MX338159B - Polioles de polieter de oxido de etileno/oxido de propileno y poliuretanos elaborados de los mismos. - Google Patents
Polioles de polieter de oxido de etileno/oxido de propileno y poliuretanos elaborados de los mismos.Info
- Publication number
- MX338159B MX338159B MX2013002152A MX2013002152A MX338159B MX 338159 B MX338159 B MX 338159B MX 2013002152 A MX2013002152 A MX 2013002152A MX 2013002152 A MX2013002152 A MX 2013002152A MX 338159 B MX338159 B MX 338159B
- Authority
- MX
- Mexico
- Prior art keywords
- polyether polyols
- made therefrom
- ethylene oxide
- propylene oxide
- polyurethanes made
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
- C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
- C08G65/2624—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups containing aliphatic amine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4845—Polyethers containing oxyethylene units and other oxyalkylene units containing oxypropylene or higher oxyalkylene end groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
Abstract
Se describen copolímeros de óxido de propileno y óxido de etileno que tienen un bloque interno que contiene del 65 al 90% en peso de unidades de oxietileno y del 10 al 35 en peso de unidades de oxipropileno. El bloque tiene un peso molecular de 150 a 350. El copolímero tiene un bloque externo el cual contiene al menos el 95% en peso de unidades de oxipropileno y de 0 a 5% unidades de oxietileno. El peso equivalente del copolímero es de 800 a 2000. Los copolímeros son útiles para elaborar espumas de poliuretano que tienen resistencias a la tensión y/o desgarre inesperadamente altas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US37664810P | 2010-08-24 | 2010-08-24 | |
PCT/US2011/047339 WO2012027113A1 (en) | 2010-08-24 | 2011-08-11 | Ethylene oxide/propylene oxide polyether polyols and polyurethanes made therefrom |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2013002152A MX2013002152A (es) | 2013-04-03 |
MX338159B true MX338159B (es) | 2016-04-05 |
Family
ID=44533166
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2013002152A MX338159B (es) | 2010-08-24 | 2011-08-11 | Polioles de polieter de oxido de etileno/oxido de propileno y poliuretanos elaborados de los mismos. |
Country Status (10)
Country | Link |
---|---|
US (2) | US9156936B2 (es) |
EP (1) | EP2609134B1 (es) |
JP (1) | JP5933551B2 (es) |
KR (1) | KR101797265B1 (es) |
CN (1) | CN103168065B (es) |
AU (1) | AU2011293802B2 (es) |
BR (1) | BR112013004058B1 (es) |
ES (1) | ES2525591T3 (es) |
MX (1) | MX338159B (es) |
WO (1) | WO2012027113A1 (es) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101987870B1 (ko) * | 2014-04-11 | 2019-06-11 | 제이에프이 엔지니어링 가부시키가이샤 | 온도-감응성 흡수제, 수처리방법, 및 수처리장치 |
PL3268406T3 (pl) * | 2015-03-12 | 2019-10-31 | Huntsmann Advanced Mat Licensing Switzerland Gmbh | Poliolowy składnik do produkcji pianek pur |
AR104981A1 (es) * | 2015-06-20 | 2017-08-30 | Dow Global Technologies Llc | Proceso continuo para producir polioles de poliéter que tienen un elevado contenido de óxido de etileno polimerizado, mediante el uso de un complejo catalizador de cianuro de metal doble y un compuesto metálico de la serie de lantanida o metal del grupo 3 - grupo 15, magnesio |
BR112017028016B1 (pt) * | 2015-06-30 | 2022-02-22 | Dow Global Technologies Llc | Polímero aleatório de poli(óxido de propileno-co-óxido de etileno), método para produzir uma espuma de poliuretano e processo para a preparação de um poliéter poliol |
US20170081491A1 (en) | 2015-09-18 | 2017-03-23 | Arkema Inc. | Polyol pre-mixes having improved shelf life |
BR112018006165B1 (pt) * | 2015-09-29 | 2022-01-18 | Basf Se | Espuma de poliuretano de alta resiliência, e, método para formar uma espuma de poliuretano de alta resiliência |
US11124595B2 (en) * | 2017-01-17 | 2021-09-21 | Dow Global Technologies Llc | Polyol blends useful for producing viscoelastic foam |
US11584822B2 (en) | 2018-06-05 | 2023-02-21 | Dow Global Technologies Llc | Polyurethane-polyisocyanurate foam |
MX2021004833A (es) * | 2018-10-30 | 2021-09-10 | Dow Global Technologies Llc | Produccion de hidroxietilpiperazina. |
JP7433313B2 (ja) * | 2018-12-13 | 2024-02-19 | ダウ グローバル テクノロジーズ エルエルシー | 洗浄ブースタ |
AU2020338477A1 (en) * | 2019-08-28 | 2022-01-06 | Indorama Ventures Oxides Australia Pty Limited | Agents for use in hydrometallurgical process streams |
CN113527616B (zh) * | 2021-06-21 | 2023-01-06 | 佳化化学科技发展(上海)有限公司 | 一种聚氨酯普通软泡及其制备方法 |
US20230049261A1 (en) * | 2021-07-28 | 2023-02-16 | Momentive Performance Materials Inc. | Flexible foams comprising additives for improving hardness |
PL440663A1 (pl) * | 2022-03-17 | 2023-09-18 | Pcc Rokita Spółka Akcyjna | Proces otrzymywania oksyalkilatów w reaktorze obiegowym |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3164149D1 (en) * | 1980-07-21 | 1984-07-19 | Mobay Chemical Corp | Process for the production of elastomeric moulded products |
US4487854A (en) * | 1983-12-27 | 1984-12-11 | Basf Wyandotte Corporation | Polyoxyalkylene polyether polyols and polyurethane foams prepared therefrom |
US4521572A (en) * | 1984-02-22 | 1985-06-04 | Texaco Inc. | Epoxy resin modified polyether polyols from mixed initiators |
DE3740634A1 (de) * | 1987-12-01 | 1989-06-15 | Bayer Ag | Polyetherpolyole auf basis o-toluylendiamin, verfahren zu ihrer herstellung und verwendung fuer polyurethan- und polyisocyanurat-kunststoffe |
DE58905978D1 (de) | 1989-02-06 | 1993-11-25 | Vickers Systems Gmbh | Elektrohydraulisches Antriebssystem. |
US5137934A (en) * | 1989-09-29 | 1992-08-11 | The Dow Chemical Company | Alkylene oxide adducts and polyurethane foams prepared therefrom |
US5122548A (en) | 1990-03-23 | 1992-06-16 | The Dow Chemical Company | Elastomeric polyisocyanate-based polymers from polyoxyalkylene polyols containing internal polyoxyethylene blocks |
DE4014923A1 (de) * | 1990-05-10 | 1991-11-14 | Basf Ag | Verfahren zur herstellung von urethan- oder urethan- und isocyanuratgruppen enthaltenden hartschaumstoffen nach dem polyisocyanat-polyadditionsverfahren und die hierfuer geeigneten polyoxyalkylen-polyole |
US5648019A (en) * | 1995-11-01 | 1997-07-15 | Basf Corporation | Three component polyol blend for use in insulating rigid polyurethane foams |
JPH10147638A (ja) * | 1996-11-19 | 1998-06-02 | Kao Corp | グリセロール変性含フッ素ポリエーテル及びその製造方法 |
DE19928156A1 (de) * | 1999-06-19 | 2000-12-28 | Bayer Ag | Aus Polyetherpolyolen hergestellte Polyurethan-Weichschäume |
DE19944762A1 (de) | 1999-09-17 | 2001-03-22 | Basf Ag | Verfahren zur Herstellung von Blockweichschaumpolyolen |
JP4927552B2 (ja) * | 2003-11-03 | 2012-05-09 | ダウ グローバル テクノロジーズ エルエルシー | トルエンジアミン開始ポリオールをベースにする硬質ポリウレタンフォーム |
KR100933761B1 (ko) * | 2007-11-16 | 2009-12-23 | 경상대학교산학협력단 | (에틸렌옥시드-프로필렌옥시드)랜덤공중합단위 및프로필렌옥시드 중합단위가 연속하여 결합되는블록공중합체 |
-
2011
- 2011-08-11 BR BR112013004058-0A patent/BR112013004058B1/pt active IP Right Grant
- 2011-08-11 US US13/812,501 patent/US9156936B2/en active Active
- 2011-08-11 WO PCT/US2011/047339 patent/WO2012027113A1/en active Application Filing
- 2011-08-11 MX MX2013002152A patent/MX338159B/es active IP Right Grant
- 2011-08-11 JP JP2013525945A patent/JP5933551B2/ja active Active
- 2011-08-11 CN CN201180050232.2A patent/CN103168065B/zh active Active
- 2011-08-11 AU AU2011293802A patent/AU2011293802B2/en active Active
- 2011-08-11 ES ES11749635.6T patent/ES2525591T3/es active Active
- 2011-08-11 KR KR1020137007130A patent/KR101797265B1/ko active IP Right Grant
- 2011-08-11 EP EP11749635.6A patent/EP2609134B1/en active Active
-
2015
- 2015-09-09 US US14/849,538 patent/US9725559B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
ES2525591T3 (es) | 2014-12-26 |
AU2011293802B2 (en) | 2014-03-27 |
US9156936B2 (en) | 2015-10-13 |
MX2013002152A (es) | 2013-04-03 |
US20150376332A1 (en) | 2015-12-31 |
US9725559B2 (en) | 2017-08-08 |
AU2011293802A1 (en) | 2013-02-28 |
BR112013004058B1 (pt) | 2020-06-30 |
JP5933551B2 (ja) | 2016-06-15 |
EP2609134A1 (en) | 2013-07-03 |
US20130143977A1 (en) | 2013-06-06 |
CN103168065B (zh) | 2016-08-10 |
BR112013004058A2 (pt) | 2016-07-05 |
CN103168065A (zh) | 2013-06-19 |
WO2012027113A1 (en) | 2012-03-01 |
EP2609134B1 (en) | 2014-09-24 |
KR101797265B1 (ko) | 2017-11-13 |
KR20130102053A (ko) | 2013-09-16 |
JP2013536296A (ja) | 2013-09-19 |
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