MX350173B - Procesos enzimaticos de transesterifacion/esterificacion que emplean lipasas immovilizadas en resinas hidrofobicas en presencia de soluciones de agua. - Google Patents

Procesos enzimaticos de transesterifacion/esterificacion que emplean lipasas immovilizadas en resinas hidrofobicas en presencia de soluciones de agua.

Info

Publication number
MX350173B
MX350173B MX2014002181A MX2014002181A MX350173B MX 350173 B MX350173 B MX 350173B MX 2014002181 A MX2014002181 A MX 2014002181A MX 2014002181 A MX2014002181 A MX 2014002181A MX 350173 B MX350173 B MX 350173B
Authority
MX
Mexico
Prior art keywords
fatty acid
water
water solutions
biocatalyst
alkyl esters
Prior art date
Application number
MX2014002181A
Other languages
English (en)
Other versions
MX2014002181A (es
Inventor
Basheer Sobhi
Egbarieh Ahmad
Masri Ramez
Original Assignee
Trans Bio Diesel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Trans Bio Diesel Ltd filed Critical Trans Bio Diesel Ltd
Publication of MX2014002181A publication Critical patent/MX2014002181A/es
Publication of MX350173B publication Critical patent/MX350173B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
    • C12N9/14—Hydrolases (3)
    • C12N9/16—Hydrolases (3) acting on ester bonds (3.1)
    • C12N9/18—Carboxylic ester hydrolases (3.1.1)
    • C12N9/20—Triglyceride splitting, e.g. by means of lipase
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12Y—ENZYMES
    • C12Y301/00—Hydrolases acting on ester bonds (3.1)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • General Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • Biomedical Technology (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)

Abstract

La presente invención se refiere a un proceso por lotes o continuo enzimático para la producción de ésteres alquílicos de ácido graso para el uso en las industrias de biocombustibles, de alimentos y detergentes y un sistema para el mismo. El proceso utiliza enzimas inmovilizadas sobre una resina hidrofóbica mezclada con una fuente de ácido graso y un alcohol o donador de alcohol en la presencia de una solución amortiguadora acuoso alcalina o levemente alcalina, o en la presencia de agua o solución acuosa. El proceso de producción para los ésteres alquílicos de ácido graso se lleva a cabo mediante transesterificación o esterificación simultáneamente o secuencialmente. La actividad del biocatalizador se mantiene sin pérdidas de actividad significativas en múltiples usos y también evita la acumulación de glicerol y sub-productos de agua u otros compuestos hidrofílicos sobre el biocatalizador.
MX2014002181A 2011-08-31 2011-08-31 Procesos enzimaticos de transesterifacion/esterificacion que emplean lipasas immovilizadas en resinas hidrofobicas en presencia de soluciones de agua. MX350173B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IL2011/000699 WO2013030816A1 (en) 2011-08-31 2011-08-31 Enzymatic transesterification with lipases immobilized on hydrophobic resins in water solutions

Publications (2)

Publication Number Publication Date
MX2014002181A MX2014002181A (es) 2014-05-13
MX350173B true MX350173B (es) 2017-08-29

Family

ID=44741695

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014002181A MX350173B (es) 2011-08-31 2011-08-31 Procesos enzimaticos de transesterifacion/esterificacion que emplean lipasas immovilizadas en resinas hidrofobicas en presencia de soluciones de agua.

Country Status (15)

Country Link
EP (1) EP2751275B1 (es)
JP (1) JP5989121B2 (es)
KR (1) KR101717828B1 (es)
CN (1) CN103781911B (es)
AR (1) AR087740A1 (es)
AU (1) AU2011376066B2 (es)
BR (1) BR112014004290A2 (es)
CA (1) CA2842032C (es)
CY (1) CY1118531T1 (es)
DK (1) DK2751275T3 (es)
ES (1) ES2601802T3 (es)
IL (1) IL230478B (es)
MX (1) MX350173B (es)
RU (1) RU2573929C9 (es)
WO (1) WO2013030816A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150353970A1 (en) * 2012-12-31 2015-12-10 Trans Bio-Diesel Ltd. Enzymatic transesterification/esterification processing systems and processes employing lipases immobilzed on hydrophobic resins
CN113293183A (zh) * 2014-05-28 2021-08-24 诺维信公司 采用碱处理进行脂肪酸烷基酯生产
CN104404023B (zh) * 2014-11-05 2018-05-08 济南大学 一种磁性载体固定化脂肪酶的制备及其催化制备生物柴油
CN108148827B (zh) * 2016-12-02 2022-09-23 丰益(上海)生物技术研发中心有限公司 固定化酶及其制备方法和用途
RU2665041C2 (ru) * 2016-12-30 2018-08-27 Федеральное государственное бюджетное образовательное учреждение высшего образования "Российский государственный университет нефти и газа (национальный исследовательский университет) имени И.М. Губкина" Способ получения биодизельного топлива
JP7250259B2 (ja) * 2017-09-26 2023-04-03 トタル リサーチ アンド テクノロジー フエリユイ 清浄剤として脂肪酸エステルを含む装置中のレッドオイル堆積物を除去するための清浄化方法及びこのような方法における清浄剤としての脂肪酸エステルの使用
US11582982B2 (en) * 2017-10-13 2023-02-21 Glycosbio Inc. Method of making monoacylglyceride oils and food products containing monoacylglyceride oils
RU2725474C1 (ru) * 2019-04-29 2020-07-02 Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН, Институт катализа СО РАН) Биокатализатор, способ его приготовления и способ получения сложных эфиров с использованием этого биокатализатора
IL286349A (en) * 2021-09-13 2023-04-01 Univice M E Ltd Processes for the production of biodiesel from fatty waste

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9404483D0 (en) * 1994-03-08 1994-04-20 Norsk Hydro As Refining marine oil compositions
DE102004015781A1 (de) * 2004-03-31 2005-10-20 Cognis Ip Man Gmbh Verfahren zur enzymatischen Synthese von Triglyceriden ungesättigter Fettsäuren
DE102005002700A1 (de) * 2005-01-19 2006-07-27 Cognis Deutschland Gmbh & Co. Kg Zusammensetzungen verwendbar als Biotreibstoff
CA2609341C (en) * 2005-05-23 2011-10-04 Natural Asa Concentration of fatty acid alkyl esters by enzymatic reactions with glycerol
ES2289943B1 (es) * 2006-07-21 2008-12-16 Universidad De Cordoba Procedimiento de produccion de biodiesel mediante el uso de lipasa pancreatica de cerdo como biocatalizador enzimatico.
IL180598A0 (en) 2007-01-08 2007-07-04 Basheer Sobhi Immobilized interfacial enzymes of improved and stabilized activity
IL183084A0 (en) * 2007-05-09 2007-09-20 Trans Biodisel Ltd Modified-immobilized enzymes of high tolerance to hydrophilic substrates in organic media
US7790429B2 (en) 2007-11-28 2010-09-07 Transbiodiesel Ltd. Robust multi-enzyme preparation for the synthesis of fatty acid alkyl esters
CN101284999A (zh) * 2008-05-21 2008-10-15 华中科技大学 一种酶法制备生物柴油的方法
CA2791836C (en) * 2010-03-01 2014-10-28 Trans Bio-Diesel Ltd. A process for the enzymatic synthesis of fatty acid alkyl esters

Also Published As

Publication number Publication date
CY1118531T1 (el) 2017-07-12
IL230478A0 (en) 2014-03-31
RU2014111167A (ru) 2015-10-10
CN103781911B (zh) 2017-12-26
JP5989121B2 (ja) 2016-09-07
JP2014525261A (ja) 2014-09-29
AR087740A1 (es) 2014-04-16
WO2013030816A1 (en) 2013-03-07
IL230478B (en) 2018-03-29
CA2842032A1 (en) 2013-03-07
AU2011376066B2 (en) 2015-11-26
BR112014004290A2 (pt) 2017-03-28
KR20140063669A (ko) 2014-05-27
EP2751275A1 (en) 2014-07-09
MX2014002181A (es) 2014-05-13
DK2751275T3 (en) 2016-12-05
CN103781911A (zh) 2014-05-07
RU2573929C9 (ru) 2016-06-10
CA2842032C (en) 2016-09-27
KR101717828B1 (ko) 2017-03-17
AU2011376066A1 (en) 2014-02-20
ES2601802T3 (es) 2017-02-16
EP2751275B1 (en) 2016-08-03
RU2573929C2 (ru) 2016-01-27

Similar Documents

Publication Publication Date Title
MX350173B (es) Procesos enzimaticos de transesterifacion/esterificacion que emplean lipasas immovilizadas en resinas hidrofobicas en presencia de soluciones de agua.
AR080117A1 (es) Un proceso para la sintesis enzimatica de esteres alquilicos de acidos grasos
PE20151447A1 (es) Sistemas para procesar transesterificacion/esterificacion enzimatica y procesos que emplean lipasas inmobilizadas en resinas hidrofobicas
CU20150105A7 (es) Método para hacer un producto a partir de biomasa sacarificada con un organismo que fermenta selectivamente un azúcar en particular
PE20090740A1 (es) Modificacion enzimatica del aceite
WO2007110394A3 (de) Verfahren zur enzymatischen herstellung von 2-hydroxy-2-methylcarbonsäuren
WO2011008564A3 (en) Compositions and methods for improved saccharification of biomass
MY159420A (en) Method for the enzymatic production of 3-hydroxy-3 methylbutyric acid from acetone and acetyl coa
WO2011047372A3 (en) Integration of anaerobic digestion in an algae-based biofuel system
WO2010005391A8 (en) Biodiesel production via enzymatic hydrolysis followed by chemical/enzymatic esterification
WO2006072256A3 (en) Process for the production of fatty acid alkyl esters from triglycerides and alcohols employing mixtures of two lipolytic enzymes
Todero Ritter et al. Cellulase and xylanase production by Penicillium echinulatum in submerged media containing cellulose amended with sorbitol
CO6430476A2 (es) Producción de productos finales fermentativos de clostridium sp.
CA2797046A1 (en) Microorganisms and methods for the biosynthesis of propylene
AU2011266953A8 (en) Production of Biodiesel by yeast from lignocellulose and glycerol
ES2530763T3 (es) Procedimiento continuo de hidrólisis enzimática
WO2009060746A1 (ja) 固体酸触媒による脂肪酸モノエステル化物の製造方法
BR112013018857A2 (pt) processo para a produção dos ésteres de álcool dos ácidos graxos e composição do processo de fermentação do álcool
BR112017000931A2 (pt) preparação de ácido lático e/ou um sal de lactato de material lignocelulósico por sacarificação separada e etapas de fermentação
WO2016094877A3 (en) High solids enzymatic hydrolysis and fermentation of pretreated biomass
JP2014525261A5 (es)
WO2013188305A3 (en) Fungal beta-xylosidase variants
WO2012068310A3 (en) Compositions and methods for improved saccharification of genetically modified plant-derived biomass
Pérez-Sánchez et al. Lipase Catalyzed In Situ Production of Acetaldehyde: A Controllable and Mild Strategy for Multi-Step Reactions.
WO2010025455A3 (en) Enhancement of enzymatic hydrolysis of pre-treated biomass by added chitosan

Legal Events

Date Code Title Description
FG Grant or registration