MX2019004949A - Composición de resina epoxi de curado rápido para productos semiterminados de matriz de fibra. - Google Patents

Composición de resina epoxi de curado rápido para productos semiterminados de matriz de fibra.

Info

Publication number
MX2019004949A
MX2019004949A MX2019004949A MX2019004949A MX2019004949A MX 2019004949 A MX2019004949 A MX 2019004949A MX 2019004949 A MX2019004949 A MX 2019004949A MX 2019004949 A MX2019004949 A MX 2019004949A MX 2019004949 A MX2019004949 A MX 2019004949A
Authority
MX
Mexico
Prior art keywords
composition
matrix
fiber
epoxy
smc
Prior art date
Application number
MX2019004949A
Other languages
English (en)
Inventor
Gehringer Lionel
Henningsen Michael
Yu Miran
Zwecker Joachim
Original Assignee
Reichhold As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reichhold As filed Critical Reichhold As
Publication of MX2019004949A publication Critical patent/MX2019004949A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/24Di-epoxy compounds carbocyclic
    • C08G59/245Di-epoxy compounds carbocyclic aromatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014Nitrogen containing compounds
    • C08G59/4021Ureas; Thioureas; Guanidines; Dicyandiamides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5006Amines aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5046Amines heterocyclic
    • C08G59/5053Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/5073Amines heterocyclic containing only nitrogen as a heteroatom having two nitrogen atoms in the ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/56Amines together with other curing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/245Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using natural fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C08J2363/02Polyglycidyl ethers of bis-phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La presente invencion se refiere a una composicion de resina epoxi como componentede la matriz para los compuestos para moldeo en laminas (SMC) y/o compuestos para moldeo en masa (BMC), que comprende un componente de resina que comprende al menos una resina epoxi y un componente endurecedor que comprende al menos un compuesto aminoalquilimidazol, al menos un compuesto diazabicicloalquileno y al menos un endurecedor latente. En dicha composicion de resina epoxi, la cantidad de los compuestos de aminoalquilimidazol usados esta en el intervalo desde 0.007 hasta 0.025 mol por mol de grupos epoxi de la composicion total. La invencion se refiere tambien a una composicion de producto semiterminado de matriz de fibra (composicion SMC o composicion BMC) con, como componente de la matriz, la composicion de resina epoxi mencionada, y con fibras de refuerzo cortas, suspendidas en el mismo, con una longitud media de 0.3 a 5.0 cm. La composicion del producto semiterminado de matriz de fibra puede ser producido a traves de la mezcla de los constituyentes, con lo cual se espesa la composicion. El producto espesado resultante (producto semiterminado de matriz de fibra semisolido) incluye un tiempo comparativamente corto de maduracion y un tiempo de funcionamiento comparativamente largo disponible. La invencion tambien se refiere al compuesto de matriz de fibra semisólido correspondiente, en particular al SMC semisolido y al producto semiterminado de matriz de fibra curado correspondiente, en particular el SMC curado.
MX2019004949A 2016-10-28 2017-10-24 Composición de resina epoxi de curado rápido para productos semiterminados de matriz de fibra. MX2019004949A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16196273 2016-10-28
PCT/EP2017/077082 WO2018077836A1 (en) 2016-10-28 2017-10-24 Rapid curing epoxy-resin composition for fiber-matrix semifinished products

Publications (1)

Publication Number Publication Date
MX2019004949A true MX2019004949A (es) 2019-09-26

Family

ID=57218743

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019004949A MX2019004949A (es) 2016-10-28 2017-10-24 Composición de resina epoxi de curado rápido para productos semiterminados de matriz de fibra.

Country Status (13)

Country Link
US (1) US20200056001A1 (es)
EP (1) EP3532526B1 (es)
JP (1) JP7053643B2 (es)
KR (1) KR102561493B1 (es)
CN (1) CN110234675B (es)
AU (1) AU2017349047B2 (es)
BR (1) BR112019008703B1 (es)
CA (1) CA3041925A1 (es)
DK (1) DK3532526T3 (es)
ES (1) ES2830751T3 (es)
MX (1) MX2019004949A (es)
MY (1) MY189465A (es)
WO (1) WO2018077836A1 (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018216643A1 (ja) * 2017-05-24 2018-11-29 東レ株式会社 繊維強化複合材料用エポキシ樹脂組成物、および繊維強化複合材料

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0625144B2 (ja) * 1986-02-24 1994-04-06 四国化成工業株式会社 新規イミダゾール化合物及び該化合物の合成方法
DE3762348D1 (de) * 1986-05-07 1990-05-23 Ciba Geigy Ag Glasfaserverstaerkte epoxidharzformmasse und deren verwendung.
JPH04117434A (ja) * 1990-09-07 1992-04-17 Sumitomo Bakelite Co Ltd 積層板の製造方法
JPH0578445A (ja) * 1991-09-25 1993-03-30 Sumitomo Chem Co Ltd エポキシ樹脂組成物
JPH06166742A (ja) * 1992-12-02 1994-06-14 Sumitomo Chem Co Ltd エポキシ樹脂組成物
JPH09241603A (ja) * 1996-03-06 1997-09-16 Sumitomo Bakelite Co Ltd 液晶表示素子用シール材組成物及びそれを用いた液晶表示素子
JPH09255802A (ja) * 1996-03-25 1997-09-30 Sumitomo Bakelite Co Ltd 積層板用プリプレグ
ZA9710293B (en) 1996-11-18 1998-06-10 Shell Int Research Epoxy resin composition suitable for sheet moulding.
GB2462996B (en) 2005-07-19 2011-10-12 Hexcel Composites Ltd A moulding material
ES2303769B1 (es) 2006-09-29 2009-07-06 Galega De Impermeabilizacion Y Revestimientos Especiales, S.A. Formulaciones de resinas epoxi para preimpregnados almacenables y adhesivos estructurales de grado de pegajosidad variable.
JP2012077426A (ja) * 2010-10-06 2012-04-19 Daicel Corp 繊維強化樹脂複合材料
CN102337007B (zh) 2011-07-01 2013-04-10 蓝星(北京)化工机械有限公司 Smc高性能环氧树脂组合物
CN104136483B (zh) * 2012-02-22 2016-08-24 巴斯夫欧洲公司 用于复合材料的共混物
JP2014167102A (ja) 2013-01-29 2014-09-11 Toray Ind Inc エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
EP2803687A1 (de) * 2013-05-13 2014-11-19 Basf Se Epoxidharzzusammensetzung für Faser-Matrix-Halbzeuge
US9546243B2 (en) * 2013-07-17 2017-01-17 Air Products And Chemicals, Inc. Amines and polymeric phenols and usage thereof as curing agents in one component epoxy resin compositions

Also Published As

Publication number Publication date
EP3532526B1 (en) 2020-08-12
ES2830751T3 (es) 2021-06-04
JP2019535886A (ja) 2019-12-12
EP3532526A1 (en) 2019-09-04
US20200056001A1 (en) 2020-02-20
AU2017349047A1 (en) 2019-05-16
JP7053643B2 (ja) 2022-04-12
WO2018077836A1 (en) 2018-05-03
BR112019008703A2 (pt) 2019-07-16
MY189465A (en) 2022-02-15
BR112019008703B1 (pt) 2022-10-04
DK3532526T3 (da) 2020-10-12
CN110234675A (zh) 2019-09-13
CN110234675B (zh) 2022-03-22
KR20190112260A (ko) 2019-10-04
CA3041925A1 (en) 2018-05-03
KR102561493B1 (ko) 2023-08-01
AU2017349047B2 (en) 2022-05-12

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