MX374199B - Ligandos de 1,1´-bis (fosfino) ferroceno para la alcoxicarbonilación. - Google Patents

Ligandos de 1,1´-bis (fosfino) ferroceno para la alcoxicarbonilación.

Info

Publication number
MX374199B
MX374199B MX2017009237A MX2017009237A MX374199B MX 374199 B MX374199 B MX 374199B MX 2017009237 A MX2017009237 A MX 2017009237A MX 2017009237 A MX2017009237 A MX 2017009237A MX 374199 B MX374199 B MX 374199B
Authority
MX
Mexico
Prior art keywords
alkyl
cycloalkyl
aryl
heteroaryl
heterocycloalkyl
Prior art date
Application number
MX2017009237A
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English (en)
Other versions
MX2017009237A (es
Inventor
Dieter Hess
Dirk Fridag
Frank Geilen
Helfried Neumann
Kaiwu Dong
Katrin Marie Dyballa
Matthias Beller
Ralf Jackstell
Robert Franke
Original Assignee
Evonik Operations Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Operations Gmbh filed Critical Evonik Operations Gmbh
Publication of MX2017009237A publication Critical patent/MX2017009237A/es
Publication of MX374199B publication Critical patent/MX374199B/es

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5045—Complexes or chelates of phosphines with metallic compounds or metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Mezcla de diastereómeros que comprende los diastereómeros de las fórmulas (I.1) y (I.2) en donde R2, R4 se seleccionan cada uno de manera independiente de -alquilo de (C1-C12)-, -cicloalquilo de (C3-C12)-, -eterocicloalquilo de (C3-C12)-, -arilo de (C6-C20)-; los radicales R1, R3 son cada uno, un radical -heteroarilo de (C3-C20)-; R1, R3 pueden cada uno, estar sustituidos de manera independiente con uno o más sustituyentes seleccionados de -alquilo de (C1-C12)-, -cicloalquilo de (C3-C12)-, -heterocicloalquilo de (C3-C12)-, -O-alquilo de(C1-C12)-, -O-alquilo de (C1-C12)-arilo de (C6-C20)-, -O-cicloalquilo de (C3-C12)-, -S-alquilo de (C1-C12)-, -S-cicloalquilo de (C3-C12)-,-COO-alquilo de (C1-C12)-, -COO-cicloalquilo de (C3-C12)-,-CONH-alquilo de (C1-C12)-, -CONH-cicloalquilo de (C3-C12)-,-CO-alquilo de (C1-C12)-, -CO-cicloalquilo de (C3-C12)-, -N-[alquilo de (C1-C12)]2, -arilo de (C6-C20)-, -arilo de (C6-C20)-alquilo de (C1-C12), -arilo de (C6-C20)-O-alquilo de (C1-C12)-,-heteroarilo de (C3-C20)-, -heteroarilo de (C3-C20)-alquilo de(C1-C12)-, -heteroarilo de (C3-C20)-O-alquilo de (C1-C12)-, -COOH, -OH, -SO3H, -NH2, halógeno; y R2, R4, si son -alquilo de (C1-C12)-, -cicloalquilo de (C3-C12)-, -heterocicloalquilo de (C3-C12)- o -arilo de (C6-C20)-, pueden cada uno, estar sustituidos de manera independiente por uno o más sustituyentes seleccionados de -alquilo de (C1-C12)-, -cicloalquilo de (C3-C12)-, -heterocicloalquilo de (C3-C12)-, -O-alquilo de (C1-C12)-, -Oalquilo de (C1-C12)-arilo de (C6-C20)-, -O-cicloalquilo de (C3- C12)-, -S-alquilo de (C1-C12)-, -S-cicloalquilo de (C3-C12)-, -COO-alquilo de (C1-C12)-, -COO-cicloalquilo de (C3-C12)-, -CONH-alquilo de (C1-C12)-, -CONH-cicloalquilo de (C3-C12)-, -CO-alquilo de (C1-C12)-, -CO-cicloalquilo de (C3-C12)-, -N-[alquilo de (C1-C12)]2, -arilo de (C6-C20)-, -arilo de (C6-C20)-alquilo de (C1-C12)-, -arilo de (C6-C20)-O-alquilo de (C1-C12)-, -heteroarilo de (C3-C20)-, -heteroarilo de (C3-C20)-alquilo de (C1-C12)-, -heteroarilo de (C3-C20)-O-alquilo de (C1-C12)-, -COOH, -OH, -SO3H, -NH2, halógeno. La invención se relaciona además con mezclas de complejos de Pd que comprenden los diastereómeros de acuerdo con la invención, y con el uso de los mismos en un proceso de alcoxicarbonilación.
MX2017009237A 2016-07-19 2017-07-13 Ligandos de 1,1´-bis (fosfino) ferroceno para la alcoxicarbonilación. MX374199B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP16180055.2A EP3272759B1 (de) 2016-07-19 2016-07-19 1,1'-bis(phosphino)ferrocenliganden für die alkoxycarbonylierung

Publications (2)

Publication Number Publication Date
MX2017009237A MX2017009237A (es) 2019-04-18
MX374199B true MX374199B (es) 2025-03-05

Family

ID=56497601

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017009237A MX374199B (es) 2016-07-19 2017-07-13 Ligandos de 1,1´-bis (fosfino) ferroceno para la alcoxicarbonilación.

Country Status (12)

Country Link
US (1) US9938310B2 (es)
EP (1) EP3272759B1 (es)
JP (1) JP6431575B2 (es)
KR (1) KR101967539B1 (es)
CN (1) CN107629092B (es)
CA (1) CA2973697C (es)
ES (1) ES2732998T3 (es)
MX (1) MX374199B (es)
MY (1) MY176315A (es)
PT (1) PT3272759T (es)
SG (1) SG10201705856QA (es)
TW (1) TWI667245B (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2787299T3 (es) 2017-12-21 2020-10-15 Evonik Degussa Gmbh Proceso para la conversión directa de alquenos en ácidos carboxílicos

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1008018A3 (nl) 1994-01-06 1995-12-12 Dsm Nv Werkwijze voor de bereiding van een ester.
JP4290265B2 (ja) * 1999-03-02 2009-07-01 第一ファインケミカル株式会社 新規な不斉配位子
GB0400720D0 (en) * 2004-01-14 2004-02-18 Stylacats Ltd Novel ferrocene-based phosphorus chiral phosphines
EP2676963B1 (en) * 2011-02-17 2016-08-24 National University Corporation Okayama University Novel compound, novel ligand, novel transition metal complexes, and catalysts consisting of novel transition metal complexes
CN106632476B (zh) 2015-07-23 2020-11-20 赢创运营有限公司 单膦化合物和以此为基础用于烯属不饱和化合物的烷氧基羰基化的钯催化剂

Also Published As

Publication number Publication date
US20180022772A1 (en) 2018-01-25
US9938310B2 (en) 2018-04-10
PT3272759T (pt) 2019-07-17
SG10201705856QA (en) 2018-02-27
KR20180009712A (ko) 2018-01-29
EP3272759B1 (de) 2019-05-08
TWI667245B (zh) 2019-08-01
ES2732998T3 (es) 2019-11-27
KR101967539B1 (ko) 2019-04-09
MY176315A (en) 2020-07-28
EP3272759A1 (de) 2018-01-24
CA2973697C (en) 2022-06-21
TW201815812A (zh) 2018-05-01
JP2018065782A (ja) 2018-04-26
CN107629092B (zh) 2020-12-15
MX2017009237A (es) 2019-04-18
JP6431575B2 (ja) 2018-11-28
CN107629092A (zh) 2018-01-26
CA2973697A1 (en) 2018-01-19

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