MX346741B - Copolimero lineal soluble en agua. - Google Patents
Copolimero lineal soluble en agua.Info
- Publication number
- MX346741B MX346741B MX2014006227A MX2014006227A MX346741B MX 346741 B MX346741 B MX 346741B MX 2014006227 A MX2014006227 A MX 2014006227A MX 2014006227 A MX2014006227 A MX 2014006227A MX 346741 B MX346741 B MX 346741B
- Authority
- MX
- Mexico
- Prior art keywords
- hydrogen
- amide
- atom
- depending
- substance
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/36—Amides or imides
- C08F222/38—Amides
- C08F222/385—Monomers containing two or more (meth)acrylamide groups, e.g. N,N'-methylenebisacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/04—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonamides, polyesteramides or polyimides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Medicinal Preparation (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Materials For Medical Uses (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
La invención se relaciona a la química de substancias de alto peso molecular, más específicamente a las substancias sintéticas de alto peso molecular, la cadena de las cuales puede ser una matriz 3D hidrófila que surge debido a los enlaces de H que emergen entre grupos amida y carboxílicos de poliamidas y proporciona la posibilidad de mantener el ambiente acuoso. De acuerdo con la investigación llevada a cabo, el dímero de heterocadena lineal soluble en agua tiene la fórmula general: (-CH2CR1R2)n-(R4-NHCO-R5CONH-R4)m donde R1 puede ser un átomo de hidrógeno o alquilo CH3, R2 puede ser COOH, CONH2, -COOCH3 dependiendo de la clase de monómero de vinilo, R3 es un átomo de hidrógeno o grupo OH, dependiendo de la clase de monómero de divinilo, R4 puede ser (CH2-CHR3) o (CH2-CHR3-CH2). R5 puede ser (CH2) o (CH(OH))2, dependiendo de la clase de monómero de divinilo, m y n son interrelaciones entre monómeros de vinilo y divinilo, con esto la correlación m/n está dentro de 10 a 100, con esto las secciones de la cadena en la cual están presentes grupos amida -CO-NH-, se conectan con las secciones similares a través de enlaces de H entre los grupos amida y carboxilo. Esta substancia corresponde a polímeros de una nueva estructura con diferentes propiedades físicas-químicas. La sección de amida de la molécula es única de acuerdo con sus propiedades estructurales y de acuerdo a interacciones intermoleculares peculiares. Debido a la hibridación de los átomos de nitrógeno, carbono e hidrógeno en el grupo amina, esta sección es casi plana, Lo que es importante es que el hidrógeno, conectado con el átomo de nitrógeno y átomo de oxígeno en grupos de carbonos, sean todos capaces de crear un fuerte enlace de hidrógeno. Además en la substancia mencionada, la red reticulada del polímero no es posible de crear. Por lo tanto, la macromolécula de la substancia es una matriz 3D hidrófila, que surge a causa de enlaces de H entre los grupos amida y carboxilo de poliamida, lo que mantiene el ambiente acuoso.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
UAU201113857U UA67354U (uk) | 2011-11-24 | 2011-11-24 | Водорозчинний лінійний гетероланцюговий диполімер |
PCT/UA2012/000052 WO2013077831A1 (en) | 2011-11-24 | 2012-05-23 | Watersoluble linear copolymer |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014006227A MX2014006227A (es) | 2015-03-06 |
MX346741B true MX346741B (es) | 2017-03-29 |
Family
ID=48470146
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014006227A MX346741B (es) | 2011-11-24 | 2012-05-23 | Copolimero lineal soluble en agua. |
Country Status (16)
Country | Link |
---|---|
US (1) | US9365668B2 (es) |
EP (1) | EP2782954A1 (es) |
JP (1) | JP6266527B2 (es) |
KR (1) | KR101345191B1 (es) |
CN (1) | CN103958574B (es) |
AU (1) | AU2012341101B2 (es) |
BR (1) | BR112014012554A2 (es) |
CA (1) | CA2856497A1 (es) |
CL (1) | CL2014001368A1 (es) |
CO (1) | CO6990744A2 (es) |
CZ (1) | CZ2012316A3 (es) |
EA (1) | EA201400608A1 (es) |
IN (1) | IN2014MN01053A (es) |
MX (1) | MX346741B (es) |
UA (1) | UA67354U (es) |
WO (1) | WO2013077831A1 (es) |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4051086A (en) | 1976-03-25 | 1977-09-27 | Hercules Incorporated | Absorption rate of absorbent polymers by treating with glyoxal |
CH643569A5 (de) * | 1980-03-21 | 1984-06-15 | Isaflex Ag | Verfahren zur herstellung von wasseraustauschendem, nicht-toxischem polymermaterial auf basis acrylamid/n,n'-methylenbisacrylamid. |
HU190910B (en) * | 1983-08-16 | 1986-12-28 | Reanal Finomvegyszergyar,Hu | Method for producing glue suitable for fixing sorbent layer of pressurized one and multiple layer chromatography |
FR2616151B1 (fr) * | 1987-06-04 | 1991-06-21 | Atochem | Agent permettant de rendre compatible au moins deux polymeres thermoplastiques incompatibles, son procede de fabrication, son application a la fabrication d'alliages thermoplastiques, alliages thermoplastiques obtenus |
SE500248C2 (sv) | 1992-12-03 | 1994-05-24 | Eka Nobel Ab | Kirala adsorbenter och framställning av dessa samt föreningar på vilka adsorbenterna är baserade och framställning av dessa föreningar |
JPH06227328A (ja) | 1993-02-03 | 1994-08-16 | Oki Electric Ind Co Ltd | 自動車用電子制御装置 |
JPH0966300A (ja) * | 1995-08-31 | 1997-03-11 | Mitsui Toatsu Chem Inc | セメント含有廃泥用凝集処理剤 |
JPH11315123A (ja) * | 1998-05-01 | 1999-11-16 | Sumitomo Chem Co Ltd | 酒石酸アミド系共重合体、その製造方法および該共重合体を含有する洗剤 |
JP2000239378A (ja) | 1998-12-25 | 2000-09-05 | Mitsui Chemicals Inc | 吸水性樹脂の製造方法 |
JP4389008B2 (ja) * | 1999-11-09 | 2009-12-24 | 独立行政法人産業技術総合研究所 | 有機ゲル複合化球形無機多孔質粒子およびその製造方法 |
ES2362583T3 (es) | 2000-08-25 | 2011-07-07 | Contura A/S | Hidrogel de poliacrilamida y su uso como una endoprótesis. |
US7282551B2 (en) * | 2001-02-23 | 2007-10-16 | Ems-Chemie Ag | Thermoplastic block copolymers consisting of polyalkyl(meth)acrylate and polyamide segments and the use thereof |
CN1465405A (zh) * | 2002-06-03 | 2004-01-07 | 吉林富华医用高分子材料有限公司 | 一种医用水凝胶的制法 |
-
2011
- 2011-11-24 UA UAU201113857U patent/UA67354U/uk unknown
-
2012
- 2012-02-08 KR KR1020120012886A patent/KR101345191B1/ko not_active IP Right Cessation
- 2012-05-14 CZ CZ20120316A patent/CZ2012316A3/cs unknown
- 2012-05-23 CA CA2856497A patent/CA2856497A1/en not_active Abandoned
- 2012-05-23 AU AU2012341101A patent/AU2012341101B2/en not_active Ceased
- 2012-05-23 BR BR112014012554A patent/BR112014012554A2/pt not_active IP Right Cessation
- 2012-05-23 CN CN201280057472.XA patent/CN103958574B/zh not_active Expired - Fee Related
- 2012-05-23 EA EA201400608A patent/EA201400608A1/ru unknown
- 2012-05-23 JP JP2014543457A patent/JP6266527B2/ja not_active Expired - Fee Related
- 2012-05-23 WO PCT/UA2012/000052 patent/WO2013077831A1/en active Application Filing
- 2012-05-23 US US14/360,800 patent/US9365668B2/en not_active Expired - Fee Related
- 2012-05-23 EP EP20120730284 patent/EP2782954A1/en not_active Withdrawn
- 2012-05-23 MX MX2014006227A patent/MX346741B/es active IP Right Grant
-
2014
- 2014-05-23 CL CL2014001368A patent/CL2014001368A1/es unknown
- 2014-05-30 IN IN1053MUN2014 patent/IN2014MN01053A/en unknown
- 2014-06-24 CO CO14136083A patent/CO6990744A2/es unknown
Also Published As
Publication number | Publication date |
---|---|
CA2856497A1 (en) | 2013-05-30 |
CL2014001368A1 (es) | 2015-01-23 |
CN103958574A (zh) | 2014-07-30 |
EA201400608A1 (ru) | 2014-12-30 |
US20150038661A1 (en) | 2015-02-05 |
CN103958574B (zh) | 2016-09-28 |
CZ2012316A3 (cs) | 2013-06-19 |
KR101345191B1 (ko) | 2013-12-27 |
AU2012341101A1 (en) | 2014-06-12 |
UA67354U (uk) | 2012-02-10 |
EP2782954A1 (en) | 2014-10-01 |
US9365668B2 (en) | 2016-06-14 |
JP2014533768A (ja) | 2014-12-15 |
CO6990744A2 (es) | 2014-07-10 |
MX2014006227A (es) | 2015-03-06 |
KR20130057925A (ko) | 2013-06-03 |
IN2014MN01053A (es) | 2015-05-15 |
JP6266527B2 (ja) | 2018-01-24 |
WO2013077831A1 (en) | 2013-05-30 |
AU2012341101B2 (en) | 2016-08-25 |
BR112014012554A2 (pt) | 2017-06-06 |
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Legal Events
Date | Code | Title | Description |
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FG | Grant or registration |