MX2019011788A - Proceso para preparar 2-exo-(2-metilbenciloxi)-1-metil-4-isopropil -7-oxabiciclo[2.2.1]heptano. - Google Patents

Proceso para preparar 2-exo-(2-metilbenciloxi)-1-metil-4-isopropil -7-oxabiciclo[2.2.1]heptano.

Info

Publication number
MX2019011788A
MX2019011788A MX2019011788A MX2019011788A MX2019011788A MX 2019011788 A MX2019011788 A MX 2019011788A MX 2019011788 A MX2019011788 A MX 2019011788A MX 2019011788 A MX2019011788 A MX 2019011788A MX 2019011788 A MX2019011788 A MX 2019011788A
Authority
MX
Mexico
Prior art keywords
exo
methyl
methylbenzyloxy
oxabicyclo
heptane
Prior art date
Application number
MX2019011788A
Other languages
English (en)
Inventor
Rack Michael
Wolf Bernd
Goetz Roland
BENSON Stefan
Alznauer Christiane
Original Assignee
Basf Agro Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Agro Bv filed Critical Basf Agro Bv
Publication of MX2019011788A publication Critical patent/MX2019011788A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para preparar (±)-2-exo-(2-metilbenciloxi)-1-metil-4-isopropil-7-oxabiciclo[2.2 .1]heptano de la Fórmula (I) (ver Fórmula) cualquiera de sus enantiómeros individuales o cualquier mezcla no racémica de estos, que comprende la etapa de hacer reaccionar (±)-2-exo-hidroxi-1-metil-4-isopropil-7-oxabiciclo[2.2.1]heptano de la Fórmula (II) (ver Fórmula) cualquiera de sus enantiómeros individuales o cualquier mezcla no racémica de estos, con un compuesto de 2-metilbencilo de la Fórmula (lII) (ver Fórmula) en donde X es un grupo saliente, en presencia de al menos una base, al menos un catalizador seleccionado de sales de rubidio, sales de cesio, y cualquier combinación de estos, y al menos un solvente orgánico inerte S1.
MX2019011788A 2017-03-31 2018-03-23 Proceso para preparar 2-exo-(2-metilbenciloxi)-1-metil-4-isopropil -7-oxabiciclo[2.2.1]heptano. MX2019011788A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17164278 2017-03-31
PCT/EP2018/057397 WO2018177907A1 (en) 2017-03-31 2018-03-23 Process for preparing 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane

Publications (1)

Publication Number Publication Date
MX2019011788A true MX2019011788A (es) 2019-11-18

Family

ID=58464418

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019011788A MX2019011788A (es) 2017-03-31 2018-03-23 Proceso para preparar 2-exo-(2-metilbenciloxi)-1-metil-4-isopropil -7-oxabiciclo[2.2.1]heptano.

Country Status (17)

Country Link
US (1) US11384093B2 (es)
EP (1) EP3601295B1 (es)
JP (1) JP7144437B2 (es)
KR (1) KR102537044B1 (es)
CN (1) CN110446716A (es)
AR (1) AR111318A1 (es)
AU (1) AU2018241503B2 (es)
BR (1) BR112019017805B1 (es)
CL (1) CL2019002795A1 (es)
DK (1) DK3601295T3 (es)
ES (1) ES2881789T3 (es)
IL (1) IL269269B (es)
MX (1) MX2019011788A (es)
MY (1) MY192335A (es)
PL (1) PL3601295T3 (es)
SI (1) SI3601295T1 (es)
WO (1) WO2018177907A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11358922B2 (en) 2017-11-02 2022-06-14 Basf Se Process for preparing 4-chlorobenzyl propargyl ether
WO2019115347A1 (en) 2017-12-15 2019-06-20 BASF Agro B.V. Process for preparing 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA829035B (en) * 1981-12-16 1983-09-28 Shell Res Ltd Oxabicycloalkane herbicides
US4670041A (en) 1981-12-16 1987-06-02 E. I. Du Pont De Nemours And Company Oxabicycloalkane herbicides
US4487945A (en) 1981-12-16 1984-12-11 Shell Oil Company Preparation of 2-exo-Hydroxy-7-oxabicyclo[2.2.1]heptanes
US4542244A (en) 1982-09-13 1985-09-17 Shell Oil Company Oxabicycloalkane herbicides
CN101602770B (zh) 2009-07-06 2011-05-11 福建森美达生物科技有限公司 一种除草剂的制备方法
KR101684640B1 (ko) * 2015-02-23 2016-12-07 한국과학기술연구원 글리세롤을 이용한 글리시돌의 제조방법 및 이에 따라 제조된 글리시돌
DK3294720T3 (da) 2015-05-08 2021-02-15 Basf Agro Bv Fremgangsmåde til fremstilling af terpinolenepoxid
DK3294700T3 (da) 2015-05-08 2020-04-14 Basf Agro Bv Fremgangsmåde til fremstilling af limonen-4-ol
BR112018015336B1 (pt) 2016-02-26 2022-04-12 BASF Agro B.V. Processo de preparação de terpineno-4-ol e uso de um éster de ácido carboxílico como um solvente
WO2017144337A1 (en) 2016-02-26 2017-08-31 BASF Agro B.V. Process for preparing a mixture of terpene alcohols
KR20190017926A (ko) 2016-06-15 2019-02-20 바스프 아그로 비.브이. 사치환된 알켄의 에폭시화 방법
EP3472138B1 (en) 2016-06-15 2020-08-26 BASF Agro B.V. Process for the epoxidation of a tetrasubstituted alkene
SI3515918T1 (sl) 2016-09-19 2021-11-30 BASF Agro B.V. Postopek za pripravo 2-ekso-(2-metilbenziloksi)-1-metil-4-izopropil-7- oksabiciklo(2.2.1)heptana
US10875873B2 (en) 2017-02-15 2020-12-29 BASF Agro B.V. Process for preparing 2-exo-(2-methylbenzyloxy)-1-methyl-4-isopropyl-7-oxabicyclo[2.2.1]heptane

Also Published As

Publication number Publication date
AU2018241503B2 (en) 2021-12-16
CN110446716A (zh) 2019-11-12
BR112019017805A2 (pt) 2020-03-31
AU2018241503A1 (en) 2019-09-26
US20200031842A1 (en) 2020-01-30
MY192335A (en) 2022-08-17
EP3601295B1 (en) 2021-05-12
DK3601295T3 (da) 2021-08-02
ES2881789T3 (es) 2021-11-30
PL3601295T3 (pl) 2021-11-22
CL2019002795A1 (es) 2019-12-27
US11384093B2 (en) 2022-07-12
KR102537044B1 (ko) 2023-05-26
BR112019017805B1 (pt) 2023-02-14
SI3601295T1 (sl) 2021-11-30
EP3601295A1 (en) 2020-02-05
IL269269A (en) 2019-11-28
IL269269B (en) 2022-03-01
KR20190136002A (ko) 2019-12-09
JP2020515597A (ja) 2020-05-28
JP7144437B2 (ja) 2022-09-29
WO2018177907A1 (en) 2018-10-04
AR111318A1 (es) 2019-06-26

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