MX338317B - Control mejorado sobre los procesos controlados de polimerizacion por radicales. - Google Patents

Control mejorado sobre los procesos controlados de polimerizacion por radicales.

Info

Publication number
MX338317B
MX338317B MX2013006381A MX2013006381A MX338317B MX 338317 B MX338317 B MX 338317B MX 2013006381 A MX2013006381 A MX 2013006381A MX 2013006381 A MX2013006381 A MX 2013006381A MX 338317 B MX338317 B MX 338317B
Authority
MX
Mexico
Prior art keywords
polymerization processes
radical polymerization
control over
controlled radical
improved control
Prior art date
Application number
MX2013006381A
Other languages
English (en)
Other versions
MX2013006381A (es
Inventor
James Spanswick
Wojciech Jakubowski
Original Assignee
Atrp Solutions Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atrp Solutions Inc filed Critical Atrp Solutions Inc
Publication of MX2013006381A publication Critical patent/MX2013006381A/es
Publication of MX338317B publication Critical patent/MX338317B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02—Monomers containing only one unsaturated aliphatic radical
    • C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06—Hydrocarbons
    • C08F112/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/10—Esters
    • C08F120/12—Esters of monohydric alcohols or phenols
    • C08F120/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/10—Esters
    • C08F120/12—Esters of monohydric alcohols or phenols
    • C08F120/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F120/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/04—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Se describe un procedimiento para mejorar el control de la temperatura en los procesos controlados de polimerización por radicales. El procedimiento se dirige a regular la concentración del radical persistente en procedimientos de polimerizaciones ATRP (polimerización radicálica de transferencia de átomos) y NMP (polimerización mediada por nitróxidos) y la concentración de los radicales en un proceso de polimerización RAFT (polimerización de transferencia de cadena por adición/fragmentación reversible) alimentando en forma continua o intermitente un agente reductor o precursor de radicales al medio de reacción a través de uno o más portales.
MX2013006381A 2010-12-08 2011-12-07 Control mejorado sobre los procesos controlados de polimerizacion por radicales. MX338317B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/926,780 US8822610B2 (en) 2008-12-22 2010-12-08 Control over controlled radical polymerization processes
PCT/US2011/063673 WO2012078716A1 (en) 2010-12-08 2011-12-07 Improved control over controlled radical polymerization processes

Publications (2)

Publication Number Publication Date
MX2013006381A MX2013006381A (es) 2013-12-09
MX338317B true MX338317B (es) 2016-04-12

Family

ID=46207492

Family Applications (3)

Application Number Title Priority Date Filing Date
MX2016004042A MX382739B (es) 2010-12-08 2011-12-07 Control mejorado sobre los procesos controlados de polimerización por radicales.
MX2015014373A MX384267B (es) 2010-12-08 2011-12-07 Control mejorado sobre los procesos controlados de polimerizacion por radicales.
MX2013006381A MX338317B (es) 2010-12-08 2011-12-07 Control mejorado sobre los procesos controlados de polimerizacion por radicales.

Family Applications Before (2)

Application Number Title Priority Date Filing Date
MX2016004042A MX382739B (es) 2010-12-08 2011-12-07 Control mejorado sobre los procesos controlados de polimerización por radicales.
MX2015014373A MX384267B (es) 2010-12-08 2011-12-07 Control mejorado sobre los procesos controlados de polimerizacion por radicales.

Country Status (7)

Country Link
US (5) US8822610B2 (es)
EP (1) EP2649105A4 (es)
JP (3) JP6235341B2 (es)
CN (2) CN103354815B (es)
CA (2) CA2820052C (es)
MX (3) MX382739B (es)
WO (1) WO2012078716A1 (es)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8815971B2 (en) 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8822610B2 (en) * 2008-12-22 2014-09-02 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US9783628B2 (en) 2009-04-23 2017-10-10 ATRP Solutions, Inc. Dual-mechanism thickening agents for hydraulic fracturing fluids
US8569421B2 (en) 2009-04-23 2013-10-29 ATRP Solutions, Inc. Star macromolecules for personal and home care
WO2011075185A1 (en) 2009-12-18 2011-06-23 Oligasis Targeted drug phosphorylcholine polymer conjugates
US9587064B2 (en) 2010-12-08 2017-03-07 ATRP Solutions, Inc. Salt-tolerant star macromolecules
US9033159B1 (en) * 2011-06-07 2015-05-19 Clemson University Membrane surface modification
EP2634198B1 (en) * 2012-03-02 2014-09-17 Suntech Co., Ltd. Copolymers containing phosphorylcholine groups and methods of preparing and using the same
EP2890760A4 (en) 2012-08-30 2016-10-12 Atrp Solutions Inc DOUBLE MECHANISM THICKENERS FOR HYDRAULIC FRACKING FLUIDS
EP2951220B1 (en) 2013-02-04 2020-11-25 Pilot Polymer Technologies, Inc. Salt-tolerant star macromolecules
WO2015035342A2 (en) 2013-09-08 2015-03-12 Oligasis Llc Factor viii zwitterionic polymer conjugates
US10336848B2 (en) 2014-07-03 2019-07-02 Pilot Polymer Technologies, Inc. Surfactant-compatible star macromolecules
CN106749907A (zh) * 2016-11-25 2017-05-31 合众（佛山）化工有限公司 一种atrp技术合成的嵌段聚合物分散剂
CN106674426A (zh) * 2016-12-30 2017-05-17 合众（佛山）化工有限公司 一种基于atrp聚合的温敏型水凝胶
CN108864385B (zh) * 2018-05-29 2020-08-04 上海交通大学 一种含精准修饰位点聚合物刷的制备方法
US20210130580A1 (en) 2018-08-09 2021-05-06 Mitsui Chemicals, Inc. Polymerization initiator, curable composition, dental material, and preparation kit for curable composition
CN110606902B (zh) * 2019-07-29 2021-08-24 长兴电子（苏州）有限公司 一种新型大分子光引发剂及其合成方法
EP4041312A4 (en) 2019-10-10 2023-12-20 Kodiak Sciences Inc. METHOD FOR TREATING AN EYE DISORDER
JP7680441B2 (ja) 2019-10-16 2025-05-20 ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング 超高度制御ラジカル重合
US11814458B2 (en) 2020-12-18 2023-11-14 Baker Hughes Oilfield Operations Llc Drag reducing agent and process of manufacture thereof
US12168702B2 (en) 2020-12-18 2024-12-17 Baker Hughes Oilfield Operations Llc Radical polymerization in sealed containers
KR20250134613A (ko) 2023-01-19 2025-09-11 제이에스알 가부시키가이샤 중합체의 제조 방법, 중합체 제조 장치 및 라디칼 중합 반응의 최적화 시스템
CN119930892A (zh) * 2025-02-27 2025-05-06 华东理工大学 一种用于高频高速覆铜板的自增韧碳氢共聚物及其制备方法

Family Cites Families (183)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3058909A (en) 1957-07-23 1962-10-16 Atlantic Refining Co Method and composition for formation fracturing
NL298888A (es) * 1962-10-08
US4409120A (en) 1981-12-21 1983-10-11 Shell Oil Company Process for forming oil-soluble product
US4386135A (en) 1982-01-11 1983-05-31 Minnesota Mining And Manufacturing Company Stable silicone-coated release liner for pressure-sensitive adhesive sheets
US5100953A (en) 1986-03-28 1992-03-31 Exxon Research And Engineering Company Solutions of hydrophobically associating terpolymers containing sulfonate functionality
US4847328A (en) 1986-08-29 1989-07-11 E. I. Du Pont De Nemours And Company Hybrid acrylic star polymers
MY106342A (en) 1989-05-02 1995-05-30 Colgate Palmolive Co Antistatic compositions, antistatic detergent compositions and articles
FR2649400B1 (fr) 1989-07-10 1993-01-08 Norsolor Sa Copolymeres en etoile et leur procede de fabrication
US5032647A (en) 1989-09-29 1991-07-16 E. I. Du Pont De Nemours And Company Process for making hybrid acrylic star polymers with polysiloxane cores
US5240963A (en) 1990-01-19 1993-08-31 Nova Pharmaceutical Corporation Branched polyanhydrides
US5310807A (en) 1992-12-30 1994-05-10 E. I. Du Pont De Nemours And Company Star polymers made from macromonomers made by cobalt chain transfer process
JPH0753630A (ja) 1993-06-30 1995-02-28 Shell Internatl Res Maatschappij Bv 末端に水酸基を有する液状スターポリマー
JP3220331B2 (ja) 1993-07-20 2001-10-22 エチコン・インコーポレーテツド 非経口投与用の吸収性液体コポリマー類
US5393841A (en) 1993-11-09 1995-02-28 Shell Oil Company Dissimilar arm asymmetric radial or star block copolymers for adhesives and sealants
CN1120180C (zh) 1994-06-03 2003-09-03 巴斯福股份公司 聚合物水分散液的制备
US5545504A (en) 1994-10-03 1996-08-13 Xerox Corporation Ink jettable toner compositions and processes for making and using
US5486563A (en) 1994-12-20 1996-01-23 Shell Oil Company Process for making dispersant viscosity index improvers
US5612107A (en) 1995-02-24 1997-03-18 Avery Dennison Corporation Mottle prevention film or coating
US6541580B1 (en) 1995-03-31 2003-04-01 Carnegie Mellon University Atom or group transfer radical polymerization
US5763548A (en) 1995-03-31 1998-06-09 Carnegie-Mellon University (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization
US5728469A (en) 1995-06-06 1998-03-17 Avery Dennison Corporation Block copolymer release surface for pressure sensitive adhesives
AU6824996A (en) 1995-08-17 1997-03-12 Dyer, Alison Margaret Controlled release products
US5807937A (en) 1995-11-15 1998-09-15 Carnegie Mellon University Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties
US5789487A (en) 1996-07-10 1998-08-04 Carnegie-Mellon University Preparation of novel homo- and copolymers using atom transfer radical polymerization
US6984491B2 (en) 1996-07-29 2006-01-10 Nanosphere, Inc. Nanoparticles having oligonucleotides attached thereto and uses therefor
US6253302B1 (en) * 1996-08-29 2001-06-26 Intel Corporation Method and apparatus for supporting multiple overlapping address spaces on a shared bus
US5783657A (en) 1996-10-18 1998-07-21 Union Camp Corporation Ester-terminated polyamides of polymerized fatty acids useful in formulating transparent gels in low polarity liquids
US7125938B2 (en) 1997-03-11 2006-10-24 Carnegie Mellon University Atom or group transfer radical polymerization
US6071980A (en) * 1997-08-27 2000-06-06 E. I. Du Pont De Nemours And Company Atom transfer radical polymerization
US6103361A (en) 1997-09-08 2000-08-15 E. I. Du Pont De Nemours And Company Patterned release finish
AU752802C (en) 1997-11-14 2006-04-13 Pacira Pharmaceuticals, Inc. Production of multivesicular liposomes
US6121371A (en) 1998-07-31 2000-09-19 Carnegie Mellon University Application of atom transfer radical polymerization to water-borne polymerization systems
US5933695A (en) 1998-08-03 1999-08-03 Xerox Corporation Rapid wake up fuser system members with silicone layer
US6252014B1 (en) 1998-08-04 2001-06-26 Colorado School Of Mines Star polymers and polymeric particles in the nanometer-sized range by step growth reactions
US6127445A (en) 1998-11-03 2000-10-03 The University Of Georgia Research Foundation, Inc. Substituted benzoylferrocene anionic photoinitiators
US6410666B1 (en) * 1999-03-18 2002-06-25 California Institute Of Technology ABA triblock and diblock copolymers and methods of preparing the same
US7030194B1 (en) 1999-04-02 2006-04-18 Kaneka Corporation Method of treating polymer
DE19930729A1 (de) 1999-07-05 2001-01-11 Achim Goepferich Blockcopolymere zur Herstellung biomimetischer Oberflächen
US7049373B2 (en) 1999-08-06 2006-05-23 Carnegie Mellon University Process for preparation of graft polymers
US6210524B1 (en) 1999-09-03 2001-04-03 Avery Dennison Corporation Method of improving peel-plate dispensability of label constructions
US7807211B2 (en) 1999-09-03 2010-10-05 Advanced Cardiovascular Systems, Inc. Thermal treatment of an implantable medical device
CA2321321A1 (en) 1999-09-30 2001-03-30 Isotis B.V. Polymers loaded with bioactive agents
US6461631B1 (en) 1999-11-16 2002-10-08 Atrix Laboratories, Inc. Biodegradable polymer composition
US6336966B1 (en) 1999-12-16 2002-01-08 Ppg Industries Ohio, Inc. Pigment dispersions containing dispersants having core and arm star architecture prepared by controlled radical polymerization
US6476079B1 (en) 1999-12-23 2002-11-05 Leiras Oy Devices for the delivery of drugs having antiprogestinic properties
US6596899B1 (en) 2000-02-16 2003-07-22 Noveon Ip Holdings Corp. S,S′BIS-(α, α′-DISUBSTITUTED-α″-ACETIC ACID)- TRITHIOCARBONATES AND DERIVATIVES AS INITIATOR-CHAIN TRANSFER AGENT-TERMINATOR FOR CONTROLLED RADICAL POLYMERIZATIONS AND THE PROCESS FOR MAKING THE SAME
US6465091B1 (en) 2000-03-27 2002-10-15 3M Innovative Properties Company Release article and adhesive article containing a polymeric release material
US6455623B1 (en) 2000-05-31 2002-09-24 Sunrise Medical Hhg Inc. Freeze-resistant fluid compositions
US20040023987A1 (en) 2000-06-14 2004-02-05 Yoshio Hata Sustained release compositions
AU2001274511A1 (en) 2000-06-19 2002-01-02 Bridgestone Corporation Adsorbent, process for producing the same, and applications thereof
US6750148B2 (en) * 2000-07-07 2004-06-15 Dainippon Printing Co., Ltd. Method of manufacturing wireless suspension blank
FI20001696L (fi) 2000-07-21 2002-01-22 Jvs Polymers Oy Biologisesti aktiivinen materiaali
US6558805B2 (en) 2000-10-05 2003-05-06 The Goodyear Tire & Rubber Company Functionalized rubbery polymer containing polysiloxane
WO2002028912A2 (en) 2000-10-06 2002-04-11 Carnegie Mellon University Preparation of nanocomposite structures by controlled polymerization
SE517421C2 (sv) 2000-10-06 2002-06-04 Bioglan Ab Mikropartiklar, lämpade för parenteral administration, väsentligen bestående av stärkelse med minst 85 % amylopektin och med reducerad molekylvikt, samt framställning därav
EP1337563B1 (en) 2000-10-06 2006-12-20 Carnegie-Mellon University Polymerization process for ionic monomers
AU2001296670A1 (en) 2000-10-06 2002-04-15 Carnegie-Mellon University A catalyst system for controlled polymerization
EP1205492A1 (en) * 2000-11-08 2002-05-15 ETHZ, Laboratorium für Technische Chemie LTC Process for producing homo- and co-polymers by RAFT miniemulsion polymerization
WO2002064193A2 (en) 2000-12-14 2002-08-22 Georgia Tech Research Corporation Microneedle devices and production thereof
US20020155309A1 (en) 2001-02-21 2002-10-24 Zhixin Li Mold release and anti-blocking coating for powder-free natural or synthetic rubber articles
ATE470647T1 (de) 2001-04-06 2010-06-15 Univ Carnegie Mellon Verfahren zur herstellung von nanostrukturierten materialien
JP4758607B2 (ja) 2001-06-22 2011-08-31 ジョンズ ホプキンズ ユニヴァーシティー スクール オブ メディシン 生分解性ポリマー組成物、及びその使用方法
US20030003127A1 (en) 2001-06-27 2003-01-02 Ethicon, Inc. Porous ceramic/porous polymer layered scaffolds for the repair and regeneration of tissue
US6626950B2 (en) 2001-06-28 2003-09-30 Ethicon, Inc. Composite scaffold with post anchor for the repair and regeneration of tissue
GB0117768D0 (en) 2001-07-20 2001-09-12 Unilever Plc Use of polymers in fabrics cleaning
DE10145529A1 (de) 2001-09-14 2003-04-03 Creavis Tech & Innovation Gmbh Biozide Retardierungsformulierungen
US6555237B1 (en) 2001-09-20 2003-04-29 Nexpress Solutions Llc Fuser system with donor roller having a controlled swell release agent surface layer
US7105181B2 (en) 2001-10-05 2006-09-12 Jagotec, Ag Microparticles
US7064166B2 (en) 2001-10-12 2006-06-20 Carnegie Mellon University Process for monomer sequence control in polymerizations
WO2003031481A2 (en) * 2001-10-12 2003-04-17 Carnegie Mellon University Simultaneous reverse and normal initiation of atrp
US20030091630A1 (en) 2001-10-25 2003-05-15 Jenny Louie-Helm Formulation of an erodible, gastric retentive oral dosage form using in vitro disintegration test data
US20030152622A1 (en) 2001-10-25 2003-08-14 Jenny Louie-Helm Formulation of an erodible, gastric retentive oral diuretic
US20030104052A1 (en) 2001-10-25 2003-06-05 Bret Berner Gastric retentive oral dosage form with restricted drug release in the lower gastrointestinal tract
CA2409552A1 (en) 2001-10-25 2003-04-25 Depomed, Inc. Gastric retentive oral dosage form with restricted drug release in the lower gastrointestinal tract
US20040068078A1 (en) 2001-12-12 2004-04-08 Milbocker Michael T. In situ polymerizing medical compositions
US6764731B2 (en) 2002-01-22 2004-07-20 National Starch And Chemical Investment Holding Corporation Process for the preparation of a rubber article having an outer polymer-coated surface and an inner chlorinated surface
US20030158344A1 (en) 2002-02-08 2003-08-21 Rodriques Klein A. Hydrophobe-amine graft copolymer
US20030158076A1 (en) 2002-02-08 2003-08-21 Rodrigues Klein A. Amide polymers for use in surface protecting formulations
US6939505B2 (en) 2002-03-12 2005-09-06 Massachusetts Institute Of Technology Methods for forming articles having very small channels therethrough, and such articles, and methods of using such articles
US20030220254A1 (en) 2002-03-29 2003-11-27 Texas Tech University System Composition and method for preparation of an oral dual controlled release formulation of a protein and inhibitor
US20030203000A1 (en) 2002-04-24 2003-10-30 Schwarz Marlene C. Modulation of therapeutic agent release from a polymeric carrier using solvent-based techniques
US20030236513A1 (en) 2002-06-19 2003-12-25 Scimed Life Systems, Inc. Implantable or insertable medical devices for controlled delivery of a therapeutic agent
US7939094B2 (en) 2002-06-19 2011-05-10 Boston Scientific Scimed, Inc. Multiphase polymeric drug release region
US8211455B2 (en) 2002-06-19 2012-07-03 Boston Scientific Scimed, Inc. Implantable or insertable medical devices for controlled delivery of a therapeutic agent
US7105175B2 (en) 2002-06-19 2006-09-12 Boston Scientific Scimed, Inc. Implantable or insertable medical devices for controlled delivery of a therapeutic agent
US7235261B2 (en) 2002-06-27 2007-06-26 Haarmann & Reimer Corporation Controlled release encapsulation
AU2003276847A1 (en) 2002-08-09 2004-02-25 Carnegie Mellon University Polymers, supersoft elastomers and methods for preparing the same
SE0202619D0 (sv) 2002-09-05 2002-09-05 Fredrik Nederberg New Polymers and Applications
DE60331860D1 (en) 2002-12-30 2010-05-06 Nektar Therapeutics Mehrarmige polypeptid-poly(ethylenglykol)-blockcopolymere als arzneistoffzufuhrvehikel
US6919405B2 (en) 2002-12-31 2005-07-19 3M Innovative Properties Company Release compositions and articles made therefrom
CN1298747C (zh) 2003-02-25 2007-02-07 日本静冈大学 聚合物的制造方法
US8313759B2 (en) 2003-03-06 2012-11-20 Boston Scientific Scimed, Inc. Implantable or insertable medical devices containing miscible polymer blends for controlled delivery of a therapeutic agent
EP1622540A4 (en) 2003-03-11 2009-12-30 Qlt Usa Inc PREPARATIONS OF ANTI-CANCER AGENTS DEPENDENT ON THE CELLULAR PROGRAM
US7241455B2 (en) 2003-04-08 2007-07-10 Boston Scientific Scimed, Inc. Implantable or insertable medical devices containing radiation-crosslinked polymer for controlled delivery of a therapeutic agent
US7132485B2 (en) * 2003-04-14 2006-11-07 Akzo Nobel N.V. Dosing of peroxide to a suspension process wherein styrene is polymerized
US20040234571A1 (en) 2003-05-22 2004-11-25 Jang Bor Z. Direct injection of nano fibers and nano fiber composites for biomedical applications
MXPA05013952A (es) 2003-06-20 2006-02-24 Akzo Nobel Nv Procedimiento de polimerizacion que involucra la dosificacion de iniciadores.
US7906148B2 (en) 2003-07-31 2011-03-15 Boston Scientific Scimed, Inc. Latex medical articles for release of antimicrobial agents
US7914805B2 (en) 2003-07-31 2011-03-29 Boston Scientific Scimed, Inc. Implantable or insertable medical devices containing radiation-treated polymer for improved delivery of therapeutic agent
US20060018951A1 (en) 2003-08-08 2006-01-26 Sri International pH-responsive film for intravaginal delivery of a beneficial agent
US20050064011A1 (en) 2003-08-11 2005-03-24 Young-Ho Song Implantable or insertable medical devices containing phenolic compound for inhibition of restenosis
KR100453273B1 (ko) 2003-09-04 2004-10-15 주식회사 펩트론 초음파 이중공급노즐을 이용한 서방성 미립구의 제조 방법
US20050238594A1 (en) * 2003-09-15 2005-10-27 Nathalie Mougin Block ethylenic copolymers comprising a vinyllactam block, cosmetic or pharmaceutical compositions comprising them and cosmetic use of these copolymers
JP2005113086A (ja) 2003-10-10 2005-04-28 Nitto Denko Corp ポリマー合成方法およびこれを用いた装置
US20060188486A1 (en) 2003-10-14 2006-08-24 Medivas, Llc Wound care polymer compositions and methods for use thereof
US7838605B2 (en) * 2003-10-17 2010-11-23 Univation Technologies, Llc Polymerization monitoring and control using improved leading indicators
WO2005041884A2 (en) 2003-10-31 2005-05-12 Engineered Release Systems, Inc Polymer-based microstructures
MY158342A (en) 2003-11-14 2016-09-30 Novartis Ag Pharmaceutical composition
US7323529B2 (en) 2003-11-26 2008-01-29 Pp6 Industries Ohio, Inc. Method of making copolymers containing olefinic type monomers
US20050181015A1 (en) 2004-02-12 2005-08-18 Sheng-Ping (Samuel) Zhong Layered silicate nanoparticles for controlled delivery of therapeutic agents from medical articles
US7537781B2 (en) 2004-02-12 2009-05-26 Boston Scientific Scimed, Inc. Polymer-filler composites for controlled delivery of therapeutic agents from medical articles
JP5171248B2 (ja) 2004-03-05 2013-03-27 カーネギー−メロン ユニバーシティ 原子移動ラジカル重合法
US8061533B2 (en) 2004-03-19 2011-11-22 University Of Tennessee Research Foundation Materials comprising polydienes and hydrophilic polymers and related methods
US9498563B2 (en) 2004-04-23 2016-11-22 Boston Scientific Scimed, Inc. Medical articles having therapeutic-agent-containing regions formed from coalesced polymer particles
US20050244640A1 (en) 2004-05-03 2005-11-03 Martin Riswick Polymer coating for powder-free elastic strands
WO2005112587A2 (en) 2004-05-12 2005-12-01 Medivas, Llc Wound healing polymer compositions and methods for use thereof
FR2870245B1 (fr) 2004-05-14 2008-08-22 Rhodia Chimie Sa Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee
JP2006002032A (ja) * 2004-06-17 2006-01-05 Nitto Denko Corp ポリマー製造方法およびその装置
US7713539B2 (en) 2004-07-19 2010-05-11 Boston Scientific Scimed, Inc. Medical devices containing radiation resistant block copolymer
DE102004059243A1 (de) 2004-08-10 2006-02-23 Basf Ag Thermoplastische Formmassen mit verbesserten Fließ- und Entformungseigenschaften
US20060051390A1 (en) 2004-09-03 2006-03-09 Schwarz Marlene C Medical devices having self-forming rate-controlling barrier for drug release
US7592021B2 (en) 2004-10-02 2009-09-22 Sri International Bioadhesive delivery system for transmucosal delivery of beneficial agents
JP4323406B2 (ja) 2004-10-04 2009-09-02 住友化学株式会社 連続重合装置およびそれを用いた連続重合方法
US8313763B2 (en) 2004-10-04 2012-11-20 Tolmar Therapeutics, Inc. Sustained delivery formulations of rapamycin compounds
US20060210604A1 (en) 2004-10-04 2006-09-21 Eric Dadey Ocular delivery of polymeric delivery formulations
CN101035823B (zh) 2004-10-08 2012-07-04 弗门尼舍有限公司 两亲星型嵌段共聚物
WO2006044716A2 (en) 2004-10-15 2006-04-27 Washington University In St.Louis CELL PERMEABLE NANOCONJUGATES OF SHELL-CROSSLINKED KNEDEL (SCK) AND PEPTIDE NUCLEIC ACIDS ('PNAs') WITH UNIQUELY EXPRESSED OR OVER-EXPRESSED mRNA TARGETING SEQUENCES FOR EARLY DIAGNOSIS AND THERAPY OF CANCER
CN101087823B (zh) 2004-10-25 2010-08-18 卢布里佐尔公司 星形聚合物及其组合物
WO2006053175A2 (en) 2004-11-10 2006-05-18 Qlt Usa Inc. A stabilized polymeric delivery system
US7964209B2 (en) 2004-12-07 2011-06-21 Boston Scientific Scimed, Inc. Orienting polymer domains for controlled drug delivery
CA2590696A1 (en) 2004-12-15 2006-06-22 Qlt Usa, Inc. Sustained delivery formulations of octreotide compounds
WO2006065991A2 (en) 2004-12-17 2006-06-22 Dr. Reddy's Laboratories Ltd. Dispersion for delivering active agents
US7884056B2 (en) 2004-12-21 2011-02-08 Rhodia Chimie Composition that can form a gel comprising a copolymer, and useful copolymers
US7919110B2 (en) 2005-01-25 2011-04-05 Boston Scientific Scimed, Inc. Medical device drug release regions containing non-covalently bound polymers
US7517914B2 (en) 2005-04-04 2009-04-14 Boston Scientificscimed, Inc. Controlled degradation materials for therapeutic agent delivery
EP1877099B1 (en) 2005-04-06 2012-09-19 Genzyme Corporation Therapeutic conjugates comprising a lysosomal enzyme, polysialic acid and a targeting moiety
ATE532540T1 (de) 2005-05-04 2011-11-15 Suprapolix Bv Modulare bioresorbierbare oder biomedizinische biologisch aktive supramolekulare stoffe
DE102005028383A1 (de) 2005-06-20 2006-12-28 Wella Aktiengesellschaft Produktabgabesystem zum Versprühen Polymere enthaltender haarkosmetischer Zusammensetzungen
US20090098079A1 (en) 2005-06-20 2009-04-16 The Procter & Gamble Company Product release system for atomizing cosmetic hair compositions containing cationic polymers
BRPI0612594A2 (pt) 2005-06-29 2010-11-23 Panacea Biotec Ltd composições farmacêuticas de liberação modificada e processo de pereparação das mesmas
US8722074B2 (en) 2005-07-19 2014-05-13 Boston Scientific Scimed, Inc. Medical devices containing radiation resistant polymers
US7559358B2 (en) 2005-08-03 2009-07-14 Baker Hughes Incorporated Downhole uses of electroactive polymers
CN101356197B (zh) 2005-08-23 2016-02-17 卡内基梅隆大学 在微乳液中的原子转移自由基聚合和真实的乳液聚合
US7893173B2 (en) * 2005-08-26 2011-02-22 Carnegie Mellon University Polymerization process with catalyst reactivation
US8357759B2 (en) * 2005-08-26 2013-01-22 CID Centro de Investigación y Desarrollo Tecnológico S.A. de C.V. Reactive block copolymers
DE102005041528A1 (de) 2005-08-31 2007-03-01 Rohmax Additives Gmbh Öllösliche Polymere
FR2894971B1 (fr) 2005-12-20 2008-05-16 Rhodia Recherches & Tech Composition pour le traitement et/ou la modification de surfaces dures, comprenant un polymere synthetique
WO2007075817A1 (en) 2005-12-21 2007-07-05 Carnegie Mellon University Preparation of block copolymers
JP5819579B2 (ja) 2006-01-13 2015-11-24 サーモディクス，インコーポレイティド 薬物送達のためのマトリックスを含む微粒子
US20070219330A1 (en) * 2006-01-17 2007-09-20 Haddleton David M Amide initiators
US7612029B2 (en) 2006-04-11 2009-11-03 The Clorox Company Controlled release using gels in a melamine foam
CN104762124A (zh) 2006-04-24 2015-07-08 路博润公司 星形聚合物润滑组合物
EP3106506A1 (en) 2006-04-24 2016-12-21 The Lubrizol Corporation Star polymer lubricating composition
US20070281031A1 (en) 2006-06-01 2007-12-06 Guohan Yang Microparticles and methods for production thereof
GB0614623D0 (en) * 2006-07-21 2006-08-30 Univ Nottingham Process for conducting dispersion polymerisations controlled by raft agents in supercritical fluids
WO2008127435A2 (en) 2006-11-27 2008-10-23 Microactive Corp. Controlled gas release from a melt processable compatible polymer blend
GB0624729D0 (en) 2006-12-12 2007-01-17 Univ Leeds Reversible micelles and applications for their use
US8507422B2 (en) 2007-04-26 2013-08-13 The Lubrizol Corporation Antiwear polymer and lubricating composition thereof
US7833577B2 (en) 2007-05-11 2010-11-16 3M Innovative Properties Company Methods of making a pressure-sensitive adhesive assembly
US8334037B2 (en) 2007-05-11 2012-12-18 3M Innovative Properties Company Multi-layer assembly, multi-layer stretch releasing pressure-sensitive adhesive assembly, and methods of making and using the same
US8168213B2 (en) 2007-05-15 2012-05-01 Boston Scientific Scimed, Inc. Medical devices having coating with improved adhesion
WO2009018092A1 (en) 2007-07-27 2009-02-05 The Board Of Trustees Of The Leland Stanford Junior University Supramolecular functionalization of graphitic nanoparticles for drug delivery
JP2010539265A (ja) 2007-09-12 2010-12-16 コンストラクション リサーチ アンド テクノロジー ゲーエムベーハー シラン変性コポリマーの製造方法
US8277832B2 (en) 2007-10-10 2012-10-02 The University Of Kansas Microsphere-based materials with predefined 3D spatial and temporal control of biomaterials, porosity and/or bioactive signals
TW200927141A (en) 2007-11-22 2009-07-01 Bayer Schering Pharma Oy Vaginal delivery system
FR2924714A1 (fr) * 2007-12-07 2009-06-12 Arkema France Procede de preparation d'une dispersion aqueuse de particules de polymeres par un procede de polymerisation radicalaire en dispersion, dispersions obtenues et revetements prepares avec celles-ci.
US20090181094A1 (en) 2008-01-15 2009-07-16 Eric Yueh-Lang Sheu Molecular Cage for Sustained Release Control of Pharmaceutical and Cosmetic Agents
CN102099382B (zh) 2008-06-18 2014-01-29 汉高公司 用于受控自由基聚合的装置和方法
US8562669B2 (en) 2008-06-26 2013-10-22 Abbott Cardiovascular Systems Inc. Methods of application of coatings composed of hydrophobic, high glass transition polymers with tunable drug release rates
US20100086597A1 (en) 2008-10-06 2010-04-08 Oakwood Laboratories LLC Microspheres for the sustained release of octreotide with a low initial burst
US20100092535A1 (en) 2008-10-10 2010-04-15 Medtronic Vascular, Inc. Nanoporous Drug Delivery System
US8822610B2 (en) * 2008-12-22 2014-09-02 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8815971B2 (en) * 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
CN102361889B (zh) * 2009-01-23 2014-09-17 联邦科学与工业研究组织 Raft聚合
US8962764B2 (en) 2009-03-27 2015-02-24 Carnegie Mellon University Preparation of functional star macromolecules
US8569421B2 (en) 2009-04-23 2013-10-29 ATRP Solutions, Inc. Star macromolecules for personal and home care
WO2010123575A1 (en) 2009-04-23 2010-10-28 Atrp Solutions Inc Well defined stars with segmented arms
US8173750B2 (en) 2009-04-23 2012-05-08 ATRP Solutions, Inc. Star macromolecules for personal and home care
JP5419081B2 (ja) * 2009-08-07 2014-02-19 旭化成ケミカルズ株式会社 熱可塑性複合材料
CN101717479B (zh) * 2009-11-24 2011-08-03 武汉理工大学 一种两亲性梯度共聚物
US8765098B2 (en) 2010-03-30 2014-07-01 International Business Machines Corporation Star polymers, methods of preparation thereof, and uses thereof
EP2604633B1 (en) 2010-08-10 2015-07-08 Kaneka Corporation Manufacturing method of (meth) acrylic polymer
WO2012061147A1 (en) 2010-10-25 2012-05-10 Isp Investments Inc. Salt-tolerant, thermally-stable rheology modifiers

Also Published As

Publication number Publication date
JP6235341B2 (ja) 2017-11-22
US11390696B2 (en) 2022-07-19
CN103354815A (zh) 2013-10-16
JP2019163480A (ja) 2019-09-26
MX382739B (es) 2025-03-13
JP6800827B2 (ja) 2020-12-16
CN103354815B (zh) 2017-04-19
EP2649105A4 (en) 2015-09-09
US8822610B2 (en) 2014-09-02
WO2012078716A1 (en) 2012-06-14
CA3086903C (en) 2022-11-22
CA2820052C (en) 2020-08-25
US20190352435A1 (en) 2019-11-21
EP2649105A1 (en) 2013-10-16
US20110213105A1 (en) 2011-09-01
US20150191552A1 (en) 2015-07-09
CN107245119A (zh) 2017-10-13
MX2013006381A (es) 2013-12-09
US20140357814A1 (en) 2014-12-04
US20180237551A1 (en) 2018-08-23
JP2014502645A (ja) 2014-02-03
US9856331B2 (en) 2018-01-02
US9546225B2 (en) 2017-01-17
MX384267B (es) 2025-03-14
JP2018048340A (ja) 2018-03-29
CA3086903A1 (en) 2012-06-14
CA2820052A1 (en) 2012-06-14

Similar Documents

Publication Publication Date Title
MX338317B (es) Control mejorado sobre los procesos controlados de polimerizacion por radicales.
MX2012007079A (es) Control mejorado sobre procesos controlados de polimerizacion de radicales.
NZ732411A (en) Plasma activated water
WO2018109553A3 (en) Sequential infiltration synthesis apparatus
TW200940752A (en) Sheet production apparatus, sheet production method, and production formed using the same
WO2011102924A3 (en) Process for activating chromium catalyst by two step thermal treatment
EP2591813A3 (en) Hydrophilic medical devices
WO2009155303A3 (en) Apparatus and methods for controlled radical polymerization
WO2012125275A3 (en) Apparatus for monitoring and controlling substrate temperature
PH12014500111A1 (en) Localized disinfection system for large water bodies
MX2014005781A (es) Metodo para la polimerizacion de polipropileno.
SI2655269T1 (sl) Postopek in naprava za obdelavo vode z nitriranjem in denitriranjem, ki obsega vsaj en prezračevalni korak in vsaj en korak preverjanja dodatka kisika med prezračevanjem
WO2012099817A3 (en) Method and system for providing ultrapure water
WO2012129420A3 (en) Chlorine dioxide precursor and methods of using same
PH12014502878A1 (en) Apparatus and method for biological sewage treatment
JP2012072475A5 (es)
WO2014105872A3 (en) Deposition systems and methods
IN2012DN06593A (es)
WO2013040602A3 (en) Waste water treatment using multi-staged oxidation reactor
WO2008136260A1 (ja) Ｔｉ膜の成膜方法
IN2012DN06565A (es)
AU2012297573A8 (en) Method for the recovery of magnesium sulphate and production of magnesium oxide
JP2011155044A5 (es)
GB201318430D0 (en) Methods and apparatus to control reaction rates of chemical reactions by applying a magnetic field
PH12011000340A1 (en) Apparatus and method for surface treatment in a furnace

Legal Events

Date Code Title Description
FG Grant or registration