MX357162B - Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx. - Google Patents

Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx.

Info

Publication number
MX357162B
MX357162B MX2014015590A MX2014015590A MX357162B MX 357162 B MX357162 B MX 357162B MX 2014015590 A MX2014015590 A MX 2014015590A MX 2014015590 A MX2014015590 A MX 2014015590A MX 357162 B MX357162 B MX 357162B
Authority
MX
Mexico
Prior art keywords
mil
mof
metal
materials
organic materials
Prior art date
Application number
MX2014015590A
Other languages
English (en)
Other versions
MX2014015590A (es
Inventor
Juventino Mora Vallejo Rodolfo
Montoya De La Fuente Ascención
Cecilia Laredo Sánchez Georgina
Meneses Ruíz Edith
Jesús Castillo Munguía J
Zapata Rendón Beatriz
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2014015590A priority Critical patent/MX357162B/es
Priority to US14/964,478 priority patent/US9777029B2/en
Publication of MX2014015590A publication Critical patent/MX2014015590A/es
Publication of MX357162B publication Critical patent/MX357162B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

La presente invención se relaciona con un proceso de obtención de materiales con estructura atómica Metal Orgánica y que se denomina MOF (MOF, por sus siglas en inglés: Metal Organic Framework) tipo MIL-101 (Cr) y MlL-101-Cr-MX+ (MIL: Material from Institute Lavoisier), donde puede ser cualquier catión metálico, tal como Mg2+, Al3+ o Ti4+, usando para su síntesis epóxidos y alcóxidos metálicos, evitando el uso de ácido fluorhídrico (HF) o bases como agentes directores de síntesis. El proceso de la presente invención para la obtención de materiales MOF MIL-101 (Cr) y MOF MlL-101-Cr-MX+, donde MX+puede ser cualquier catión metálico, tal como Mg2+, Al3+ o Ti4+, consiste en: a) Sintetizar el MOF MIL-101 (Cr) con epóxidos, o Sintetizar el MOF MlL-101-Cr-MX+ con alcóxidos metálicos; y b) Purificación del MOF sintetizado. para obtener materiales 100 %puros, con una mesoporosidad controlada, asociada a una histéresis P/P0 de 0.7 a 0.99, área superficial BET de 2,500 a 3,500 m2/g, volumen de poro 1.1 a 2.2 cm3/g, y diámetro de poro de 15 a 55 nm.
MX2014015590A 2014-12-17 2014-12-17 Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx. MX357162B (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2014015590A MX357162B (es) 2014-12-17 2014-12-17 Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx.
US14/964,478 US9777029B2 (en) 2014-12-17 2015-12-09 Process for obtaining metal-organic materials with structure type MIL-101 (Cr) and MIL-101-Cr-MX+

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2014015590A MX357162B (es) 2014-12-17 2014-12-17 Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx.

Publications (2)

Publication Number Publication Date
MX2014015590A MX2014015590A (es) 2016-06-16
MX357162B true MX357162B (es) 2018-06-08

Family

ID=56163430

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014015590A MX357162B (es) 2014-12-17 2014-12-17 Proceso de obtencion de materiales metal-organicos con estructura tipo mil-101 (cr) y mil-101-cr-mx.

Country Status (2)

Country Link
US (1) US9777029B2 (es)
MX (1) MX357162B (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11478774B2 (en) * 2016-08-29 2022-10-25 Cornell University Metal organic frameworks and methods of making and using same
CN107129429B (zh) * 2017-05-23 2020-06-02 南通职业大学 羧酸盐为有机配体合成金属有机骨架材料MIL-101-Cr的方法及其纯化方法
CN111686694B (zh) * 2019-03-15 2023-07-04 中国石油化工股份有限公司 Mil-101材料的制备方法和应用
CN111229320B (zh) * 2020-01-16 2022-07-19 辽宁大学 一种接枝离子液体的金属有机框架复合材料及其制备方法和应用
CN111359670A (zh) * 2020-03-10 2020-07-03 浙江工业大学 一种Au-Pd/NH2-MIL-101(Cr)催化剂及其制备与应用
CN113694894A (zh) * 2020-05-21 2021-11-26 湖南大学 一种多孔流体及其制备方法和应用
CN112979984B (zh) * 2021-03-03 2023-05-30 辽宁大学 一种离子型MOFs材料及其制备方法和在制备环状碳酸酯中的应用
CN113817172B (zh) * 2021-08-11 2023-03-17 梅州绿盛林业科技有限公司 用于纯化铁皮石斛多糖类化合物的金属有机骨架材料及纯化方法
CN113861434B (zh) * 2021-09-14 2022-10-21 南开大学 一种新型镁基mof材料及mof材料的溶液加工方法
CN114933710B (zh) * 2022-05-26 2023-04-07 北京工业大学 一种具有mil-101结构的铝的金属有机框架材料及制备方法
CN115318341B (zh) * 2022-08-30 2023-12-15 广西大学 一种咪唑功能化双金属mof多相催化剂及其应用
CN115945206B (zh) * 2022-12-13 2024-05-31 华南理工大学 一种CrN-TiN NSs及其制备与应用
CN116351397B (zh) * 2023-03-28 2024-03-12 菏泽学院 一种对甲醛具有高效捕集的复合材料制备方法及应用
CN120189910A (zh) * 2025-02-17 2025-06-24 南开大学 用于吸附修复水体pfas污染的多特性铁-碳衍生物材料及其制备方法、应用

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100680767B1 (ko) 2006-02-07 2007-02-09 한국화학연구원 다공성 유무기혼성체의 제조방법
WO2008066293A1 (en) 2006-11-27 2008-06-05 Korea Research Institute Of Chemical Technology A method for preparing porous organic-inorganic hybrid materials, porous organic-inorganic hybrid materials obtained by the method and catalytic uses of the materials
EP2101912B1 (en) * 2006-12-13 2017-06-28 Korea Research Institute Of Chemical Technology Porous organic-inorganic hybrid materials containing iron and an absorbent comprising the same
KR100864313B1 (ko) 2007-05-21 2008-10-20 한국화학연구원 불포화 금속자리를 갖는 다공성 유-무기 혼성체 또는메조세공체의 표면 기능화 및 그의 응용
FR2932397B1 (fr) 2008-06-11 2010-07-30 Centre Nat Rech Scient Solide hybride cristallin poreux reductible pour la separation de melanges de molecules ayant des degres et/ou un nombre d'insaturations differents

Also Published As

Publication number Publication date
US9777029B2 (en) 2017-10-03
MX2014015590A (es) 2016-06-16
US20160185806A1 (en) 2016-06-30

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