MX340293B - Polietileno bimodal para aplicaciones de moldeo por inyeccion-soplado y estirado. - Google Patents

Polietileno bimodal para aplicaciones de moldeo por inyeccion-soplado y estirado.

Info

Publication number
MX340293B
MX340293B MX2012005361A MX2012005361A MX340293B MX 340293 B MX340293 B MX 340293B MX 2012005361 A MX2012005361 A MX 2012005361A MX 2012005361 A MX2012005361 A MX 2012005361A MX 340293 B MX340293 B MX 340293B
Authority
MX
Mexico
Prior art keywords
stretch blow
blow moulding
injection stretch
bimodal polyethylene
moulding applications
Prior art date
Application number
MX2012005361A
Other languages
English (en)
Other versions
MX2012005361A (es
Inventor
Aurélien Vantomme
Jean-Marie Boissiere
Pierre Belloir
Sinoy Alain Van
Original Assignee
Total Petrochemicals Res Feluy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP10156984A external-priority patent/EP2366722A1/en
Application filed by Total Petrochemicals Res Feluy filed Critical Total Petrochemicals Res Feluy
Publication of MX2012005361A publication Critical patent/MX2012005361A/es
Publication of MX340293B publication Critical patent/MX340293B/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/0005Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/02Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • B65D1/0207Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/40Details of walls
    • B65D1/42Reinforcing or strengthening parts or members
    • B65D1/44Corrugations
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/0715Preforms or parisons characterised by their configuration the preform having one end closed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/06Injection blow-moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2501/00Containers having bodies formed in one piece
    • B65D2501/0009Bottles or similar containers with necks or like restricted apertures designed for pouring contents
    • B65D2501/0018Ribs
    • B65D2501/0036Hollow circonferential ribs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/05Bimodal or multimodal molecular weight distribution
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/07High density, i.e. > 0.95 g/cm3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/13Environmental stress cracking resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1397Single layer [continuous layer]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)

Abstract

Una resina de polietileno que presenta una distribución de peso molecular multimodal que comprende al menos dos fracciones de polietileno A y B, estando la fracción A considerablemente libre de comonómero y presentando un peso molecular medio expresado en peso menor y una densidad mayor que la fracción B, cada una de las fracciones preparada en reactores diferentes de dos reactores conectados en serie en presencia de un sistema de catalizador de Ziegler-Natta, presentando la resina de polietileno una densidad de 0,950 a 0,965 g/cm3 y un índice de fusión MI2 de 0,5 a 5 g/10 min.
MX2012005361A 2009-11-10 2010-11-03 Polietileno bimodal para aplicaciones de moldeo por inyeccion-soplado y estirado. MX340293B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09175544 2009-11-10
EP10156984A EP2366722A1 (en) 2010-03-19 2010-03-19 Bimodal polyethylene for injection stretch blow moulding applications.
PCT/EP2010/066703 WO2011057924A1 (en) 2009-11-10 2010-11-03 Bimodal polyethylene for injection stretch blow moulding applications

Publications (2)

Publication Number Publication Date
MX2012005361A MX2012005361A (es) 2012-06-13
MX340293B true MX340293B (es) 2016-07-04

Family

ID=43218503

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012005361A MX340293B (es) 2009-11-10 2010-11-03 Polietileno bimodal para aplicaciones de moldeo por inyeccion-soplado y estirado.

Country Status (11)

Country Link
US (2) US9610723B2 (es)
EP (1) EP2464675B1 (es)
KR (1) KR20120093277A (es)
CN (1) CN102686618B (es)
BR (1) BR112012010847A2 (es)
DK (1) DK2464675T3 (es)
EA (1) EA021841B1 (es)
ES (1) ES2603054T3 (es)
MX (1) MX340293B (es)
PT (1) PT2464675T (es)
WO (1) WO2011057924A1 (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112014007199A2 (pt) 2011-09-30 2017-04-04 Total Res & Technology Feluy polietileno de alta densidade para tampas e fechamentos
JP6175501B2 (ja) * 2012-08-31 2017-08-02 ソシエテ アノニム デ ゾ ミネラル デヴィアン エ オン ナブレジェ“エス.ア.ウ.エム.ウ” ボトルの製造方法
JP6473284B2 (ja) * 2012-11-28 2019-02-20 株式会社吉野工業所 ボトル
WO2014125105A1 (en) * 2013-02-18 2014-08-21 Ineos Europe Ag Composition for injection stretch blow-moulding
BR112016002478A2 (pt) * 2013-08-12 2017-08-01 Total Res & Technology Feluy polietileno para aplicações de moldagem por injeção com estiramento e sopro
EP2878623B1 (en) 2013-11-28 2018-07-11 Abu Dhabi Polymers Company Limited (Borouge) Multimodal polymer
US9505161B2 (en) * 2014-04-10 2016-11-29 Fina Technology, Inc. Solid-state stretched HDPE
US9624321B2 (en) * 2014-06-13 2017-04-18 Fina Technology, Inc. Formation of a Ziegler-Natta catalyst
RU2685268C2 (ru) * 2014-06-16 2019-04-17 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Способы модификации отношения текучестей расплава и/или набухания полиэтиленовых смол
WO2017001474A1 (en) * 2015-06-30 2017-01-05 Borealis Ag Process for preparing propylene polymer compositions
US11577443B2 (en) 2016-03-11 2023-02-14 Polyplastics USA, Inc Injection stretch blow-molding (ISBM) enhancement for semi-crystalline polyolefin containers utilizing alicyclic polyolefins
WO2019096745A1 (en) * 2017-11-17 2019-05-23 Total Research & Technology Feluy Polyethylene resin and caps or closures made therefrom
EP3749707A1 (en) 2018-02-05 2020-12-16 ExxonMobil Chemical Patents Inc. Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
JP6696547B2 (ja) * 2018-10-05 2020-05-20 サンスター株式会社 液体用容器
EP3887410A1 (en) * 2018-11-28 2021-10-06 Abu Dhabi Polymers Co. Ltd (Borouge) L.L.C. Polyethylene composition for film applications
CN112745408B (zh) * 2019-10-29 2022-10-21 中国石油化工股份有限公司 用于挤出吹塑小中空制品的双峰聚乙烯树脂及其制备方法和应用

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EP0151741A3 (en) 1983-12-13 1985-09-25 MITSUI TOATSU CHEMICALS, Inc. Injection stretch-blow molded container and resin composition therefor
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
JP2940684B2 (ja) 1989-12-29 1999-08-25 三井化学株式会社 オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法
DE69329313T3 (de) 1992-06-17 2008-07-31 Mitsui Chemicals, Inc. Ethylencopolymerzusammensetzung
EP0725722B1 (en) 1993-10-27 1997-07-23 BEKUM Maschinenfabriken GmbH Method of forming molecularly oriented preforms
JP3543466B2 (ja) 1996-01-22 2004-07-14 三井化学株式会社 二軸延伸ブロー成形品およびその製造方法
US6930071B2 (en) * 1997-01-28 2005-08-16 Fina Technology, Inc. Ziegler-natta catalyst for polyolefins
JP2000086722A (ja) 1998-09-16 2000-03-28 Asahi Chem Ind Co Ltd 射出延伸ブロー成形用高密度ポリエチレン樹脂
JP2000086833A (ja) 1998-09-17 2000-03-28 Asahi Chem Ind Co Ltd 射出延伸ブロー成形用高密度ポリエチレン樹脂組成物
EP0989140A1 (en) * 1998-09-25 2000-03-29 Fina Research S.A. Production of multimodal polyethylene
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JP2003253062A (ja) * 2001-12-26 2003-09-10 Asahi Kasei Corp ポリエチレン組成物
EP1495861A1 (en) 2003-07-10 2005-01-12 Total Petrochemicals Research Feluy High transparency, high impact resistance containers
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JP5016258B2 (ja) 2005-05-23 2012-09-05 日本ポリエチレン株式会社 ポリエチレン樹脂・その製造方法並びにその樹脂を用いたパイプおよび継手
ATE416465T1 (de) * 2005-06-30 2008-12-15 Borealis Tech Oy Überzug-schicht für energie- oder kommunikationskabel
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Also Published As

Publication number Publication date
BR112012010847A2 (pt) 2016-04-05
CN102686618B (zh) 2014-12-24
US9610723B2 (en) 2017-04-04
US20170348891A1 (en) 2017-12-07
US20120282422A1 (en) 2012-11-08
EP2464675B1 (en) 2016-08-17
ES2603054T3 (es) 2017-02-23
DK2464675T3 (en) 2016-12-12
PT2464675T (pt) 2016-11-16
CN102686618A (zh) 2012-09-19
WO2011057924A1 (en) 2011-05-19
US10016923B2 (en) 2018-07-10
MX2012005361A (es) 2012-06-13
EA201270613A1 (ru) 2012-10-30
KR20120093277A (ko) 2012-08-22
EA021841B1 (ru) 2015-09-30
EP2464675A1 (en) 2012-06-20

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