MX9307322A - Copolimeros de bloque, resinosos, acoplados, polimodales, de dieno y monovinilareno y metodo para su preparacion. - Google Patents
Copolimeros de bloque, resinosos, acoplados, polimodales, de dieno y monovinilareno y metodo para su preparacion.Info
- Publication number
- MX9307322A MX9307322A MX9307322A MX9307322A MX9307322A MX 9307322 A MX9307322 A MX 9307322A MX 9307322 A MX9307322 A MX 9307322A MX 9307322 A MX9307322 A MX 9307322A MX 9307322 A MX9307322 A MX 9307322A
- Authority
- MX
- Mexico
- Prior art keywords
- monovinylaromatic
- monomers
- conjugated diene
- mixture
- block copolymers
- Prior art date
Links
- 229920001400 block copolymer Polymers 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 8
- 150000001993 dienes Chemical class 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 4
- 239000003999 initiator Substances 0.000 abstract 3
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- 230000006353 environmental stress Effects 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Polymerisation Methods In General (AREA)
Abstract
En la presente invención se describe un método para preparar copolímeros de bloques ahusados. polimodales, en un proceso de polimerización, al cargar en forma secuencial: (a) un iniciador y monómeros monovinilaromáticos en la presencia de un agente de aleatoriedad; (b) un iniciador y monómeros monovinilaromáticos; (c) una mezcla de monómeros de dieno conjugado y de monovinilaromáticos; (d) una mezcla de monómeros de dieno conjugado y de monovinilaromáticos; (e) un iniciador y monómeros monovinilaromáticos; (f) una mezcla de monómeros de dieno conjugado, y de monovinilaromáticos; (g) una mezcla de monómeros de dieno conjugado, y de monovilaromáticos; (h) monómeros de dieno conjugado; y (i) un agente de acoplamiento. Los copolímeros son útiles particularmente para aplicaciones en envases, que requieren buena resistencia al agrietamiento por fatiga ambiental.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/982,938 US5290875A (en) | 1992-11-30 | 1992-11-30 | Conjugated diene/monovinylarene block copolymers with multiple tapered blocks |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9307322A true MX9307322A (es) | 1994-06-30 |
Family
ID=25529665
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9307322A MX9307322A (es) | 1992-11-30 | 1993-11-23 | Copolimeros de bloque, resinosos, acoplados, polimodales, de dieno y monovinilareno y metodo para su preparacion. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US5290875A (es) |
| EP (1) | EP0600405B1 (es) |
| JP (1) | JP2935796B2 (es) |
| KR (1) | KR100251074B1 (es) |
| AT (1) | ATE147412T1 (es) |
| CA (1) | CA2105157C (es) |
| DE (1) | DE69307284T2 (es) |
| ES (1) | ES2096186T3 (es) |
| MX (1) | MX9307322A (es) |
| TW (1) | TW268954B (es) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5436298A (en) * | 1993-09-30 | 1995-07-25 | Phillips Petroleum Company | Block copolymers of monovinylarenes and conjugated dienes and preparation thereof |
| US6265484B1 (en) * | 1993-11-15 | 2001-07-24 | Phillips Petroleum Company | Tapered block copolymers of monovinylarenes and conjugated dienes |
| CA2134026C (en) * | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
| US5399628A (en) * | 1993-12-02 | 1995-03-21 | Phillips Petroleum Company | Block copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks |
| FR2714384B1 (fr) * | 1993-12-29 | 1996-02-02 | Atochem Elf Sa | Copolymère bloc étoile d'un monomère vinylaromatique et d'un diène conjugué, son procédé d'obtention, et les compositions comprenant ledit copolymère et du polystyrène cristal. |
| US5438103A (en) * | 1994-03-23 | 1995-08-01 | Phillips Petroleum Company | Block copolymers of monovinylaromatic and conjugated diene monomers |
| DE19523585A1 (de) * | 1995-06-29 | 1997-01-02 | Basf Ag | Schlagzähe Formmasse aus Styrolpolymeren |
| CN1036346C (zh) * | 1995-08-04 | 1997-11-05 | 中国石油化工总公司 | 丁苯嵌段共聚物热塑弹性体及制法 |
| US6096828A (en) | 1995-08-29 | 2000-08-01 | Phillips Petroleum Company | Conjugated diene/monovinylarene block copolymers, methods for preparing same, and polymer blends |
| US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
| US6127487A (en) * | 1998-10-14 | 2000-10-03 | Phillips Petroleum Company | Process to produce coupled block copolymers and said copolymers |
| US6956084B2 (en) * | 2001-10-04 | 2005-10-18 | Bridgestone Corporation | Nano-particle preparation and applications |
| US6987142B2 (en) * | 2002-02-07 | 2006-01-17 | Kraton Polymers U.S. Llc | Adhesives and sealants from controlled distribution block copolymers |
| US20040138371A1 (en) * | 2002-02-07 | 2004-07-15 | St. Clair David John | Gels from controlled distribution block copolymers |
| US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
| US20040115381A1 (en) * | 2002-12-12 | 2004-06-17 | Chevron Phillips Chemical Company, Lp | Method for manufacturing articles with materials containing tapered polymers |
| AU2003301053A1 (en) * | 2002-12-18 | 2004-07-22 | Bridgestone Corporation | Method for clay exfoliation, compositions therefore, and modified rubber contaiing same |
| US6875818B2 (en) | 2003-01-16 | 2005-04-05 | Bridgestone Corporation | Polymer nano-strings |
| WO2004083269A1 (ja) * | 2003-03-19 | 2004-09-30 | Denki Kagaku Kogyo Kabushiki Kaisha | 分岐状ブロック共重合体を含有するブロック共重合体混合物 |
| KR100984995B1 (ko) * | 2003-03-19 | 2010-10-04 | 덴끼 가가꾸 고교 가부시키가이샤 | 선형 블록 공중합체 조성물 |
| US7037980B2 (en) * | 2003-11-10 | 2006-05-02 | Chevron Phillips Chemical Company, Lp | Monovinylarene/conjugated diene copolymers having lower glass transition temperatures |
| US7205370B2 (en) * | 2004-01-12 | 2007-04-17 | Bridgestone Corporation | Polymeric nano-particles of flower-like structure and applications |
| US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
| US8063142B2 (en) | 2004-03-02 | 2011-11-22 | Bridgestone Corporation | Method of making nano-particles of selected size distribution |
| US7718737B2 (en) * | 2004-03-02 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing functionalized polymer nanoparticles |
| US7112369B2 (en) * | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
| US20050215693A1 (en) * | 2004-03-29 | 2005-09-29 | Xiaorong Wang | Clay modified rubber composition and a method for manufacturing same |
| US20050228074A1 (en) * | 2004-04-05 | 2005-10-13 | Bridgestone Corporation | Amphiphilic polymer micelles and use thereof |
| US20050282956A1 (en) * | 2004-06-21 | 2005-12-22 | Xiaorong Wang | Reversible polymer/metal nano-composites and method for manufacturing same |
| US7998554B2 (en) * | 2004-07-06 | 2011-08-16 | Bridgestone Corporation | Hydrophobic surfaces with nanoparticles |
| US7572855B2 (en) | 2005-01-28 | 2009-08-11 | Bridgestone Corporation | Nano-composite and compositions manufactured thereof |
| US7579398B2 (en) * | 2005-02-02 | 2009-08-25 | Bridgestone Corporation | Nano-composite and compositions therefrom |
| US7659342B2 (en) * | 2005-02-03 | 2010-02-09 | Bridgestone Corporation | Polymer nano-particle with polar core and method for manufacturing same |
| US20070066753A1 (en) * | 2005-09-16 | 2007-03-22 | Ehrlich Martin L | Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers |
| US7538159B2 (en) | 2005-12-16 | 2009-05-26 | Bridgestone Corporation | Nanoparticles with controlled architecture and method thereof |
| US9061900B2 (en) * | 2005-12-16 | 2015-06-23 | Bridgestone Corporation | Combined use of liquid polymer and polymeric nanoparticles for rubber applications |
| US8288473B2 (en) | 2005-12-19 | 2012-10-16 | Bridgestone Corporation | Disk-like nanoparticles |
| US7884160B2 (en) | 2005-12-19 | 2011-02-08 | Bridgestone Corporation | Non-spherical nanoparticles made from living triblock polymer chains |
| US7560510B2 (en) | 2005-12-20 | 2009-07-14 | Bridgestone Corporation | Nano-sized inorganic metal particles, preparation thereof, and application thereof in improving rubber properties |
| US8877250B2 (en) * | 2005-12-20 | 2014-11-04 | Bridgestone Corporation | Hollow nano-particles and method thereof |
| US7601772B2 (en) * | 2005-12-20 | 2009-10-13 | Bridgestone Corporation | Nano-composite and method thereof |
| US8697775B2 (en) * | 2005-12-20 | 2014-04-15 | Bridgestone Corporation | Vulcanizable nanoparticles having a core with a high glass transition temperature |
| US7935184B2 (en) | 2006-06-19 | 2011-05-03 | Bridgestone Corporation | Method of preparing imidazolium surfactants |
| WO2008014464A2 (en) | 2006-07-28 | 2008-01-31 | Bridgestone Corporation | Polymeric core-shell nanoparticles with interphase region |
| US8415429B2 (en) * | 2006-12-11 | 2013-04-09 | Chervron Phillips Chemical Company LP | Styrene butadiene block copolymers for film applications |
| US7597959B2 (en) * | 2006-12-19 | 2009-10-06 | Bridgestone Corporation | Core-shell fluorescent nanoparticles |
| US7649049B2 (en) * | 2006-12-20 | 2010-01-19 | Bridgestone Corporation | Rubber composition containing a polymer nanoparticle |
| US7829624B2 (en) * | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
| CN101628959A (zh) * | 2008-07-15 | 2010-01-20 | 中国石油化工集团公司 | 一种可发泡苯乙烯属单体-二烯烃共聚物、其制备方法和用途 |
| EP2370349B1 (en) | 2008-12-31 | 2014-10-29 | Bridgestone Corporation | Core-first nanoparticle formation process, nanoparticle, and composition |
| US9062144B2 (en) | 2009-04-03 | 2015-06-23 | Bridgestone Corporation | Hairy polymeric nanoparticles with first and second shell block polymer arms |
| US20100272975A1 (en) * | 2009-04-23 | 2010-10-28 | Chevron Phillips Chemical Company Lp | System and method for the production and use of lamination films |
| US20110172364A1 (en) * | 2009-12-29 | 2011-07-14 | Chen Yaohong | Charged Nanoparticles And Method Of Controlling Charge |
| US9115222B2 (en) * | 2009-12-29 | 2015-08-25 | Bridgestone Corporation | Well defined, highly crosslinked nanoparticles and method for making same |
| US9428604B1 (en) | 2011-12-30 | 2016-08-30 | Bridgestone Corporation | Nanoparticle fillers and methods of mixing into elastomers |
| EP2848650B2 (en) | 2012-05-08 | 2020-05-27 | Denka Company Limited | Block copolymer composition, and sheet |
| TWI458768B (zh) | 2012-12-28 | 2014-11-01 | Chi Mei Corp | 橡膠組成及其製造方法 |
| KR102641191B1 (ko) * | 2015-03-12 | 2024-02-26 | 이네오스 스티롤루션 그룹 게엠베하 | 튜빙 적용을 위한 스티렌-부타디엔 블록 공중합체 |
| US9598524B1 (en) | 2015-09-18 | 2017-03-21 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications |
| US9540475B2 (en) | 2015-03-12 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers for tubing applications |
| US9441090B1 (en) | 2015-03-12 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Methods for controlling hardness of styrene-butadiene block copolymers |
| US9738781B2 (en) | 2015-09-03 | 2017-08-22 | Ineos Styrolution Group Gmbh | Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications |
| US9828455B2 (en) | 2016-02-24 | 2017-11-28 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
| US10023676B2 (en) | 2016-02-24 | 2018-07-17 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
| KR102696384B1 (ko) * | 2021-07-23 | 2024-08-19 | 주식회사 원익홀딩스 | 자동용접장치 |
| KR102686412B1 (ko) * | 2021-07-23 | 2024-07-18 | 주식회사 원익홀딩스 | 자동용접방법 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4054616A (en) * | 1973-09-29 | 1977-10-18 | Sumitomo Chemical Company, Limited | Process for producing transparent block copolymer resins |
| US4208356A (en) * | 1974-09-17 | 1980-06-17 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing mixture of block copolymers |
| US4167545A (en) * | 1975-11-08 | 1979-09-11 | Basf Aktiengesellschaft | Branched block copolymers and their manufacture |
| US4248981A (en) * | 1979-04-30 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
| DE2940861A1 (de) * | 1979-10-09 | 1981-04-23 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von mischungen linearer dreiblockcopolymerisate sowie formteile aus diesen |
| US4390663A (en) * | 1981-02-17 | 1983-06-28 | Atlantic Richfield Company | Semi-continuous process for making star-block copolymers |
| US4584346A (en) * | 1984-02-29 | 1986-04-22 | Phillips Petroleum Company | Craze-resistant transparent resinous polymodal block copolymers |
| US4704434A (en) * | 1986-03-24 | 1987-11-03 | Phillips Petroleum Company | Craze-resistant polymodal linear block copolymers with terminal tapered blocks |
| US4704435A (en) * | 1986-03-24 | 1987-11-03 | Phillips Petroleum Company | Craze-resistant polymodal linear block copolymers with resinous terminal blocks |
| IT1196517B (it) * | 1986-07-17 | 1988-11-16 | Montedipe Spa | Copolimeri a blocco radiali e bimodali aventi ottime proprieta' ottiche e reistenza agli urti e processo per la loro preparazione |
| CA2028410C (en) * | 1990-01-02 | 1996-09-17 | William J. Trepka | Tapered block styrene/butadiene copolymers |
| US5227419A (en) * | 1990-12-20 | 1993-07-13 | Phillips Petroleum Company | Tapered block styrene/butadiene copolymers |
| US5256736A (en) * | 1991-05-08 | 1993-10-26 | Phillips Petroleum Company | Tapered block copolymers of conjugated dienes and monovinylarenes |
-
1992
- 1992-11-30 US US07/982,938 patent/US5290875A/en not_active Expired - Lifetime
-
1993
- 1993-08-30 CA CA002105157A patent/CA2105157C/en not_active Expired - Fee Related
- 1993-11-08 TW TW082109344A patent/TW268954B/zh active
- 1993-11-23 MX MX9307322A patent/MX9307322A/es not_active IP Right Cessation
- 1993-11-24 KR KR1019930025564A patent/KR100251074B1/ko not_active Expired - Fee Related
- 1993-11-25 JP JP5294810A patent/JP2935796B2/ja not_active Expired - Fee Related
- 1993-11-29 ES ES93119192T patent/ES2096186T3/es not_active Expired - Lifetime
- 1993-11-29 AT AT93119192T patent/ATE147412T1/de not_active IP Right Cessation
- 1993-11-29 DE DE69307284T patent/DE69307284T2/de not_active Expired - Fee Related
- 1993-11-29 EP EP93119192A patent/EP0600405B1/en not_active Expired - Lifetime
- 1993-12-06 US US08/163,785 patent/US5393838A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0600405A1 (en) | 1994-06-08 |
| JPH06206953A (ja) | 1994-07-26 |
| CA2105157A1 (en) | 1994-05-31 |
| US5393838A (en) | 1995-02-28 |
| ATE147412T1 (de) | 1997-01-15 |
| JP2935796B2 (ja) | 1999-08-16 |
| KR940011512A (ko) | 1994-06-21 |
| US5290875A (en) | 1994-03-01 |
| EP0600405B1 (en) | 1997-01-08 |
| ES2096186T3 (es) | 1997-03-01 |
| KR100251074B1 (ko) | 2000-04-15 |
| DE69307284T2 (de) | 1997-04-30 |
| TW268954B (es) | 1996-01-21 |
| DE69307284D1 (de) | 1997-02-20 |
| CA2105157C (en) | 1996-09-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration | ||
| MM | Annulment or lapse due to non-payment of fees |