MX365277B - Sistemas de poliuretano 2k con temperatura de transición vítrea elevada. - Google Patents
Sistemas de poliuretano 2k con temperatura de transición vítrea elevada.Info
- Publication number
- MX365277B MX365277B MX2014010290A MX2014010290A MX365277B MX 365277 B MX365277 B MX 365277B MX 2014010290 A MX2014010290 A MX 2014010290A MX 2014010290 A MX2014010290 A MX 2014010290A MX 365277 B MX365277 B MX 365277B
- Authority
- MX
- Mexico
- Prior art keywords
- mol
- transition temperature
- high glass
- polyurethane systems
- mpas
- Prior art date
Links
- 239000004814 polyurethane Substances 0.000 title abstract 3
- 229920002635 polyurethane Polymers 0.000 title abstract 3
- 230000009477 glass transition Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- 239000005056 polyisocyanate Substances 0.000 abstract 3
- 229920001228 polyisocyanate Polymers 0.000 abstract 3
- 239000011230 binding agent Substances 0.000 abstract 1
- 150000001718 carbodiimides Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/1701—Component parts, details or accessories; Auxiliary operations using a particular environment during moulding, e.g. moisture-free or dust-free
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/42—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
- B29C70/46—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
- B29C70/48—Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/20—Heterocyclic amines; Salts thereof
- C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring
- C08G18/2027—Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/249—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2075/00—Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Composite Materials (AREA)
- Inorganic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12157301 | 2012-02-28 | ||
| EP12157299 | 2012-02-28 | ||
| PCT/EP2013/053703 WO2013127734A1 (de) | 2012-02-28 | 2013-02-25 | 2k-polyurethansysteme mit hoher glasübergangstemperatur |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2014010290A MX2014010290A (es) | 2014-10-13 |
| MX365277B true MX365277B (es) | 2019-05-29 |
Family
ID=47748639
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014010290A MX365277B (es) | 2012-02-28 | 2013-02-25 | Sistemas de poliuretano 2k con temperatura de transición vítrea elevada. |
| MX2014010292A MX365691B (es) | 2012-02-28 | 2013-02-25 | Sistemas de poliuretano de dos componentes con separacion de fases. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014010292A MX365691B (es) | 2012-02-28 | 2013-02-25 | Sistemas de poliuretano de dos componentes con separacion de fases. |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US10093766B2 (enExample) |
| EP (2) | EP2820061B1 (enExample) |
| JP (3) | JP2015510011A (enExample) |
| KR (2) | KR102046197B1 (enExample) |
| CN (2) | CN104136476B (enExample) |
| AU (1) | AU2013225178B2 (enExample) |
| CA (2) | CA2863141C (enExample) |
| ES (1) | ES2885763T3 (enExample) |
| MX (2) | MX365277B (enExample) |
| WO (2) | WO2013127732A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102011002809A1 (de) * | 2011-01-18 | 2012-07-19 | Henkel Ag & Co. Kgaa | 2K-PU-Zusammensetzung mit verzögerter Vernetzung |
| ES2885763T3 (es) * | 2012-02-28 | 2021-12-15 | Henkel Ag & Co Kgaa | Sistemas de poliuretano 2k con temperatura alta de transición vítrea |
| DE102014208353A1 (de) * | 2014-05-05 | 2015-11-05 | Henkel Ag & Co. Kgaa | Mehrphasige Polyurethan-Zusammensetzung mit reduzierter Schaumentwicklung |
| ES2620980T3 (es) * | 2014-09-30 | 2017-06-30 | Henkel Ag & Co. Kgaa | Composiciones que comprenden un material de fibra y un aglutinante termoplástico |
| EP3562853B1 (en) * | 2016-12-28 | 2021-11-17 | Henkel AG & Co. KGaA | Two-component polyurethane adhesive |
| EP3533530A1 (en) | 2018-03-01 | 2019-09-04 | Henkel AG & Co. KGaA | Process for the production of composite materials at low temperatures |
| MX2019015665A (es) * | 2018-11-22 | 2020-12-11 | Formtap Interni Sist Automotivos S/A | Perfeccionamiento introducido en proceso de obtencion de compuestos termoestructurales. |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2966876D1 (en) | 1978-12-11 | 1984-05-10 | Ici Plc | Modified diisocyanate compositions and polyurethanes thereof |
| DE3626223A1 (de) * | 1986-08-02 | 1988-02-04 | Henkel Kgaa | Polyurethan-praepolymere auf basis oleochemischer polyole, ihre herstellung und verwendung |
| JPS63309510A (ja) * | 1987-06-12 | 1988-12-16 | Nippon Polyurethan Kogyo Kk | ポリイソシアヌレ−ト複合体の製造法 |
| DE8711301U1 (de) * | 1987-08-20 | 1987-10-29 | Pelzer, Helmut, 58313 Herdecke | Faserverstärkter, hoch temperaturstabiler, plattenförmiger Werkstoff |
| US4800058A (en) | 1987-08-24 | 1989-01-24 | Arco Chemical Company | Method for the preparation of rigid cast or transfer molded thermoset polyurethane modified polyisocyanurate compositions |
| US4743626A (en) | 1987-09-14 | 1988-05-10 | Basf Corporation | Liquid carbodiimide-uretonimine modified polymethylene polyphenylene polyisocyanates and polyurethane foams made therefrom |
| ES2099240T3 (es) | 1991-05-03 | 1997-05-16 | Ciba Geigy Ag | Componente poliolico para la fabricacion de piezas moldeadas de poliuretano. |
| CA2188503A1 (en) * | 1995-12-22 | 1997-06-23 | Neil H. Nodelman | Polyurethane resin transfer molding systems |
| DE69817385T2 (de) * | 1997-09-26 | 2004-03-25 | The Dow Chemical Co., Midland | Hochtemperaturbeständige polyurethanzusammensetzungen |
| DE19750820B4 (de) * | 1997-11-17 | 2004-04-29 | Höpner Lacke GmbH | Beschichtungsstoff für mit Restrost behaftete Oberflächen |
| CA2359560C (en) | 1998-11-16 | 2009-02-03 | Huntsman International Llc | Polyisocyanurate compositions and composites |
| JP4031632B2 (ja) * | 2001-10-31 | 2008-01-09 | 三菱重工業株式会社 | 繊維強化型プラスチックの製造方法 |
| JP3924258B2 (ja) * | 2003-04-01 | 2007-06-06 | 三菱重工業株式会社 | 繊維強化プラスチックの製造方法 |
| DE10318740A1 (de) | 2003-04-25 | 2004-11-11 | Bayer Materialscience Ag | Polyurethan-Formulierungen und ihre Verwendung |
| DE10356767A1 (de) * | 2003-12-05 | 2005-07-07 | Henkel Kgaa | Platten und Formkörper auf Basis von Polyurethanbindemittel |
| DE102004033849A1 (de) | 2004-07-13 | 2006-02-16 | Bayer Materialscience Ag | Verfahren zur Herstellung flüssiger, lagerstabiler Carbodiimid- und/oder Uretonimingruppen aufweisender organischer Isocyanate mit niedriger Farbzahl |
| US20060014890A1 (en) * | 2004-07-14 | 2006-01-19 | Zielinski David P | Polyisocyanates with improved compatibility with high hydroxyl content polyols |
| US8048935B2 (en) * | 2004-11-08 | 2011-11-01 | Carpenter Co. | Liquid foam systems and ASTM E-84 class 1 rated rigid, high-density polyurethane foams and articles prepared therefrom |
| US20060264534A1 (en) * | 2005-05-23 | 2006-11-23 | Zeying Ma | Inkjet inks having reduced bronzing |
| DE102006002158A1 (de) * | 2006-01-17 | 2007-07-19 | Bayer Materialscience Ag | Verfahren zur Herstellung flüssiger, lagerstabiler Carboddimid- und/oder Uretonimingruppen aufweisender organischer Isocyanate |
| ITMI20061107A1 (it) * | 2006-06-08 | 2007-12-09 | Diab Int Ab | Formulazioni per prodotti cellulari di polimero espanso basati su polivinl cloruro prodotti cellulari di polimero espanso migliorati basati su polivinil cloruro e processo per produrre detti prodotti cellulari di polimero espanso migliorati |
| US20080099141A1 (en) * | 2006-10-26 | 2008-05-01 | Ashland Inc. | Method of producing flexible laminates |
| JP5041794B2 (ja) * | 2006-12-07 | 2012-10-03 | 住化バイエルウレタン株式会社 | 変性ポリイソシアネートの製造方法 |
| EP1970420A1 (en) * | 2007-03-15 | 2008-09-17 | Huntsman International Llc | Polyisocyanate-based adhesive composition |
| US7842349B2 (en) * | 2007-10-11 | 2010-11-30 | Tse Industries, Inc. | Method for spray forming high modulus polyurethane structures |
| DE102007062529A1 (de) * | 2007-12-20 | 2009-06-25 | Henkel Ag & Co. Kgaa | 2K-PU-Klebstoff zum Verkleben von Faserformteilen |
| PT2238195E (pt) * | 2008-01-29 | 2015-04-02 | Basf Se | Método para a produção de poliéter álcoois |
| DE102008027914A1 (de) | 2008-06-12 | 2009-12-17 | Henkel Ag & Co. Kgaa | Vernetzende 2K-Isocyanat-Zusammensetzungen |
| CA2732421C (en) | 2008-08-28 | 2016-05-17 | Huntsman International Llc | Mixture obtained by reacting polyol and anhydride and its use in polyisocyanates for making polyisocyanurates |
| EP2507041B1 (de) | 2009-12-01 | 2014-02-26 | Basf Se | Pultrusionsharzsystem auf basis von polyurethan |
| DE102011002809A1 (de) * | 2011-01-18 | 2012-07-19 | Henkel Ag & Co. Kgaa | 2K-PU-Zusammensetzung mit verzögerter Vernetzung |
| ES2885763T3 (es) * | 2012-02-28 | 2021-12-15 | Henkel Ag & Co Kgaa | Sistemas de poliuretano 2k con temperatura alta de transición vítrea |
| HUP1400402A2 (hu) * | 2014-08-29 | 2016-03-29 | Borsodchem Zrt | Eljárás világos színû, stabilan tárolható uretonimin modifikált poliizocianát elõállítására |
| CN105447437B (zh) | 2015-02-13 | 2017-05-03 | 比亚迪股份有限公司 | 指纹识别方法和装置 |
-
2013
- 2013-02-25 ES ES13706002T patent/ES2885763T3/es active Active
- 2013-02-25 EP EP13706002.6A patent/EP2820061B1/de active Active
- 2013-02-25 CN CN201380010852.2A patent/CN104136476B/zh active Active
- 2013-02-25 EP EP13705802.0A patent/EP2820060A1/de active Pending
- 2013-02-25 WO PCT/EP2013/053699 patent/WO2013127732A1/de not_active Ceased
- 2013-02-25 CN CN201380010986.4A patent/CN104136477B/zh active Active
- 2013-02-25 KR KR1020147023787A patent/KR102046197B1/ko not_active Expired - Fee Related
- 2013-02-25 MX MX2014010290A patent/MX365277B/es active IP Right Grant
- 2013-02-25 JP JP2014559167A patent/JP2015510011A/ja active Pending
- 2013-02-25 CA CA2863141A patent/CA2863141C/en active Active
- 2013-02-25 WO PCT/EP2013/053703 patent/WO2013127734A1/de not_active Ceased
- 2013-02-25 JP JP2014559166A patent/JP6534260B2/ja not_active Expired - Fee Related
- 2013-02-25 KR KR1020147027024A patent/KR20140129304A/ko not_active Ceased
- 2013-02-25 CA CA2863145A patent/CA2863145C/en not_active Expired - Fee Related
- 2013-02-25 MX MX2014010292A patent/MX365691B/es active IP Right Grant
- 2013-02-25 AU AU2013225178A patent/AU2013225178B2/en not_active Ceased
-
2014
- 2014-08-25 US US14/467,550 patent/US10093766B2/en active Active
- 2014-08-25 US US14/467,782 patent/US10131738B2/en active Active
-
2018
- 2018-10-10 JP JP2018191609A patent/JP2019035088A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013127734A1 (de) | 2013-09-06 |
| KR20140129304A (ko) | 2014-11-06 |
| CA2863141C (en) | 2021-08-17 |
| ES2885763T3 (es) | 2021-12-15 |
| AU2013225176A1 (en) | 2014-09-18 |
| US10093766B2 (en) | 2018-10-09 |
| JP2015512979A (ja) | 2015-04-30 |
| US20160362516A1 (en) | 2016-12-15 |
| JP2015510011A (ja) | 2015-04-02 |
| JP6534260B2 (ja) | 2019-06-26 |
| US10131738B2 (en) | 2018-11-20 |
| CN104136476A (zh) | 2014-11-05 |
| EP2820061B1 (de) | 2021-07-21 |
| MX2014010290A (es) | 2014-10-13 |
| CA2863141A1 (en) | 2013-09-06 |
| CN104136476B (zh) | 2017-04-19 |
| WO2013127732A1 (de) | 2013-09-06 |
| JP2019035088A (ja) | 2019-03-07 |
| CN104136477A (zh) | 2014-11-05 |
| AU2013225178B2 (en) | 2016-01-07 |
| CA2863145C (en) | 2021-03-16 |
| AU2013225176B2 (en) | 2016-01-28 |
| KR102046197B1 (ko) | 2019-11-18 |
| US20140371391A1 (en) | 2014-12-18 |
| EP2820060A1 (de) | 2015-01-07 |
| MX2014010292A (es) | 2014-10-13 |
| MX365691B (es) | 2019-06-11 |
| EP2820061A1 (de) | 2015-01-07 |
| CA2863145A1 (en) | 2013-09-06 |
| CN104136477B (zh) | 2016-06-29 |
| AU2013225178A1 (en) | 2014-09-18 |
| KR20140127830A (ko) | 2014-11-04 |
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