MX385680B - Polibutadienos de dos bloques estereoregulares que tienen una estructura 1,4-cis/1,2 sindiotactica de polimerizacion estereoespecifica. - Google Patents
Polibutadienos de dos bloques estereoregulares que tienen una estructura 1,4-cis/1,2 sindiotactica de polimerizacion estereoespecifica.Info
- Publication number
- MX385680B MX385680B MX2016005602A MX2016005602A MX385680B MX 385680 B MX385680 B MX 385680B MX 2016005602 A MX2016005602 A MX 2016005602A MX 2016005602 A MX2016005602 A MX 2016005602A MX 385680 B MX385680 B MX 385680B
- Authority
- MX
- Mexico
- Prior art keywords
- stereoregular
- block
- cis
- syndiotactic
- polybutadienes
- Prior art date
Links
- 229920002857 polybutadiene Polymers 0.000 title abstract 5
- 238000012721 stereospecific polymerization Methods 0.000 title 1
- 239000005062 Polybutadiene Substances 0.000 abstract 4
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F295/00—Macromolecular compounds obtained by polymerisation using successively different catalyst types without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
- C08F4/6028—Component covered by group C08F4/60 with an organo-aluminium compound with an alumoxane, i.e. a compound containing an -Al-O-Al-group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7004—Neutral ligand
- C08F4/7006—NN
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7004—Neutral ligand
- C08F4/7008—NO
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7039—Tridentate ligand
- C08F4/704—Neutral ligand
- C08F4/7042—NNN
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7039—Tridentate ligand
- C08F4/704—Neutral ligand
- C08F4/7044—NNO
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI20131830 ITMI20131830A1 (it) | 2013-11-05 | 2013-11-05 | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
| PCT/IB2014/065768 WO2015068095A1 (en) | 2013-11-05 | 2014-11-03 | Stereoregular diblock polybutadienes having a 1,4-cis/syndiotactic 1,2 structure from stereospecific polymerization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2016005602A MX2016005602A (es) | 2016-12-09 |
| MX385680B true MX385680B (es) | 2025-03-18 |
Family
ID=49683905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016005602A MX385680B (es) | 2013-11-05 | 2014-11-03 | Polibutadienos de dos bloques estereoregulares que tienen una estructura 1,4-cis/1,2 sindiotactica de polimerizacion estereoespecifica. |
Country Status (18)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20131828A1 (it) * | 2013-11-05 | 2015-05-06 | Versalis Spa | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
| PL3428200T3 (pl) * | 2016-03-11 | 2022-07-18 | Jsr Corporation | Katalizator polimeryzacji, kopolimer, kompozycja polimerowa i usieciowany polimer |
| IT201600105530A1 (it) * | 2016-10-20 | 2018-04-20 | Versalis Spa | Procedimento per la preparazione di polibutadiene 1,2 sindiotattico in presenza di un sistema catalitico comprendente un complesso piridilico di ferro |
| IT201700006307A1 (it) * | 2017-01-20 | 2018-07-20 | Versalis Spa | Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati |
| IT201700059763A1 (it) | 2017-05-31 | 2018-12-01 | Versalis Spa | Copolimeri butadiene-isoprene di-blocco e procedimento per la loro preparazione |
| EP4148072B1 (en) * | 2020-05-21 | 2026-06-03 | China Petroleum & Chemical Corporation | Liquid polybutadiene, and preparation method therefor and application thereof, composition, polymer coating, adhesive, and crosslinking agent |
| IT202000028823A1 (it) | 2020-11-27 | 2022-05-27 | Consiglio Nazionale Ricerche | Copolimeri dienici a stereoblocchi e relativo processo di preparazione. |
| CN115246913B (zh) * | 2021-04-27 | 2023-10-10 | 中国石油化工股份有限公司 | 一种立构嵌段聚异戊二烯及其制备方法 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3498963A (en) | 1966-09-26 | 1970-03-03 | Japan Synthetic Rubber Co Ltd | Process for the catalytic preparation of 1,2-polybutadiene having a high percentage of vinyl configuration |
| US3522332A (en) | 1967-06-02 | 1970-07-28 | Japan Synthetic Rubber Co Ltd | Process for the preparation of 1,2-polybutadiene |
| JPS4917666B1 (cg-RX-API-DMAC10.html) * | 1970-12-25 | 1974-05-02 | ||
| JPS4917667B1 (cg-RX-API-DMAC10.html) * | 1970-12-25 | 1974-05-02 | ||
| US3817968A (en) | 1972-11-28 | 1974-06-18 | Bridgestone Tire Co Ltd | Method of producing equibinary (cis 1.4-1.2) polybutadiene |
| DE2447203C3 (de) | 1974-10-03 | 1982-03-18 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polybutadien |
| JPS53143685A (en) | 1977-05-23 | 1978-12-14 | Japan Synthetic Rubber Co Ltd | Preparation of 1,2-polybutadiene |
| US4255296A (en) | 1977-12-02 | 1981-03-10 | Bridgestone Tire Company Limited | Polybutadiene rubber composition |
| DE2911262A1 (de) | 1979-03-22 | 1980-10-02 | Bayer Ag | Katalysator, dessen herstellung und verfahren zur polymerisation von butadien |
| DE3000708A1 (de) | 1980-01-10 | 1981-07-16 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur herstellung von reaktionsprodukten aus konjugierten diolefinen und aromatischen kohlenwasserstoffen |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| IT1231774B (it) | 1989-08-03 | 1991-12-21 | Enichem Anic Spa | Catalizzatore e procedimento per la polimerizzazione e per la copolimerizzazione di alfa olefine. |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| CA2024830A1 (en) | 1989-09-29 | 1991-03-30 | Richard E. Campbell, Jr. | Process for preparation of syndiotactic vinyl aromatic polymers |
| DE69026907T2 (de) | 1989-10-10 | 1996-10-10 | Fina Technology | Metallocenkatalysator mit Lewissäure und Alkylaluminium |
| EP0672689A1 (en) | 1990-06-22 | 1995-09-20 | Exxon Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| CA2090962A1 (en) | 1990-09-14 | 1992-03-15 | Howard W. Turner | Ionic catalyst for the production of poly-.alpha.-olefins of controlled tacticity |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| JP3463811B2 (ja) | 1991-04-24 | 2003-11-05 | Ｊｓｒ株式会社 | ブタジエン系重合体の製造方法 |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5258475A (en) | 1991-07-12 | 1993-11-02 | Mobil Oil Corporation | Catalyst systems for polymerization and copolymerization of olefins |
| US5879805A (en) | 1997-09-09 | 1999-03-09 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization of vinylpolybutadiene |
| US6271313B1 (en) | 1998-12-21 | 2001-08-07 | The Goodyear Tire & Rubber Company | Styrene-butadiene block copolymer |
| ITMI20011813A1 (it) | 2001-08-24 | 2003-02-24 | Enichem Spa | Complessi di cobalto utili nella polimerizzazione del 1,3-butadiene |
| CN1305913C (zh) | 2002-07-22 | 2007-03-21 | Jsr株式会社 | 结晶性1,2－聚丁二烯的制造方法 |
| US7868103B2 (en) | 2006-05-22 | 2011-01-11 | Ube Industries, Ltd. | Method for producing polybutadiene |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| ITMI20122201A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
| ITMI20122199A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto |
| ITMI20122203A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto |
| ITMI20122206A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-immino-piridinico di cobalto |
| ITMI20131828A1 (it) | 2013-11-05 | 2015-05-06 | Versalis Spa | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
-
2013
- 2013-11-05 IT ITMI20131830 patent/ITMI20131830A1/it unknown
-
2014
- 2014-10-30 TW TW103137597A patent/TWI653250B/zh active
- 2014-11-03 HU HUE14812613A patent/HUE057995T2/hu unknown
- 2014-11-03 SG SG11201603256RA patent/SG11201603256RA/en unknown
- 2014-11-03 WO PCT/IB2014/065768 patent/WO2015068095A1/en not_active Ceased
- 2014-11-03 LT LTEPPCT/IB2014/065768T patent/LT3066140T/lt unknown
- 2014-11-03 KR KR1020167015093A patent/KR102209232B1/ko active Active
- 2014-11-03 CA CA2925377A patent/CA2925377C/en active Active
- 2014-11-03 MX MX2016005602A patent/MX385680B/es unknown
- 2014-11-03 EP EP14812613.9A patent/EP3066140B1/en active Active
- 2014-11-03 CN CN201480059603.7A patent/CN105683231B/zh active Active
- 2014-11-03 ES ES14812613T patent/ES2903392T3/es active Active
- 2014-11-03 EA EA201690624A patent/EA031605B1/ru not_active IP Right Cessation
- 2014-11-03 PL PL14812613T patent/PL3066140T3/pl unknown
- 2014-11-03 MY MYPI2016000784A patent/MY172668A/en unknown
- 2014-11-03 JP JP2016551097A patent/JP6526032B2/ja not_active Expired - Fee Related
- 2014-11-03 BR BR112016009334-8A patent/BR112016009334B1/pt active IP Right Grant
- 2014-11-03 US US15/032,207 patent/US10066044B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| TW201522394A (zh) | 2015-06-16 |
| US10066044B2 (en) | 2018-09-04 |
| EA201690624A1 (ru) | 2016-12-30 |
| JP6526032B2 (ja) | 2019-06-05 |
| CA2925377A1 (en) | 2015-05-14 |
| BR112016009334B1 (pt) | 2022-02-01 |
| PL3066140T3 (pl) | 2022-02-28 |
| HK1223387A1 (zh) | 2017-07-28 |
| CN105683231B (zh) | 2019-06-07 |
| KR102209232B1 (ko) | 2021-01-29 |
| HUE057995T2 (hu) | 2022-06-28 |
| WO2015068095A1 (en) | 2015-05-14 |
| EA031605B1 (ru) | 2019-01-31 |
| CN105683231A (zh) | 2016-06-15 |
| TWI653250B (zh) | 2019-03-11 |
| BR112016009334A2 (cg-RX-API-DMAC10.html) | 2017-08-01 |
| ES2903392T3 (es) | 2022-04-01 |
| SG11201603256RA (en) | 2016-05-30 |
| KR20160084855A (ko) | 2016-07-14 |
| ITMI20131830A1 (it) | 2015-05-06 |
| MX2016005602A (es) | 2016-12-09 |
| LT3066140T (lt) | 2022-04-11 |
| JP2016536448A (ja) | 2016-11-24 |
| CA2925377C (en) | 2021-10-26 |
| EP3066140A1 (en) | 2016-09-14 |
| EP3066140B1 (en) | 2021-12-29 |
| US20160264706A1 (en) | 2016-09-15 |
| MY172668A (en) | 2019-12-09 |
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