MX376956B - Catalizador para la oxicloracion de etileno a 1,2-dicloroetano. - Google Patents

Catalizador para la oxicloracion de etileno a 1,2-dicloroetano.

Info

Publication number
MX376956B
MX376956B MX2015005670A MX2015005670A MX376956B MX 376956 B MX376956 B MX 376956B MX 2015005670 A MX2015005670 A MX 2015005670A MX 2015005670 A MX2015005670 A MX 2015005670A MX 376956 B MX376956 B MX 376956B
Authority
MX
Mexico
Prior art keywords
oxychlorination
moles
catalyst
dichloroethane
ethylene
Prior art date
Application number
MX2015005670A
Other languages
English (en)
Other versions
MX2015005670A (es
Inventor
Keith Kramer
Rolf Tompers
Original Assignee
Basf Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Corp filed Critical Basf Corp
Priority claimed from PCT/US2013/068705 external-priority patent/WO2014071423A1/en
Publication of MX2015005670A publication Critical patent/MX2015005670A/es
Publication of MX376956B publication Critical patent/MX376956B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/122—Halides of copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00—Acyclic saturated compounds containing halogen atoms
    • C07C19/01—Acyclic saturated compounds containing halogen atoms containing chlorine
    • C07C19/043—Chloroethanes
    • C07C19/045—Dichloroethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Esta invención se refiere a un catalizador que contiene de aproximadamente 2 a aproximadamente 8% en peso de cobre, de cero a aproximadamente 0.6 moles/kg de uno o más metales alcalinos, de aproximadamente 0.08 a aproximadamente 0.85 moles/kg de uno o más metales alcalinotérreos y de aproximadamente 0.09 a aproximadamente 0.9 moles/kg de uno más metales de transición seleccionados del grupo que consiste de Mn, Re y mezclas de los mismos, en donde todos los metales se impregnan en forma de sus cloruros u otras sales solubles en agua sobre un soporte fluidizable con un área superficial BET de aproximadamente 80 a alrededor de 220 m2/g. un proceso para la oxicloración de etileno para formar 1,2-dicloroetano que usa dicho catalizador que tiene buena actividad, buena selectividad y baja tendencia a adherirse en reacciones de oxicloración de lecho fluidizado.
MX2015005670A 2012-11-06 2013-11-06 Catalizador para la oxicloracion de etileno a 1,2-dicloroetano. MX376956B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201261723009P 2012-11-06 2012-11-06
US14/072,057 US9248434B2 (en) 2012-11-06 2013-11-05 Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane
PCT/US2013/068705 WO2014071423A1 (en) 2012-11-05 2013-11-06 Catalyst for the oxychlorination of ethylene to 1, 2-dichloroethane

Publications (2)

Publication Number Publication Date
MX2015005670A MX2015005670A (es) 2016-02-05
MX376956B true MX376956B (es) 2025-03-07

Family

ID=50622947

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015005670A MX376956B (es) 2012-11-06 2013-11-06 Catalizador para la oxicloracion de etileno a 1,2-dicloroetano.

Country Status (9)

Country Link
US (2) US9248434B2 (es)
JP (1) JP6427494B2 (es)
KR (1) KR102162685B1 (es)
CN (1) CN104918699B (es)
BR (1) BR112015005088B1 (es)
CA (1) CA2890210C (es)
MX (1) MX376956B (es)
SA (1) SA515360394B1 (es)
UA (1) UA116788C2 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102183954B1 (ko) * 2013-03-15 2020-11-30 옥시 비닐스, 엘.피. 에틸렌의 디클로로에탄으로의 옥시염소화를 위한 촉매 및 방법
BR112016028625B1 (pt) * 2014-06-23 2022-05-03 Oxy Vinyls, Lp Catalisador e processo para a oxicloração de etileno para dicloroetano
CN111565838B (zh) * 2018-02-23 2023-09-26 株式会社Lg化学 用于烃的氧氯化工艺的催化剂、其制备方法和使用该催化剂制备烃的氧氯化化合物的方法
CN118748989A (zh) 2022-01-19 2024-10-08 氧乙烯有限合伙公司 氧氯化工艺

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DD90127A (es)
CA925103A (en) 1968-05-20 1973-04-24 Denki Kagaku Kogyo Kabushiki Kaisha Method for producing chloroprene
DE2949530A1 (de) * 1979-12-08 1981-06-11 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von 1,2-dichlorethan
US4460699A (en) 1982-08-04 1984-07-17 Conoco Inc. Fixed bed catalyst for oxychlorination
DE3608043A1 (de) * 1986-03-11 1987-09-17 Wacker Chemie Gmbh Verbessertes verfahren zur herstellung von 1,2-dichlorethan durch gasphasenchlorierung von ethylenhaltigen gasen
GB8829706D0 (en) * 1988-12-20 1989-02-15 Ici Plc Oxychlorination catalyst composition
US5292703A (en) 1992-07-28 1994-03-08 The Geon Company Catalyst and process for oxychlorination of ethylene to EDC
RU2148432C1 (ru) 1999-04-23 2000-05-10 Акционерное общество открытого типа "Катализатор" Способ приготовления катализатора для оксихлорирования этилена в 1,2-дихлорэтан
ITMI20030630A1 (it) 2003-03-31 2004-10-01 Sued Chemie Mt Srl Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano.
TWI341218B (en) * 2005-11-14 2011-05-01 Oxy Vinyls Lp Catalyst compositions and process for oxychlorination
EP2070898B1 (de) * 2007-12-03 2013-02-20 Basf Se Katalysator zur Oxichlorierung

Also Published As

Publication number Publication date
BR112015005088B1 (pt) 2023-05-02
KR20150082475A (ko) 2015-07-15
BR112015005088B8 (es) 2023-08-01
UA116788C2 (uk) 2018-05-10
JP6427494B2 (ja) 2018-11-21
US20160129426A1 (en) 2016-05-12
SA515360394B1 (ar) 2017-07-09
CA2890210A1 (en) 2014-05-08
CN104918699B (zh) 2017-10-13
CA2890210C (en) 2021-02-02
MX2015005670A (es) 2016-02-05
US20140128643A1 (en) 2014-05-08
US9744525B2 (en) 2017-08-29
JP2016501712A (ja) 2016-01-21
CN104918699A (zh) 2015-09-16
US9248434B2 (en) 2016-02-02
BR112015005088A2 (pt) 2018-04-17
KR102162685B1 (ko) 2020-10-07

Similar Documents

Publication Publication Date Title
MX376956B (es) Catalizador para la oxicloracion de etileno a 1,2-dicloroetano.
WO2010088006A3 (en) Catalyst with bimodal pore size distribution and the use thereof
JP2017536228A5 (es)
WO2015025286A3 (en) Selective zeolite supported catalysts for propane and butane dehydrogenation
MX2014005243A (es) Proceso para producir 2,3,3,3-tetrafluoropropeno.
HK1198256A1 (en) Heat transfer compositions
SG11201504141VA (en) HIGH PERFORMANCE ZIEGLER-NATTA CATALYST SYSTEMS, PROCESS FOR PRODUCING SUCH MgCl<sb>2</sb> BASED CATALYSTS AND USE THEREOF
GB201000078D0 (en) Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
ZA202104193B (en) Carbon nanomaterial for use as a catalyst
MX2015011888A (es) Metodo para mejorar selectividad de 1,1,3-tricloropropene y/o 3,3,3-tricloropropeno durante la deshidrocloracion de 1,1,1,3-tetracloropropano.
MY182458A (en) Hydrocarbon synthesis catalyst, its preparation process and its use
UA95620C2 (ru) Каталитические композиции и способ оксихлорирования углеводорода с их использованием
WO2014190126A3 (en) Catalytic process of making 1,3,3,3-tetrafluoropropene
JP6509807B2 (ja) ジクロロエタンへのエチレンのオキシ塩素化のための触媒及びプロセス
TH162259A (th) ตัวเร่งปฏิกิริยาสำหรับออกซีคลอริเนชันของเอธิลีนไปเป็น 1.2-ไดคลอโรอีเธน
WO2005091697A3 (en) Thiourea compositions and uses thereof
RU2017101810A (ru) Катализатор и способ оксихлорирования этилена до дихлорэтана
JP2017520541A5 (es)
WO2016089824A3 (en) Disproportionation of hydrocarbons using solid acid catalysts
RU2015121320A (ru) Катализатор для оксихлорирования этилена до 1,2-дихлорэтана
MY194211A (en) Method of manufacturing hydrocarbons
MX2016013879A (es) Procedimiento para preparar bifenilaminas a partir de anilidas por catalisis con rutenio.
Умрихин teclot
Hutchings Showcasing research from the Cardiff Catalysis Institute, Department of Chemistry, Cardiff University, Cardiff, Wales, UK
Novikov CHOOSING SOFTWARE FOR DEPLOYMENT OF HETEROGENEOUS COMPUTING SYSTEM

Legal Events

Date Code Title Description
FG Grant or registration