MX9302180A - Proceso mejorado de hidroconversion empleando un catalizador con una distribucion especifica de medida de los poros. - Google Patents

Proceso mejorado de hidroconversion empleando un catalizador con una distribucion especifica de medida de los poros.

Info

Publication number
MX9302180A
MX9302180A MX9302180A MX9302180A MX9302180A MX 9302180 A MX9302180 A MX 9302180A MX 9302180 A MX9302180 A MX 9302180A MX 9302180 A MX9302180 A MX 9302180A MX 9302180 A MX9302180 A MX 9302180A
Authority
MX
Mexico
Prior art keywords
present
diameter
catalyst
micropores
less
Prior art date
Application number
MX9302180A
Other languages
English (en)
Inventor
Ray Earl Pratt
David Edward Sherwood
Pei Shing Eugene Dai
Gerald Verdell Nelson
Govanon Nongbri
Original Assignee
Texaco Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texaco Development Corp filed Critical Texaco Development Corp
Publication of MX9302180A publication Critical patent/MX9302180A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Los aceites pesados pueden someterse a hidrotratamiento en presencia de un soporte de alumina porosa, metales antifricción de los Grupos VIII y VI y VI-B y, optativamente, fósforo, con el catalizador teniendo: una extensión superficial total de 165 a 230 m2/g, un volumen total de los poros de 0.5 a 0.8 mm3/g, y una distribución del diámetro de los poros tal que menos de aproximadamente el 5 del volumen total de los poros esté presente en forma de microporos primarios de diámetro menor a 80A, y estando presentes microporos secundarios de - 20A, de entre un modo de poros de 100 a 135A, en cantidad de , cuando menos, el 65, aproximadamente, del volumen de microporos, comprendiendo poros con diámetro menor de 250A, y del 22 al 29 del volumen total de poros estando presente en forma de macroporos de diámetro mayor de 250A. El proceso del presente invento es particularmente efectivo en cuanto a alcanzar los niveles deseados de hidrodesmetalación , hidrosulfuración, hidrofisuración e hidrocraqueo, de asfaltenos de la fracción de productos residuales de petróleo hidrotratados/hidrofisurados, que tienen un punto de ebullición superior a 1000ºF (537.78ªC).
MX9302180A 1992-04-20 1993-04-15 Proceso mejorado de hidroconversion empleando un catalizador con una distribucion especifica de medida de los poros. MX9302180A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/870,970 US5399259A (en) 1992-04-20 1992-04-20 Hydroconversion process employing catalyst with specified pore size distribution

Publications (1)

Publication Number Publication Date
MX9302180A true MX9302180A (es) 1994-07-29

Family

ID=25356436

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9302180A MX9302180A (es) 1992-04-20 1993-04-15 Proceso mejorado de hidroconversion empleando un catalizador con una distribucion especifica de medida de los poros.

Country Status (8)

Country Link
US (2) US5399259A (es)
EP (1) EP0567272B1 (es)
JP (1) JP3439790B2 (es)
AT (1) ATE158339T1 (es)
CA (1) CA2093410C (es)
DE (1) DE69313912T2 (es)
MX (1) MX9302180A (es)
PL (1) PL172041B1 (es)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5868923A (en) * 1991-05-02 1999-02-09 Texaco Inc Hydroconversion process
US5827421A (en) * 1992-04-20 1998-10-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution and no added silica
US5928499A (en) * 1993-10-01 1999-07-27 Texaco Inc Hydroconversion process employing catalyst with specified pore size distribution, median pore diameter by surface area, and pore mode by volume
US5968348A (en) * 1994-05-16 1999-10-19 Texaco Inc. Hydroconversion process employing a phosphorus loaded NiMo catalyst with specified pore size distribution
US5620592A (en) * 1994-07-29 1997-04-15 Chevron U.S.A. Inc. Low macropore resid conversion catalyst
JPH08224484A (ja) * 1994-11-03 1996-09-03 Shell Internatl Res Maatschappij Bv 触媒及び水素処理方法
PL328308A1 (en) * 1996-02-14 1999-01-18 Texaco Development Corp Low-pressure process for hydroconcentring heavy hydrocarbons
US6248924B1 (en) * 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
WO1998046353A1 (en) 1997-04-15 1998-10-22 Massachusetts Institute Of Technology Synthesis and application of vapor grafted porous materials
US6387248B2 (en) 1997-11-06 2002-05-14 Texaco Inc. Method of preparing a catalyst for use in the hydrotreating of high boiling hydrocarbon feedstocks
KR20010032469A (ko) * 1997-11-27 2001-04-25 도미나가 가즈토 알루미나 담체 루테늄 촉매
JP4865940B2 (ja) * 1999-09-29 2012-02-01 一般財団法人石油エネルギー技術センター 水素化処理触媒及び該触媒を用いた重質炭化水素油の水素化処理方法
JP2003171671A (ja) * 2000-06-08 2003-06-20 Japan Energy Corp 重質油の水素化精製方法
JP4567877B2 (ja) * 2000-12-15 2010-10-20 Ｊｘ日鉱日石エネルギー株式会社 重質油の水素化処理触媒及び重油基材の製造方法
JP4638610B2 (ja) * 2001-01-05 2011-02-23 日本ケッチェン株式会社 水素化処理用触媒並びに水素化処理方法
JP4612229B2 (ja) * 2001-06-08 2011-01-12 日本ケッチェン株式会社 重質炭化水素油の水素化処理用触媒並びに水素化処理方法
JP4773634B2 (ja) * 2001-06-08 2011-09-14 日本ケッチェン株式会社 重質炭化水素油の２段階水素化処理方法
JP4773633B2 (ja) * 2001-06-08 2011-09-14 日本ケッチェン株式会社 重質炭化水素油の２段階水素化処理方法
US7745369B2 (en) 2003-12-19 2010-06-29 Shell Oil Company Method and catalyst for producing a crude product with minimal hydrogen uptake
US20100098602A1 (en) 2003-12-19 2010-04-22 Opinder Kishan Bhan Systems, methods, and catalysts for producing a crude product
US20050167328A1 (en) 2003-12-19 2005-08-04 Bhan Opinder K. Systems, methods, and catalysts for producing a crude product
BRPI0405572A (pt) * 2003-12-19 2005-08-30 Shell Int Research Métodos de produzir um produto de petróleo bruto e combustìvel de transporte, combustìvel de aquecimento, lubrificantes ou substâncias quìmicas, e, produtos de petróleo bruto
CN100335165C (zh) * 2004-12-21 2007-09-05 中国科学院山西煤炭化学研究所 一种加氢催化剂及其制备工艺和应用
CN101166811A (zh) 2005-04-11 2008-04-23 国际壳牌研究有限公司 生产具有降低氮含量的原油产品的方法和催化剂
EP1874897A1 (en) 2005-04-11 2008-01-09 Shell Internationale Research Maatschappij B.V. Method and catalyst for producing a crude product having a reduced mcr content
US20080085225A1 (en) 2006-10-06 2008-04-10 Bhan Opinder K Systems for treating a hydrocarbon feed
FR2917647B1 (fr) * 2007-06-25 2011-05-06 Inst Francais Du Petrole Procede de preparation de catalyseur d'hydrotraitement par impregnation d'un compose phosphore
WO2011087467A1 (en) * 2008-10-27 2011-07-21 Wen-Qing Xu Nickel-based reforming catalyst
EA020295B1 (ru) 2009-04-21 2014-10-30 Альбемарл Юроп Спрл Катализатор гидроочистки, содержащий фосфор и бор
KR101911123B1 (ko) 2011-09-01 2018-10-23 어드벤스드 리파이닝 테크놀로지즈 엘엘씨 촉매 지지체 및 이로부터 제조된 촉매
TWI594795B (zh) 2012-05-21 2017-08-11 蜆殼國際研究所 用於重質進料之氫轉化之經改良觸媒及方法

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JPS50123588A (es) * 1974-02-07 1975-09-29
US4278566A (en) * 1979-03-19 1981-07-14 Standard Oil Company (Indiana) Hydrotreating process
US4255282A (en) * 1979-05-11 1981-03-10 Union Oil Company Of California Hydrotreating catalyst and process for its preparation
FR2486094B1 (es) * 1980-07-02 1985-03-22 Catalyse Soc Prod Francais
US4317746A (en) * 1980-11-28 1982-03-02 Union Oil Company Of California Hydrotreating catalysts
JPS594440A (ja) * 1982-06-29 1984-01-11 Shokubai Kasei Kogyo Kk 水素化精製触媒の製造法
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EP0235411A1 (en) * 1986-02-24 1987-09-09 Union Oil Company Of California Hydroprocessing with a large pore catalyst
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Also Published As

Publication number Publication date
EP0567272B1 (en) 1997-09-17
CA2093410C (en) 2002-09-03
JP3439790B2 (ja) 2003-08-25
EP0567272A1 (en) 1993-10-27
US5416054A (en) 1995-05-16
PL298636A1 (en) 1994-02-21
ATE158339T1 (de) 1997-10-15
JPH0688081A (ja) 1994-03-29
DE69313912T2 (de) 1998-01-22
DE69313912D1 (de) 1997-10-23
PL172041B1 (pl) 1997-07-31
CA2093410A1 (en) 1993-10-21
US5399259A (en) 1995-03-21

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