
1992
- 1992-11-30 US US07/982,938 patent/US5290875A/en not_active Expired - Lifetime
-
1993
- 1993-08-30 CA CA002105157A patent/CA2105157C/en not_active Expired - Fee Related
- 1993-11-08 TW TW082109344A patent/TW268954B/zh active
- 1993-11-23 MX MX9307322A patent/MX9307322A/es not_active IP Right Cessation
- 1993-11-24 KR KR1019930025564A patent/KR100251074B1/ko not_active IP Right Cessation
- 1993-11-25 JP JP5294810A patent/JP2935796B2/ja not_active Expired - Fee Related
- 1993-11-29 AT AT93119192T patent/ATE147412T1/de not_active IP Right Cessation
- 1993-11-29 ES ES93119192T patent/ES2096186T3/es not_active Expired - Lifetime
- 1993-11-29 EP EP93119192A patent/EP0600405B1/en not_active Expired - Lifetime
- 1993-11-29 DE DE69307284T patent/DE69307284T2/de not_active Expired - Fee Related
- 1993-12-06 US US08/163,785 patent/US5393838A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CA2105157A1 (en) | 1994-05-31 |
EP0600405B1 (en) | 1997-01-08 |
ES2096186T3 (es) | 1997-03-01 |
DE69307284T2 (de) | 1997-04-30 |
EP0600405A1 (en) | 1994-06-08 |
KR940011512A (ko) | 1994-06-21 |
TW268954B (es) | 1996-01-21 |
US5290875A (en) | 1994-03-01 |
JP2935796B2 (ja) | 1999-08-16 |
KR100251074B1 (ko) | 2000-04-15 |
US5393838A (en) | 1995-02-28 |
JPH06206953A (ja) | 1994-07-26 |
CA2105157C (en) | 1996-09-17 |
ATE147412T1 (de) | 1997-01-15 |
DE69307284D1 (de) | 1997-02-20 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FG | Grant or registration | ||
MM | Annulment or lapse due to non-payment of fees |