MX387545B - Control de malezas con herbicida proveniente de combinaciones de fluroxipir e inhibidores de acetolactato sintetasa (als). - Google Patents

Control de malezas con herbicida proveniente de combinaciones de fluroxipir e inhibidores de acetolactato sintetasa (als).

Info

Publication number
MX387545B
MX387545B MX2016015864A MX2016015864A MX387545B MX 387545 B MX387545 B MX 387545B MX 2016015864 A MX2016015864 A MX 2016015864A MX 2016015864 A MX2016015864 A MX 2016015864A MX 387545 B MX387545 B MX 387545B
Authority
MX
Mexico
Prior art keywords
als
crop
fluroxypyr
weed control
herbicide
Prior art date
Application number
MX2016015864A
Other languages
English (en)
Other versions
MX2016015864A (es
Inventor
Christopher J Voglewede
David G Ouse
James M Gifford
Richard K Mann
Ändrea C Mcveigh-Nelson
Original Assignee
Corteva Agriscience Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corteva Agriscience Llc filed Critical Corteva Agriscience Llc
Publication of MX2016015864A publication Critical patent/MX2016015864A/es
Publication of MX387545B publication Critical patent/MX387545B/es

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/12—Powders or granules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • A01N25/28—Microcapsules or nanocapsules
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

En la presente solicitud se proveen composiciones herbicidas que contienen (a) fluroxipir o un éster o sal del mismo aceptable desde el punto de vista agrícola y (b) un herbicida inhibidor de acetolactato sintetasa (ALS), en las cuales el herbicida inhibidor de ALS es diclosulam, cloransulam, clorimuron, o tifensulfurón, o un éster o sal de los mismos aceptable desde el punto de vista agrícola. Las composiciones proveen control de maleza sinergístico de vegetación indeseable en áreas que incluyen, pero no se limitan a, soya, algodón, maíz, sorgo, girasol, caña de azúcar, remolacha azucarera, alfalfa, cereales (incluyendo pero sin limitarse a trigo, cebada, arroz y avena), áreas no cultivadas, de barbecho, de cultivos de perenes, cultivos de frutales o cultivos de plantación.
MX2016015864A 2014-06-09 2015-06-09 Control de malezas con herbicida proveniente de combinaciones de fluroxipir e inhibidores de acetolactato sintetasa (als). MX387545B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462009717P 2014-06-09 2014-06-09
PCT/US2015/034893 WO2015191573A1 (en) 2014-06-09 2015-06-09 Herbicidal weed control from combinations of fluroxypyr and als inhibitors

Publications (2)

Publication Number Publication Date
MX2016015864A MX2016015864A (es) 2017-04-05
MX387545B true MX387545B (es) 2025-03-18

Family

ID=53434505

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2016015864A MX387545B (es) 2014-06-09 2015-06-09 Control de malezas con herbicida proveniente de combinaciones de fluroxipir e inhibidores de acetolactato sintetasa (als).
MX2021009645A MX2021009645A (es) 2014-06-09 2016-12-01 Control de malezas con herbicida proveniente de combinaciones de fluroxipir e inhibidores de acetolactato sintetasa (als).

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2021009645A MX2021009645A (es) 2014-06-09 2016-12-01 Control de malezas con herbicida proveniente de combinaciones de fluroxipir e inhibidores de acetolactato sintetasa (als).

Country Status (24)

Country Link
US (2) US9737073B2 (es)
EP (2) EP3151668B1 (es)
JP (1) JP2017521383A (es)
KR (1) KR20170015336A (es)
CN (2) CN110622974B (es)
AP (1) AP2016009644A0 (es)
AR (1) AR100785A1 (es)
AU (2) AU2015274816B2 (es)
BR (2) BR102015013454B8 (es)
DK (1) DK3508062T3 (es)
ES (1) ES2968878T3 (es)
HR (1) HRP20240114T1 (es)
HU (1) HUE064918T2 (es)
IL (1) IL249350B (es)
LT (1) LT3508062T (es)
MX (2) MX387545B (es)
PL (1) PL3508062T3 (es)
PY (1) PY1525026A (es)
RS (1) RS65071B1 (es)
RU (1) RU2016149889A (es)
UA (1) UA121390C2 (es)
UY (1) UY36159A (es)
WO (1) WO2015191573A1 (es)
ZA (1) ZA201608738B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11589583B2 (en) 2013-12-03 2023-02-28 Fmc Corporation Pyrrolidinones herbicides
CN113402394B (zh) 2015-05-12 2024-04-26 Fmc公司 作为除草剂的芳基取代的双环化合物
CA2983590C (en) 2015-05-29 2021-11-30 E I Du Pont De Nemours And Company Substituted cyclic amides as herbicides
WO2016196593A1 (en) 2015-06-02 2016-12-08 E I Du Pont De Nemours And Company Substituted cyclic amides and their use as herbicides
WO2018118384A1 (en) 2016-12-21 2018-06-28 Fmc Corporation Nitrone herbicides
SG11201908640TA (en) 2017-03-21 2019-10-30 Fmc Corp Pyrrolidinones and a process to prepare them
JP7548697B2 (ja) 2017-03-21 2024-09-10 エフ エム シー コーポレーション 除草剤混合物、組成物、及び方法
AR111967A1 (es) 2017-05-30 2019-09-04 Fmc Corp Amidas herbicidas
AR111839A1 (es) 2017-05-30 2019-08-21 Fmc Corp Lactamas 3-sustituidas herbicidas
CN107810970A (zh) * 2017-12-28 2018-03-20 广东美景园林建设有限公司 一种应用于禾本科草坪的除草剂
BR112021012577B1 (pt) * 2018-12-27 2024-01-30 Qingdao Kingagroot Chemical Compound Co., Ltd Derivados de piridilóxi tioéster, método de preparação do derivado de piridilóxi tio éster, composição herbicida, método para controlar uma erva daninha e uso de pelo menos um dos derivados de piridilóxi tioéster
WO2020133092A1 (zh) * 2018-12-27 2020-07-02 青岛清原化合物有限公司 吡啶氧基羧酸酯衍生物及其制备方法、除草组合物和应用
MX2022000846A (es) * 2019-07-27 2022-02-10 Qingdao Kingagroot Chemical Compound Co Ltd Composicion herbicida que comprende acido r-piridiloxicarboxilico y derivado y una aplicacion de los mismos.
WO2021036251A1 (zh) * 2019-08-27 2021-03-04 青岛清原化合物有限公司 一种包含r型吡啶氧基羧酸衍生物的除草组合物及其应用
WO2023031846A1 (en) * 2021-09-02 2023-03-09 Parijat Industries (India) Pvt. Ltd. Herbicidal composition for crop management and method thereof
CN116172055B (zh) * 2022-12-05 2025-03-18 华中农业大学 一种防腐保鲜剂在柑橘留树和贮藏保鲜中的应用

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2018274T5 (es) 1986-03-11 1996-12-16 Plant Genetic Systems Nv Celulas vegetales resistentes a los inhibidores de glutamina sintetasa, preparadas por ingenieria genetica.
DE3629890A1 (de) 1986-08-29 1988-03-10 Schering Ag Mikroorganismen und plasmide fuer die 2,4-dichlorphenoxyessigsaeure (2,4-d)-monooxigenase - bildung und verfahren zur herstellung dieser plasmide und staemme
ATE213774T1 (de) 1990-06-25 2002-03-15 Monsanto Technology Llc Glyphosattolerante pflanzen
US5633435A (en) 1990-08-31 1997-05-27 Monsanto Company Glyphosate-tolerant 5-enolpyruvylshikimate-3-phosphate synthases
US5236887B1 (en) * 1991-05-03 1996-04-16 Dowelanco Herbicidal heterocyclic sulfonylurea compositions safened by herbicidal acids such as 2,4-d below a ph of 5
US5587903A (en) 1994-06-22 1996-12-24 Yale; Thomas W. Artificial intelligence language program
DE19520839A1 (de) * 1995-06-08 1996-12-12 Hoechst Schering Agrevo Gmbh Herbizide Mittel mit 4-Iodo-2-[3- (4-methoxy-6-methyl-1,3,5-triazin-2-yl) ureidosulfonyl] -benzoesäureestern
FR2736926B1 (fr) 1995-07-19 1997-08-22 Rhone Poulenc Agrochimie 5-enol pyruvylshikimate-3-phosphate synthase mutee, gene codant pour cette proteine et plantes transformees contenant ce gene
CN100429311C (zh) 2003-08-08 2008-10-29 四川禾本生物工程有限公司 高抗草苷膦的epsp合成酶及其编码序列
US7405074B2 (en) 2004-04-29 2008-07-29 Pioneer Hi-Bred International, Inc. Glyphosate-N-acetyltransferase (GAT) genes
PT2319932E (pt) 2004-04-30 2013-11-27 Dow Agrosciences Llc Novo gene de resistência a herbicida
CN1303881C (zh) * 2004-09-17 2007-03-14 王洲 一种小麦田除草剂
JP4879969B2 (ja) 2005-04-08 2012-02-22 アセニクス コーポレイション 新規なクラスのｅｐｓｐシンターゼの同定
EP1947926B1 (en) 2005-10-28 2014-11-26 Dow AgroSciences LLC Novel herbicide resistance genes
AU2007323316B2 (en) * 2006-11-23 2012-12-06 Fmc Corporation Novel agrochemical formulations containing microcapsules
JP5563825B2 (ja) 2006-12-07 2014-07-30 ダウ アグロサイエンシズ リミテッド ライアビリティー カンパニー 選択マーカー遺伝子
CN101688219B (zh) 2007-05-09 2017-06-30 美国陶氏益农公司 新除草剂抗性基因
WO2009152827A2 (en) * 2008-05-28 2009-12-23 Gat Microencapsulation, Ag Suspension concentrates in oil of sulfonylureas and combinations with fluroxypyr or other agrochemicals
CN101530105A (zh) * 2009-04-21 2009-09-16 北京颖泰嘉和科技股份有限公司 一种含有磺酰脲、吡啶类、五氟磺草胺的除草剂组合物及其应用
BR112012009908B8 (pt) * 2009-10-28 2022-10-11 Dow Agrosciences Llc Mistura herbicida sinérgica, composição herbicida, e métodos para controlar vegetação indesejável, e para proteger grama centípede e girassol contra os efeitos nocivos individuais de penoxsulam e fluroxipir
EP3028570B1 (en) * 2009-10-28 2018-08-08 Dow AgroSciences LLC Synergistic herbicidal composition containing fluroxypyr and metamifop
CN101911947A (zh) * 2010-06-28 2010-12-15 陕西上格之路生物科学有限公司 一种小麦田除草剂组合物
GB2483050B (en) * 2010-08-17 2012-12-19 Rotam Agrochem Int Co Ltd Herbicidal compositions
EP2615912A4 (en) * 2010-09-17 2015-04-01 Dow Agrosciences Llc LIQUID AGRICULTURAL FORMULATIONS OF IMPROVED STABILITY
UA105451C2 (uk) * 2010-10-27 2014-05-12 ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи Синергічна гербіцидна композиція, яка містить флуроксипір і квінклорак
US9247735B2 (en) * 2011-01-19 2016-02-02 Rotam Agrochem International Company Limited Crop plant-compatible herbicidal compositions containing herbicides and safeners
MX343558B (es) * 2011-12-06 2016-11-10 Dow Agrosciences Llc Composición herbicida que contiene ácido de 4-amino-3-cloro-6-(4-c loro-2-flúor-3-metoxifenil) piridina-2-carboxílico, o los derivados del mismo y fluroxipir, o los derivados del mismo.
BR112014014884A2 (pt) * 2011-12-20 2017-06-13 Dow Agrosciences Llc composição herbicida contendo fluroxipir e glifosato
ES2716481T3 (es) 2012-02-01 2019-06-12 Dow Agrosciences Llc Plantas resistentes al glifosato y métodos asociados
CN102726400A (zh) * 2012-07-18 2012-10-17 安徽丰乐农化有限责任公司 一种小麦苗后复配除草剂
US8912120B2 (en) * 2012-07-24 2014-12-16 Dow Agrosciences, Llc. Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and synthetic auxin herbicides
WO2014052795A1 (en) * 2012-09-28 2014-04-03 Dow Agrosciences Llc Synergistic weed control from applications of aminocyclopyrachlor and fluroxypyr
CN103060279B (zh) 2012-12-25 2014-08-13 北京大北农科技集团股份有限公司 除草剂抗性蛋白质、其编码基因及用途
WO2015094885A1 (en) * 2013-12-20 2015-06-25 Dow Agrosciences Llc Herbicidal compositions containing flumioxazin, aminopyralid and fluroxypyr or 2,4-d

Also Published As

Publication number Publication date
IL249350A0 (en) 2017-02-28
MX2016015864A (es) 2017-04-05
RS65071B1 (sr) 2024-02-29
CN106455564B (zh) 2020-03-03
EP3508062B1 (en) 2023-10-25
ES2968878T3 (es) 2024-05-14
AP2016009644A0 (en) 2016-12-31
WO2015191573A1 (en) 2015-12-17
KR20170015336A (ko) 2017-02-08
CN110622974A (zh) 2019-12-31
EP3151668A1 (en) 2017-04-12
MX2021009645A (es) 2021-09-08
PL3508062T3 (pl) 2024-04-02
BR122021022279B1 (pt) 2023-03-28
EP3151668B1 (en) 2020-11-11
AU2017232060B2 (en) 2019-10-10
HRP20240114T1 (hr) 2024-04-12
DK3508062T3 (da) 2024-01-22
BR102015013454A2 (pt) 2021-07-20
BR102015013454B1 (pt) 2022-02-01
BR102015013454B8 (pt) 2022-11-29
US20150351395A1 (en) 2015-12-10
CN106455564A (zh) 2017-02-22
JP2017521383A (ja) 2017-08-03
PY1525026A (es) 2018-01-01
AU2017232060A1 (en) 2017-10-12
RU2016149889A (ru) 2018-07-18
LT3508062T (lt) 2024-02-12
RU2019107580A (ru) 2019-04-04
UY36159A (es) 2016-01-08
AU2015274816A1 (en) 2016-12-15
IL249350B (en) 2019-11-28
UA121390C2 (uk) 2020-05-25
HUE064918T2 (hu) 2024-04-28
US9737073B2 (en) 2017-08-22
CN110622974B (zh) 2021-11-19
AU2015274816B2 (en) 2017-10-26
EP3508062A1 (en) 2019-07-10
AR100785A1 (es) 2016-11-02
US20170347649A1 (en) 2017-12-07
RU2016149889A3 (es) 2019-01-10
ZA201608738B (en) 2018-05-30

Similar Documents

Publication Publication Date Title
MX387545B (es) Control de malezas con herbicida proveniente de combinaciones de fluroxipir e inhibidores de acetolactato sintetasa (als).
IN2015DN01381A (es)
CO7200279A2 (es) Composiciones herbicidas que comprenden ácido 4–amino–3–cloro–5–fluoro–6–(4–cloro–2–fluoro–3–metoxifenil)piridina–2–carboxílico o un derivado del mismo e inhibidores de acetil–coa carboxilasa (accasa)
NZ704889A (en) Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid
IN2015DN01374A (es)
SA113340750B1 (ar) تركيبة مبيد أعشاب تشتمل على4-أمينو-3-كلورو-5-فلورو-6-(4-كلورو-2-فلورو-3-ميثوكسي فينيل) بيريدين-2- حمض كربوكسيلي أو مشتقات منه و بروموبيوتيد، دايمورون، أوكسازيكالمويفون، أو بيربيوتيكارب
IN2014DN05694A (es)
AR082786A1 (es) Composicion herbicida sinergistica que contiene penoxsulam y bentazon
MX377775B (es) Composiciones herbicidas que contienen aminopiralid y triclopir.
MX2015009608A (es) Composiciones herbicidas que comprenden acido 4-amino-3-cloro-6-(4-cloro-2-fluoro-3-metoxifenil) piridin-2-carboxilico o uno de sus derivados y picloram o uno de sus derivados.
PH12015502145A1 (en) Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and fungicides
CO2018002567A2 (es) Composiciones herbicidas que contienen ácido 4–amino–3–cloro–6–(4–cloro–2–fluoro–3–metoxifenil)piridin–2–carboxílico o uno de sus derivados, un herbicida de triazolopirimidinsulfonamida o uno de sus derivados, y glifosato o uno de sus derivados
PH12017501092A1 (en) Synergistic herbicidal composition containing penoxsulam, triclopyr and bispyribac
PY1361140A (es) Composiciones herbicidas que comprenden fluroxypyr y flumetsulam
PH12017501093A1 (en) Synergistic herbicidal composition containing penoxsulam, triclopyr and bispyribac
PH12015500503A1 (en) Herbicidal compositions comprising aminopyralid and bentazon
CO6690817A2 (es) Composición herbicida sinergica de fluroxipir y quinclorac
CR20150166A (es) Composiciones herbicidas que comprenden aminopiralid y propanil
TH1601007263A (th) การควบคุมวัชพืชด้วยสารที่มีฤทธิ์ฆ่าวัชพืชจากการผสมผสานกันของฟลูออกซิไพร์และตัวยับยั้ง als