MX2014006227A - Copolimero lineal soluble en agua. - Google Patents

Copolimero lineal soluble en agua.

Info

Publication number
MX2014006227A
MX2014006227A MX2014006227A MX2014006227A MX2014006227A MX 2014006227 A MX2014006227 A MX 2014006227A MX 2014006227 A MX2014006227 A MX 2014006227A MX 2014006227 A MX2014006227 A MX 2014006227A MX 2014006227 A MX2014006227 A MX 2014006227A
Authority
MX
Mexico
Prior art keywords
hydrogen
amide
atom
depending
substance
Prior art date
Application number
MX2014006227A
Other languages
English (en)
Other versions
MX346741B (es
Inventor
Liudmyla Dmytrivna Zheldak
Original Assignee
Biomatrix Internat Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Biomatrix Internat Ltd filed Critical Biomatrix Internat Ltd
Publication of MX2014006227A publication Critical patent/MX2014006227A/es
Publication of MX346741B publication Critical patent/MX346741B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56—Acrylamide; Methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/36—Amides or imides
    • C08F222/38—Amides
    • C08F222/385—Monomers containing two or more (meth)acrylamide groups, e.g. N,N'-methylenebisacrylamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a single or double bond to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/04—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polycarbonamides, polyesteramides or polyimides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Medicinal Preparation (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Materials For Medical Uses (AREA)

Abstract

La invención se relaciona a la química de substancias de alto peso molecular, más específicamente a las substancias sintéticas de alto peso molecular, la cadena de las cuales puede ser una matriz 3D hidrófila que surge debido a los enlaces de H que emergen entre grupos amida y carboxílicos de poliamidas y proporciona la posibilidad de mantener el ambiente acuoso. De acuerdo con la investigación llevada a cabo, el dímero de heterocadena lineal soluble en agua tiene la fórmula general: (-CH2CR1R2)n-(R4-NHCO-R5CONH-R4)m donde R1 puede ser un átomo de hidrógeno o alquilo CH3, R2 puede ser COOH, CONH2, -COOCH3 dependiendo de la clase de monómero de vinilo, R3 es un átomo de hidrógeno o grupo OH, dependiendo de la clase de monómero de divinilo, R4 puede ser (CH2-CHR3) o (CH2-CHR3-CH2). R5 puede ser (CH2) o (CH(OH))2, dependiendo de la clase de monómero de divinilo, m y n son interrelaciones entre monómeros de vinilo y divinilo, con esto la correlación m/n está dentro de 10 a 100, con esto las secciones de la cadena en la cual están presentes grupos amida -CO-NH-, se conectan con las secciones similares a través de enlaces de H entre los grupos amida y carboxilo. Esta substancia corresponde a polímeros de una nueva estructura con diferentes propiedades físicas-químicas. La sección de amida de la molécula es única de acuerdo con sus propiedades estructurales y de acuerdo a interacciones intermoleculares peculiares. Debido a la hibridación de los átomos de nitrógeno, carbono e hidrógeno en el grupo amina, esta sección es casi plana, Lo que es importante es que el hidrógeno, conectado con el átomo de nitrógeno y átomo de oxígeno en grupos de carbonos, sean todos capaces de crear un fuerte enlace de hidrógeno. Además en la substancia mencionada, la red reticulada del polímero no es posible de crear. Por lo tanto, la macromolécula de la substancia es una matriz 3D hidrófila, que surge a causa de enlaces de H entre los grupos amida y carboxilo de poliamida, lo que mantiene el ambiente acuoso.
MX2014006227A 2011-11-24 2012-05-23 Copolimero lineal soluble en agua. MX346741B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
UAU201113857U UA67354U (uk) 2011-11-24 2011-11-24 Водорозчинний лінійний гетероланцюговий диполімер
PCT/UA2012/000052 WO2013077831A1 (en) 2011-11-24 2012-05-23 Watersoluble linear copolymer

Publications (2)

Publication Number Publication Date
MX2014006227A true MX2014006227A (es) 2015-03-06
MX346741B MX346741B (es) 2017-03-29

Family

ID=48470146

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014006227A MX346741B (es) 2011-11-24 2012-05-23 Copolimero lineal soluble en agua.

Country Status (16)

Country Link
US (1) US9365668B2 (es)
EP (1) EP2782954A1 (es)
JP (1) JP6266527B2 (es)
KR (1) KR101345191B1 (es)
CN (1) CN103958574B (es)
AU (1) AU2012341101B2 (es)
BR (1) BR112014012554A2 (es)
CA (1) CA2856497A1 (es)
CL (1) CL2014001368A1 (es)
CO (1) CO6990744A2 (es)
CZ (1) CZ2012316A3 (es)
EA (1) EA201400608A1 (es)
IN (1) IN2014MN01053A (es)
MX (1) MX346741B (es)
UA (1) UA67354U (es)
WO (1) WO2013077831A1 (es)

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4051086A (en) 1976-03-25 1977-09-27 Hercules Incorporated Absorption rate of absorbent polymers by treating with glyoxal
CH643569A5 (de) * 1980-03-21 1984-06-15 Isaflex Ag Verfahren zur herstellung von wasseraustauschendem, nicht-toxischem polymermaterial auf basis acrylamid/n,n'-methylenbisacrylamid.
HU190910B (en) * 1983-08-16 1986-12-28 Reanal Finomvegyszergyar,Hu Method for producing glue suitable for fixing sorbent layer of pressurized one and multiple layer chromatography
FR2616151B1 (fr) * 1987-06-04 1991-06-21 Atochem Agent permettant de rendre compatible au moins deux polymeres thermoplastiques incompatibles, son procede de fabrication, son application a la fabrication d'alliages thermoplastiques, alliages thermoplastiques obtenus
SE9203646L (sv) 1992-12-03 1994-05-24 Eka Nobel Ab Kirala adsorbenter och framställning av dessa samt föreningar på vilka adsorbenterna är baserade och framställning av dessa föreningar
JPH06227328A (ja) 1993-02-03 1994-08-16 Oki Electric Ind Co Ltd 自動車用電子制御装置
JPH0966300A (ja) * 1995-08-31 1997-03-11 Mitsui Toatsu Chem Inc セメント含有廃泥用凝集処理剤
JPH11315123A (ja) * 1998-05-01 1999-11-16 Sumitomo Chem Co Ltd 酒石酸アミド系共重合体、その製造方法および該共重合体を含有する洗剤
JP2000239378A (ja) 1998-12-25 2000-09-05 Mitsui Chemicals Inc 吸水性樹脂の製造方法
JP4389008B2 (ja) * 1999-11-09 2009-12-24 独立行政法人産業技術総合研究所 有機ゲル複合化球形無機多孔質粒子およびその製造方法
EP1564230B1 (en) 2000-08-25 2011-03-09 Contura A/S Polyacrylamide hydrogel and its use as an endoprosthesis
CN1243041C (zh) * 2001-02-23 2006-02-22 Ems化学股份有限公司 由聚(甲基)丙烯酸烷基酯链段和聚酰胺链段构成的热塑性嵌段共聚物和其用途
CN1465405A (zh) * 2002-06-03 2004-01-07 吉林富华医用高分子材料有限公司 一种医用水凝胶的制法

Also Published As

Publication number Publication date
CN103958574A (zh) 2014-07-30
KR20130057925A (ko) 2013-06-03
MX346741B (es) 2017-03-29
EA201400608A1 (ru) 2014-12-30
BR112014012554A2 (pt) 2017-06-06
UA67354U (uk) 2012-02-10
KR101345191B1 (ko) 2013-12-27
CO6990744A2 (es) 2014-07-10
US20150038661A1 (en) 2015-02-05
CZ2012316A3 (cs) 2013-06-19
EP2782954A1 (en) 2014-10-01
JP6266527B2 (ja) 2018-01-24
WO2013077831A1 (en) 2013-05-30
AU2012341101A1 (en) 2014-06-12
IN2014MN01053A (es) 2015-05-15
US9365668B2 (en) 2016-06-14
JP2014533768A (ja) 2014-12-15
CA2856497A1 (en) 2013-05-30
CL2014001368A1 (es) 2015-01-23
CN103958574B (zh) 2016-09-28
AU2012341101B2 (en) 2016-08-25

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