MX357162B - Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx. - Google Patents
Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx.Info
- Publication number
- MX357162B MX357162B MX2014015590A MX2014015590A MX357162B MX 357162 B MX357162 B MX 357162B MX 2014015590 A MX2014015590 A MX 2014015590A MX 2014015590 A MX2014015590 A MX 2014015590A MX 357162 B MX357162 B MX 357162B
- Authority
- MX
- Mexico
- Prior art keywords
- mil
- mof
- metal
- materials
- organic materials
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000013212 metal-organic material Substances 0.000 title 1
- 239000012621 metal-organic framework Substances 0.000 abstract 8
- 239000002184 metal Substances 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 abstract 3
- 239000013178 MIL-101(Cr) Substances 0.000 abstract 3
- 150000004703 alkoxides Chemical class 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- 150000002118 epoxides Chemical class 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- 238000003786 synthesis reaction Methods 0.000 abstract 2
- 230000002194 synthesizing effect Effects 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
- C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Catalysts (AREA)
Abstract
La presente invención se relaciona con un proceso de obtención de materiales con estructura atómica Metal Orgánica y que se denomina MOF (MOF, por sus siglas en inglés: Metal Organic Framework) tipo MIL-101 (Cr) y MlL-101-Cr-MX+ (MIL: Material from Institute Lavoisier), donde puede ser cualquier catión metálico, tal como Mg2+, Al3+ o Ti4+, usando para su síntesis epóxidos y alcóxidos metálicos, evitando el uso de ácido fluorhídrico (HF) o bases como agentes directores de síntesis. El proceso de la presente invención para la obtención de materiales MOF MIL-101 (Cr) y MOF MlL-101-Cr-MX+, donde MX+puede ser cualquier catión metálico, tal como Mg2+, Al3+ o Ti4+, consiste en: a) Sintetizar el MOF MIL-101 (Cr) con epóxidos, o Sintetizar el MOF MlL-101-Cr-MX+ con alcóxidos metálicos; y b) Purificación del MOF sintetizado. para obtener materiales 100 %puros, con una mesoporosidad controlada, asociada a una histéresis P/P0 de 0.7 a 0.99, área superficial BET de 2,500 a 3,500 m2/g, volumen de poro 1.1 a 2.2 cm3/g, y diámetro de poro de 15 a 55 nm.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014015590A MX357162B (es) | 2014-12-17 | 2014-12-17 | Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx. |
US14/964,478 US9777029B2 (en) | 2014-12-17 | 2015-12-09 | Process for obtaining metal-organic materials with structure type MIL-101 (Cr) and MIL-101-Cr-MX+ |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2014015590A MX357162B (es) | 2014-12-17 | 2014-12-17 | Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx. |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014015590A MX2014015590A (es) | 2016-06-16 |
MX357162B true MX357162B (es) | 2018-06-08 |
Family
ID=56163430
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014015590A MX357162B (es) | 2014-12-17 | 2014-12-17 | Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx. |
Country Status (2)
Country | Link |
---|---|
US (1) | US9777029B2 (es) |
MX (1) | MX357162B (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11478774B2 (en) * | 2016-08-29 | 2022-10-25 | Cornell University | Metal organic frameworks and methods of making and using same |
CN107129429B (zh) * | 2017-05-23 | 2020-06-02 | 南通职业大学 | 羧酸盐为有机配体合成金属有机骨架材料MIL-101-Cr的方法及其纯化方法 |
CN111686694B (zh) * | 2019-03-15 | 2023-07-04 | 中国石油化工股份有限公司 | Mil-101材料的制备方法和应用 |
CN111229320B (zh) * | 2020-01-16 | 2022-07-19 | 辽宁大学 | 一种接枝离子液体的金属有机框架复合材料及其制备方法和应用 |
CN111359670A (zh) * | 2020-03-10 | 2020-07-03 | 浙江工业大学 | 一种Au-Pd/NH2-MIL-101(Cr)催化剂及其制备与应用 |
CN113694894A (zh) * | 2020-05-21 | 2021-11-26 | 湖南大学 | 一种多孔流体及其制备方法和应用 |
CN112979984B (zh) * | 2021-03-03 | 2023-05-30 | 辽宁大学 | 一种离子型MOFs材料及其制备方法和在制备环状碳酸酯中的应用 |
CN113817172B (zh) * | 2021-08-11 | 2023-03-17 | 梅州绿盛林业科技有限公司 | 用于纯化铁皮石斛多糖类化合物的金属有机骨架材料及纯化方法 |
CN113861434B (zh) * | 2021-09-14 | 2022-10-21 | 南开大学 | 一种新型镁基mof材料及mof材料的溶液加工方法 |
CN114933710B (zh) * | 2022-05-26 | 2023-04-07 | 北京工业大学 | 一种具有mil-101结构的铝的金属有机框架材料及制备方法 |
CN115318341B (zh) * | 2022-08-30 | 2023-12-15 | 广西大学 | 一种咪唑功能化双金属mof多相催化剂及其应用 |
CN115945206B (zh) * | 2022-12-13 | 2024-05-31 | 华南理工大学 | 一种CrN-TiN NSs及其制备与应用 |
CN116351397B (zh) * | 2023-03-28 | 2024-03-12 | 菏泽学院 | 一种对甲醛具有高效捕集的复合材料制备方法及应用 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100680767B1 (ko) | 2006-02-07 | 2007-02-09 | 한국화학연구원 | 다공성 유무기혼성체의 제조방법 |
WO2008066293A1 (en) | 2006-11-27 | 2008-06-05 | Korea Research Institute Of Chemical Technology | A method for preparing porous organic-inorganic hybrid materials, porous organic-inorganic hybrid materials obtained by the method and catalytic uses of the materials |
WO2008072896A1 (en) * | 2006-12-13 | 2008-06-19 | Korea Research Institute Of Chemical Technology | A porous organic-inorganic hybrid materials and an absorbent comprising the same |
KR100864313B1 (ko) | 2007-05-21 | 2008-10-20 | 한국화학연구원 | 불포화 금속자리를 갖는 다공성 유-무기 혼성체 또는메조세공체의 표면 기능화 및 그의 응용 |
FR2932397B1 (fr) | 2008-06-11 | 2010-07-30 | Centre Nat Rech Scient | Solide hybride cristallin poreux reductible pour la separation de melanges de molecules ayant des degres et/ou un nombre d'insaturations differents |
-
2014
- 2014-12-17 MX MX2014015590A patent/MX357162B/es active IP Right Grant
-
2015
- 2015-12-09 US US14/964,478 patent/US9777029B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US9777029B2 (en) | 2017-10-03 |
US20160185806A1 (en) | 2016-06-30 |
MX2014015590A (es) | 2016-06-16 |
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